SK13572000A3 - Spôsob výroby čírych polyuretán/močovinových elastomérov - Google Patents

Spôsob výroby čírych polyuretán/močovinových elastomérov Download PDF

Info

Publication number: SK13572000A3
Authority: SK; Slovakia
Prior art keywords: prepolymer; nco; mixture; polyol; elastomer
Prior art date: 1998-03-16

Application number

SK1357-2000A

Other languages

English (en)

Slovak (sk)

Inventor

Stephen Seneker

Chin-Chang Shen

Original Assignee

Bayer Antwerpen N. V.

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-03-16

Filing date

1999-03-11

Publication date

2001-02-12

1999-03-11 Application filed by Bayer Antwerpen N. V. filed Critical Bayer Antwerpen N. V.

2001-02-12 Publication of SK13572000A3 publication Critical patent/SK13572000A3/sk

Links

229920001971 elastomer Polymers 0.000 title claims abstract description 116
239000000806 elastomer Substances 0.000 title claims abstract description 116
238000000034 method Methods 0.000 title claims abstract description 78
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims description 21
239000004814 polyurethane Substances 0.000 title claims description 20
229920002635 polyurethane Polymers 0.000 title claims description 20
239000004202 carbamide Substances 0.000 title claims description 19
239000000203 mixture Substances 0.000 claims abstract description 109
229920005862 polyol Polymers 0.000 claims abstract description 105
150000003077 polyols Chemical class 0.000 claims abstract description 104
150000004984 aromatic diamines Chemical class 0.000 claims abstract description 31
NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical class CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 92
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 39
150000002009 diols Chemical class 0.000 claims description 27
239000004721 Polyphenylene oxide Substances 0.000 claims description 25
229920000570 polyether Polymers 0.000 claims description 25
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical class CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 20
238000004519 manufacturing process Methods 0.000 claims description 10
HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 4
FJWZMLSQLCKKGV-UHFFFAOYSA-N 1-(2-ethylphenyl)propane-1,1-diamine Chemical class CCC1=CC=CC=C1C(N)(N)CC FJWZMLSQLCKKGV-UHFFFAOYSA-N 0.000 claims description 3
IIGAAOXXRKTFAM-UHFFFAOYSA-N N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C Chemical class N=C=O.N=C=O.CC1=C(C)C(C)=C(C)C(C)=C1C IIGAAOXXRKTFAM-UHFFFAOYSA-N 0.000 claims description 3
KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 claims description 3
238000009826 distribution Methods 0.000 abstract description 5
239000005058 Isophorone diisocyanate Substances 0.000 description 55
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 39
230000000052 comparative effect Effects 0.000 description 33
125000002887 hydroxy group Chemical group [H]O* 0.000 description 29
229920000642 polymer Polymers 0.000 description 26
239000000463 material Substances 0.000 description 24
HGXVKAPCSIXGAK-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine;4,6-diethyl-2-methylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(C)=C1N.CCC1=CC(C)=C(N)C(CC)=C1N HGXVKAPCSIXGAK-UHFFFAOYSA-N 0.000 description 23
235000019589 hardness Nutrition 0.000 description 23
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 14
239000003054 catalyst Substances 0.000 description 14
125000006353 oxyethylene group Chemical group 0.000 description 14
230000015572 biosynthetic process Effects 0.000 description 13
229920000909 polytetrahydrofuran Polymers 0.000 description 11
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 10
230000000694 effects Effects 0.000 description 10
-1 polyoxypropylene Polymers 0.000 description 9
AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
239000000047 product Substances 0.000 description 7
239000004970 Chain extender Substances 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
229920005906 polyester polyol Polymers 0.000 description 6
229920001451 polypropylene glycol Polymers 0.000 description 6
230000009257 reactivity Effects 0.000 description 5
238000005266 casting Methods 0.000 description 4
125000005442 diisocyanate group Chemical group 0.000 description 4
SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 4
229920003225 polyurethane elastomer Polymers 0.000 description 4
238000002360 preparation method Methods 0.000 description 4
239000000126 substance Substances 0.000 description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000012975 dibutyltin dilaurate Substances 0.000 description 3
230000001747 exhibiting effect Effects 0.000 description 3
PISLZQACAJMAIO-UHFFFAOYSA-N 2,4-diethyl-6-methylbenzene-1,3-diamine Chemical compound CCC1=CC(C)=C(N)C(CC)=C1N PISLZQACAJMAIO-UHFFFAOYSA-N 0.000 description 2
TXDBDYPHJXUHEO-UHFFFAOYSA-N 2-methyl-4,6-bis(methylsulfanyl)benzene-1,3-diamine Chemical compound CSC1=CC(SC)=C(N)C(C)=C1N TXDBDYPHJXUHEO-UHFFFAOYSA-N 0.000 description 2
RQEOBXYYEPMCPJ-UHFFFAOYSA-N 4,6-diethyl-2-methylbenzene-1,3-diamine Chemical compound CCC1=CC(CC)=C(N)C(C)=C1N RQEOBXYYEPMCPJ-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
125000001931 aliphatic group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 2
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
150000004292 cyclic ethers Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
231100000614 poison Toxicity 0.000 description 2
229920005604 random copolymer Polymers 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 2
239000003440 toxic substance Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
PLFFHJWXOGYWPR-HEDMGYOXSA-N (4r)-4-[(3r,3as,5ar,5br,7as,11as,11br,13ar,13bs)-5a,5b,8,8,11a,13b-hexamethyl-1,2,3,3a,4,5,6,7,7a,9,10,11,11b,12,13,13a-hexadecahydrocyclopenta[a]chrysen-3-yl]pentan-1-ol Chemical compound C([C@]1(C)[C@H]2CC[C@H]34)CCC(C)(C)[C@@H]1CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@@H]1[C@@H](CCCO)C PLFFHJWXOGYWPR-HEDMGYOXSA-N 0.000 description 1
MTZUIIAIAKMWLI-UHFFFAOYSA-N 1,2-diisocyanatobenzene Chemical group O=C=NC1=CC=CC=C1N=C=O MTZUIIAIAKMWLI-UHFFFAOYSA-N 0.000 description 1
AOFIWCXMXPVSAZ-UHFFFAOYSA-N 4-methyl-2,6-bis(methylsulfanyl)benzene-1,3-diamine Chemical compound CSC1=CC(C)=C(N)C(SC)=C1N AOFIWCXMXPVSAZ-UHFFFAOYSA-N 0.000 description 1
229910015900 BF3 Inorganic materials 0.000 description 1
241000282472 Canis lupus familiaris Species 0.000 description 1
239000001879 Curdlan Substances 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
WWEXBGFSEVKZNE-UHFFFAOYSA-N N=C=O.N=C=O.C1=CC=CC2=CC=CC=C21 Chemical group N=C=O.N=C=O.C1=CC=CC2=CC=CC=C21 WWEXBGFSEVKZNE-UHFFFAOYSA-N 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
235000004443 Ricinus communis Nutrition 0.000 description 1
240000000528 Ricinus communis Species 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
238000013459 approach Methods 0.000 description 1
229910052797 bismuth Inorganic materials 0.000 description 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
210000000481 breast Anatomy 0.000 description 1
VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
125000004427 diamine group Chemical group 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
229920006247 high-performance elastomer Polymers 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
230000008676 import Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
239000006082 mold release agent Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
125000002524 organometallic group Chemical group 0.000 description 1
150000002924 oxiranes Chemical class 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000002310 reflectometry Methods 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
150000007984 tetrahydrofuranes Chemical class 0.000 description 1
150000003606 tin compounds Chemical class 0.000 description 1
AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
- C08G18/724—Combination of aromatic polyisocyanates with (cyclo)aliphatic polyisocyanates
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/485—Polyethers containing oxyethylene units and other oxyalkylene units containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/906—Fiber or elastomer prepared from an isocyanate reactant
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyurethanes Or Polyureas (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

SK1357-2000A 1998-03-16 1999-03-11 Spôsob výroby čírych polyuretán/močovinových elastomérov SK13572000A3 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US09/039,964 US5962619A (en)	1998-03-16	1998-03-16	Process for making clear polyurethane/urea elastomers
PCT/EP1999/001604 WO1999047577A1 (en)	1998-03-16	1999-03-11	Process for making clear polyurethane/urea elastomers

Publications (1)

Publication Number	Publication Date
SK13572000A3 true SK13572000A3 (sk)	2001-02-12

Family

ID=21908332

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1357-2000A SK13572000A3 (sk)	1998-03-16	1999-03-11	Spôsob výroby čírych polyuretán/močovinových elastomérov

Country Status (26)

Country	Link
US (1)	US5962619A (de)
EP (1)	EP1066332B1 (de)
JP (1)	JP2002506896A (de)
KR (1)	KR20010041893A (de)
CN (1)	CN1152900C (de)
AR (1)	AR018760A1 (de)
AT (1)	ATE222269T1 (de)
AU (1)	AU746777B2 (de)
BR (1)	BR9908812A (de)
CA (1)	CA2324241A1 (de)
DE (1)	DE69902522T2 (de)
DK (1)	DK1066332T3 (de)
ES (1)	ES2182506T3 (de)
HR (1)	HRP20000606A2 (de)
HU (1)	HUP0101082A3 (de)
IL (1)	IL138204A0 (de)
IS (1)	IS5629A (de)
NO (1)	NO20004586L (de)
NZ (1)	NZ506946A (de)
PL (1)	PL342953A1 (de)
PT (1)	PT1066332E (de)
SK (1)	SK13572000A3 (de)
TR (1)	TR200002666T2 (de)
TW (1)	TW436501B (de)
WO (1)	WO1999047577A1 (de)
YU (1)	YU56500A (de)

Families Citing this family (54)

* Cited by examiner, † Cited by third party
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US6127505A (en) *	1995-02-02	2000-10-03	Simula Inc.	Impact resistant polyurethane and method of manufacture thereof
AR019107A1 (es) *	1998-04-27	2001-12-26	Dow Global Technologies Inc	Polioles de alto peso molecular, proceso para su preparacion y uso de los mismos.
GB9926006D0 (en)	1999-11-04	2000-01-12	Ciba Sc Holding Ag	Polurethane/polyurea-forming compositions
US7473754B1 (en)	2000-10-17	2009-01-06	Ppg Industries Ohio, Inc.	Optical resin composition
US7098290B1 (en)	1999-11-18	2006-08-29	Ppg Industries Ohio, Inc.	Method of preparing an optical polymerizate
US7087698B1 (en)	1999-11-18	2006-08-08	Ppg Industries Ohio, Inc.	Method of preparing an optical polymerizate
US6531076B2 (en)	2000-02-04	2003-03-11	Ppg Industries Ohio, Inc.	Photochromic organic resin composition
US6509434B1 (en)	2000-03-20	2003-01-21	Albemarle Corporation	Aromatic amine curatives and their use
US6433043B1 (en) *	2000-11-28	2002-08-13	Transitions Optical, Inc.	Removable imbibition composition of photochromic compound and kinetic enhancing additive
WO2002064658A1 (en) *	2001-02-12	2002-08-22	Uniroyal Chemical Company, Inc.	Low cost, resilient, shear resistant polyurethane elastomers for golf ball covers
US6562932B1 (en) *	2001-10-12	2003-05-13	Bayer Corporation	Light stable one-shot urethane-urea elastomers
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1998
- 1998-03-16 US US09/039,964 patent/US5962619A/en not_active Expired - Fee Related
1999
- 1999-03-11 HU HU0101082A patent/HUP0101082A3/hu unknown
- 1999-03-11 NZ NZ506946A patent/NZ506946A/en unknown
- 1999-03-11 SK SK1357-2000A patent/SK13572000A3/sk unknown
- 1999-03-11 CN CNB998040797A patent/CN1152900C/zh not_active Expired - Fee Related
- 1999-03-11 JP JP2000536766A patent/JP2002506896A/ja active Pending
- 1999-03-11 DE DE69902522T patent/DE69902522T2/de not_active Expired - Fee Related
- 1999-03-11 WO PCT/EP1999/001604 patent/WO1999047577A1/en not_active Ceased
- 1999-03-11 KR KR1020007010195A patent/KR20010041893A/ko not_active Withdrawn
- 1999-03-11 DK DK99914513T patent/DK1066332T3/da active
- 1999-03-11 TR TR2000/02666T patent/TR200002666T2/xx unknown
- 1999-03-11 HR HR20000606A patent/HRP20000606A2/hr not_active Application Discontinuation
- 1999-03-11 PL PL99342953A patent/PL342953A1/xx unknown
- 1999-03-11 PT PT99914513T patent/PT1066332E/pt unknown
- 1999-03-11 YU YU56500A patent/YU56500A/sh unknown
- 1999-03-11 BR BR9908812-6A patent/BR9908812A/pt not_active IP Right Cessation
- 1999-03-11 IL IL13820499A patent/IL138204A0/xx unknown
- 1999-03-11 CA CA002324241A patent/CA2324241A1/en not_active Abandoned
- 1999-03-11 ES ES99914513T patent/ES2182506T3/es not_active Expired - Lifetime
- 1999-03-11 EP EP99914513A patent/EP1066332B1/de not_active Expired - Lifetime
- 1999-03-11 AU AU33304/99A patent/AU746777B2/en not_active Ceased
- 1999-03-11 AT AT99914513T patent/ATE222269T1/de not_active IP Right Cessation
- 1999-03-15 TW TW088103980A patent/TW436501B/zh active
- 1999-03-16 AR ARP990101144A patent/AR018760A1/es unknown
2000
- 2000-09-14 NO NO20004586A patent/NO20004586L/no unknown
- 2000-09-15 IS IS5629A patent/IS5629A/is unknown

Also Published As

Publication number	Publication date
JP2002506896A (ja)	2002-03-05
HRP20000606A2 (en)	2000-12-31
BR9908812A (pt)	2000-11-21
CN1293683A (zh)	2001-05-02
CN1152900C (zh)	2004-06-09
EP1066332A1 (de)	2001-01-10
NO20004586L (no)	2000-11-15
DE69902522T2 (de)	2002-12-19
PT1066332E (pt)	2002-11-29
CA2324241A1 (en)	1999-09-23
YU56500A (sh)	2002-09-19
IS5629A (is)	2000-09-15
AU746777B2 (en)	2002-05-02
AR018760A1 (es)	2001-12-12
DE69902522D1 (de)	2002-09-19
AU3330499A (en)	1999-10-11
PL342953A1 (en)	2001-07-16
KR20010041893A (ko)	2001-05-25
ATE222269T1 (de)	2002-08-15
WO1999047577A1 (en)	1999-09-23
HUP0101082A3 (en)	2002-06-28
EP1066332B1 (de)	2002-08-14
ES2182506T3 (es)	2003-03-01
NO20004586D0 (no)	2000-09-14
HUP0101082A2 (hu)	2001-07-30
IL138204A0 (en)	2001-10-31
TR200002666T2 (tr)	2000-11-21
DK1066332T3 (da)	2002-12-02
US5962619A (en)	1999-10-05
TW436501B (en)	2001-05-28
NZ506946A (en)	2002-03-28

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