SK280457B6 - Spôsob prípravy chloridov kyselín - Google Patents
Spôsob prípravy chloridov kyselín Download PDFInfo
- Publication number
- SK280457B6 SK280457B6 SK1203-94A SK120394A SK280457B6 SK 280457 B6 SK280457 B6 SK 280457B6 SK 120394 A SK120394 A SK 120394A SK 280457 B6 SK280457 B6 SK 280457B6
- Authority
- SK
- Slovakia
- Prior art keywords
- formula
- preparation
- compound
- water
- group
- Prior art date
Links
- 239000002253 acid Substances 0.000 title claims abstract description 4
- 150000001805 chlorine compounds Chemical class 0.000 title claims abstract description 4
- 238000000034 method Methods 0.000 title claims description 23
- 238000002360 preparation method Methods 0.000 title claims description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 10
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 10
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000005843 halogen group Chemical group 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000001188 haloalkyl group Chemical group 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000004076 pyridyl group Chemical group 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 abstract description 13
- 239000000460 chlorine Substances 0.000 abstract description 11
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052731 fluorine Inorganic materials 0.000 abstract description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract description 4
- 239000011737 fluorine Substances 0.000 abstract description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052794 bromium Inorganic materials 0.000 abstract description 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 description 16
- 239000002841 Lewis acid Substances 0.000 description 12
- 150000007517 lewis acids Chemical class 0.000 description 12
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 11
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 239000011541 reaction mixture Substances 0.000 description 8
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 7
- 125000001309 chloro group Chemical group Cl* 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- -1 aromatic acid chlorides Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000010992 reflux Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
- KRZCOLNOCZKSDF-UHFFFAOYSA-N 4-fluoroaniline Chemical compound NC1=CC=C(F)C=C1 KRZCOLNOCZKSDF-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000001072 heteroaryl group Chemical group 0.000 description 3
- XEMRAKSQROQPBR-UHFFFAOYSA-N (trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=CC=C1 XEMRAKSQROQPBR-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical class ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
- DCUJJWWUNKIJPH-UHFFFAOYSA-N nitrapyrin Chemical compound ClC1=CC=CC(C(Cl)(Cl)Cl)=N1 DCUJJWWUNKIJPH-UHFFFAOYSA-N 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 125000000547 substituted alkyl group Chemical group 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- UGEJOEBBMPOJMT-UHFFFAOYSA-N 3-(trifluoromethyl)phenol Chemical compound OC1=CC=CC(C(F)(F)F)=C1 UGEJOEBBMPOJMT-UHFFFAOYSA-N 0.000 description 1
- KASGMHMVKYJQKR-UHFFFAOYSA-N 6-chloro-n-(4-fluorophenyl)pyridine-2-carboxamide Chemical compound C1=CC(F)=CC=C1NC(=O)C1=CC=CC(Cl)=N1 KASGMHMVKYJQKR-UHFFFAOYSA-N 0.000 description 1
- INDXGKMKACLIJS-UHFFFAOYSA-N 6-chloropyridine-2-carbonyl chloride Chemical compound ClC(=O)C1=CC=CC(Cl)=N1 INDXGKMKACLIJS-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 230000005526 G1 to G0 transition Effects 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 101100311330 Schizosaccharomyces pombe (strain 972 / ATCC 24843) uap56 gene Proteins 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000003302 alkenyloxy group Chemical group 0.000 description 1
- 125000005108 alkenylthio group Chemical group 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 125000004644 alkyl sulfinyl group Chemical group 0.000 description 1
- 125000004390 alkyl sulfonyl group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 125000005133 alkynyloxy group Chemical group 0.000 description 1
- 125000005109 alkynylthio group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229940053202 antiepileptics carboxamide derivative Drugs 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000012824 chemical production Methods 0.000 description 1
- XOYLJNJLGBYDTH-UHFFFAOYSA-M chlorogallium Chemical compound [Ga]Cl XOYLJNJLGBYDTH-UHFFFAOYSA-M 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 125000001207 fluorophenyl group Chemical group 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000004438 haloalkoxy group Chemical group 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- OMWWTMOLTFYGAK-UHFFFAOYSA-N n-(4-fluorophenyl)benzamide Chemical compound C1=CC(F)=CC=C1NC(=O)C1=CC=CC=C1 OMWWTMOLTFYGAK-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- IBBMAWULFFBRKK-UHFFFAOYSA-N picolinamide Chemical compound NC(=O)C1=CC=CC=N1 IBBMAWULFFBRKK-UHFFFAOYSA-N 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 101150018444 sub2 gene Proteins 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910021381 transition metal chloride Inorganic materials 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/58—Preparation of carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
- C07C63/04—Monocyclic monocarboxylic acids
- C07C63/06—Benzoic acid
- C07C63/10—Halides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/81—Amides; Imides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP93307903 | 1993-10-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SK120394A3 SK120394A3 (en) | 1995-05-10 |
| SK280457B6 true SK280457B6 (sk) | 2000-02-14 |
Family
ID=8214567
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK1203-94A SK280457B6 (sk) | 1993-10-05 | 1994-10-05 | Spôsob prípravy chloridov kyselín |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP0646566B1 (de) |
| JP (1) | JP4101311B2 (de) |
| KR (1) | KR100357221B1 (de) |
| CN (1) | CN1050833C (de) |
| AT (1) | ATE160337T1 (de) |
| AU (1) | AU676370B2 (de) |
| BR (1) | BR9403998A (de) |
| CA (1) | CA2133612A1 (de) |
| CZ (1) | CZ286844B6 (de) |
| DE (1) | DE69406885T2 (de) |
| DK (1) | DK0646566T3 (de) |
| ES (1) | ES2110700T3 (de) |
| GR (1) | GR3025449T3 (de) |
| HK (1) | HK1005336A1 (de) |
| HU (1) | HU213629B (de) |
| IL (1) | IL111117A0 (de) |
| RU (1) | RU2141940C1 (de) |
| SG (1) | SG86305A1 (de) |
| SK (1) | SK280457B6 (de) |
| TW (1) | TW378202B (de) |
| UA (1) | UA27882C2 (de) |
| ZA (1) | ZA947672B (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ294098B6 (cs) * | 1996-08-23 | 2004-10-13 | Americanácyanamidácompany | Způsob přípravy chloridů azinylových kyselin |
| US6087506A (en) * | 1997-08-19 | 2000-07-11 | American Cyanamid Company | Preparation of hetero arylcarboxamides |
| TW575563B (en) * | 1997-08-19 | 2004-02-11 | American Cyanamid Co | Process for the preparation of pyridyl carboxylic amides and esters |
| ATE460400T1 (de) * | 2005-11-07 | 2010-03-15 | Basf Se | Verfahren zur herstellung von pyridylcarbonsäureamiden und estern |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US387226A (en) * | 1888-08-07 | Hose-coupling | ||
| US1557154A (en) * | 1924-07-22 | 1925-10-13 | Mathieson Alkali Works Inc | Manufacture of benzoyl chloride |
| JPS5843380B2 (ja) * | 1977-07-15 | 1983-09-27 | 日軽化工株式会社 | 塩化ベンゾイルの製造法 |
| DE2841541A1 (de) * | 1978-09-23 | 1980-04-03 | Bayer Ag | Verfahren zur herstellung von gegebenenfalls substituiertem benzoylchlorid |
| US4562286A (en) * | 1984-11-01 | 1985-12-31 | Occidental Chemical Corporation | Process for preparing methoxytrifluoromethylnaphthoic acid from dimethylnaphthalene |
| DE3723069A1 (de) * | 1987-07-11 | 1989-01-19 | Bayer Ag | 5-halogen-6-amino-nikotinsaeurehalogenide, ihre herstellung und ihre verwendung |
| EP0447044A1 (de) * | 1990-02-23 | 1991-09-18 | Eaton Corporation | Magnetoelastischer Film und Verfahren |
| GB9005965D0 (en) * | 1990-03-16 | 1990-05-09 | Shell Int Research | Herbicidal carboxamide derivatives |
-
1994
- 1994-09-30 IL IL11111794A patent/IL111117A0/xx unknown
- 1994-09-30 AT AT94307194T patent/ATE160337T1/de not_active IP Right Cessation
- 1994-09-30 ES ES94307194T patent/ES2110700T3/es not_active Expired - Lifetime
- 1994-09-30 ZA ZA947672A patent/ZA947672B/xx unknown
- 1994-09-30 SG SG9607810A patent/SG86305A1/en unknown
- 1994-09-30 AU AU74318/94A patent/AU676370B2/en not_active Ceased
- 1994-09-30 DK DK94307194.4T patent/DK0646566T3/da active
- 1994-09-30 DE DE69406885T patent/DE69406885T2/de not_active Expired - Fee Related
- 1994-09-30 EP EP94307194A patent/EP0646566B1/de not_active Expired - Lifetime
- 1994-10-04 UA UA94105886A patent/UA27882C2/uk unknown
- 1994-10-04 RU RU94035677/04A patent/RU2141940C1/ru not_active IP Right Cessation
- 1994-10-04 CA CA002133612A patent/CA2133612A1/en not_active Abandoned
- 1994-10-05 JP JP26624194A patent/JP4101311B2/ja not_active Expired - Fee Related
- 1994-10-05 HU HU9402858A patent/HU213629B/hu not_active IP Right Cessation
- 1994-10-05 SK SK1203-94A patent/SK280457B6/sk unknown
- 1994-10-05 KR KR1019940025458A patent/KR100357221B1/ko not_active Expired - Fee Related
- 1994-10-05 CN CN94117018A patent/CN1050833C/zh not_active Expired - Fee Related
- 1994-10-05 CZ CZ19942451A patent/CZ286844B6/cs not_active IP Right Cessation
- 1994-10-05 BR BR9403998A patent/BR9403998A/pt not_active IP Right Cessation
- 1994-11-03 TW TW083110136A patent/TW378202B/zh not_active IP Right Cessation
-
1997
- 1997-11-20 GR GR970401988T patent/GR3025449T3/el unknown
-
1998
- 1998-05-13 HK HK98104129A patent/HK1005336A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| IL111117A0 (en) | 1994-11-28 |
| HU213629B (en) | 1997-08-28 |
| DE69406885D1 (de) | 1998-01-02 |
| CN1050833C (zh) | 2000-03-29 |
| JP4101311B2 (ja) | 2008-06-18 |
| CA2133612A1 (en) | 1995-04-06 |
| DE69406885T2 (de) | 1998-04-09 |
| AU676370B2 (en) | 1997-03-06 |
| JPH07258147A (ja) | 1995-10-09 |
| ATE160337T1 (de) | 1997-12-15 |
| TW378202B (en) | 2000-01-01 |
| EP0646566A1 (de) | 1995-04-05 |
| RU94035677A (ru) | 1996-09-10 |
| BR9403998A (pt) | 1995-06-13 |
| HUT69030A (en) | 1995-08-28 |
| AU7431894A (en) | 1995-04-27 |
| DK0646566T3 (da) | 1997-12-22 |
| KR100357221B1 (ko) | 2003-03-03 |
| KR950011393A (ko) | 1995-05-15 |
| HU9402858D0 (en) | 1995-01-30 |
| UA27882C2 (uk) | 2000-10-16 |
| CZ245194A3 (en) | 1995-10-18 |
| CN1109876A (zh) | 1995-10-11 |
| ES2110700T3 (es) | 1998-02-16 |
| EP0646566B1 (de) | 1997-11-19 |
| SK120394A3 (en) | 1995-05-10 |
| SG86305A1 (en) | 2002-02-19 |
| RU2141940C1 (ru) | 1999-11-27 |
| ZA947672B (en) | 1995-06-29 |
| CZ286844B6 (en) | 2000-07-12 |
| HK1005336A1 (en) | 1998-12-31 |
| GR3025449T3 (en) | 1998-02-27 |
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