SK287211B6 - Spôsob prípravy polyamidov - Google Patents

Spôsob prípravy polyamidov Download PDF

Info

Publication number: SK287211B6
Authority: SK; Slovakia
Prior art keywords: acid; nylon; group; polyamide; polyamides
Prior art date: 2000-11-23

Application number

SK613-2003A

Other languages

English (en)

Slovak (sk)

Other versions

SK6132003A3 (en

Inventor

Helmut Winterling

Michael Fischer

Original Assignee

Basf Aktiengesellschaft

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2000-11-23

Filing date

2001-11-22

Publication date

2010-03-08

2001-11-22 Application filed by Basf Aktiengesellschaft filed Critical Basf Aktiengesellschaft

2004-02-03 Publication of SK6132003A3 publication Critical patent/SK6132003A3/sk

2010-03-08 Publication of SK287211B6 publication Critical patent/SK287211B6/sk

Links

239000004952 Polyamide Substances 0.000 title claims abstract description 41
229920002647 polyamide Polymers 0.000 title claims abstract description 41
238000004519 manufacturing process Methods 0.000 title claims abstract description 7
239000000178 monomer Substances 0.000 claims abstract description 29
125000005392 carboxamide group Chemical group NC(=O)* 0.000 claims abstract description 22
125000000524 functional group Chemical group 0.000 claims abstract description 16
125000002560 nitrile group Chemical group 0.000 claims abstract description 15
239000000835 fiber Substances 0.000 claims description 15
-1 nitrile carboxylic acid Chemical class 0.000 claims description 15
238000000034 method Methods 0.000 claims description 7
238000000465 moulding Methods 0.000 claims description 7
238000002360 preparation method Methods 0.000 claims description 7
125000005219 aminonitrile group Chemical group 0.000 claims description 6
230000000379 polymerizing effect Effects 0.000 claims description 2
150000001875 compounds Chemical class 0.000 abstract description 14
239000012986 chain transfer agent Substances 0.000 abstract 1
229920000642 polymer Polymers 0.000 description 18
238000006116 polymerization reaction Methods 0.000 description 18
239000002253 acid Substances 0.000 description 12
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 12
JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 12
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 12
239000000539 dimer Substances 0.000 description 11
239000013638 trimer Substances 0.000 description 11
239000000243 solution Substances 0.000 description 10
229920002292 Nylon 6 Polymers 0.000 description 9
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 9
229920002302 Nylon 6,6 Polymers 0.000 description 8
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
150000007513 acids Chemical class 0.000 description 8
230000000052 comparative effect Effects 0.000 description 8
QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
150000004985 diamines Chemical class 0.000 description 7
150000001991 dicarboxylic acids Chemical class 0.000 description 7
239000000203 mixture Substances 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
239000001361 adipic acid Substances 0.000 description 6
235000011037 adipic acid Nutrition 0.000 description 6
150000001805 chlorine compounds Chemical class 0.000 description 6
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 6
TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 6
KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 6
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
230000032683 aging Effects 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 4
239000000049 pigment Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
MMEDJBFVJUFIDD-UHFFFAOYSA-N 2-[2-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1CC(O)=O MMEDJBFVJUFIDD-UHFFFAOYSA-N 0.000 description 3
GDYYIJNDPMFMTB-UHFFFAOYSA-N 2-[3-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC(CC(O)=O)=C1 GDYYIJNDPMFMTB-UHFFFAOYSA-N 0.000 description 3
SLWIPPZWFZGHEU-UHFFFAOYSA-N 2-[4-(carboxymethyl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=C(CC(O)=O)C=C1 SLWIPPZWFZGHEU-UHFFFAOYSA-N 0.000 description 3
KBMSFJFLSXLIDJ-UHFFFAOYSA-N 6-aminohexanenitrile Chemical compound NCCCCCC#N KBMSFJFLSXLIDJ-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 3
229920000299 Nylon 12 Polymers 0.000 description 3
229920000305 Nylon 6,10 Polymers 0.000 description 3
FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 3
ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 3
125000003368 amide group Chemical group 0.000 description 3
125000003277 amino group Chemical group 0.000 description 3
239000004760 aramid Substances 0.000 description 3
150000004984 aromatic diamines Chemical class 0.000 description 3
229920003235 aromatic polyamide Polymers 0.000 description 3
150000003951 lactams Chemical class 0.000 description 3
239000000155 melt Substances 0.000 description 3
235000019260 propionic acid Nutrition 0.000 description 3
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 3
230000008646 thermal stress Effects 0.000 description 3
239000004408 titanium dioxide Substances 0.000 description 3
WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 2
CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 2
SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
241000531908 Aramides Species 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
229920000571 Nylon 11 Polymers 0.000 description 2
229920003189 Nylon 4,6 Polymers 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
150000001413 amino acids Chemical class 0.000 description 2
229910021529 ammonia Inorganic materials 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
238000010923 batch production Methods 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
238000007796 conventional method Methods 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
JBDSSBMEKXHSJF-UHFFFAOYSA-N cyclopentanecarboxylic acid Chemical compound OC(=O)C1CCCC1 JBDSSBMEKXHSJF-UHFFFAOYSA-N 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
FPIQZBQZKBKLEI-UHFFFAOYSA-N ethyl 1-[[2-chloroethyl(nitroso)carbamoyl]amino]cyclohexane-1-carboxylate Chemical compound ClCCN(N=O)C(=O)NC1(C(=O)OCC)CCCCC1 FPIQZBQZKBKLEI-UHFFFAOYSA-N 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
239000003365 glass fiber Substances 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
238000006068 polycondensation reaction Methods 0.000 description 2
LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical class C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
CELROVGXVNNJCW-UHFFFAOYSA-N 11-aminoundecanamide Chemical compound NCCCCCCCCCCC(N)=O CELROVGXVNNJCW-UHFFFAOYSA-N 0.000 description 1
FTVFPPFZRRKJIH-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidin-4-amine Chemical compound CC1(C)CC(N)CC(C)(C)N1 FTVFPPFZRRKJIH-UHFFFAOYSA-N 0.000 description 1
RXXCIBALSKQCAE-UHFFFAOYSA-N 3-methylbutoxymethylbenzene Chemical compound CC(C)CCOCC1=CC=CC=C1 RXXCIBALSKQCAE-UHFFFAOYSA-N 0.000 description 1
GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
238000006237 Beckmann rearrangement reaction Methods 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 description 1
238000004566 IR spectroscopy Methods 0.000 description 1
229920000271 Kevlar® Polymers 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
229920000784 Nomex Polymers 0.000 description 1
239000004677 Nylon Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical class NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229960002684 aminocaproic acid Drugs 0.000 description 1
QFNNDGVVMCZKEY-UHFFFAOYSA-N azacyclododecan-2-one Chemical compound O=C1CCCCCCCCCCN1 QFNNDGVVMCZKEY-UHFFFAOYSA-N 0.000 description 1
FFHRTSKTHPDADK-UHFFFAOYSA-N benzene naphthalene-1,2-dicarboxylic acid Chemical class C1=CC=CC=C1.C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 FFHRTSKTHPDADK-UHFFFAOYSA-N 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000003857 carboxamides Chemical class 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
150000003997 cyclic ketones Chemical class 0.000 description 1
VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 description 1
PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
230000000694 effects Effects 0.000 description 1
ZLHYDRXTDZFRDZ-UHFFFAOYSA-N epsilon-aminocaproamide Chemical compound NCCCCCC(N)=O ZLHYDRXTDZFRDZ-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
QZUPTXGVPYNUIT-UHFFFAOYSA-N isophthalamide Chemical compound NC(=O)C1=CC=CC(C(N)=O)=C1 QZUPTXGVPYNUIT-UHFFFAOYSA-N 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QVGONMHQKGSFOB-UHFFFAOYSA-N methyl 11-aminoundecanoate Chemical compound COC(=O)CCCCCCCCCCN QVGONMHQKGSFOB-UHFFFAOYSA-N 0.000 description 1
TZJVWRXHKAXSEA-UHFFFAOYSA-N methyl 6-aminohexanoate Chemical compound COC(=O)CCCCCN TZJVWRXHKAXSEA-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000004763 nomex Substances 0.000 description 1
229920001778 nylon Polymers 0.000 description 1
150000002923 oximes Chemical class 0.000 description 1
238000012667 polymer degradation Methods 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000007363 ring formation reaction Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
239000007790 solid phase Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000009987 spinning Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/14—Lactams
- C08G69/16—Preparatory processes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/04—Preparatory processes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/28—Preparatory processes

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polyamides (AREA)

SK613-2003A 2000-11-23 2001-11-22 Spôsob prípravy polyamidov SK287211B6 (sk)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE10058292A DE10058292A1 (de)	2000-11-23	2000-11-23	Polyamide
PCT/EP2001/013595 WO2002042357A2 (de)	2000-11-23	2001-11-22	Polyamid

Publications (2)

Publication Number	Publication Date
SK6132003A3 SK6132003A3 (en)	2004-02-03
SK287211B6 true SK287211B6 (sk)	2010-03-08

Family

ID=7664469

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK613-2003A SK287211B6 (sk)	2000-11-23	2001-11-22	Spôsob prípravy polyamidov

Country Status (23)

Country	Link
US (1)	US6958381B2 (cs)
EP (1)	EP1349886B1 (cs)
JP (1)	JP4096043B2 (cs)
KR (1)	KR100760766B1 (cs)
CN (1)	CN1233691C (cs)
AR (1)	AR031329A1 (cs)
AT (1)	ATE370180T1 (cs)
AU (1)	AU2002227941A1 (cs)
BG (1)	BG107775A (cs)
BR (1)	BR0115543B1 (cs)
CA (1)	CA2429322C (cs)
CZ (1)	CZ298974B6 (cs)
DE (2)	DE10058292A1 (cs)
ES (1)	ES2288523T3 (cs)
HU (1)	HU227165B1 (cs)
IL (1)	IL155652A0 (cs)
MX (1)	MXPA03004281A (cs)
MY (1)	MY130453A (cs)
PL (1)	PL362468A1 (cs)
SK (1)	SK287211B6 (cs)
TW (1)	TW574260B (cs)
WO (1)	WO2002042357A2 (cs)
ZA (1)	ZA200304800B (cs)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE10321788A1 (de) *	2003-05-14	2004-12-09	Basf Ag	Polyamide
WO2006116683A1 (en) *	2005-04-27	2006-11-02	The Trustees Of The University Of Pennsylvania	Nanostructure enhanced luminescence
WO2006116687A2 (en) *	2005-04-27	2006-11-02	The Trustees Of The University Of Pennsylvania	Nanoassays
US8895779B2 (en)	2010-04-30	2014-11-25	Bioamber Inc.	Processes for producing monoammonium adipate and conversion of monoammonium adipate to adipic acid
CN102939276A (zh) *	2010-05-19	2013-02-20	生物琥珀酸有限公司	二氨基丁烷（dab）、琥珀腈（sdn）和琥珀酰胺（dam）的制备方法
KR20130047693A (ko) *	2010-05-19	2013-05-08	바이오엠버, 에스.아.에스.	디아미노부탄(ｄａｂ), 석신산 디니트릴(ｓｄｎ) 및 석신아미드(ｄａｍ)의 제조방법
WO2011159555A1 (en) *	2010-06-16	2011-12-22	Bioamber S.A.S.	Processes for producing caprolactam and derivatives thereof from fermentation broths containing diammonium adipate or monoammonium adipate
CA2800733A1 (en) *	2010-06-16	2011-12-22	Bioamber S.A.S.	Processes for the production of hydrogenated products and derivatives thereof
BR112012031597A2 (pt)	2010-06-16	2017-05-23	Bioamber Sas	processos para produzir hexametilenodiamina (hmd), adiponitrilo (adn), adipamida (adm) e derivados dos mesmos.
KR20130020838A (ko) *	2010-06-16	2013-02-28	바이오엠버, 에스.아.에스.	디암모늄 아디페이트, 모노암모늄 아디페이트 및/또는 아디프산을 함유한 발효 브로쓰로부터 카프로락탐 및 이의 유도체를 제조하는 방법
BR112012031822A2 (pt) *	2010-06-16	2015-09-22	Bioamber Sas	processos para a produção de produtos hidrogenados e seus derivados.
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2000
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Publication number	Publication date
CZ298974B6 (cs)	2008-03-26
CN1476458A (zh)	2004-02-18
DE10058292A1 (de)	2002-05-29
BG107775A (bg)	2004-02-27
TW574260B (en)	2004-02-01
US6958381B2 (en)	2005-10-25
SK6132003A3 (en)	2004-02-03
IL155652A0 (en)	2003-11-23
EP1349886A2 (de)	2003-10-08
AU2002227941A1 (en)	2002-06-03
HUP0301517A3 (en)	2006-07-28
MY130453A (en)	2007-06-29
ATE370180T1 (de)	2007-09-15
PL362468A1 (en)	2004-11-02
KR100760766B1 (ko)	2007-10-04
AR031329A1 (es)	2003-09-17
CA2429322C (en)	2009-05-26
WO2002042357A3 (de)	2002-08-01
BR0115543B1 (pt)	2010-11-30
CA2429322A1 (en)	2002-05-30
BR0115543A (pt)	2003-09-09
HU227165B1 (en)	2010-09-28
ES2288523T3 (es)	2008-01-16
JP4096043B2 (ja)	2008-06-04
ZA200304800B (en)	2004-08-27
JP2004531586A (ja)	2004-10-14
CZ20031428A3 (cs)	2003-10-15
US20040102600A1 (en)	2004-05-27
MXPA03004281A (es)	2003-08-19
WO2002042357A2 (de)	2002-05-30
HUP0301517A2 (hu)	2003-10-28
CN1233691C (zh)	2005-12-28
EP1349886B1 (de)	2007-08-15
DE50112877D1 (de)	2007-09-27
KR20030068156A (ko)	2003-08-19

Legal Events

Date	Code	Title	Description
2012-08-06	MM4A	Patent lapsed due to non-payment of maintenance fees	Effective date: 20111122

Publication	Publication Date	Title
KR100760766B1 (ko)	2007-10-04	폴리아미드
KR100973620B1 (ko)	2010-08-02	폴리아미드
KR100965013B1 (ko)	2010-06-21	본질적으로 가교성인 폴리아미드
JP4586023B2 (ja)	2010-11-24	ポリアミド
JP4566998B2 (ja)	2010-10-20	ポリアミド
US6812322B2 (en)	2004-11-02	Polyamide
JP5073145B2 (ja)	2012-11-14	ポリアミド