SK73396A3 - Producing method of agent in microcapsules form, microcapsules, offenders suppression method and pesticidal agent - Google Patents

Producing method of agent in microcapsules form, microcapsules, offenders suppression method and pesticidal agent Download PDF

Info

Publication number: SK73396A3
Authority: SK; Slovakia
Prior art keywords: salt; aqueous; chloride; immiscible; microcapsules
Prior art date: 1995-06-07

Application number

SK733-96A

Other languages

English (en)

Slovak (sk)

Inventor

Brian E Benoff

Robin W Dexter

Original Assignee

American Cyanamid Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-06-07

Filing date

1996-06-06

Publication date

1997-02-05

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23916642&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=SK73396(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1996-06-06 Application filed by American Cyanamid Co filed Critical American Cyanamid Co

1997-02-05 Publication of SK73396A3 publication Critical patent/SK73396A3/sk

Links

238000000034 method Methods 0.000 title claims abstract description 61
239000003094 microcapsule Substances 0.000 title claims abstract description 58
230000000361 pesticidal effect Effects 0.000 title claims description 10
239000003795 chemical substances by application Substances 0.000 title description 6
230000001629 suppression Effects 0.000 title 1
239000000203 mixture Substances 0.000 claims abstract description 80
238000002360 preparation method Methods 0.000 claims abstract description 5
235000002639 sodium chloride Nutrition 0.000 claims description 48
150000003839 salts Chemical class 0.000 claims description 39
239000012266 salt solution Substances 0.000 claims description 28
239000000243 solution Substances 0.000 claims description 21
239000000126 substance Substances 0.000 claims description 19
239000003995 emulsifying agent Substances 0.000 claims description 18
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 15
239000007864 aqueous solution Substances 0.000 claims description 14
230000002363 herbicidal effect Effects 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 11
239000004009 herbicide Substances 0.000 claims description 9
239000000463 material Substances 0.000 claims description 9
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 8
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 7
239000001110 calcium chloride Substances 0.000 claims description 7
229910001628 calcium chloride Inorganic materials 0.000 claims description 7
238000003756 stirring Methods 0.000 claims description 7
TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
241000607479 Yersinia pestis Species 0.000 claims description 6
235000011148 calcium chloride Nutrition 0.000 claims description 6
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims description 6
239000011780 sodium chloride Substances 0.000 claims description 6
VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 6
239000006185 dispersion Substances 0.000 claims description 5
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
239000005591 Pendimethalin Substances 0.000 claims description 4
229920002396 Polyurea Polymers 0.000 claims description 4
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 4
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims description 4
IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 claims description 4
CHIFOSRWCNZCFN-UHFFFAOYSA-N pendimethalin Chemical compound CCC(CC)NC1=C([N+]([O-])=O)C=C(C)C(C)=C1[N+]([O-])=O CHIFOSRWCNZCFN-UHFFFAOYSA-N 0.000 claims description 4
239000000575 pesticide Substances 0.000 claims description 4
239000001103 potassium chloride Substances 0.000 claims description 4
235000011164 potassium chloride Nutrition 0.000 claims description 4
FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 4
239000002917 insecticide Substances 0.000 claims description 3
239000011777 magnesium Substances 0.000 claims description 3
229910052749 magnesium Inorganic materials 0.000 claims description 3
229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
235000011147 magnesium chloride Nutrition 0.000 claims description 3
LZGUHMNOBNWABZ-UHFFFAOYSA-N n-nitro-n-phenylnitramide Chemical group [O-][N+](=O)N([N+]([O-])=O)C1=CC=CC=C1 LZGUHMNOBNWABZ-UHFFFAOYSA-N 0.000 claims description 3
235000010344 sodium nitrate Nutrition 0.000 claims description 3
239000004317 sodium nitrate Substances 0.000 claims description 3
229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
235000011152 sodium sulphate Nutrition 0.000 claims description 3
ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 claims description 3
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
239000004952 Polyamide Substances 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
XCSGPAVHZFQHGE-UHFFFAOYSA-N alachlor Chemical compound CCC1=CC=CC(CC)=C1N(COC)C(=O)CCl XCSGPAVHZFQHGE-UHFFFAOYSA-N 0.000 claims description 2
235000019270 ammonium chloride Nutrition 0.000 claims description 2
LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 2
229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 2
BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
235000011130 ammonium sulphate Nutrition 0.000 claims description 2
239000012267 brine Substances 0.000 claims description 2
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
235000019837 monoammonium phosphate Nutrition 0.000 claims description 2
229910000402 monopotassium phosphate Inorganic materials 0.000 claims description 2
235000019796 monopotassium phosphate Nutrition 0.000 claims description 2
229910000403 monosodium phosphate Inorganic materials 0.000 claims description 2
235000019799 monosodium phosphate Nutrition 0.000 claims description 2
PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims description 2
229920002647 polyamide Polymers 0.000 claims description 2
239000004417 polycarbonate Substances 0.000 claims description 2
229920000515 polycarbonate Polymers 0.000 claims description 2
239000004814 polyurethane Substances 0.000 claims description 2
229920002635 polyurethane Polymers 0.000 claims description 2
229910052700 potassium Inorganic materials 0.000 claims description 2
239000011591 potassium Substances 0.000 claims description 2
235000010333 potassium nitrate Nutrition 0.000 claims description 2
239000004323 potassium nitrate Substances 0.000 claims description 2
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
235000011151 potassium sulphates Nutrition 0.000 claims description 2
239000002728 pyrethroid Chemical class 0.000 claims description 2
AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 claims description 2
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 2
WVQBLGZPHOPPFO-UHFFFAOYSA-N 2-chloro-N-(2-ethyl-6-methylphenyl)-N-(1-methoxypropan-2-yl)acetamide Chemical compound CCC1=CC=CC(C)=C1N(C(C)COC)C(=O)CCl WVQBLGZPHOPPFO-UHFFFAOYSA-N 0.000 claims 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 1
FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 claims 1
NBIIXXVUZAFLBC-UHFFFAOYSA-L Phosphate ion(2-) Chemical compound OP([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-L 0.000 claims 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
229960001413 acetanilide Drugs 0.000 claims 1
150000008061 acetanilides Chemical class 0.000 claims 1
BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 claims 1
238000005538 encapsulation Methods 0.000 claims 1
229910052744 lithium Inorganic materials 0.000 claims 1
235000001055 magnesium Nutrition 0.000 claims 1
150000003014 phosphoric acid esters Chemical class 0.000 claims 1
239000011833 salt mixture Substances 0.000 claims 1
238000009472 formulation Methods 0.000 description 18
238000004519 manufacturing process Methods 0.000 description 12
239000013078 crystal Substances 0.000 description 11
-1 ester ester salt Chemical class 0.000 description 11
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical class COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 8
NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000000654 additive Substances 0.000 description 6
230000012010 growth Effects 0.000 description 6
159000000000 sodium salts Chemical class 0.000 description 6
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
238000011156 evaluation Methods 0.000 description 5
229920005610 lignin Polymers 0.000 description 5
229910052943 magnesium sulfate Inorganic materials 0.000 description 5
235000019341 magnesium sulphate Nutrition 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000011734 sodium Substances 0.000 description 5
239000002904 solvent Substances 0.000 description 5
238000010186 staining Methods 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
229920000147 Styrene maleic anhydride Polymers 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
229920000768 polyamine Polymers 0.000 description 4
239000005056 polyisocyanate Substances 0.000 description 4
229920001228 polyisocyanate Polymers 0.000 description 4
241000196324 Embryophyta Species 0.000 description 3
239000002518 antifoaming agent Substances 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
241000218691 Cupressaceae Species 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
239000004480 active ingredient Substances 0.000 description 2
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
239000002519 antifouling agent Substances 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
VHRGRCVQAFMJIZ-UHFFFAOYSA-N cadaverine Chemical compound NCCCCCN VHRGRCVQAFMJIZ-UHFFFAOYSA-N 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000000295 complement effect Effects 0.000 description 2
230000000749 insecticidal effect Effects 0.000 description 2
239000007788 liquid Substances 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
238000002156 mixing Methods 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 2
XLNZEKHULJKQBA-UHFFFAOYSA-N terbufos Chemical compound CCOP(=S)(OCC)SCSC(C)(C)C XLNZEKHULJKQBA-UHFFFAOYSA-N 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 2
KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
QBIAZVPERXOGAL-OWOJBTEDSA-N (e)-prop-1-ene-1,3-diamine Chemical compound NC\C=C\N QBIAZVPERXOGAL-OWOJBTEDSA-N 0.000 description 1
WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
OVBFMUAFNIIQAL-UHFFFAOYSA-N 1,4-diisocyanatobutane Chemical compound O=C=NCCCCN=C=O OVBFMUAFNIIQAL-UHFFFAOYSA-N 0.000 description 1
DFPJRUKWEPYFJT-UHFFFAOYSA-N 1,5-diisocyanatopentane Chemical compound O=C=NCCCCCN=C=O DFPJRUKWEPYFJT-UHFFFAOYSA-N 0.000 description 1
VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
RLYCRLGLCUXUPO-UHFFFAOYSA-N 2,6-diaminotoluene Chemical compound CC1=C(N)C=CC=C1N RLYCRLGLCUXUPO-UHFFFAOYSA-N 0.000 description 1
FZZMTSNZRBFGGU-UHFFFAOYSA-N 2-chloro-7-fluoroquinazolin-4-amine Chemical compound FC1=CC=C2C(N)=NC(Cl)=NC2=C1 FZZMTSNZRBFGGU-UHFFFAOYSA-N 0.000 description 1
UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical compound C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 1
CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
ZMWAXVAETNTVAT-UHFFFAOYSA-N 7-n,8-n,5-triphenylphenazin-5-ium-2,3,7,8-tetramine;chloride Chemical compound [Cl-].C=1C=CC=CC=1NC=1C=C2[N+](C=3C=CC=CC=3)=C3C=C(N)C(N)=CC3=NC2=CC=1NC1=CC=CC=C1 ZMWAXVAETNTVAT-UHFFFAOYSA-N 0.000 description 1
241000238876 Acari Species 0.000 description 1
239000005877 Alpha-Cypermethrin Substances 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
239000005944 Chlorpyrifos Substances 0.000 description 1
239000005946 Cypermethrin Substances 0.000 description 1
RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
241000221785 Erysiphales Species 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
241000233866 Fungi Species 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
241000238631 Hexapoda Species 0.000 description 1
241000237852 Mollusca Species 0.000 description 1
241000244206 Nematoda Species 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
229920000538 Poly[(phenyl isocyanate)-co-formaldehyde] Polymers 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
230000000895 acaricidal effect Effects 0.000 description 1
239000000642 acaricide Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000003619 algicide Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000007798 antifreeze agent Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
229960005424 cypermethrin Drugs 0.000 description 1
FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 1
JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
229910000396 dipotassium phosphate Inorganic materials 0.000 description 1
235000019797 dipotassium phosphate Nutrition 0.000 description 1
YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000013057 ectoparasiticide Substances 0.000 description 1
239000004495 emulsifiable concentrate Substances 0.000 description 1
239000003623 enhancer Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000004088 foaming agent Substances 0.000 description 1
239000000417 fungicide Substances 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
239000011521 glass Substances 0.000 description 1
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
238000006703 hydration reaction Methods 0.000 description 1
150000003840 hydrochlorides Chemical class 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
239000012948 isocyanate Substances 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
229920005611 kraft lignin Polymers 0.000 description 1
230000002045 lasting effect Effects 0.000 description 1
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
239000005645 nematicide Substances 0.000 description 1
238000000399 optical microscopy Methods 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
229960000490 permethrin Drugs 0.000 description 1
230000005501 phase interface Effects 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000005648 plant growth regulator Substances 0.000 description 1
229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
QYMMJNLHFKGANY-UHFFFAOYSA-N profenofos Chemical compound CCCSP(=O)(OCC)OC1=CC=C(Br)C=C1Cl QYMMJNLHFKGANY-UHFFFAOYSA-N 0.000 description 1
MFOUDYKPLGXPGO-UHFFFAOYSA-N propachlor Chemical compound ClCC(=O)N(C(C)C)C1=CC=CC=C1 MFOUDYKPLGXPGO-UHFFFAOYSA-N 0.000 description 1
235000015424 sodium Nutrition 0.000 description 1
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000001273 sulfonato group Chemical class [O-]S(*)(=O)=O 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000000230 xanthan gum Substances 0.000 description 1
229920001285 xanthan gum Polymers 0.000 description 1
229940082509 xanthan gum Drugs 0.000 description 1
235000010493 xanthan gum Nutrition 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
- Y10T428/2987—Addition polymer from unsaturated monomers only

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Dispersion Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Life Sciences & Earth Sciences (AREA)
General Health & Medical Sciences (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Agronomy & Crop Science (AREA)
Plant Pathology (AREA)
Toxicology (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Manufacturing Of Micro-Capsules (AREA)

SK733-96A 1995-06-07 1996-06-06 Producing method of agent in microcapsules form, microcapsules, offenders suppression method and pesticidal agent SK73396A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US08/482,586 US5705174A (en)	1995-06-07	1995-06-07	Process for the preparation of microcapsule compositions

Publications (1)

Publication Number	Publication Date
SK73396A3 true SK73396A3 (en)	1997-02-05

Family

ID=23916642

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK733-96A SK73396A3 (en)	1995-06-07	1996-06-06	Producing method of agent in microcapsules form, microcapsules, offenders suppression method and pesticidal agent

Country Status (19)

Country	Link
US (2)	US5705174A (fr)
EP (1)	EP0747116B1 (fr)
JP (1)	JP4268685B2 (fr)
KR (1)	KR100433160B1 (fr)
AR (1)	AR010198A1 (fr)
AT (1)	ATE206072T1 (fr)
AU (1)	AU722027B2 (fr)
BR (1)	BR9602652A (fr)
CA (1)	CA2178262C (fr)
DE (1)	DE69615453T2 (fr)
DK (1)	DK0747116T3 (fr)
ES (1)	ES2164842T3 (fr)
HU (1)	HU216094B (fr)
NZ (1)	NZ286751A (fr)
PL (1)	PL185843B1 (fr)
PT (1)	PT747116E (fr)
SK (1)	SK73396A3 (fr)
TW (1)	TW398955B (fr)
ZA (1)	ZA964624B (fr)

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US5705174A (en) *	1995-06-07	1998-01-06	American Cyanamid Company	Process for the preparation of microcapsule compositions
JPH09169610A (ja) *	1995-12-20	1997-06-30	Sumitomo Chem Co Ltd	マイクロカプセル化された有害生物防除剤組成物
ES2174127T3 (es) *	1995-12-29	2002-11-01	Ciba Spec Chem Water Treat Ltd	Particulas con una cubierta polimerica y su obtencion.
DE10104991A1 (de) *	2001-02-03	2002-08-08	Clariant Gmbh	Mikroverkapselte biologisch aktive Wirkstoffe enthaltend ein wasserlösliches oder wasserdispergierbares Kammpolymer
PT1524902E (pt) *	2002-07-22	2007-03-30	Basf Corp	Métodos de utilizar compostos de dinitroanilina na forma de formulações de microcapsula
JP4580382B2 (ja) *	2003-04-14	2010-11-10	ビーエーエスエフソシエタス・ヨーロピア	ペンジメタンの水性流動性濃縮組成物
US7101617B2 (en) *	2003-07-10	2006-09-05	Motorola, Inc.	Silicone dispensing with a conformal film
JP4851465B2 (ja)	2004-11-08	2012-01-11	フレッシュポイント・ホールディングス・ソシエテ・アノニム	時間温度指示装置
MY146405A (en) *	2005-03-01	2012-08-15	Basf Ag	Fast-release microcapsule products
RU2291402C1 (ru) *	2005-04-22	2007-01-10	Гоу Впо "Тюменский Государственный Университет"	Способ инкапсулирования порций жидкости в газовые пузырьки
CN101272849A (zh) *	2005-09-23	2008-09-24	巴斯夫欧洲公司	新型农用化学品配制剂
GB0807919D0 (fr)	2008-05-01	2008-06-04	Moorlodge Biotech Ventures Ltd
CN102077060B (zh)	2008-06-04	2014-10-29	G·帕特尔	一种基于腐蚀金属的监测系统
AU2009256212B2 (en)	2008-06-04	2015-12-10	Jp Laboratories Inc.	A monitoring system based on etching of metals
AU2009329535B2 (en) *	2008-12-19	2015-08-13	Basf Se	Aqueous flowable concentrate compositions of a microencapsulated dinitroaniline herbicide
HUE030498T2 (en)	2009-03-20	2017-05-29	Basf Se	A method of treating sowing with an encapsulated pesticide
US9687424B2 (en)	2009-09-18	2017-06-27	International Flavors & Fragrances	Polyurea capsules prepared with aliphatic isocyanates and amines
US9816059B2 (en)	2009-09-18	2017-11-14	International Flavors & Fragrances	Stabilized capsule compositions
US10226405B2 (en)	2009-09-18	2019-03-12	International Flavors & Fragrances Inc.	Purified polyurea capsules, methods of preparation, and products containing the same
US11311467B2 (en)	2009-09-18	2022-04-26	International Flavors & Fragrances Inc.	Polyurea capsules prepared with a polyisocyanate and cross-linking agent
US10085925B2 (en)	2009-09-18	2018-10-02	International Flavors & Fragrances Inc.	Polyurea capsule compositions
PE20130566A1 (es)	2010-01-22	2013-04-28	Basf Se	Un metodo para controlar artropodos, que comprende la aplicacion de un gel en forma de manchas
AU2011212201B2 (en) *	2010-02-03	2014-09-25	Upl Limited	An improved formulation
CN101966441A (zh) *	2010-09-09	2011-02-09	天津大学	聚多巴胺微囊和制备方法
US9241912B2 (en)	2011-01-11	2016-01-26	Basf Se	Agrochemical formulation comprising encapsulated pesticide
JP2014502990A (ja) *	2011-01-24	2014-02-06	ビーエーエスエフソシエタス・ヨーロピア	カプセル化した農薬を含む農薬製剤
MX350838B (es)	2011-02-11	2017-09-18	Grain Proc Corporation *	Composicion de sal.
WO2012130823A1 (fr)	2011-03-30	2012-10-04	Basf Se	Concentrés en suspension
ITMI20110784A1 (it)	2011-05-09	2012-11-10	Sipcam Spa	Processo per l'ottenimento di microcapsule
PY1141124A (es)	2011-08-10	2015-09-01	Upl Ltd	Una formula de herbicida mejorada
IN2014CN00795A (fr)	2011-08-19	2015-04-03	Basf Se
PL2589290T3 (pl)	2011-11-04	2015-04-30	Endura Spa	Mikrokapsułki zawierające pyretroid i/lub neonikotynoid i środek synergizujący
PE20181145A1 (es)	2015-07-24	2018-07-17	Basf Se	Compuestos de piridina
CN107920509A (zh)	2015-09-03	2018-04-17	巴斯夫农业公司	包含苯嘧磺草胺的微粒组合物
CN105875607B (zh) *	2016-05-16	2018-07-03	中国农业大学	一种二甲戊乐灵微囊悬浮剂及其制备方法
US12048755B2 (en)	2018-12-18	2024-07-30	International Flavors & Fragrances Inc.	Microcapsule compositions prepared from polysaccharides
US12303856B2 (en)	2018-12-18	2025-05-20	International Flavors & Fragrances Inc.	Hydroxyethyl cellulose microcapsules
JP7692268B2 (ja) *	2020-02-03	2025-06-13	日本化薬株式会社	マイクロカプセル農薬組成物
EP4011208A1 (fr)	2020-12-08	2022-06-15	BASF Corporation	Compositions de microparticules comprenant du fluopyram
EP4011205A1 (fr)	2020-12-08	2022-06-15	Basf Se	Compositions de microparticules comprenant de la trifludimoxazine
CN119730951A (zh)	2022-08-18	2025-03-28	巴斯夫欧洲公司	用于生产微粒的方法
CN117701255B (zh) *	2024-02-06	2024-04-19	中国石油大学(华东)	一种钻井液降温用相变胶囊及其制备方法与应用

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US4280833A (en) *	1979-03-26	1981-07-28	Monsanto Company	Encapsulation by interfacial polycondensation, and aqueous herbicidal composition containing microcapsules produced thereby
JPS57103891A (en) *	1980-12-19	1982-06-28	Fuji Photo Film Co Ltd	Microcapsule dispersing liquid
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US4640709A (en) *	1984-06-12	1987-02-03	Monsanto Company	High concentration encapsulation by interfacial polycondensation
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US4785048A (en) *	1988-02-08	1988-11-15	Moore Business Forms, Inc.	Polyurea and polyurea-epoxy microcapsules
US5235211A (en) *	1990-06-22	1993-08-10	Digital Equipment Corporation	Semiconductor package having wraparound metallization
DK0551796T3 (da) *	1992-01-03	1998-03-23	Ciba Geigy Ag	Suspension af mikrokapsler og fremgangsmåde til dens fremstiling
EP0619073A3 (fr) *	1993-04-05	1994-10-26	Monsanto Co	Formulations fluides pesticides à base d'eau.
US5705174A (en) *	1995-06-07	1998-01-06	American Cyanamid Company	Process for the preparation of microcapsule compositions

1995
- 1995-06-07 US US08/482,586 patent/US5705174A/en not_active Expired - Lifetime
1996
- 1996-06-04 EP EP96304060A patent/EP0747116B1/fr not_active Expired - Lifetime
- 1996-06-04 ZA ZA9604624A patent/ZA964624B/xx unknown
- 1996-06-04 DK DK96304060T patent/DK0747116T3/da active
- 1996-06-04 AT AT96304060T patent/ATE206072T1/de active
- 1996-06-04 DE DE69615453T patent/DE69615453T2/de not_active Expired - Lifetime
- 1996-06-04 PT PT96304060T patent/PT747116E/pt unknown
- 1996-06-04 ES ES96304060T patent/ES2164842T3/es not_active Expired - Lifetime
- 1996-06-05 PL PL96314633A patent/PL185843B1/pl unknown
- 1996-06-05 KR KR1019960020043A patent/KR100433160B1/ko not_active Expired - Lifetime
- 1996-06-05 NZ NZ286751A patent/NZ286751A/en not_active IP Right Cessation
- 1996-06-05 BR BR9602652A patent/BR9602652A/pt not_active IP Right Cessation
- 1996-06-05 AU AU54719/96A patent/AU722027B2/en not_active Expired
- 1996-06-05 JP JP16532996A patent/JP4268685B2/ja not_active Expired - Lifetime
- 1996-06-05 CA CA002178262A patent/CA2178262C/fr not_active Expired - Lifetime
- 1996-06-06 HU HUP9601555A patent/HU216094B/hu unknown
- 1996-06-06 AR ARP960102995A patent/AR010198A1/es active IP Right Grant
- 1996-06-06 SK SK733-96A patent/SK73396A3/sk unknown
- 1996-08-07 TW TW085109562A patent/TW398955B/zh not_active IP Right Cessation
1997
- 1997-10-07 US US08/946,464 patent/US5910314A/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
HU216094B (hu)	1999-04-28
ZA964624B (en)	1997-12-04
EP0747116B1 (fr)	2001-09-26
HUP9601555A3 (en)	1997-08-28
ES2164842T3 (es)	2002-03-01
HU9601555D0 (en)	1996-08-28
PL185843B1 (pl)	2003-08-29
TW398955B (en)	2000-07-21
PT747116E (pt)	2002-03-28
EP0747116A3 (fr)	1997-04-16
KR100433160B1 (ko)	2004-08-16
DK0747116T3 (da)	2001-11-26
NZ286751A (en)	1997-06-24
CA2178262A1 (fr)	1996-12-08
ATE206072T1 (de)	2001-10-15
CA2178262C (fr)	2006-08-15
US5705174A (en)	1998-01-06
JPH09103669A (ja)	1997-04-22
DE69615453D1 (de)	2001-10-31
AR010198A1 (es)	2000-06-07
AU5471996A (en)	1996-12-19
DE69615453T2 (de)	2002-05-02
PL314633A1 (en)	1996-12-09
BR9602652A (pt)	1998-04-22
JP4268685B2 (ja)	2009-05-27
KR970000032A (ko)	1997-01-21
EP0747116A2 (fr)	1996-12-11
US5910314A (en)	1999-06-08
HUP9601555A2 (en)	1997-05-28
AU722027B2 (en)	2000-07-20

Publication	Publication Date	Title
SK73396A3 (en)	1997-02-05	Producing method of agent in microcapsules form, microcapsules, offenders suppression method and pesticidal agent
EP0823993B1 (fr)	2002-02-13	Microcapsules sensibles au PH.
EP0824313B1 (fr)	2000-08-09	Microcapsules contenant des suspensions de composes biologiquement actifs et d'un photo-protecteur
EP1652433B1 (fr)	2009-11-04	Compositions herbicides
AU678074B2 (en)	1997-05-15	Microcapsules containing suspensions of biologically active compounds
EP0017409B1 (fr)	1983-03-16	Encapsulation par polycondensation interfaciale
AP926A (en)	2001-01-08	Microencapsulated Compositions
US6133197A (en)	2000-10-17	Microencapsulated compositions
SK1362001A3 (en)	2001-10-08	Acid-triggered release microcapsules
TWI581710B (zh)	2017-05-11	農用化學組合物、其製法及用途
EP0619073A2 (fr)	1994-10-12	Formulations fluides pesticides à base d'eau
HRP20000526A2 (en)	2001-06-30	Water-dispersible flake compositions
KR20000015910A (ko)	2000-03-15	마이크로캡슐화된 조성물
CZ2000748A3 (cs)	2000-09-13	Mikrotobolky se snadno nastavitelnými poměry uvolňování
CZ20002827A3 (cs)	2001-03-14	Ve vodě dispergovatelné vločkovité kompozice