SK96297A3 - Amorphous alkaline silicate compounds, manufacturing process thereof and washing or cleaning agent containing the same - Google Patents

Amorphous alkaline silicate compounds, manufacturing process thereof and washing or cleaning agent containing the same Download PDF

Info

Publication number: SK96297A3
Authority: SK; Slovakia
Prior art keywords: weight; alkali metal; alkali; silicate compounds; silicate
Prior art date: 1995-01-18

Application number

SK962-97A

Other languages

English (en)

Slovak (sk)

Inventor

Kathrin Schnepp

Gonzalez Rene-Andres Artiga

Katrin Burmeister

Hubert Freese

Manfred Greger

Bernd Larson

Volker Bauer

Peter Sandkuhler

Wilfried Rahse

Original Assignee

Henkel Kgaa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-01-18

Filing date

1996-01-09

Publication date

1998-01-14

1996-01-09 Application filed by Henkel Kgaa filed Critical Henkel Kgaa

1998-01-14 Publication of SK96297A3 publication Critical patent/SK96297A3/sk

Links

239000012459 cleaning agent Substances 0.000 title claims abstract description 36
150000004760 silicates Chemical class 0.000 title claims abstract description 25
238000005406 washing Methods 0.000 title claims abstract description 16
238000004519 manufacturing process Methods 0.000 title claims description 9
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 31
238000000034 method Methods 0.000 claims abstract description 20
239000007788 liquid Substances 0.000 claims abstract description 17
239000004094 surface-active agent Substances 0.000 claims abstract description 16
239000000126 substance Substances 0.000 claims abstract description 11
125000000129 anionic group Chemical group 0.000 claims abstract description 8
238000012545 processing Methods 0.000 claims abstract description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract 5
229910052681 coesite Inorganic materials 0.000 claims abstract 4
229910052906 cristobalite Inorganic materials 0.000 claims abstract 4
229910052682 stishovite Inorganic materials 0.000 claims abstract 4
229910052905 tridymite Inorganic materials 0.000 claims abstract 4
239000000203 mixture Substances 0.000 claims description 155
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 76
239000003599 detergent Substances 0.000 claims description 54
239000003945 anionic surfactant Substances 0.000 claims description 43
-1 alkylbenzene sulfonates Chemical class 0.000 claims description 34
239000010457 zeolite Substances 0.000 claims description 34
239000002736 nonionic surfactant Substances 0.000 claims description 32
229910021536 Zeolite Inorganic materials 0.000 claims description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
238000004140 cleaning Methods 0.000 claims description 20
238000002360 preparation method Methods 0.000 claims description 13
238000001125 extrusion Methods 0.000 claims description 11
238000001694 spray drying Methods 0.000 claims description 11
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 10
229910052783 alkali metal Inorganic materials 0.000 claims description 10
150000001875 compounds Chemical class 0.000 claims description 9
238000005201 scrubbing Methods 0.000 claims description 8
150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 8
150000001340 alkali metals Chemical group 0.000 claims description 7
239000008187 granular material Substances 0.000 claims description 7
238000010521 absorption reaction Methods 0.000 claims description 6
239000004480 active ingredient Substances 0.000 claims description 6
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 5
150000008041 alkali metal carbonates Chemical class 0.000 claims description 5
239000007900 aqueous suspension Substances 0.000 claims description 4
238000005469 granulation Methods 0.000 claims description 4
230000003179 granulation Effects 0.000 claims description 4
229920003023 plastic Polymers 0.000 claims description 2
239000004033 plastic Substances 0.000 claims description 2
229910004298 SiO 2 Inorganic materials 0.000 claims 1
239000008247 solid mixture Substances 0.000 claims 1
235000012239 silicon dioxide Nutrition 0.000 abstract description 6
229910052751 metal Inorganic materials 0.000 abstract description 2
239000002184 metal Substances 0.000 abstract description 2
239000000470 constituent Substances 0.000 abstract 1
239000000377 silicon dioxide Substances 0.000 abstract 1
235000002639 sodium chloride Nutrition 0.000 description 28
150000003839 salts Chemical class 0.000 description 25
150000002191 fatty alcohols Chemical class 0.000 description 22
239000000194 fatty acid Substances 0.000 description 21
235000014113 dietary fatty acids Nutrition 0.000 description 20
229930195729 fatty acid Natural products 0.000 description 20
150000004665 fatty acids Chemical class 0.000 description 16
239000002253 acid Substances 0.000 description 12
239000004615 ingredient Substances 0.000 description 11
239000000047 product Substances 0.000 description 11
102000004190 Enzymes Human genes 0.000 description 10
108090000790 Enzymes Proteins 0.000 description 10
108091005804 Peptidases Proteins 0.000 description 10
102000035195 Peptidases Human genes 0.000 description 10
239000004365 Protease Substances 0.000 description 10
125000004432 carbon atom Chemical group C* 0.000 description 10
229940088598 enzyme Drugs 0.000 description 10
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 9
239000002671 adjuvant Substances 0.000 description 9
238000001035 drying Methods 0.000 description 9
239000000843 powder Substances 0.000 description 9
239000011734 sodium Substances 0.000 description 9
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
150000001298 alcohols Chemical class 0.000 description 8
239000003112 inhibitor Substances 0.000 description 8
229910052708 sodium Inorganic materials 0.000 description 8
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 7
159000000000 sodium salts Chemical class 0.000 description 7
239000003760 tallow Substances 0.000 description 7
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
239000004367 Lipase Substances 0.000 description 6
102000004882 Lipase Human genes 0.000 description 6
108090001060 Lipase Proteins 0.000 description 6
229920002472 Starch Polymers 0.000 description 6
150000007513 acids Chemical class 0.000 description 6
150000008051 alkyl sulfates Chemical class 0.000 description 6
239000002585 base Substances 0.000 description 6
239000007844 bleaching agent Substances 0.000 description 6
235000019421 lipase Nutrition 0.000 description 6
239000000344 soap Substances 0.000 description 6
235000019698 starch Nutrition 0.000 description 6
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 5
230000000694 effects Effects 0.000 description 5
239000006260 foam Substances 0.000 description 5
229920005646 polycarboxylate Polymers 0.000 description 5
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 5
229910000029 sodium carbonate Inorganic materials 0.000 description 5
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 5
239000007787 solid Substances 0.000 description 5
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
102000005575 Cellulases Human genes 0.000 description 4
108010084185 Cellulases Proteins 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 4
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
239000012190 activator Substances 0.000 description 4
239000000654 additive Substances 0.000 description 4
125000005907 alkyl ester group Chemical group 0.000 description 4
125000000217 alkyl group Chemical group 0.000 description 4
150000004649 carbonic acid derivatives Chemical class 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
238000009826 distribution Methods 0.000 description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
239000011976 maleic acid Substances 0.000 description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000000546 pharmaceutical excipient Substances 0.000 description 4
235000021317 phosphate Nutrition 0.000 description 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
239000007921 spray Substances 0.000 description 4
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
102000013142 Amylases Human genes 0.000 description 3
108010065511 Amylases Proteins 0.000 description 3
244000060011 Cocos nucifera Species 0.000 description 3
235000013162 Cocos nucifera Nutrition 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
235000019418 amylase Nutrition 0.000 description 3
229940025131 amylases Drugs 0.000 description 3
239000004305 biphenyl Substances 0.000 description 3
239000000969 carrier Substances 0.000 description 3
229920003086 cellulose ether Polymers 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000004090 dissolution Methods 0.000 description 3
239000007789 gas Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
239000003921 oil Substances 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
229920001296 polysiloxane Polymers 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
239000011591 potassium Substances 0.000 description 3
235000019353 potassium silicate Nutrition 0.000 description 3
150000003138 primary alcohols Chemical class 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
239000008107 starch Substances 0.000 description 3
229910021653 sulphate ion Inorganic materials 0.000 description 3
239000000725 suspension Substances 0.000 description 3
238000012360 testing method Methods 0.000 description 3
XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
108010010803 Gelatin Proteins 0.000 description 2
239000004594 Masterbatch (MB) Substances 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
239000002202 Polyethylene glycol Substances 0.000 description 2
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
125000003342 alkenyl group Chemical group 0.000 description 2
235000010290 biphenyl Nutrition 0.000 description 2
125000006267 biphenyl group Chemical group 0.000 description 2
238000004061 bleaching Methods 0.000 description 2
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
235000013539 calcium stearate Nutrition 0.000 description 2
239000008116 calcium stearate Substances 0.000 description 2
239000003093 cationic surfactant Substances 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 2
DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 2
238000002003 electron diffraction Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
229920000159 gelatin Polymers 0.000 description 2
239000008273 gelatin Substances 0.000 description 2
235000019322 gelatine Nutrition 0.000 description 2
235000011852 gelatine desserts Nutrition 0.000 description 2
LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
239000003607 modifier Substances 0.000 description 2
150000004682 monohydrates Chemical class 0.000 description 2
230000007935 neutral effect Effects 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
229920006324 polyoxymethylene Polymers 0.000 description 2
229920000036 polyvinylpyrrolidone Polymers 0.000 description 2
239000001267 polyvinylpyrrolidone Substances 0.000 description 2
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 2
229910000027 potassium carbonate Inorganic materials 0.000 description 2
159000000001 potassium salts Chemical class 0.000 description 2
229920006395 saturated elastomer Polymers 0.000 description 2
229910000077 silane Inorganic materials 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
238000005507 spraying Methods 0.000 description 2
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
229920001897 terpolymer Polymers 0.000 description 2
HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
239000004753 textile Substances 0.000 description 2
239000001993 wax Substances 0.000 description 2
SWMBOMMGMHMOHE-MHLULTLJSA-N (2r,3r,4r,5r)-hexane-1,2,3,4,5,6-hexol;(2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO SWMBOMMGMHMOHE-MHLULTLJSA-N 0.000 description 1
ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
LYPVKWMHGFMDPD-UHFFFAOYSA-N 1,5-diacetyl-1,3,5-triazinane-2,4-dione Chemical compound CC(=O)N1CN(C(C)=O)C(=O)NC1=O LYPVKWMHGFMDPD-UHFFFAOYSA-N 0.000 description 1
DHLFKRNCGLBPRR-UHFFFAOYSA-N 1-methyl-2-phenylhydrazine Chemical compound CNNC1=CC=CC=C1 DHLFKRNCGLBPRR-UHFFFAOYSA-N 0.000 description 1
ASUDFOJKTJLAIK-UHFFFAOYSA-N 2-methoxyethanamine Chemical compound COCCN ASUDFOJKTJLAIK-UHFFFAOYSA-N 0.000 description 1
LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 1
VKELSQNRSVJHGR-UHFFFAOYSA-N 4-oxo-4-sulfooxybutanoic acid Chemical compound OC(=O)CCC(=O)OS(O)(=O)=O VKELSQNRSVJHGR-UHFFFAOYSA-N 0.000 description 1
REJHVSOVQBJEBF-OWOJBTEDSA-N 5-azaniumyl-2-[(e)-2-(4-azaniumyl-2-sulfonatophenyl)ethenyl]benzenesulfonate Chemical class OS(=O)(=O)C1=CC(N)=CC=C1\C=C\C1=CC=C(N)C=C1S(O)(=O)=O REJHVSOVQBJEBF-OWOJBTEDSA-N 0.000 description 1
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
BNDRECGBDISUAI-UHFFFAOYSA-N 6-(2-phenylethenyl)cyclohexa-2,4-diene-1,1-disulfonic acid Chemical class OS(=O)(=O)C1(S(O)(=O)=O)C=CC=CC1C=CC1=CC=CC=C1 BNDRECGBDISUAI-UHFFFAOYSA-N 0.000 description 1
229920002126 Acrylic acid copolymer Polymers 0.000 description 1
229910011255 B2O3 Inorganic materials 0.000 description 1
241000193422 Bacillus lentus Species 0.000 description 1
241000194108 Bacillus licheniformis Species 0.000 description 1
244000063299 Bacillus subtilis Species 0.000 description 1
235000014469 Bacillus subtilis Nutrition 0.000 description 1
235000021357 Behenic acid Nutrition 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
241000233866 Fungi Species 0.000 description 1
229920001503 Glucan Polymers 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
229910003544 H2B4O7 Inorganic materials 0.000 description 1
241001480714 Humicola insolens Species 0.000 description 1
229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
229930195725 Mannitol Natural products 0.000 description 1
YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical group C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 1
102000004316 Oxidoreductases Human genes 0.000 description 1
108090000854 Oxidoreductases Proteins 0.000 description 1
239000004435 Oxo alcohol Substances 0.000 description 1
239000005662 Paraffin oil Substances 0.000 description 1
108700020962 Peroxidase Proteins 0.000 description 1
102000003992 Peroxidases Human genes 0.000 description 1
229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
229920000805 Polyaspartic acid Polymers 0.000 description 1
239000004280 Sodium formate Substances 0.000 description 1
229920002125 Sokalan® Polymers 0.000 description 1
108090000787 Subtilisin Proteins 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
238000005903 acid hydrolysis reaction Methods 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000010933 acylation Effects 0.000 description 1
238000005917 acylation reaction Methods 0.000 description 1
125000004423 acyloxy group Chemical group 0.000 description 1
125000003158 alcohol group Chemical group 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000003973 alkyl amines Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
230000001580 bacterial effect Effects 0.000 description 1
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
229940077388 benzenesulfonate Drugs 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
235000010338 boric acid Nutrition 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
229960002645 boric acid Drugs 0.000 description 1
150000001639 boron compounds Chemical class 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
235000011089 carbon dioxide Nutrition 0.000 description 1
229960004424 carbon dioxide Drugs 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
239000008112 carboxymethyl-cellulose Substances 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
235000010980 cellulose Nutrition 0.000 description 1
229960000541 cetyl alcohol Drugs 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
238000000576 coating method Methods 0.000 description 1
229940096386 coconut alcohol Drugs 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
239000013065 commercial product Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
238000007257 deesterification reaction Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
238000007922 dissolution test Methods 0.000 description 1
UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 1
LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
239000004744 fabric Substances 0.000 description 1
239000003925 fat Substances 0.000 description 1
235000019387 fatty acid methyl ester Nutrition 0.000 description 1
125000000373 fatty alcohol group Chemical group 0.000 description 1
239000000835 fiber Substances 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000000174 gluconic acid Substances 0.000 description 1
235000012208 gluconic acid Nutrition 0.000 description 1
239000008103 glucose Substances 0.000 description 1
229930182470 glycoside Natural products 0.000 description 1
229940015043 glyoxal Drugs 0.000 description 1
238000000227 grinding Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 description 1
229910052739 hydrogen Chemical group 0.000 description 1
239000001257 hydrogen Chemical group 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
239000008011 inorganic excipient Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
238000004900 laundering Methods 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
150000002689 maleic acids Chemical class 0.000 description 1
239000000594 mannitol Substances 0.000 description 1
235000010355 mannitol Nutrition 0.000 description 1
238000002844 melting Methods 0.000 description 1
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
239000004200 microcrystalline wax Substances 0.000 description 1
235000019808 microcrystalline wax Nutrition 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
239000000178 monomer Substances 0.000 description 1
229940043348 myristyl alcohol Drugs 0.000 description 1
GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
SXLLDUPXUVRMEE-UHFFFAOYSA-N nonanediperoxoic acid Chemical compound OOC(=O)CCCCCCCC(=O)OO SXLLDUPXUVRMEE-UHFFFAOYSA-N 0.000 description 1
235000014593 oils and fats Nutrition 0.000 description 1
229940055577 oleyl alcohol Drugs 0.000 description 1
XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
238000006384 oligomerization reaction Methods 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
239000008012 organic excipient Substances 0.000 description 1
150000004967 organic peroxy acids Chemical class 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
239000004584 polyacrylic acid Substances 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
230000002028 premature Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
238000006268 reductive amination reaction Methods 0.000 description 1
238000009490 roller compaction Methods 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
239000002002 slurry Substances 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
235000019254 sodium formate Nutrition 0.000 description 1
239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical group OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
238000009736 wetting Methods 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/02—Preparation in the form of powder by spray drying

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Dental Preparations (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)

SK962-97A 1995-01-18 1996-01-09 Amorphous alkaline silicate compounds, manufacturing process thereof and washing or cleaning agent containing the same SK96297A3 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19501269A DE19501269A1 (de)	1995-01-18	1995-01-18	Amorphes Alkalisilikat-Compound
PCT/EP1996/000063 WO1996022349A1 (fr)	1995-01-18	1996-01-09	Compose silicate alcalin amorphe

Publications (1)

Publication Number	Publication Date
SK96297A3 true SK96297A3 (en)	1998-01-14

Family

ID=7751688

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK962-97A SK96297A3 (en)	1995-01-18	1996-01-09	Amorphous alkaline silicate compounds, manufacturing process thereof and washing or cleaning agent containing the same

Country Status (15)

Country	Link
US (2)	US6191096B1 (fr)
EP (1)	EP0804529B1 (fr)
JP (1)	JPH10512321A (fr)
KR (1)	KR19980701494A (fr)
CN (1)	CN1168154A (fr)
AT (1)	ATE190645T1 (fr)
CZ (1)	CZ226797A3 (fr)
DE (2)	DE19501269A1 (fr)
ES (1)	ES2144721T3 (fr)
HU (1)	HUP9702001A3 (fr)
PL (1)	PL324033A1 (fr)
PT (1)	PT804529E (fr)
RU (1)	RU2168542C2 (fr)
SK (1)	SK96297A3 (fr)
WO (1)	WO1996022349A1 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE19501269A1 (de) *	1995-01-18	1996-07-25	Henkel Kgaa	Amorphes Alkalisilikat-Compound
DE19525378A1 (de) *	1995-07-12	1997-01-16	Henkel Kgaa	Amorphes Alkalisilicat-Compound
DE19529908A1 (de) *	1995-08-15	1997-02-20	Henkel Kgaa	Verfahren zur Herstellung eines amorphen Alkalisilikats mit Imprägnierung
DE19533790A1 (de) *	1995-09-13	1997-03-20	Henkel Kgaa	Verfahren zur Herstellung eines amorphen Alkalisilikats mit Imprägnierung
DE19700775A1 (de) *	1997-01-13	1998-07-16	Henkel Kgaa	Verfahren zur Herstellung aniontensidhaltiger wasch- und reinigungsaktiver Tensidgranulate
DE19953792A1 (de) *	1999-11-09	2001-05-17	Cognis Deutschland Gmbh	Waschmitteltabletten
WO2003022085A2 (fr) *	2001-09-13	2003-03-20	Daniel James Plant	Materiau souple absorbant l'energie et procedes de fabrication associes
DE10161597B4 (de)	2001-12-14	2005-10-20	Celanese Chem Europe Gmbh	Verfahren zur Reinigung alicyclischer Alkohole
US20030203832A1 (en) *	2002-04-26	2003-10-30	The Procter & Gamble Company	Low organic spray drying process and composition formed thereby
GB0221430D0 (en) *	2002-09-16	2002-10-23	Ineos Silicas Ltd	Powder coating compositions
RU2006138054A (ru) *	2004-03-30	2008-05-10	Смиткайн Бичам Корпорейшн (Us)	Высушенные распылением фармацевтические композиции
US20060178289A1 (en) *	2004-07-20	2006-08-10	Enrique Hernandez	Multifunctional material compositions and methods
US20060019865A1 (en) *	2004-07-20	2006-01-26	Enrique Hernandez	Methods and compositions of multifunctional detergent components
US20070161539A1 (en) *	2006-01-12	2007-07-12	Enrique Hernandez	Method of regulating degree of polymerization of an alkali metal silicate in solution using pH
US20150182960A1 (en) *	2013-12-31	2015-07-02	Ecowater Systems Llc	Zeolite regeneration

Family Cites Families (41)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3234258A (en)	1963-06-20	1966-02-08	Procter & Gamble	Sulfation of alpha olefins
US3838193A (en)	1971-03-13	1974-09-24	Kawasaki Heavy Ind Ltd	Method of treating nitrogen oxide generating substances by combustion
US3879527A (en)	1971-10-28	1975-04-22	Huber Corp J M	Alkali metal polysilicates and their production
US3838192A (en)	1971-10-28	1974-09-24	Huber Corp J M	Production of alkali metal polysilicates
US4006110A (en)	1971-11-30	1977-02-01	Colgate-Palmolive Company	Manufacture of free-flowing particulate heavy duty synthetic detergent composition
US3956467A (en)	1974-06-07	1976-05-11	Bertorelli Orlando L	Process for producing alkali metal polysilicates
JPS6018717B2 (ja) *	1976-05-18	1985-05-11	ライオン株式会社	粒状洗剤組成物
JPS6059280B2 (ja) *	1976-07-09	1985-12-24	ライオン株式会社	粒状洗剤組成物の製造方法
US4129526A (en)	1977-07-14	1978-12-12	The Lion Fat & Oil Co., Ltd.	Granular detergent compositions and a process for producing same
DE3209631A1 (de) *	1982-03-17	1983-09-29	Degussa Ag, 6000 Frankfurt	Waessrige stabile suspension wasserunloeslicher, zum binden von calciumionen befaehigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln
JPS58217598A (ja)	1982-06-10	1983-12-17	日本油脂株式会社	洗剤組成物
DE3413571A1 (de)	1984-04-11	1985-10-24	Hoechst Ag, 6230 Frankfurt	Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
AU597909B2 (en)	1985-10-09	1990-06-14	Procter & Gamble Company, The	Granular detergent compositions having improved solubility
DE3706036A1 (de)	1987-02-25	1988-09-08	Basf Ag	Polyacetale, verfahren zu deren herstellung aus dialdehyden und polyolcarbonsaeuren und verwendung der polyacetale
DE3914131A1 (de)	1989-04-28	1990-10-31	Henkel Kgaa	Verwendung von calcinierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung von fettsaeureestern
DE4010533A1 (de)	1990-04-02	1991-10-10	Henkel Kgaa	Tablettierte wasch- und/oder reinigungsmittel fuer haushalt und gewerbe und verfahren zu ihrer herstellung
DK0486592T3 (da) *	1989-08-09	1994-07-18	Henkel Kgaa	Fremstilling af kompakterede granulater til vaskemidler
US5075041A (en)	1990-06-28	1991-12-24	Shell Oil Company	Process for the preparation of secondary alcohol sulfate-containing surfactant compositions
ATE134381T1 (de)	1990-11-30	1996-03-15	Rhone Poulenc Chimie	Gerüststoff auf basis von alkalimetallsilikaten für reinigungsmittelzusammensetzungen
ATE133637T1 (de)	1991-07-02	1996-02-15	Crosfield Joseph & Sons	Silicate
DE4124701A1 (de)	1991-07-25	1993-01-28	Henkel Kgaa	Verfahren zur herstellung fester wasch- und reinigungsmittel mit hohem schuettgewicht und verbesserter loesegeschwindigkeit
ATE155165T1 (de)	1991-07-31	1997-07-15	Ausimont Spa	Verfahren zur erhöhung der bleichwirksamkeit eines inorganischen persalzes
DE4134914A1 (de)	1991-10-23	1993-04-29	Henkel Kgaa	Wasch- und reinigungsmittel mit ausgewaehlten builder-systemen
IT1252682B (it)	1991-11-13	1995-06-23	Vomm Impianti & Processi Srl	Prodotto in granuli di elevato peso specifico, particolarmente quale additivo di detersivi in polvere e metodo per il suo ottenimento
DE4221381C1 (de)	1992-07-02	1994-02-10	Stockhausen Chem Fab Gmbh	Pfropf-Copolymerisate von ungesättigten Monomeren und Zuckern, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4203031A1 (de)	1992-02-04	1993-08-05	Henkel Kgaa	Verfahren zur herstellung fester wasch- und reinigungsmittel mit hohem schuettgewicht und verbesserter loesegeschwindigkeit
DE4203923A1 (de)	1992-02-11	1993-08-12	Henkel Kgaa	Verfahren zur herstellung von polycarboxylaten auf polysaccharid-basis
FR2688798B1 (fr)	1992-03-20	1994-10-14	Rhobb Poulenc Chimie	Agent "builder" a base de silicate et d'un produit mineral.
DE4216775A1 (de) *	1992-05-21	1993-11-25	Henkel Kgaa	Pulverförmige Tensidmischung
DE4235646A1 (de)	1992-10-22	1994-04-28	Henkel Kgaa	Verfahren zur Herstellung wasch- und reinigungsaktiver Extrudate
DE4300772C2 (de)	1993-01-14	1997-03-27	Stockhausen Chem Fab Gmbh	Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4303320C2 (de)	1993-02-05	1995-12-21	Degussa	Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür
EP0651050A1 (fr)	1993-11-03	1995-05-03	The Procter & Gamble Company	Agglomérat de tensioactifs en forme de particule
DE4400024A1 (de) *	1994-01-03	1995-07-06	Henkel Kgaa	Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet
DE4405511A1 (de) *	1994-02-22	1995-08-24	Henkel Kgaa	Waschmittel mit amorphen silikatischen Buildersubstanzen
DE4406592A1 (de) *	1994-03-01	1995-09-07	Henkel Kgaa	Verbesserte Mehrstoffgemische auf Basis wasserlöslicher Alkalisilikatverbindungen und ihre Verwendung, insbesondere zum Einsatz als Builder in Wasch- und Reinigungsmitteln
DE4415362A1 (de) *	1994-05-02	1995-11-09	Henkel Kgaa	Verfahren zur Herstellung silikatischer Buildergranulate mit erhöhtem Schüttgewicht
DE4417734A1 (de)	1994-05-20	1995-11-23	Degussa	Polycarboxylate
DE4419745A1 (de)	1994-06-06	1995-12-07	Henkel Kgaa	Granuliertes wasserlösliches kieselsäurehaltiges Alkalisilicat
DE19501269A1 (de) *	1995-01-18	1996-07-25	Henkel Kgaa	Amorphes Alkalisilikat-Compound
DE19525378A1 (de) *	1995-07-12	1997-01-16	Henkel Kgaa	Amorphes Alkalisilicat-Compound

1995
- 1995-01-18 DE DE19501269A patent/DE19501269A1/de not_active Withdrawn
1996
- 1996-01-09 US US08/875,232 patent/US6191096B1/en not_active Expired - Lifetime
- 1996-01-09 HU HU9702001A patent/HUP9702001A3/hu unknown
- 1996-01-09 RU RU97113710/04A patent/RU2168542C2/ru active
- 1996-01-09 ES ES96900573T patent/ES2144721T3/es not_active Expired - Lifetime
- 1996-01-09 WO PCT/EP1996/000063 patent/WO1996022349A1/fr not_active Ceased
- 1996-01-09 DE DE59604687T patent/DE59604687D1/de not_active Expired - Lifetime
- 1996-01-09 SK SK962-97A patent/SK96297A3/sk unknown
- 1996-01-09 PL PL96324033A patent/PL324033A1/xx unknown
- 1996-01-09 EP EP96900573A patent/EP0804529B1/fr not_active Expired - Lifetime
- 1996-01-09 KR KR1019970704885A patent/KR19980701494A/ko not_active Ceased
- 1996-01-09 CN CN96191455A patent/CN1168154A/zh active Pending
- 1996-01-09 CZ CZ972267A patent/CZ226797A3/cs unknown
- 1996-01-09 JP JP8522010A patent/JPH10512321A/ja active Pending
- 1996-01-09 AT AT96900573T patent/ATE190645T1/de not_active IP Right Cessation
- 1996-01-09 PT PT96900573T patent/PT804529E/pt unknown
2000
- 2000-12-11 US US09/734,052 patent/US6458755B2/en not_active Expired - Lifetime

Also Published As

Publication number	Publication date
RU2168542C2 (ru)	2001-06-10
EP0804529B1 (fr)	2000-03-15
US6191096B1 (en)	2001-02-20
DE59604687D1 (de)	2000-04-20
PL324033A1 (en)	1998-05-11
US20020002130A1 (en)	2002-01-03
EP0804529A1 (fr)	1997-11-05
JPH10512321A (ja)	1998-11-24
ATE190645T1 (de)	2000-04-15
DE19501269A1 (de)	1996-07-25
WO1996022349A1 (fr)	1996-07-25
KR19980701494A (ko)	1998-05-15
US6458755B2 (en)	2002-10-01
PT804529E (pt)	2000-09-29
CN1168154A (zh)	1997-12-17
HUP9702001A2 (hu)	1998-03-02
ES2144721T3 (es)	2000-06-16
CZ226797A3 (cs)	1998-03-18
HUP9702001A3 (en)	1999-03-01

Publication	Publication Date	Title
KR100416832B1 (ko)	2004-07-22	함침된무정형의알칼리금속실리케이트의제조방법
US5616550A (en)	1997-04-01	Process for the continuous production of a granular detergent
US4925585A (en)	1990-05-15	Detergent granules from cold dough using fine dispersion granulation
US5866531A (en)	1999-02-02	Process for the production of detergent or cleaning tablets
US5798328A (en)	1998-08-25	Detergent composition comprising carbonate-amorphous silicate compound as builder and processes of using same
JP2001500557A (ja)	2001-01-16	粒状洗浄または清浄剤の製法
SK96297A3 (en)	1998-01-14	Amorphous alkaline silicate compounds, manufacturing process thereof and washing or cleaning agent containing the same
US5668100A (en)	1997-09-16	Detergent mixtures and detergents or cleaning formulations with improved dissolving properties
US20070225197A1 (en)	2007-09-27	Method for Producing Granules and the Use Thereof in Washing and/or Cleaning Agents
JP3841431B2 (ja)	2006-11-01	噴霧乾燥洗剤またはその成分
JPH08504458A (ja)	1996-05-14	高い界面活性剤含量を有する顆粒洗剤
US6034050A (en)	2000-03-07	Amorphous alkali metal silicate compound
DE19637606A1 (de)	1998-03-26	Bruchfeste Wasch- oder Reinigungsmittelformkörper
EP0793708B1 (fr)	1999-01-13	Procede de preparation par extrusion d' agents de lavage ou de nettoyage contenant des adjuvants de lavage hydrosolubles
SK79897A3 (en)	1998-02-04	Impregnated amorphous alkaline silicate
KR19990036368A (ko)	1999-05-25	함침에 의한 무정형 알칼리 실리케이트의 제조 방법
JPH09504046A (ja)	1997-04-22	向上した再分散性を有する洗浄活性または清浄活性押出物の製造方法
EP0919614B1 (fr)	2003-10-01	Procédé de production des compositions détergentes à haute densité
CA2300786A1 (fr)	2000-09-16	Granules de surfactant anionique
JP2002510342A (ja)	2002-04-02	清浄性能を向上した洗浄または清浄剤
CZ104097A3 (cs)	1998-06-17	Prací a čisticí prostředek