SU577965A3 - Способ получени алкенилбензолов - Google Patents

Способ получени алкенилбензолов

Info

Publication number: SU577965A3
Authority: SU; USSR - Soviet Union
Prior art keywords: reaction; catalyst; yield; product; liquid
Prior art date: 1973-02-19

Application number

SU7301959303A

Other languages

English (en)

Russian (ru)

Inventor

Сима Такео

Урасаки Таканори

Омаи Ивао

Original Assignee

Тейдзин Лимитед (Фирма)

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-02-19

Filing date

1973-09-21

Publication date

1977-10-25

1973-09-21 Application filed by Тейдзин Лимитед (Фирма) filed Critical Тейдзин Лимитед (Фирма)

1977-10-25 Application granted granted Critical

1977-10-25 Publication of SU577965A3 publication Critical patent/SU577965A3/ru

Links

238000000034 method Methods 0.000 title claims description 12
-1 alkenyl benzenes Chemical class 0.000 title description 2
238000006243 chemical reaction Methods 0.000 claims description 28
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 22
239000003054 catalyst Substances 0.000 claims description 19
239000000047 product Substances 0.000 claims description 19
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 18
229910052708 sodium Inorganic materials 0.000 claims description 18
239000011734 sodium Substances 0.000 claims description 18
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 17
229910052700 potassium Inorganic materials 0.000 claims description 17
239000011591 potassium Substances 0.000 claims description 17
239000007788 liquid Substances 0.000 claims description 15
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
239000000956 alloy Substances 0.000 claims description 8
229910045601 alloy Inorganic materials 0.000 claims description 8
239000011541 reaction mixture Substances 0.000 claims description 8
229910052751 metal Inorganic materials 0.000 claims description 7
239000002184 metal Substances 0.000 claims description 7
239000008096 xylene Substances 0.000 claims description 6
239000007795 chemical reaction product Substances 0.000 claims description 5
238000010924 continuous production Methods 0.000 claims description 5
238000003756 stirring Methods 0.000 claims description 5
239000012295 chemical reaction liquid Substances 0.000 claims description 4
238000010438 heat treatment Methods 0.000 claims description 3
238000010992 reflux Methods 0.000 claims description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
238000002156 mixing Methods 0.000 claims description 2
239000001301 oxygen Substances 0.000 claims description 2
229910052760 oxygen Inorganic materials 0.000 claims description 2
230000035484 reaction time Effects 0.000 claims description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
238000004821 distillation Methods 0.000 claims 4
229940078552 o-xylene Drugs 0.000 claims 4
238000009835 boiling Methods 0.000 claims 3
238000002474 experimental method Methods 0.000 claims 3
239000000203 mixture Substances 0.000 claims 3
239000007789 gas Substances 0.000 claims 2
229910052757 nitrogen Inorganic materials 0.000 claims 2
239000000725 suspension Substances 0.000 claims 2
241001026509 Kata Species 0.000 claims 1
238000003723 Smelting Methods 0.000 claims 1
229910052783 alkali metal Inorganic materials 0.000 claims 1
150000001340 alkali metals Chemical class 0.000 claims 1
230000029936 alkylation Effects 0.000 claims 1
238000005804 alkylation reaction Methods 0.000 claims 1
238000007664 blowing Methods 0.000 claims 1
230000003197 catalytic effect Effects 0.000 claims 1
238000004587 chromatography analysis Methods 0.000 claims 1
238000004140 cleaning Methods 0.000 claims 1
238000001816 cooling Methods 0.000 claims 1
238000001914 filtration Methods 0.000 claims 1
238000004817 gas chromatography Methods 0.000 claims 1
229910052738 indium Inorganic materials 0.000 claims 1
230000003993 interaction Effects 0.000 claims 1
238000011068 loading method Methods 0.000 claims 1
125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 claims 1
QMMOXUPEWRXHJS-UHFFFAOYSA-N pentene-2 Natural products CCC=CC QMMOXUPEWRXHJS-UHFFFAOYSA-N 0.000 claims 1
230000008929 regeneration Effects 0.000 claims 1
238000011069 regeneration method Methods 0.000 claims 1
238000005292 vacuum distillation Methods 0.000 claims 1
239000002699 waste material Substances 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000004996 alkyl benzenes Chemical class 0.000 description 3
FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000000969 carrier Substances 0.000 description 2
235000019441 ethanol Nutrition 0.000 description 2
UOHMMEJUHBCKEE-UHFFFAOYSA-N prehnitene Chemical compound CC1=CC=C(C)C(C)=C1C UOHMMEJUHBCKEE-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical class [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000011437 continuous method Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical class [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000003863 metallic catalyst Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
150000003112 potassium compounds Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/72—Addition to a non-aromatic carbon atom of hydrocarbons containing a six-membered aromatic ring
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

SU7301959303A 1973-02-19 1973-09-21 Способ получени алкенилбензолов SU577965A3 (ru)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP1918073A JPS5634570B2 (fr)	1973-02-19	1973-02-19

Publications (1)

Publication Number	Publication Date
SU577965A3 true SU577965A3 (ru)	1977-10-25

Family

ID=11992135

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SU7301959303A SU577965A3 (ru)	1973-02-19	1973-09-21	Способ получени алкенилбензолов

Country Status (8)

Country	Link
JP (1)	JPS5634570B2 (fr)
BE (1)	BE803710A (fr)
CA (1)	CA1017364A (fr)
FR (1)	FR2218309B1 (fr)
GB (1)	GB1434399A (fr)
IT (1)	IT1006600B (fr)
NL (1)	NL161735C (fr)
SU (1)	SU577965A3 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP3317614B2 (ja) *	1995-08-30	2002-08-26	新日本石油株式会社	モノアルケニルベンゼンの製造方法

1973
- 1973-02-19 JP JP1918073A patent/JPS5634570B2/ja not_active Expired
- 1973-08-16 GB GB3885173A patent/GB1434399A/en not_active Expired
- 1973-08-17 BE BE134667A patent/BE803710A/fr unknown
- 1973-08-20 IT IT2800173A patent/IT1006600B/it active
- 1973-09-21 SU SU7301959303A patent/SU577965A3/ru active
- 1973-09-26 FR FR7334509A patent/FR2218309B1/fr not_active Expired
- 1973-09-28 NL NL7313400A patent/NL161735C/xx not_active IP Right Cessation
- 1973-12-18 CA CA188,412A patent/CA1017364A/en not_active Expired

Also Published As

Publication number	Publication date
GB1434399A (en)	1976-05-05
JPS5634570B2 (fr)	1981-08-11
JPS49132017A (fr)	1974-12-18
FR2218309A1 (fr)	1974-09-13
CA1017364A (en)	1977-09-13
DE2342043B2 (de)	1977-06-23
NL161735C (nl)	1980-03-17
FR2218309B1 (fr)	1976-07-09
DE2342043A1 (de)	1974-08-22
BE803710A (fr)	1973-12-17
NL161735B (nl)	1979-10-15
NL7313400A (fr)	1974-08-21
IT1006600B (it)	1976-10-20

Publication	Publication Date	Title
RU2121992C1 (ru)	1998-11-20	Способ получения 1,1,1-трихлортрифторэтана
JP4377234B2 (ja)	2009-12-02	アリルアルコールの異性化方法
JPH0320372B2 (fr)	1991-03-19
US4138437A (en)	1979-02-06	Process for the preparation of tertiary aliphatic amines
SU577965A3 (ru)	1977-10-25	Способ получени алкенилбензолов
JPH07188117A (ja)	1995-07-25	Ｃｕ触媒使用ジメチルカーボネート製造で得られる液状反応生成物の処理方法
SU953985A3 (ru)	1982-08-23	Способ получени алюминиево-галоидного комплекса
JPH04230226A (ja)	1992-08-19	接触的アルケニルベンゼン環化
ES8307692A1 (es)	1983-08-01	Procedimiento para la preparacion de 1,2-dicloroetano.
EP0191120A1 (fr)	1986-08-20	Isomérisation de crésols
US3953535A (en)	1976-04-27	Process for the preparation of alkenylbenzenes
EP0444750A2 (fr)	1991-09-04	Procédé pour la conversion de toluène et de butadiène en styrène et pentène-1
US4018840A (en)	1977-04-19	Process for preparing alkenylbenzenes
JP2528067B2 (ja)	1996-08-28	１，４−シクロヘキサンジメタノ―ルの製造方法
US4605547A (en)	1986-08-12	Continuous hydrogenation of lithium into lithium hydride
US3954895A (en)	1976-05-04	Method of separating and recovering alkenylbenzenes and unreacted alkylbenzenes from the alkenylation reaction product
EP0121420B1 (fr)	1986-12-10	Procédé en continu pour la production de méthomyl
SU1581734A1 (ru)	1990-07-30	Способ переработки нефт ного сырь и устройство дл его осуществлени
JPH0782178A (ja)	1995-03-28	モノアルケニルベンゼンの製造方法
JPH06321823A (ja)	1994-11-22	１，３−シクロヘキサンジメタノールの製造方法
JPH101447A (ja)	1998-01-06	段階的なアルキル化方法
US3375290A (en)	1968-03-26	Process for work-up of aromatic c9-hydrocarbons
US5767333A (en)	1998-06-16	Process for preparing 2,2'-dimethyl-1,1'binaphthyl and 2,7'-dimethyl-1,1'-binaphthyl
KR920009789B1 (ko)	1992-10-22	에틸비페닐류의 제조방법
CA1039755A (fr)	1978-10-03	Procede de preparation d'alkenylbenzenes