TWI301152B - - Google Patents

Download PDF

Info

Publication number: TWI301152B
Authority: TW; Taiwan
Prior art keywords: monomer; water; group; polymer; emulsion
Prior art date: 2001-04-13

Application number

TW091107649A

Other languages

English (en)

Chinese (zh)

Inventor

Takashige Maekawa

Minako Shimada

Ryuji Seki

Original Assignee

Asahi Glass Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2001-04-13

Filing date

2002-04-12

Publication date

2008-09-21

2002-04-12 Application filed by Asahi Glass Co Ltd filed Critical Asahi Glass Co Ltd

2008-09-21 Application granted granted Critical

2008-09-21 Publication of TWI301152B publication Critical patent/TWI301152B/zh

Links

XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 93
239000000178 monomer Substances 0.000 claims abstract description 75
239000005871 repellent Substances 0.000 claims abstract description 36
239000000203 mixture Substances 0.000 claims abstract description 25
229920001577 copolymer Polymers 0.000 claims abstract description 18
230000002940 repellent Effects 0.000 claims abstract description 16
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 37
238000006116 polymerization reaction Methods 0.000 claims description 30
229910052799 carbon Inorganic materials 0.000 claims description 17
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims description 16
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
150000001875 compounds Chemical class 0.000 claims description 8
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
125000001183 hydrocarbyl group Chemical group 0.000 claims description 2
NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical group FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 claims 1
238000002844 melting Methods 0.000 abstract description 52
230000008018 melting Effects 0.000 abstract description 52
229920001519 homopolymer Polymers 0.000 abstract description 16
238000011282 treatment Methods 0.000 abstract description 15
239000013078 crystal Substances 0.000 abstract description 5
229920000642 polymer Polymers 0.000 description 73
239000000839 emulsion Substances 0.000 description 67
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 57
239000003921 oil Substances 0.000 description 44
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 30
239000007787 solid Substances 0.000 description 28
238000012360 testing method Methods 0.000 description 22
229910052757 nitrogen Inorganic materials 0.000 description 20
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 19
239000004744 fabric Substances 0.000 description 17
238000000034 method Methods 0.000 description 17
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 17
238000006467 substitution reaction Methods 0.000 description 17
239000013081 microcrystal Substances 0.000 description 15
-1 ester compound Chemical class 0.000 description 13
238000011156 evaluation Methods 0.000 description 13
UCAHJECAHMOSHI-UHFFFAOYSA-N n-[(5-bromo-2-methoxyphenyl)methyl]adamantan-1-amine Chemical compound COC1=CC=C(Br)C=C1CNC1(C2)CC(C3)CC2CC3C1 UCAHJECAHMOSHI-UHFFFAOYSA-N 0.000 description 13
125000000962 organic group Chemical group 0.000 description 13
102100024440 Phosphoacetylglucosamine mutase Human genes 0.000 description 12
108010074307 Phosphoacetylglucosamine mutase Proteins 0.000 description 12
239000011521 glass Substances 0.000 description 12
239000011248 coating agent Substances 0.000 description 11
230000002079 cooperative effect Effects 0.000 description 11
239000003795 chemical substances by application Substances 0.000 description 10
150000002430 hydrocarbons Chemical class 0.000 description 9
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
125000000217 alkyl group Chemical group 0.000 description 8
238000000576 coating method Methods 0.000 description 8
239000000835 fiber Substances 0.000 description 8
239000000047 product Substances 0.000 description 8
238000005406 washing Methods 0.000 description 8
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
239000010985 leather Substances 0.000 description 7
239000007788 liquid Substances 0.000 description 7
229920000233 poly(alkylene oxides) Polymers 0.000 description 7
229910052731 fluorine Inorganic materials 0.000 description 6
125000001153 fluoro group Chemical group F* 0.000 description 6
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 6
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
238000012545 processing Methods 0.000 description 5
229920005989 resin Polymers 0.000 description 5
239000011347 resin Substances 0.000 description 5
239000000758 substrate Substances 0.000 description 5
YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical compound CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 4
125000002947 alkylene group Chemical group 0.000 description 4
239000003708 ampul Substances 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
229930195733 hydrocarbon Natural products 0.000 description 4
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
238000005259 measurement Methods 0.000 description 4
239000003960 organic solvent Substances 0.000 description 4
239000001294 propane Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
229920001567 vinyl ester resin Polymers 0.000 description 4
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
241001092040 Crataegus Species 0.000 description 3
235000009917 Crataegus X brevipes Nutrition 0.000 description 3
235000013204 Crataegus X haemacarpa Nutrition 0.000 description 3
235000009685 Crataegus X maligna Nutrition 0.000 description 3
235000009444 Crataegus X rubrocarnea Nutrition 0.000 description 3
235000009486 Crataegus bullatus Nutrition 0.000 description 3
235000017181 Crataegus chrysocarpa Nutrition 0.000 description 3
235000009682 Crataegus limnophila Nutrition 0.000 description 3
235000004423 Crataegus monogyna Nutrition 0.000 description 3
235000002313 Crataegus paludosa Nutrition 0.000 description 3
235000009840 Crataegus x incaedua Nutrition 0.000 description 3
BVTJGGGYKAMDBN-UHFFFAOYSA-N Dioxetane Chemical compound C1COO1 BVTJGGGYKAMDBN-UHFFFAOYSA-N 0.000 description 3
239000005977 Ethylene Substances 0.000 description 3
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 3
239000004480 active ingredient Substances 0.000 description 3
239000000853 adhesive Substances 0.000 description 3
230000001070 adhesive effect Effects 0.000 description 3
150000001336 alkenes Chemical class 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
125000001309 chloro group Chemical group Cl* 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
229920001971 elastomer Polymers 0.000 description 3
239000012948 isocyanate Substances 0.000 description 3
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
125000004430 oxygen atom Chemical group O* 0.000 description 3
230000035515 penetration Effects 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 2
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
239000004640 Melamine resin Substances 0.000 description 2
229920000877 Melamine resin Polymers 0.000 description 2
239000004677 Nylon Substances 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
229920002675 Polyoxyl Polymers 0.000 description 2
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical group [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
230000003373 anti-fouling effect Effects 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
230000006378 damage Effects 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
OXEMATRCWUHWJV-UHFFFAOYSA-N decane;hexane Chemical compound CCCCCC.CCCCCCCCCC OXEMATRCWUHWJV-UHFFFAOYSA-N 0.000 description 2
SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
238000003618 dip coating Methods 0.000 description 2
239000002612 dispersion medium Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
238000007720 emulsion polymerization reaction Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
125000005677 ethinylene group Chemical group [*:2]C#C[*:1] 0.000 description 2
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 2
125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
201000003373 familial cold autoinflammatory syndrome 3 Diseases 0.000 description 2
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
125000005843 halogen group Chemical group 0.000 description 2
230000002209 hydrophobic effect Effects 0.000 description 2
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
150000002513 isocyanates Chemical class 0.000 description 2
239000011976 maleic acid Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
229920001778 nylon Polymers 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
125000005010 perfluoroalkyl group Chemical group 0.000 description 2
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
229920000728 polyester Polymers 0.000 description 2
229920002098 polyfluorene Polymers 0.000 description 2
229920001451 polypropylene glycol Polymers 0.000 description 2
229920005749 polyurethane resin Polymers 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
229930195734 saturated hydrocarbon Chemical group 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
239000012085 test solution Substances 0.000 description 2
BGHCVCJVXZWKCC-UHFFFAOYSA-N tetradecane Chemical compound CCCCCCCCCCCCCC BGHCVCJVXZWKCC-UHFFFAOYSA-N 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
CCJAYIGMMRQRAO-UHFFFAOYSA-N 2-[4-[(2-hydroxyphenyl)methylideneamino]butyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCCCN=CC1=CC=CC=C1O CCJAYIGMMRQRAO-UHFFFAOYSA-N 0.000 description 1
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
WBHAUHHMPXBZCQ-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound COC1=CC=CC(C)=C1O WBHAUHHMPXBZCQ-UHFFFAOYSA-N 0.000 description 1
GXCJLVVUIVSLOQ-UHFFFAOYSA-N 2-propyl-4,5-dihydro-1,3-oxazole Chemical compound CCCC1=NCCO1 GXCJLVVUIVSLOQ-UHFFFAOYSA-N 0.000 description 1
SDXAWLJRERMRKF-UHFFFAOYSA-N 3,5-dimethyl-1h-pyrazole Chemical compound CC=1C=C(C)NN=1 SDXAWLJRERMRKF-UHFFFAOYSA-N 0.000 description 1
BFFQFGGITJXTFP-UHFFFAOYSA-N 3-methyldioxetane Chemical compound CC1COO1 BFFQFGGITJXTFP-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
229910020587 CmF2m+1 Inorganic materials 0.000 description 1
229920000742 Cotton Polymers 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
240000008415 Lactuca sativa Species 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
DFGMFVYRMVYRRA-UHFFFAOYSA-N [O].CC Chemical compound [O].CC DFGMFVYRMVYRRA-UHFFFAOYSA-N 0.000 description 1
USDJGQLNFPZEON-UHFFFAOYSA-N [[4,6-bis(hydroxymethylamino)-1,3,5-triazin-2-yl]amino]methanol Chemical compound OCNC1=NC(NCO)=NC(NCO)=N1 USDJGQLNFPZEON-UHFFFAOYSA-N 0.000 description 1
238000005299 abrasion Methods 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
229920003054 adipate polyester Polymers 0.000 description 1
238000004220 aggregation Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
230000001153 anti-wrinkle effect Effects 0.000 description 1
239000002518 antifoaming agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
238000003556 assay Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000012752 auxiliary agent Substances 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229920001400 block copolymer Polymers 0.000 description 1
238000007707 calorimetry Methods 0.000 description 1
150000001721 carbon Chemical group 0.000 description 1
CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 1
239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
230000008034 disappearance Effects 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
238000012674 dispersion polymerization Methods 0.000 description 1
238000009826 distribution Methods 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
238000005108 dry cleaning Methods 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
150000002168 ethanoic acid esters Chemical class 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
125000004005 formimidoyl group Chemical group [H]\N=C(/[H])* 0.000 description 1
238000010528 free radical solution polymerization reaction Methods 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000001879 gelation Methods 0.000 description 1
238000007429 general method Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
YCOZIPAWZNQLMR-UHFFFAOYSA-N heptane - octane Natural products CCCCCCCCCCCCCCC YCOZIPAWZNQLMR-UHFFFAOYSA-N 0.000 description 1
PZDUWXKXFAIFOR-UHFFFAOYSA-N hexadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCOC(=O)C=C PZDUWXKXFAIFOR-UHFFFAOYSA-N 0.000 description 1
PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 description 1
RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
239000012943 hotmelt Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
230000001771 impaired effect Effects 0.000 description 1
239000003999 initiator Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000002650 laminated plastic Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 description 1
HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
239000010702 perfluoropolyether Chemical group 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
229920001281 polyalkylene Polymers 0.000 description 1
125000003367 polycyclic group Chemical group 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000193 polymethacrylate Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
239000003223 protective agent Substances 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
235000012045 salad Nutrition 0.000 description 1
229920006395 saturated elastomer Chemical group 0.000 description 1
238000004513 sizing Methods 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
239000006104 solid solution Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000007921 spray Substances 0.000 description 1
210000002784 stomach Anatomy 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
229920002803 thermoplastic polyurethane Polymers 0.000 description 1
229920001187 thermosetting polymer Polymers 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
238000012549 training Methods 0.000 description 1
OWGHQYPQNSZTFQ-UHFFFAOYSA-M triethyl(octadecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](CC)(CC)CC OWGHQYPQNSZTFQ-UHFFFAOYSA-M 0.000 description 1
AQZSPJRLCJSOED-UHFFFAOYSA-M trimethyl(octyl)azanium;chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(C)C AQZSPJRLCJSOED-UHFFFAOYSA-M 0.000 description 1
229930195735 unsaturated hydrocarbon Chemical group 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
229920003169 water-soluble polymer Polymers 0.000 description 1
239000001993 wax Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Combustion & Propulsion (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Paper (AREA)

TW091107649A 2001-04-13 2002-04-12 TWI301152B (2)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP2001115676		2001-04-13

Publications (1)

Publication Number	Publication Date
TWI301152B true TWI301152B (2)	2008-09-21

Family

ID=18966539

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
TW091107649A TWI301152B (2)	2001-04-13	2002-04-12

Country Status (9)

Country	Link
US (1)	US6716944B2 (2)
EP (1)	EP1298180B1 (2)
JP (4)	JPWO2002083809A1 (2)
KR (1)	KR100889714B1 (2)
CN (1)	CN100445344C (2)
CA (1)	CA2412602C (2)
DE (1)	DE60233192D1 (2)
TW (1)	TWI301152B (2)
WO (1)	WO2002083809A1 (2)

Families Citing this family (74)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ITMI20011424A1 (it) *	2001-07-05	2003-01-05	Ausimont Spa	Dispersioni di polimeri fluorurati
KR100901097B1 (ko) *	2002-10-15	2009-06-08	아사히 가라스 가부시키가이샤	발수 발유제 조성물
JP4206767B2 (ja)	2003-02-07	2009-01-14	旭硝子株式会社	撥水撥油剤水性組成物
CA2545349A1 (en) *	2003-11-13	2005-05-26	Daikin Industries, Ltd.	Aqueous liquid dispersion of water and oil repellent agent containing nonionic surfactant
US6995222B2 (en) *	2003-12-17	2006-02-07	3M Innovative Properties Company	Coating compositions with reactive fluorinated copolymers having pendant perfluoropolyether groups
CA2551874A1 (en) *	2003-12-31	2005-07-21	3M Innovative Properties Company	Water-and oil-repellent fluoroacrylates
KR101153762B1 (ko) *	2004-03-23	2012-06-13	아사히 가라스 가부시키가이샤	내수 내유제 조성물
JP4760707B2 (ja)	2004-04-20	2011-08-31	ダイキン工業株式会社	撥水撥油剤組成物およびその製造法
JP4752197B2 (ja) *	2004-06-04	2011-08-17	ユニマテック株式会社	撥水撥油剤の製造法
ATE533775T1 (de) *	2004-08-24	2011-12-15	Btg Int Ltd	Verfahren zur herstellung von 17-vinyl-triflaten als intermediate
EP1788047B1 (en)	2004-08-25	2013-11-20	Daikin Industries, Ltd.	Water-repellent/oil-repellent composition
US7411020B2 (en) *	2004-12-28	2008-08-12	3M Innovative Properties Company	Water-based release coating containing fluorochemical
US7253241B2 (en) *	2004-12-28	2007-08-07	3M Innovative Properties Company	Fluorochemical containing low adhesion backsize
US7291688B2 (en) *	2004-12-28	2007-11-06	3M Innovative Properties Company	Fluoroacrylate-mercaptofunctional copolymers
US20060142530A1 (en)	2004-12-28	2006-06-29	Moore George G	Water- and oil-repellent fluorourethanes and fluoroureas
US7345123B2 (en) *	2004-12-28	2008-03-18	3M Innovative Properties Company	Fluoroacrylate-multifunctional acrylate copolymer compositions
JP5072219B2 (ja) *	2005-03-31	2012-11-14	小林製薬株式会社	親水処理剤
EP2484831A1 (en) *	2005-04-12	2012-08-08	E. I. du Pont de Nemours and Company	Fabric treated with durable stain repel and stain release finish and method of industrial laundering to maintain durability of finish
WO2007026716A1 (ja) *	2005-08-30	2007-03-08	Asahi Glass Company, Limited	水系表面処理剤および表面処理された構造物
US7754836B2 (en)	2005-09-01	2010-07-13	Daikin Industries, Ltd.	Water and oil repellent composition and treatment method
WO2007102993A1 (en) *	2006-03-08	2007-09-13	3M Innovative Properties Company	Controlled architecture materials
JP5200403B2 (ja) *	2006-03-30	2013-06-05	旭硝子株式会社	撥液剤組成物、撥液加工方法、撥液膜を有する物品
CN101415792B (zh)	2006-03-30	2012-05-30	旭硝子株式会社	防液剂组合物、防液加工方法、具有防液膜的物品
US7722955B2 (en) *	2006-04-13	2010-05-25	3M Innovative Properties Company	Flooring substrate having a coating of a curable composition
EP2057201B1 (en) *	2006-08-25	2009-12-23	Clariant Finance (BVI) Limited	Oil-, water- and soil-repellent perfluoroalkylethyl methacrylate copolymers
CN101145451B (zh) *	2006-08-29	2010-04-14	松下电器产业株式会社	触点开关
US7964657B2 (en) *	2007-03-23	2011-06-21	Peach State Labs, Inc.	Polymeric dispersions and applications thereof
CN101668827A (zh) *	2007-04-27	2010-03-10	旭硝子株式会社	斥水斥油剂组合物及其制造方法及物品
WO2008136435A1 (ja) *	2007-04-27	2008-11-13	Asahi Glass Company, Limited	撥水撥油剤組成物、その製造方法および物品
EP2166059B1 (en) *	2007-06-12	2015-09-02	Asahi Glass Company, Limited	Water-repellent/oil-repellent composition, method for producing the same, and article
TW200920752A (en)	2007-07-11	2009-05-16	Asahi Glass Co Ltd	Method for production of water-repellant/oil-repellant composition, and article
EP2204429A4 (en) *	2007-09-28	2012-11-21	Asahi Glass Co Ltd	HYDROGEN AND OLEOPHOBILIZER AND PRODUCT
EP2045276A1 (en) *	2007-10-05	2009-04-08	E.I. Du Pont De Nemours And Company	Fluoropolymer
JP5439743B2 (ja) *	2007-10-11	2014-03-12	ユニマテック株式会社	撥水撥油剤
KR101600101B1 (ko)	2008-03-12	2016-03-04	아사히 가라스 가부시키가이샤	공중합체 및 그 제조 방법
US10077327B2 (en)	2008-03-28	2018-09-18	Daikin Industries, Ltd.	Fluorine-containing copolymer and water- and oil-repellent agent
KR101533135B1 (ko) *	2008-06-02	2015-07-01	아사히 가라스 가부시키가이샤	공중합체, 그 제조 방법 및 발유제 조성물 그리고 그 처리 물품
KR101578243B1 (ko) *	2008-06-04	2015-12-16	아사히 가라스 가부시키가이샤	공중합체, 그 제조 방법 및 발수 발유제 조성물
CN102197106A (zh)	2008-10-24	2011-09-21	旭硝子株式会社	斥水斥油剂组合物及其制造方法
US20100113691A1 (en) *	2008-11-06	2010-05-06	E. I. Du Pont De Nemours And Company	Fluoro olefin polymerization
EP2233633A1 (de) *	2009-03-28	2010-09-29	Huntsman Textile Effects (Germany) GmbH	Fluorfreie wässrige Dispersion für die Behandlung von textilen Flächengebilden
JP5741855B2 (ja) *	2009-06-05	2015-07-01	旭硝子株式会社	撥水撥油剤組成物、その製造方法および物品の処理方法
GB0919014D0 (en)	2009-10-30	2009-12-16	3M Innovative Properties Co	Soll and stain resistant coating composition for finished leather substrates
EP2497788B1 (en)	2009-11-02	2014-09-24	Asahi Glass Company, Limited	Fluorine-containing compound, fluorine-containing polymer and fluorine-containing copolymer
JP5637141B2 (ja)	2009-11-02	2014-12-10	旭硝子株式会社	含フッ素化合物および含フッ素重合体
KR20120089698A (ko)	2009-11-02	2012-08-13	아사히 가라스 가부시키가이샤	함불소 화합물 및 함불소 중합체
KR101728576B1 (ko)	2009-11-13	2017-04-19	아사히 가라스 가부시키가이샤	내수 내유제 조성물, 이것으로 처리된 물품 및 이들의 제조 방법
US8298674B2 (en) *	2009-11-25	2012-10-30	Tri-Tex Co. Inc.	Protecting agent for concrete, masonry surface, bricks, clay roofing, tiles, marble, granite, concrete slate, stucco, paving stones, unglazed ceramic, sandstone, limestone, wood and other objects against stains, dirt, water and oil penetration
KR20120104576A (ko) *	2009-12-25	2012-09-21	아사히 가라스 가부시키가이샤	발수 발유제 조성물, 그 제조 방법 및 물품의 처리 방법
CN102782075A (zh) *	2010-02-15	2012-11-14	旭硝子株式会社	脱模剂组合物
CN102812057B (zh) *	2010-04-01	2014-12-10	旭硝子株式会社	含氟化合物及含氟聚合物
WO2012020735A1 (ja) *	2010-08-11	2012-02-16	旭硝子株式会社	撥水剤組成物、その製造方法、疎水性基材処理剤組成物および物品
JPWO2012020806A1 (ja) *	2010-08-11	2013-10-28	旭硝子株式会社	撥水撥油剤組成物および物品
WO2012147573A1 (ja) *	2011-04-27	2012-11-01	旭硝子株式会社	撥水撥油剤組成物、その製造方法および物品
KR101892775B1 (ko) *	2011-04-27	2018-08-28	에이지씨 가부시키가이샤	발수발유제 조성물, 그 제조 방법 및 물품
WO2013115196A1 (ja)	2012-01-31	2013-08-08	旭硝子株式会社	含フッ素共重合体およびその製造方法、ならびに撥水撥油剤組成物
WO2013115197A1 (ja)	2012-01-31	2013-08-08	旭硝子株式会社	含フッ素共重合体およびその製造方法、ならびに撥水撥油剤組成物
JP5922774B2 (ja) *	2012-07-06	2016-05-24	ダイキン工業株式会社	透湿防水布帛
KR101790918B1 (ko) *	2012-07-06	2017-10-26	다이킨 고교 가부시키가이샤	투습 방수 포백 및 그 제법
KR102074120B1 (ko)	2012-08-01	2020-02-06	에이지씨 가부시키가이샤	발수발유제 조성물 및 물품
CN105339398B (zh)	2013-06-25	2017-06-20	优迈特株式会社	含氟共聚物的水性分散液
JP6456293B2 (ja) *	2013-09-30	2019-01-23	株式会社ネオス	親水撥油性付与剤およびこれを含有する組成物
CN103554353B (zh) *	2013-10-12	2015-10-28	中科院广州化学有限公司	一种可交联型含氟聚合物纳米微球及其制备方法与应用
DE102013224140A1 (de)	2013-11-26	2015-05-28	Rudolf Gmbh	Ausrüstungsmittel mit blockierten Polyisocyanaten
JP6502644B2 (ja) *	2014-10-14	2019-04-17	リンテック株式会社	剥離剤組成物、剥離シートおよび両面粘着シート
CN105274902A (zh) *	2015-01-29	2016-01-27	焦建党	一种纳米拒水、拒油、低附着力空气滤纸及其制造方法
JPWO2016178429A1 (ja)	2015-05-07	2018-02-22	日華化学株式会社	撥水撥油剤組成物及び撥水撥油性繊維製品の製造方法
KR102528045B1 (ko) *	2015-05-27	2023-05-02	에이지씨 가부시키가이샤	발수 발유제 조성물, 그 제조 방법 및 물품
CN106146727A (zh) *	2016-08-02	2016-11-23	厦门爱思康新材料有限公司	一种纸品用防水防油剂及其制备方法和运用
EP3421558A1 (en) *	2017-06-30	2019-01-02	3M Innovative Properties Company	Amphiphilic copolymer-based protective coating composition for metal surfaces
CN109957060B (zh) *	2017-12-19	2021-05-11	东莞东阳光科研发有限公司	一种高分子聚合物、其制备方法及包含其的电解液
CN114163562B (zh) *	2021-12-24	2023-02-14	宁波市嘉化新材料科技有限公司	一种纸张防透湿剂及其制备方法
CN119998336A (zh)	2022-10-04	2025-05-13	大金工业株式会社	聚合物和拒水耐油剂组合物
JP7785407B1 (ja)	2025-03-24	2025-12-15	株式会社ハーベス	重合体、樹脂組成物、分散剤、および潤滑剤組成物

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS6399285A (ja)	1986-05-28	1988-04-30	Daikin Ind Ltd	撥水撥油剤
EP0247489B1 (en) *	1986-05-28	1993-08-25	Daikin Industries, Limited	Fluorine containing water and oil repellent composition
JPS6375082A (ja) *	1986-09-18	1988-04-05	Daikin Ind Ltd	エアゾル型撥水撥油剤組成物
CN87210448U (zh) *	1987-08-17	1988-12-07	中国医科大学附属二院	急救心脏起博穿刺器械和起博电极
JPH01153784A (ja) *	1987-12-11	1989-06-15	Daikin Ind Ltd	撥水撥油剤組成物
EP0332141B1 (en) *	1988-03-08	1995-02-01	Asahi Glass Company Ltd.	Water and oil repellant
DE3843922A1 (de)	1988-12-24	1990-06-28	Hoechst Ag	Neue copolymere, deren mischungen mit poly(meth)acrylsaeureestern und deren verwendung zur verbesserung der fliessfaehigkeit von rohoelen in der kaelte
DE69310815T2 (de) *	1992-07-03	1997-08-28	Asahi Glass Co Ltd	Polyfluorkohlenwasserstoffgruppe enthaltende Monomere, ihre Polymere und die Anwendungen dieser Polymere
JP3399107B2 (ja) *	1994-09-05	2003-04-21	ダイキン工業株式会社	撥水撥油性を有する防汚加工剤組成物
JP3277092B2 (ja)	1995-04-05	2002-04-22	アヴェンティス・リサーチ・ウント・テクノロジーズ・ゲーエムベーハー・ウント・コー・カーゲー	有機ガス検知用ポリマーフィルム
AU707886B2 (en) *	1995-07-27	1999-07-22	Asahi Glass Company Limited	Water and oil repellent composition, treating method therewith and copolymer
JPH09291481A (ja) *	1996-04-22	1997-11-11	Dai Ichi Kogyo Seiyaku Co Ltd	繊維用撥水撥油加工剤
JP3433024B2 (ja) *	1996-09-05	2003-08-04	信越化学工業株式会社	撥水撥油剤組成物
JP3624615B2 (ja) *	1997-02-28	2005-03-02	ユニマテック株式会社	新規共重合体およびそれを含有する撥水撥油剤
JP3399286B2 (ja) *	1997-04-11	2003-04-21	ダイキン工業株式会社	防汚加工剤組成物
JP2000136377A (ja)	1998-08-24	2000-05-16	Asahi Glass Co Ltd	水分散型撥水撥油剤組成物
JP3807130B2 (ja)	1998-11-13	2006-08-09	旭硝子株式会社	水分散型防汚加工剤組成物
JP3864591B2 (ja) *	1998-11-26	2007-01-10	旭硝子株式会社	撥水撥油加工剤

2002
- 2002-04-12 TW TW091107649A patent/TWI301152B/zh not_active IP Right Cessation
- 2002-04-12 CA CA2412602A patent/CA2412602C/en not_active Expired - Lifetime
- 2002-04-12 DE DE60233192T patent/DE60233192D1/de not_active Expired - Lifetime
- 2002-04-12 KR KR1020027016893A patent/KR100889714B1/ko not_active Expired - Lifetime
- 2002-04-12 EP EP02718564A patent/EP1298180B1/en not_active Expired - Lifetime
- 2002-04-12 JP JP2002582148A patent/JPWO2002083809A1/ja active Pending
- 2002-04-12 WO PCT/JP2002/003686 patent/WO2002083809A1/ja not_active Ceased
- 2002-04-12 CN CNB028011937A patent/CN100445344C/zh not_active Expired - Lifetime
- 2002-12-13 US US10/317,991 patent/US6716944B2/en not_active Expired - Lifetime
2009
- 2009-10-07 JP JP2009233709A patent/JP5110064B2/ja not_active Expired - Lifetime
2012
- 2012-08-17 JP JP2012180844A patent/JP5712982B2/ja not_active Expired - Lifetime
2014
- 2014-05-02 JP JP2014095234A patent/JP5825395B2/ja not_active Expired - Lifetime

Also Published As

Publication number	Publication date
JP5825395B2 (ja)	2015-12-02
JPWO2002083809A1 (ja)	2004-08-05
CA2412602C (en)	2010-07-20
EP1298180A1 (en)	2003-04-02
JP2010001499A (ja)	2010-01-07
JP5110064B2 (ja)	2012-12-26
JP5712982B2 (ja)	2015-05-07
DE60233192D1 (de)	2009-09-17
CA2412602A1 (en)	2002-12-11
US6716944B2 (en)	2004-04-06
EP1298180B1 (en)	2009-08-05
EP1298180A4 (en)	2005-03-09
KR100889714B1 (ko)	2009-03-23
JP2014169449A (ja)	2014-09-18
CN1461334A (zh)	2003-12-10
JP2013007044A (ja)	2013-01-10
US20030130457A1 (en)	2003-07-10
KR20030011886A (ko)	2003-02-11
WO2002083809A1 (en)	2002-10-24
CN100445344C (zh)	2008-12-24

Legal Events

Date	Code	Title	Description
2022-05-21	MK4A	Expiration of patent term of an invention patent

Publication	Publication Date	Title
TWI301152B (2)	2008-09-21
TWI740104B (zh)	2021-09-21	表面處理劑
KR102041857B1 (ko)	2019-11-08	불소 함유 조성물 및 불소 함유 중합체
TWI304837B (2)	2009-01-01
CN102822309B (zh)	2015-12-09	使用α-氯丙烯酸酯的拨水拨油剂
KR20160076525A (ko)	2016-06-30	수계 에멀전 표면 처리제
TW200804581A (en)	2008-01-16	Liquid repellent composition, method for liquid-repellent finishing, and articles with liquid-repellent films
TWI675045B (zh)	2019-10-21	共聚物及表面處理劑
KR102650932B1 (ko)	2024-03-26	불소 함유 중합체 및 표면 처리제
TWI781360B (zh)	2022-10-21	撥水性柔軟劑
CN107177982B (zh)	2021-09-07	表面处理剂组合物
CN104204079B (zh)	2016-03-23	水性乳液组合物
JP2001098033A (ja)	2001-04-10	共重合体、撥水撥油剤、および水分散型撥水撥油剤組成物