UA79121C2 - Способ извлечения бетаина - Google Patents
Способ извлечения бетаина Download PDFInfo
- Publication number
- UA79121C2 UA79121C2 UA20041210653A UA20041210653A UA79121C2 UA 79121 C2 UA79121 C2 UA 79121C2 UA 20041210653 A UA20041210653 A UA 20041210653A UA 20041210653 A UA20041210653 A UA 20041210653A UA 79121 C2 UA79121 C2 UA 79121C2
- Authority
- UA
- Ukraine
- Prior art keywords
- fraction
- nanofiltration
- enriched
- betaine
- sucrose
- Prior art date
Links
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 title claims abstract description 297
- 229960003237 betaine Drugs 0.000 title claims abstract description 150
- 238000000034 method Methods 0.000 title claims description 111
- 230000008569 process Effects 0.000 title claims description 27
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 title abstract 3
- 238000001728 nano-filtration Methods 0.000 claims abstract description 169
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims abstract description 116
- 229930006000 Sucrose Natural products 0.000 claims abstract description 116
- 239000005720 sucrose Substances 0.000 claims abstract description 116
- 238000005194 fractionation Methods 0.000 claims abstract description 68
- 235000013379 molasses Nutrition 0.000 claims abstract description 34
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 claims abstract description 18
- 235000021536 Sugar beet Nutrition 0.000 claims abstract description 18
- 239000012528 membrane Substances 0.000 claims description 94
- 239000000706 filtrate Substances 0.000 claims description 34
- 239000011347 resin Substances 0.000 claims description 28
- 229920005989 resin Polymers 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 26
- 239000012141 concentrate Substances 0.000 claims description 22
- 239000000047 product Substances 0.000 claims description 22
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 19
- 239000003729 cation exchange resin Substances 0.000 claims description 19
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 16
- MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 claims description 15
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 claims description 15
- 239000003480 eluent Substances 0.000 claims description 15
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- 150000001413 amino acids Chemical class 0.000 claims description 11
- 230000002378 acidificating effect Effects 0.000 claims description 10
- 238000000605 extraction Methods 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 claims description 10
- SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 claims description 9
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims description 9
- 229960000367 inositol Drugs 0.000 claims description 9
- 238000012856 packing Methods 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 150000002772 monosaccharides Chemical class 0.000 claims description 6
- 239000003957 anion exchange resin Substances 0.000 claims description 4
- 238000010923 batch production Methods 0.000 claims description 3
- 229940023913 cation exchange resins Drugs 0.000 claims description 3
- 238000010924 continuous production Methods 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000005349 anion exchange Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 abstract description 23
- 239000000243 solution Substances 0.000 description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 42
- 238000013375 chromatographic separation Methods 0.000 description 21
- 235000008504 concentrate Nutrition 0.000 description 18
- 230000014759 maintenance of location Effects 0.000 description 14
- 235000016068 Berberis vulgaris Nutrition 0.000 description 13
- 241000335053 Beta vulgaris Species 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000004587 chromatography analysis Methods 0.000 description 12
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 10
- 239000008103 glucose Substances 0.000 description 10
- 230000035699 permeability Effects 0.000 description 10
- 229920002492 poly(sulfone) Polymers 0.000 description 10
- 239000002994 raw material Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000004695 Polyether sulfone Substances 0.000 description 7
- 229920006393 polyether sulfone Polymers 0.000 description 7
- 239000006188 syrup Substances 0.000 description 6
- 235000020357 syrup Nutrition 0.000 description 6
- 239000004760 aramid Substances 0.000 description 5
- 229920003235 aromatic polyamide Polymers 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 238000004811 liquid chromatography Methods 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- 238000000108 ultra-filtration Methods 0.000 description 5
- 239000003463 adsorbent Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 238000005374 membrane filtration Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 238000011026 diafiltration Methods 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229940024606 amino acid Drugs 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- -1 beet molasses Chemical compound 0.000 description 2
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 230000021523 carboxylation Effects 0.000 description 2
- 238000006473 carboxylation reaction Methods 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 150000002016 disaccharides Chemical class 0.000 description 2
- 230000007717 exclusion Effects 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- JLEQUYOQVZXFFW-UHFFFAOYSA-N 2-chlorobenzoate;dimethylazanium Chemical compound C[NH2+]C.[O-]C(=O)C1=CC=CC=C1Cl JLEQUYOQVZXFFW-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002307 Dextran Polymers 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 108010073178 Glucan 1,4-alpha-Glucosidase Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 238000003109 Karl Fischer titration Methods 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 235000015191 beet juice Nutrition 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 239000012526 feed medium Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 229910052500 inorganic mineral Chemical class 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011707 mineral Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229960002796 polystyrene sulfonate Drugs 0.000 description 1
- 239000011970 polystyrene sulfonate Substances 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/14—Purification of sugar juices using ion-exchange materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/027—Nanofiltration
- B01D61/0271—Nanofiltration comprising multiple nanofiltration steps
-
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13B—PRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
- C13B20/00—Purification of sugar juices
- C13B20/16—Purification of sugar juices by physical means, e.g. osmosis or filtration
- C13B20/165—Purification of sugar juices by physical means, e.g. osmosis or filtration using membranes, e.g. osmosis, ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/10—Selective adsorption, e.g. chromatography characterised by constructional or operational features
- B01D15/18—Selective adsorption, e.g. chromatography characterised by constructional or operational features relating to flow patterns
- B01D15/1814—Recycling of the fraction to be distributed
- B01D15/1821—Simulated moving beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
- B01D15/361—Ion-exchange
- B01D15/362—Cation-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
- B01D15/08—Selective adsorption, e.g. chromatography
- B01D15/26—Selective adsorption, e.g. chromatography characterised by the separation mechanism
- B01D15/36—Selective adsorption, e.g. chromatography characterised by the separation mechanism involving ionic interaction, e.g. ion-exchange, ion-pair, ion-suppression or ion-exclusion
- B01D15/361—Ion-exchange
- B01D15/363—Anion-exchange
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Nanotechnology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Peptides Or Proteins (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
Способ фракционирования раствора, который содержит бетаин и сахарозу, с помощью хроматографического фракционирования и нанофильтрации указанного раствора и извлечение фракции, обогащенной бетаином, и, при необходимости, фракции, обогащенной сахарозой. Раствор, который подлежит фракционированию, обычно является раствором, полученным из сахарной свеклы, например, раствор мелассы.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20021251A FI20021251A0 (fi) | 2002-06-26 | 2002-06-26 | Menetelmä betaiinin talteenottamiseksi |
| PCT/FI2003/000509 WO2004002938A1 (en) | 2002-06-26 | 2003-06-23 | Process for recovering betaine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA79121C2 true UA79121C2 (ru) | 2007-05-25 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA20041210653A UA79121C2 (ru) | 2002-06-26 | 2003-06-23 | Способ извлечения бетаина |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7009076B2 (ru) |
| EP (2) | EP2923749A1 (ru) |
| JP (1) | JP4605368B2 (ru) |
| AU (1) | AU2003239641A1 (ru) |
| FI (1) | FI20021251A0 (ru) |
| RU (1) | RU2314288C2 (ru) |
| UA (1) | UA79121C2 (ru) |
| WO (1) | WO2004002938A1 (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105566137A (zh) * | 2015-12-25 | 2016-05-11 | 安徽丰原发酵技术工程研究有限公司 | 一种从甜菜糖蜜中分离纯化甜菜碱的方法 |
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| FI20020592A7 (fi) * | 2002-03-27 | 2003-09-28 | Danisco Sweeteners Oy | Menetelmä sokereiden, sokerialkoholien, hiilihydraattien ja niiden seosten erottamiseksi niitä sisältävistä liuoksista |
| WO2004041003A1 (en) * | 2002-11-06 | 2004-05-21 | Danisco Sugar Oy | Edible flavor improver, process for its production and use |
| PT1649068E (pt) * | 2003-07-16 | 2013-01-10 | Amalgamated Res Inc | Um método para purificação de material de sacarose de elevada pureza |
| US7077953B2 (en) * | 2003-09-11 | 2006-07-18 | Harris Group, Inc. | Nanofilter system and method of use |
| JP5112859B2 (ja) * | 2004-06-04 | 2013-01-09 | ホリズン サイエンス ピーティーワイ リミテッド | 天然甘味料 |
| GB2416776A (en) * | 2004-07-28 | 2006-02-08 | British Sugar Plc | Enhancement of the fermentability of carbohydrate substrates by chromatographic purification |
| FI119731B (fi) * | 2004-12-28 | 2009-02-27 | Neste Oil Oyj | Menetelmä trimetyyliglysiiniä ja glykolia sisältävien vesipitoisten nesteiden regeneroimiseksi |
| US8021697B2 (en) * | 2005-06-03 | 2011-09-20 | Horizon Science Pty. Ltd. | Substances having body mass redistribution properties |
| FI120590B (fi) * | 2005-10-28 | 2009-12-15 | Danisco Sweeteners Oy | Erotusmenetelmä |
| US8864995B2 (en) * | 2006-01-10 | 2014-10-21 | Dupont Nutrition Biosciences Aps | Method for separating betaine |
| FI20065363A0 (fi) * | 2006-05-30 | 2006-05-30 | Danisco Sweeteners Oy | Erotusmenetelmä |
| US9364016B2 (en) * | 2006-09-19 | 2016-06-14 | The Product Makers (Australia) Pty Ltd | Extracts derived from sugar cane and a process for their manufacture |
| EP2297291A4 (en) * | 2008-06-02 | 2012-08-22 | Univ Saskatchewan | RECOVERING MULTIPLE COMPOUNDS AND WATER RECYCLING DISTILLATION RESIDUES |
| EP2216088A1 (en) * | 2009-02-04 | 2010-08-11 | Lonza Ltd. | Recovery of product losses from ED waste streams |
| CN102413891B (zh) * | 2009-02-25 | 2014-11-05 | 杜邦营养生物科学有限公司 | 分离方法 |
| CN102946961B (zh) * | 2010-03-30 | 2015-11-25 | 杜邦营养生物科学有限公司 | 分离方法 |
| EP2386649A1 (en) | 2010-05-12 | 2011-11-16 | Tiense Suikerraffinaderij N.V. | Process for the recovery of betaine from molasses |
| CN103561585B (zh) | 2011-02-08 | 2016-05-25 | 产品制造者(澳大利亚)有限公司 | 糖提取物 |
| GB201120138D0 (en) * | 2011-11-22 | 2012-01-04 | Glaxo Group Ltd | Novel process |
| WO2013161935A1 (ja) * | 2012-04-26 | 2013-10-31 | 東レ株式会社 | 糖液の製造方法 |
| EP2847342B1 (en) * | 2012-05-07 | 2020-08-12 | Archer Daniels Midland Co. | Purification of succinic acid |
| JP2014029294A (ja) * | 2012-07-31 | 2014-02-13 | Nippon Rensui Co Ltd | クロマト分離法 |
| AU2013308395C1 (en) | 2012-08-28 | 2018-03-15 | Poly Gain Pte Ltd | Extraction method |
| AU2014306366B9 (en) | 2013-08-16 | 2020-03-26 | Poly Gain Pte Ltd | Sugar cane derived extracts and methods of treatment |
| US20160115560A1 (en) * | 2014-10-23 | 2016-04-28 | Amalgamated Research Llc | Methods of separating components using multi-scale simulated moving bed chromatography |
| CN104788509B (zh) * | 2015-04-09 | 2016-06-29 | 浙江大学 | 一种从脱脂麦胚中提取制备高纯度棉子糖的工艺 |
| MY186792A (en) | 2016-02-04 | 2021-08-20 | Ind Tech Res Inst | Method for separating hydrolysis product of biomass |
| WO2018095897A1 (en) * | 2016-11-22 | 2018-05-31 | Sika Technology Ag | Producing dispersants for solid suspensions from vinasse type materials |
| US10549238B2 (en) | 2017-05-01 | 2020-02-04 | Amalgamated Research Llc | Methods of regenerating a resin used to decolorize a biomass feedstream and related systems |
| FR3115283B1 (fr) | 2020-10-15 | 2023-06-02 | Lesaffre & Cie | Mélasse fermentée et estérifiée |
| CN114525318A (zh) * | 2022-01-21 | 2022-05-24 | 新疆绿原糖业有限公司 | 一种复合酶耦合连续纳滤膜分离甜菜多糖和甜菜碱的方法 |
| CN114471168A (zh) * | 2022-01-21 | 2022-05-13 | 新疆绿原糖业有限公司 | 一种利用热絮凝联合多级纳滤膜分离浓缩甜菜多糖和甜菜碱的方法 |
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| DE2362211C3 (de) | 1973-12-14 | 1978-05-11 | Sueddeutsche Zucker Ag, 6800 Mannheim | Verfahren zur Aufarbeitung von Melassen |
| GR73024B (ru) * | 1980-02-29 | 1984-01-25 | Suomen Sokeri Oy | |
| US4359430A (en) | 1980-02-29 | 1982-11-16 | Suomen Sokeri Osakeyhtio | Betaine recovery process |
| US4333770A (en) | 1980-09-08 | 1982-06-08 | Uop Inc. | Extraction of sucrose from molasses |
| US4405378A (en) | 1981-02-17 | 1983-09-20 | Uop Inc. | Extraction of sucrose |
| US4405377A (en) | 1982-02-10 | 1983-09-20 | Uop Inc. | Process for the separation of monosaccharides |
| US4511654A (en) | 1982-03-19 | 1985-04-16 | Uop Inc. | Production of high sugar syrups |
| JPH01109000A (ja) * | 1987-10-23 | 1989-04-26 | Hokuren Federation Of Agricult Coop:The | 甜菜糖液の処理方法 |
| US5177008A (en) | 1987-12-22 | 1993-01-05 | Kampen Willem H | Process for manufacturing ethanol and for recovering glycerol, succinic acid, lactic acid, betaine, potassium sulfate, and free flowing distiller's dry grain and solubles or a solid fertilizer therefrom |
| FI86416C (fi) * | 1988-06-09 | 1992-08-25 | Suomen Sokeri Oy | Foerfarande foer tillvaratagande av betain ur melass. |
| HU210627B (en) * | 1989-07-18 | 1995-06-28 | Kampen | Process for manufacturing glycerol and betaine |
| FI96225C (fi) | 1993-01-26 | 1996-05-27 | Cultor Oy | Menetelmä melassin fraktioimiseksi |
| JP3117596B2 (ja) * | 1993-12-29 | 2000-12-18 | オルガノ株式会社 | ３分子以上の単糖類分子がグリコシド結合してなる糖類の製造方法 |
| US5795398A (en) | 1994-09-30 | 1998-08-18 | Cultor Ltd. | Fractionation method of sucrose-containing solutions |
| AU6043598A (en) | 1997-01-29 | 1998-08-18 | Amalgamated Research, Inc. | Method of displacement chromatography |
| US6329182B1 (en) | 1997-11-26 | 2001-12-11 | Novozymes A/S | Method of producing oligosaccharide syrups, a system for producing the same and oligosaccharide syrups |
| JP2000109453A (ja) * | 1998-10-01 | 2000-04-18 | Nippon Beet Sugar Mfg Co Ltd | ベタイン及びアミノ酸の回収方法 |
| EP1788100A2 (en) | 1999-08-19 | 2007-05-23 | TATE & LYLE INDUSTRIES LIMITED | Sugar beet membrane filtration process |
| US6387186B1 (en) * | 1999-08-19 | 2002-05-14 | Tate & Lyle, Inc. | Process for production of purified beet juice for sugar manufacture |
| FI20002150A7 (fi) | 2000-09-29 | 2002-03-30 | Finnfeeds Finland Oy | Menetelmä tuotteiden talteenottamiseksi prosessiliuoksista |
| FI111959B (fi) | 2000-12-28 | 2003-10-15 | Danisco Sweeteners Oy | Menetelmä maltoosin puhdistamiseksi |
| DK1366198T3 (da) * | 2000-12-28 | 2012-03-19 | Danisco | Fremgangsmåde til separation |
-
2002
- 2002-06-26 FI FI20021251A patent/FI20021251A0/fi unknown
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2003
- 2003-02-25 US US10/373,476 patent/US7009076B2/en not_active Expired - Fee Related
- 2003-06-23 EP EP14193923.1A patent/EP2923749A1/en not_active Withdrawn
- 2003-06-23 EP EP03732616A patent/EP1534662A1/en not_active Ceased
- 2003-06-23 UA UA20041210653A patent/UA79121C2/ru unknown
- 2003-06-23 JP JP2004516816A patent/JP4605368B2/ja not_active Expired - Fee Related
- 2003-06-23 AU AU2003239641A patent/AU2003239641A1/en not_active Abandoned
- 2003-06-23 RU RU2005101767/04A patent/RU2314288C2/ru not_active IP Right Cessation
- 2003-06-23 WO PCT/FI2003/000509 patent/WO2004002938A1/en not_active Ceased
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105566137A (zh) * | 2015-12-25 | 2016-05-11 | 安徽丰原发酵技术工程研究有限公司 | 一种从甜菜糖蜜中分离纯化甜菜碱的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20040006222A1 (en) | 2004-01-08 |
| EP2923749A1 (en) | 2015-09-30 |
| US7009076B2 (en) | 2006-03-07 |
| WO2004002938A1 (en) | 2004-01-08 |
| EP1534662A1 (en) | 2005-06-01 |
| RU2005101767A (ru) | 2005-07-20 |
| RU2314288C2 (ru) | 2008-01-10 |
| AU2003239641A1 (en) | 2004-01-19 |
| JP2005530850A (ja) | 2005-10-13 |
| FI20021251A0 (fi) | 2002-06-26 |
| JP4605368B2 (ja) | 2011-01-05 |
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