WO1991006880A1 - Materiau reflechissant - Google Patents

Materiau reflechissant Download PDF

Info

Publication number
WO1991006880A1
WO1991006880A1 PCT/GB1990/001690 GB9001690W WO9106880A1 WO 1991006880 A1 WO1991006880 A1 WO 1991006880A1 GB 9001690 W GB9001690 W GB 9001690W WO 9106880 A1 WO9106880 A1 WO 9106880A1
Authority
WO
WIPO (PCT)
Prior art keywords
carrier sheet
film
microparticles
reflective
embossing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB1990/001690
Other languages
English (en)
Inventor
Douglas Lees
Anthony Arthur Oldman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
STORECHANGE Ltd
Original Assignee
STORECHANGE Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by STORECHANGE Ltd filed Critical STORECHANGE Ltd
Publication of WO1991006880A1 publication Critical patent/WO1991006880A1/fr
Priority to GB9202856A priority Critical patent/GB2251091B/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/12—Reflex reflectors
    • G02B5/126—Reflex reflectors including curved refracting surface
    • G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix

Definitions

  • the present invention relates to a reflective material which is useful particularly but by no means exclusively in road safety applications (eg. for providing a reflective sleeve on a road cone so as to render the cone more visible in the light from a car headlamps during day and night time driving) or traffic signs.
  • road safety applications eg. for providing a reflective sleeve on a road cone so as to render the cone more visible in the light from a car headlamps during day and night time driving
  • traffic signs eg. for providing a reflective sleeve on a road cone so as to render the cone more visible in the light from a car headlamps during day and night time driving
  • BS 873:Part 6:1983 specifies criteria which retroreflective and non-retrofeflective signs should meet.
  • retroreflective materials are classified as Class 1, 2 or 3 according to their minimum coefficients of retroreflection.
  • a retroreflective material for use on a road cone must meet the Class 2 reflectivity requirements for white light and furthermore must have a minimum luminance factor (for white light) of 0.25.
  • There is a problem with prior art reflective material for use on road cones in that the production methods used for the prior art materials produce inconsistent products in that the minimum values of reflectivity and luminance (as specified by the above mentioned BS 873 Class 2) are not always simultaneously met.
  • the prior art material may satisfy the luminance minimum but not the reflectivity minima or vice versa.
  • a reflective material comprising a carrier sheet with a finely embossed surface, a thin reflective film deposited on said surface and of a thickness such that the exposed surface of the film follows the contours of the embossing, and transparent microparticles received within the recesses and bonded c the surface of the reflective film-
  • a method of producing a reflective material comprising providing a base material which itself comprises a carrier sheet with a finely embossed surface having deposited thereon a thin reflective film of a thickness such that the exposed surface of the film follows the contours of the embossing, and bonding transparent microparticles to said exposed surface of the film such that the microparticles are received within the recesses of the film.
  • the carrier sheet is preferably of a plastics material, most preferably a flexible plastics carrier sheet.
  • the material of the invention is particularly- useful as a reflective sleeve for a traffic cone.
  • a suitably shaped blank of the material eg. trapezoidal
  • a general conical or frusto-conical shape which may simply be located on the cone.
  • the carrier sheet may be clear or opaque and preferably has a thickness of 150 to 300 microns dependent on final application.
  • the carrier sheet is preferably of PVC.
  • the PVC should be a high impact PVC (ie. of low plasticiser content).
  • the PVC sheet is a calendered sheet. Such materials are comparatively easy to emboss and their high impact properties are required for the preferred use of the reflective material (ie. as a sleeve for a road cone).
  • the size of the embossed pattern is preferably so related to the cross- sectional size of the microparticles that the surface depressions of the embossed pattern will receive only a single microparticle, a portion of which will project out of the depression.
  • the number of depressions (in the embossed pattern) per unit area should preferably be such that adjacent portions of microparticles projecting from the depressions are either in contact with each other or in close proximity thereto. It should not however be assumed that every depressison of the embossed pattern must receive a microparticle since the methods by which the material will be produced (see below) cannot guarantee that this will be the case. However, a substantial proportion of the depressions will receive a microparticle. Furthermore, not all microparticles in the material will be received within a depression since some (although only a minor proportion) of the microparticles may simply be located on the surface of the material.
  • the embossing applied to the sheet is preferably a fine embossing pattern, particularly of the type known as satin, poplin, rayon, or suede embossing.
  • the reflective film is preferably a metallized film (most preferably aluminium) which can be deposited on the carrier sheet by conventional metallizing techniques, (eg. by electrodischarge).
  • the metal film should be very thin such that the exposed surface of the film substantially reproduces the embossed pattern of the sheet.
  • a printed marking may be applied to the metallized film. This will particularly be the case where the reflective material is to be used for signposts, road signs, clothing for emergency service officers, advertising posters etc. In this case the printing is done before the microparticles are applied. Alternativley for certain applications it may be desirable to print onto the microparticles .
  • the metallized film (with or without printed marking) is sprayed or otherwise coated with an adhesive, typically a low solids/high solvent based adhesive.
  • the adhesive may take the form of a silver ink (preferably matt).
  • Transparent microparticles (which are preferably of glass and which are preferably microspheres) are scattered onto the adhesive so that they become bonded to the metallic film.
  • the adhesive may then be dried and excess microparticles removed.
  • the reflective side of the material may be coated with a protective layer, utilising a self-cleaning sealing medium, this being dependent upon final application.
  • the advantage of the film is that the reflective material may be considered to be self-cleaning in that (during outdoor use) any deposits of dirt on the material are easily washed off by rain.
  • the reflective film be "silvery" aluminium and that the adhesive be a silver ink. It is however within the scope of the invention for the reflective film (which may be a metallic layer) and/or the adhesive to be of another colour for the case where the material is required to have special reflectivity requirements for that colour. It will be appreciated from the foregoing description that the material of the invention is comparatively easy to produce.
  • Fig 1 is a schematic cross-section to an enlarged scale showing one embodiment of light reflective material in accordance with the invention.
  • Fig 2 is an enlarged view of Fig 1.
  • the reflective material 1 illustrated in Fig 1 comprises a base layer 2, a metallized film 3, and microspheres 4.
  • Base layer 2 is of a calendered, high impact PVC having a thickness of up to 300 microns, preferably 150 to 300 microns (the exact value in this range being dependent on the intended use of the material 1).
  • the PVC will typically have a specific gravity of about 1.33.
  • the base layer 2 has been pre-formed (ie prior to the manufacture of the material 1) with a fine embossing pattern of the rayon, poplin, satin or suede type so that there are a multitude of the surface depressions per square centimetre of the material.
  • the metallized film 3 is of aluminium and has been deposited by conventional techniques onto the base layer so that the embossed pattern thereof is substantially reproduced in the film 3.
  • the aluminium will be deposited in an amount of about 0.08 grammes per square metre onto the base layer 1 thus giving a coating thickness of about .003 microns.
  • microspheres 4 are bonded to the metallic coating preferably by means of a layer of a silver printing ink 5 (preferably a matt ink).
  • the microspheres 3 will typically be in the size range 50 to 150 microns. Furthermore, it is possible to use non-spherical glass microparticles instead of the microspheres 4.
  • the illustrated microspheres 4 each locate (or "sit") in a reflectove cup with a portion of the microsphere 4 projecting above layer 1.
  • the size of the microspheres 4 is so related to the embossing pattern that the projecting portions of adjacent microspheres 4 are in contact with each other or at least are in close proximity to each other. It should however be noted that the structure illustrated in Fig.l is somewhat idealised in that each depression in the embossing pattern is shown as receiving a microsphere. In practice a minor proportion of the depressions may not be so occupied. Furthermore a minor proportion of microspheres may "sit" on the layer of microspheres 4.
  • the exemplary process starts with a reel of base material which comprises the embossed PVC carrier sheet 2 on which has been deposited the metallized layer 3.
  • the base material is unwound and is passed successively through the following sequence of operations.
  • a) Application of adhesive preferably a silver printing ink onto the exposed surface of the metallized layer 3.
  • the purpose of the ink is to serve as a binding agent.
  • the ink may be applied by a spray and the amount used is dependent on the requirements for the finished product.
  • Glass microspheres are scattered in excess onto the ink layer (ie an amount of glass microspheres are used greater than that required for the final product). The microspheres may be applied by means of a scatter coating roller.
  • the material is then passed through a curing or drying oven by means of a heat resistant belt, eg. Kevlar (Registered Trade Mark) belt so that the ink may be cured/dried.
  • a heat resistant belt eg. Kevlar (Registered Trade Mark) belt
  • the heating medium used is preferably air drawn down onto the ink (preferably with fan assistance) although "infra-red” or “gas heated” systems could be used. d) Once the drying/curing of the ink has been achieved the excess microspheres are removed from the surface by means of a variable speed elliptical roller vibrating on the reverse surface of the material. Any beads shaken free are collected for recycling. e) The material is then passed through a second stage warm air drier to complete the drying process. This completes preparation of the material as illustrated in Fig 1 which may now be cut into panel form or rolled dependent on final requirements.
  • stage (e) it is possible to apply a polyurethane or acrylic coating or a vinyl acrylic VARNISH over the microspheres to provide self-cleaning sealing medium.
  • an adhesive coating may be applied to the reverse (ie exposed) surface of the PVC layer if so required.
  • provision may be made immediately after stage (e) for further microsphere removal as in stage (d). This will enable extra control on luminance and reflectivity/refractivity as necessary.
  • the material tested comprised a flexible PVC carrier sheet with a suede emboss on which was deposited a metallized aluminium layer.
  • the microspheres were size 16s which have a size range of 74-105 microns.
  • the material had a luminance factor of 0.29 (for white light) which is to be compared with the minimum value of 0.25 as specified by BS 873: Part 6.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Laminated Bodies (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Optical Elements Other Than Lenses (AREA)

Abstract

Un matériau (1) réflechissant comprend une feuille porteuse (2) à surface finement bosselée, une couche (3) mince réflechissante déposée sur la surface et d'une épaisseur telle que la surface exposée du film suit les contours des bosses et des micro-particules transparentes (4) logées dans les creux du film réfléchissant et agglomérées à celui-ci.
PCT/GB1990/001690 1989-11-02 1990-11-02 Materiau reflechissant Ceased WO1991006880A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB9202856A GB2251091B (en) 1989-11-02 1992-02-11 Reflective material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB898924751A GB8924751D0 (en) 1989-11-02 1989-11-02 Reflective material
GB8924751.4 1989-11-02

Publications (1)

Publication Number Publication Date
WO1991006880A1 true WO1991006880A1 (fr) 1991-05-16

Family

ID=10665614

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1990/001690 Ceased WO1991006880A1 (fr) 1989-11-02 1990-11-02 Materiau reflechissant

Country Status (6)

Country Link
EP (1) EP0498826A1 (fr)
AU (1) AU6629090A (fr)
GB (1) GB8924751D0 (fr)
IE (1) IE903964A1 (fr)
WO (1) WO1991006880A1 (fr)
ZA (1) ZA908811B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0590405A1 (fr) * 1992-10-02 1994-04-06 E. DITTRICH KG "Schlüssel"-Erzeugnisse Matériau en bande avec une couche de base en mousse
US6641880B1 (en) 1998-04-30 2003-11-04 3M Innovative Properties Company Signage having films to reduce power consumption and improve luminance uniformity and method for using same
CN112526659A (zh) * 2021-01-27 2021-03-19 叶县广达铝业有限责任公司 一种机动车号牌用反光铝卷带及其生产工艺和反光铝板

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989775A (en) * 1971-03-01 1976-11-02 Bakelite Xylonite Limited Method of making a retro-reflective beaded material
DE2929313A1 (de) * 1978-07-20 1980-01-31 Minnesota Mining & Mfg Formkoerper mit mikrostrukturierter oberflaeche sowie verfahren und formmassen zu deren herstellung
US4332847A (en) * 1979-09-20 1982-06-01 Relfexite Corporation Method for compression molding of retroreflective sheeting and sheeting produced thereby
US4388359A (en) * 1982-04-23 1983-06-14 Minnesota Mining And Manufacturing Company Embossed pavement-marking sheet material
EP0170518A2 (fr) * 1984-08-03 1986-02-05 Minnesota Mining And Manufacturing Company Feuille rétroréfléchissante comportant un motif dépendant de la direction de vision
FR2572023A1 (fr) * 1984-10-23 1986-04-25 Arib Procede de realisation d'un revetement retroreflechissant a surface lisse sur une piece moulee ainsi qu'un element moule obtenu selon ledit procede
EP0223565A2 (fr) * 1985-11-18 1987-05-27 Minnesota Mining And Manufacturing Company Revêtement rétroréflecteur à lentilles encapsulées avec film de couverture transparent résistant aux intempéries
EP0227448A2 (fr) * 1985-12-23 1987-07-01 Minnesota Mining And Manufacturing Company Revêtement rétroréflecteur plat encapsulé et sa méthode de mise en oeuvre

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3989775A (en) * 1971-03-01 1976-11-02 Bakelite Xylonite Limited Method of making a retro-reflective beaded material
DE2929313A1 (de) * 1978-07-20 1980-01-31 Minnesota Mining & Mfg Formkoerper mit mikrostrukturierter oberflaeche sowie verfahren und formmassen zu deren herstellung
US4332847A (en) * 1979-09-20 1982-06-01 Relfexite Corporation Method for compression molding of retroreflective sheeting and sheeting produced thereby
US4388359A (en) * 1982-04-23 1983-06-14 Minnesota Mining And Manufacturing Company Embossed pavement-marking sheet material
EP0170518A2 (fr) * 1984-08-03 1986-02-05 Minnesota Mining And Manufacturing Company Feuille rétroréfléchissante comportant un motif dépendant de la direction de vision
FR2572023A1 (fr) * 1984-10-23 1986-04-25 Arib Procede de realisation d'un revetement retroreflechissant a surface lisse sur une piece moulee ainsi qu'un element moule obtenu selon ledit procede
EP0223565A2 (fr) * 1985-11-18 1987-05-27 Minnesota Mining And Manufacturing Company Revêtement rétroréflecteur à lentilles encapsulées avec film de couverture transparent résistant aux intempéries
EP0227448A2 (fr) * 1985-12-23 1987-07-01 Minnesota Mining And Manufacturing Company Revêtement rétroréflecteur plat encapsulé et sa méthode de mise en oeuvre

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Patent Abstracts of Japan, volume 10, no. 22, (P-424)(2079), 28 January 1986; & JP-A-60175004 (IDEKOOGYO K.K.), 9 September 1985 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0590405A1 (fr) * 1992-10-02 1994-04-06 E. DITTRICH KG "Schlüssel"-Erzeugnisse Matériau en bande avec une couche de base en mousse
US6641880B1 (en) 1998-04-30 2003-11-04 3M Innovative Properties Company Signage having films to reduce power consumption and improve luminance uniformity and method for using same
CN112526659A (zh) * 2021-01-27 2021-03-19 叶县广达铝业有限责任公司 一种机动车号牌用反光铝卷带及其生产工艺和反光铝板

Also Published As

Publication number Publication date
AU6629090A (en) 1991-05-31
EP0498826A1 (fr) 1992-08-19
IE903964A1 (en) 1991-05-08
GB8924751D0 (en) 1989-12-20
ZA908811B (en) 1991-08-28

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