WO2002043965A2 - Support imprimable a jet d'encre - Google Patents

Support imprimable a jet d'encre Download PDF

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Publication number
WO2002043965A2
WO2002043965A2 PCT/US2001/044524 US0144524W WO0243965A2 WO 2002043965 A2 WO2002043965 A2 WO 2002043965A2 US 0144524 W US0144524 W US 0144524W WO 0243965 A2 WO0243965 A2 WO 0243965A2
Authority
WO
WIPO (PCT)
Prior art keywords
recited
construction
composition
solvent
ink jet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2001/044524
Other languages
English (en)
Other versions
WO2002043965A9 (fr
WO2002043965A3 (fr
Inventor
Frank Yen-Jer Shih
Dalubhai M. Lad
Zhisong Huang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Avery Dennison Corp
Original Assignee
Avery Dennison Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avery Dennison Corp filed Critical Avery Dennison Corp
Priority to AU2002227003A priority Critical patent/AU2002227003A1/en
Publication of WO2002043965A2 publication Critical patent/WO2002043965A2/fr
Publication of WO2002043965A3 publication Critical patent/WO2002043965A3/fr
Anticipated expiration legal-status Critical
Publication of WO2002043965A9 publication Critical patent/WO2002043965A9/fr
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0091—Complexes with metal-heteroatom-bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
    • C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
    • C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29—Laminated material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/334—Applications of adhesives in processes or use of adhesives in the form of films or foils as a label
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • C09J2301/162—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only

Definitions

  • the present invention relates to compositions for enhancing the ink-receptiveness of printable materials, and coated substrates and constructions made with such compositions .
  • Transparent labels have been made with a clear film facestock, a pressure-sensitive adhesive laminated thereto, and a protective release liner, such as a siliconized film or paper backing.
  • transparent plastic film facestocks are not particularly ink-receptive and do not provide the high print quality demanded by consumers.
  • U.S. Patent No. 5,407,718 Popat et al .
  • the '718 patent describes transparent paper label sheets that can be printed with a high quality image in ink jet, xerographic, and other printers. Despite the commercial success of the label sheets described in the '718 patent, a continuing need exists for improved ink-receptive compositions and coated products.
  • a coatable composition comprises a mixture of polyvinyl pyrrolidone, silica, and a chromium complex capable of crosslinking polyvinyl pyrrolidone, with the components preferably being dissolved or dispersed in a solvent, e.g., an alcohol, or a mixture of alcohol and water. It is also preferred to include in the composition a solvent, such as alcohol or a mixture of alcohol and water. In water-free systems, a small amount of organic acid is preferably added to improve pot life. In mixed alcohol/water-based systems, it is preferred to include a small amount of polyethylene imine, which acts as a mordant and improves the ink-receptivity of the composition.
  • ink-receptive constructions are prepared by coating the improved composition onto a facestock or label stock and drying the coated construction.
  • the products exhibit good ink-receptivity and are particularly suited for use in ink jet printers.
  • Transparent, as well as opaque, label constructions, coated papers, films, signage, and other products are made using the improved ink-receptive compositions.
  • a particularly preferred transparent label construction has a polyester film facestock, one surface of which is coated with a pressure-sensitive adhesive layer, which is protected until use by a release liner.
  • An ink-receptive topcoat is applied to the outer surface of the polyester film. Labels can be die-cut into the construction, which is designed to perform well in ink jet and other printers . BRIEF DESCRIPTION OF THE DRAWINGS
  • the Figure is a schematic side view of a label sheet according to one embodiment of the invention.
  • a coatable composition in a first aspect of the invention, comprises a mixture of polyvinyl pyrrolidone, silica, and a chromium complex capable of crosslinking polyvinyl pyrrolidone.
  • the components are dissolved or dispersed in a solvent.
  • Other components can be added to improve pot life, coatability, and other properties as described below.
  • compositions contain, on a parts-by- weight basis, from about 2 to 30% (preferably about 5 to 20%) polyvinyl pyrrolidone, about 2 to 10% (preferably about 3 to 7%) silica, and about 0.25 to 1% chromium complex. Where a solvent is present, it comprises from about 50 to 95% (preferably about 75 to 95%) of the composition.
  • compositions prepared in accordance with the present invention utilize PVP having a K value of from about 60 to 100 and a weight average molecular weight (M w ) of from, about 300,000 to 2,500,000. More preferably, the PVP has a K value of from about 75 to 90 and a M w of from about 750,000 to 1,000,000.
  • PVP is available from a number of companies, including ISP Technologies, Inc. and BASF.
  • the silica component imparts ink absorptivity and ink permanency to the coated construction.
  • silica Several types of silica are known, with varying pore size (and hence, varying ink-absorptivity) , including fumed silica, preciptated silica, and silica gel.
  • Silica gel has the highst pore volume and is preferred.
  • a nonlimiting example is Gasil HP-39, from Crosfield Company (Joliet, IL) .
  • the resulting coated label stock will not exhibit the desired "touch clear” property (the ability to appear clear when pressed against a substrate, such as an envelope) .
  • the chromium complex present in the composition is capable of crosslinking polyvinyl pyrrolidone.
  • a preferred, nonlimiting example of such a complex is Quilon C, made by E.I. du Pont de Nemours and Company. Other grades of Quilon complexes are also available.
  • Du Pont product literature describes Quilon as "a solution, largely m isopropanol, of a dark green, chemically reactive complex in which a C 1 -C ⁇ 8 fatty acid is coordinated with trivalent chromium.”
  • Quilon C has CAS Registry No. 65229-24-5. It has been described as pentahydrox (tetradecanoato) dichromium.
  • a number of organic and mixed organic/aqueous solvents can be used to prepare coatable compositions according to the present invention.
  • the solvent is an alcohol.
  • the solvent is a mixture of alcohol and water.
  • other organic solvents may be used.
  • n-butanol 117.7°C
  • the preferred alcohol is isopropanol, which is much more miscible with water than is n-butanol.
  • an organic acid for example, acetic acid
  • the acid retards the chromium complex-catalyzed crosslinking of PVP at room temperature, thus improving the pot life of the composition and facilitating coating in conventional coaters.
  • the viscosity of the composition may build undesirably with time, making it extremely difficult to coat the composition.
  • the organic acid is present in a positive amount up to about 5%, preferably from about 0.1 to 5%, based on the weight of all components.
  • the ink-receptivity of mixed alcohol/water-based systems can be improved by the addition of a mordant, such as polyethylene imine (PEI) .
  • a mordant such as polyethylene imine (PEI)
  • PEI polyethylene imine
  • a positive amount up to about 25%, more preferably from about 1 to 10%, of an aqueous polyethylene, imine solution is included in some embodiments of the invention. It has been found that adding neat PEI to the composition can cause gelling. This is avoided by pre-diluting the PEI with water.
  • the coatable compositions are prepared by mixing polyvinyl pyrrolidone, silica, chromium complex and other components (e.g., solvent, organic acid, PEI, etc.) using mixing techniques and apparatus well known in the art .
  • the chromium complex, as well as any organic acid, is preferably added to the composition just prior to coating. Once the components are mixed, the composition can be stored with continuous mixing for at least one month without chromium complex, and up to 8-10 hours with the complex.
  • the composition can be coated on a facestock or label stock, using conventional coating techniques.
  • Nonlimiting examples of such techniques include slot die, air knife, brush, curtain, extrusion, blade, floating knife, gravure, kiss roll, knife-over-blanket, knife-over-roll, offset gravure, reverse roll, reverse-smoothing roll, rod, and squeeze roll coating.
  • the composition can also be applied to paper substrates in a size press, during paper manufacture.
  • the composition can be applied using any conventional technique or process, including without limitation, coating "on-press” during the converting process (e.g., in concert with the processes of die-cutting, matrix stripping, etc.), coating "off-press” using a separate coater, and other application methods known in the art.
  • the coated construction After being coated or otherwise applied to a facestock or label stock, the coated construction is dried at room temperature or in an oven to remove most of the solvent and other volatile components.
  • coating technique for a given application depends on several factors, including the cost and availability of equipment, the facestock or labelstock to be coated, the viscosity and solids content of the composition, the choice of solvent used, the desired coat weight, etc. For some applications, a solids content as high as 40% is acceptable, with 15 to 20% being somewhat more preferred. Typical (but nonlimiting) values of the viscosity of the composition prior to coating range from about 500 to 1,000 centipoise. In general, coat weights of from about 2-30g/m 2 , more preferably about 5-15g/m 2 , (measured on a dry basis) are preferred. Coated clear film facestocks (e.g., polyester) are advantageously prepared with composition coat weights of from about 5 to 15g/m 2 (dry weight) .
  • Wide format products are generally manufactured as wide rolls (24 or more inches wide) , and are roll-fed into large printers for imaging. They are typically employed in commercial settings and are used to make, e.g., movie theater posters, outdoor signage, large advertisements, fleet marking (i.e., truck panel advertising) , and other products .
  • Narrow format products are generally manufactured as narrow rolls or individual sheets, and can be roll-fed or sheet-fed into printers for imaging. They are typically used in the office or home, and include, without limitation, computer printer paper, labels, transparencies, and similar products.
  • Coatable substrates useful in the practice of the present invention include plastic film, especially transparent film, as well as paper, cardboard, corrugated board, metal film or foil, fabric, and other facestocks and label stocks traditionally used for ink printing application, particularly ink jet printing.
  • Self-wound materials and other linerless materials are also suitable substrates.
  • a nonlimiting example includes self-wound tapes.
  • Nonlimiting examples of plastic facestocks suitable for use with the present invention include polyester, polystyrene, polyvinyl chloride, nylon, and polyolefin (for example, polyethylene) films, as well as polymer blends.
  • the films may be cast, extruded, or coextruded.
  • film facestocks may be pre-treated with a primer to improve coating anchorage to the film.
  • a nonlimiting example is Adcote 69X 100 - from Morton International (now a subsidiary of Rohm Haas) - in tolulene) .
  • Primer coated PET facestock is also available from SKC America, Inc. (Covington, GA) .
  • Nonlimiting examples of paper facestocks include offset, bond, text, cover, index, lightweight printing paper, litho paper, and sulfite paper.
  • Label stocks include, without limitation, a variety of printable label constructions or assemblies well known in the art, each typically comprising a label facestock (sheet or roll) having at least one inner and at least one outer surface, a pressure-sensitive adhesive (PSA) adhered to at least one inner surface of the label facestock, and a removable release liner protecting the PSA until use, the entire assembly forming a sandwich-like construction.
  • a label facestock sheet or roll
  • PSA pressure-sensitive adhesive
  • Figure- 1 is a schematic illustration of a sheet of ink- receptive labels prepared in accordance with one embodiment of the invention.
  • the construction 10 has a sandwich structure, in which a facestock 12, a pressure-sensitive adhesive (PSA) layer 18, a release liner 24, and an ink-receptive topcoat 30 are coated on or laminated to each other in the order shown.
  • the facestock 12 has first and second surfaces 14 and 16;
  • the PSA layer 18 has first and second surfaces 20 and 22;
  • the release liner 24 has first and second surfaces 26 and 28, and
  • the ink-receptive top coat has first and second surfaces 32 and 34.
  • ES relative thickness
  • a plurality of die cuts 36 extend through the ink- receptive top coat, the facestock, and the pressure-sensitive adhesive, but not the release liner.
  • the die cuts facilitate detachment and removal of individual labels from the label sheet .
  • a construction as shown in Figure 1 is prepared in a conventional manner.
  • a PSA is coated on a siliconized release liner; an ink-receptive coating is applied to one side of a facestock; and the two subassemblies are laminated to each other.
  • a PSA is coated on one side of a facestock and laminated to a protective release liner.
  • An ink-receptive coating is then applied to the other side of the facestock.
  • the layers of the construction can also be applied in other ways and in alternative sequences known to those skilled in the art.
  • ink-receptive label construction prepared in accordance with the invention.
  • ink-receptive papers, films, and other products can be made by coating or otherwise applying an ink-receptive composition to a substrate.
  • Example 1 contains Quilon C.
  • Example 2 is the same as Example 1, but additionally contains acetic acid.
  • Example 3 contains Quilon C, no acetic acid, and a solvent consisting of a mixture of isopropyl alcohol, water, and polyethylene imine.
  • Controls 1-3 were examined for eleven ink jet image properties.
  • Optical density measurements were taken using a reflective densitometer (e.g., an X-rite densitometer) with an aperature of 4 mm.
  • Black dry time A measure of the rate of absorption of black ink into a sheet of the printable media.
  • Black text quality A visual assessment of black ink printed letters and their acceptability. Wicking, feathering, dot gain, and other defects take away from text quality.
  • Black fill Refers to cascading and mottling effects with black ink.
  • Color dry time A measure of the rate of colored ink absorption into a sheet of printable media.
  • Color text quality A visual assessment of colored ink printed letters, and their acceptability. Wicking, feathering, dot gain and other defects take away from text quality. Color fill: Refers the cascading and mottling effects of colored inks .
  • Color-to-color bleed A common characteristic of ink-to- printable media interaction causing degradation in print quality by the bleeding of one color into an adjacent color. Black-to- yellow color bleed is the most noticeable.
  • Black density A measure of black ink image intensity using a reflectance densitometer.
  • CMY denisty A measure of color ink image intensity (cyan (C) , magenta (M) , and yellow (Y) ) using a reflectance densitometer.
  • Edge acuity/resolution The process or capability of making distinguishable the individual parts of an object, in closely adjacent optical images.
  • Water fastness The amount of colorant transferred from a printed area to an unprinted area when deionized water is dispensed at a 45° angle on the printed sample.
  • Examples 1-3 the print quality of Examples 1-3 was comparable or superior to that of Controls 1 and 2 in every category, with notable improvements in color-to-color bleed, edge accuity/resolution, and waterfastness.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Paints Or Removers (AREA)
  • Paper (AREA)

Abstract

L'invention concerne des compostions d'enduction et des supports réceptifs à l'encre, fabriqués avec lesdites compositions. Ces compositions contiennent un mélange de polyvinyl-pyrrolidone, de silice et de complexe de chrome servant à réticuler le polyvinyl-pyrrolidone. Ces compositions sont particulièrement utiles en tant que couches de finition réceptives à l'encre pour pellicules frontales et pour films à étiquettes utilisés dans les imprimantes à jet d'encre et autres types.
PCT/US2001/044524 2000-11-29 2001-11-29 Support imprimable a jet d'encre Ceased WO2002043965A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002227003A AU2002227003A1 (en) 2000-11-29 2001-11-29 Ink jet-printable media

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US72619600A 2000-11-29 2000-11-29
US09/726,196 2000-11-29

Publications (3)

Publication Number Publication Date
WO2002043965A2 true WO2002043965A2 (fr) 2002-06-06
WO2002043965A3 WO2002043965A3 (fr) 2002-08-22
WO2002043965A9 WO2002043965A9 (fr) 2003-11-20

Family

ID=24917604

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/044524 Ceased WO2002043965A2 (fr) 2000-11-29 2001-11-29 Support imprimable a jet d'encre

Country Status (2)

Country Link
AU (1) AU2002227003A1 (fr)
WO (1) WO2002043965A2 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005049753A1 (fr) * 2003-11-14 2005-06-02 3M Innovative Properties Company Indicateur de contact avec l'eau
EP1584467A1 (fr) * 2004-04-07 2005-10-12 Kawashima Co., Ltd. Feuille jetable pour la detection des substances radioactives
WO2006036556A1 (fr) * 2004-09-23 2006-04-06 Avery Dennison Corporation Etiquette et procede d'etiquetage
WO2006069332A3 (fr) * 2004-12-22 2007-04-19 Imation Corp Supports optiques pour recepteur de jet d'encre stratifie
US7744997B2 (en) 2001-10-05 2010-06-29 3M Innovative Properties Company Water contact indicator
WO2011010085A3 (fr) * 2009-07-23 2011-05-26 Gmc Marketing Limited MONTURE POUR oeUVRE D'ART
US8959812B2 (en) 2010-11-23 2015-02-24 Circle Graphics, Inc. Image display
US9738108B2 (en) 2013-03-14 2017-08-22 Circle Graphics, Inc. Image display and kit
US9861215B2 (en) 2010-11-23 2018-01-09 Circle Graphics, Inc. Image display with leather image substrate
WO2019097469A2 (fr) 2017-11-17 2019-05-23 3M Innovative Properties Company Couches réceptrices d'encre pour étiquettes durables
WO2020003188A2 (fr) 2018-06-29 2020-01-02 3M Innovative Properties Company Couches de réception d'encre pour étiquettes durables
US20230256765A1 (en) * 2020-07-10 2023-08-17 Brady Worldwide, Inc. Outdoor-Durable Inkjet-Receptive Topcoat Formula and Article

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5407718A (en) 1993-08-05 1995-04-18 Avery Dennison Corporation Transparent paper label sheets

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4592951A (en) * 1984-07-18 1986-06-03 Polaroid Corporation Ink jet recording sheet
US5241006A (en) * 1990-10-24 1993-08-31 Minnesota Mining And Manufacturing Company Printable transparency

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5407718A (en) 1993-08-05 1995-04-18 Avery Dennison Corporation Transparent paper label sheets
US5407718B1 (en) 1993-08-05 1999-03-02 Avery Dennison Corp Transparent paper label sheets

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7744997B2 (en) 2001-10-05 2010-06-29 3M Innovative Properties Company Water contact indicator
WO2005049753A1 (fr) * 2003-11-14 2005-06-02 3M Innovative Properties Company Indicateur de contact avec l'eau
US7732046B2 (en) 2003-11-14 2010-06-08 3M Innovative Properties Company Water contact indicator
US8182914B2 (en) 2003-11-14 2012-05-22 3M Innovative Properties Company Water contact indicator
EP1584467A1 (fr) * 2004-04-07 2005-10-12 Kawashima Co., Ltd. Feuille jetable pour la detection des substances radioactives
WO2006036556A1 (fr) * 2004-09-23 2006-04-06 Avery Dennison Corporation Etiquette et procede d'etiquetage
WO2006069332A3 (fr) * 2004-12-22 2007-04-19 Imation Corp Supports optiques pour recepteur de jet d'encre stratifie
WO2011010085A3 (fr) * 2009-07-23 2011-05-26 Gmc Marketing Limited MONTURE POUR oeUVRE D'ART
US9174483B2 (en) 2010-11-23 2015-11-03 Circle Graphics, Inc. Image display
US8966796B2 (en) 2010-11-23 2015-03-03 Circle Graphics, Inc. Image display
US8959812B2 (en) 2010-11-23 2015-02-24 Circle Graphics, Inc. Image display
US9545162B2 (en) 2010-11-23 2017-01-17 Circle Graphics, Inc. Method for manufacturing image display
US9861215B2 (en) 2010-11-23 2018-01-09 Circle Graphics, Inc. Image display with leather image substrate
US10092118B2 (en) 2010-11-23 2018-10-09 Circle Graphics, Inc. Method for manufacturing image display
US9738108B2 (en) 2013-03-14 2017-08-22 Circle Graphics, Inc. Image display and kit
WO2019097469A2 (fr) 2017-11-17 2019-05-23 3M Innovative Properties Company Couches réceptrices d'encre pour étiquettes durables
US11905429B2 (en) 2017-11-17 2024-02-20 3M Innovative Properties Company Ink-receptive layers for durable labels
WO2020003188A2 (fr) 2018-06-29 2020-01-02 3M Innovative Properties Company Couches de réception d'encre pour étiquettes durables
US12331213B2 (en) 2018-06-29 2025-06-17 3M Innovative Properties Company Ink-receptive layers for durable labels
US20230256765A1 (en) * 2020-07-10 2023-08-17 Brady Worldwide, Inc. Outdoor-Durable Inkjet-Receptive Topcoat Formula and Article

Also Published As

Publication number Publication date
AU2002227003A1 (en) 2002-06-11
WO2002043965A9 (fr) 2003-11-20
WO2002043965A3 (fr) 2002-08-22

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