WO2004016829A3 - Solutions de cuivrage electrolytique - Google Patents

Solutions de cuivrage electrolytique Download PDF

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Publication number
WO2004016829A3
WO2004016829A3 PCT/US2003/024747 US0324747W WO2004016829A3 WO 2004016829 A3 WO2004016829 A3 WO 2004016829A3 US 0324747 W US0324747 W US 0324747W WO 2004016829 A3 WO2004016829 A3 WO 2004016829A3
Authority
WO
WIPO (PCT)
Prior art keywords
solutions
copper plating
electrolytic copper
plating solutions
methods
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2003/024747
Other languages
English (en)
Other versions
WO2004016829A2 (fr
Inventor
Nicholas Michael Martyak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema Inc
Original Assignee
Atofina Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina Chemicals Inc filed Critical Atofina Chemicals Inc
Priority to CA002465363A priority Critical patent/CA2465363A1/fr
Priority to AU2003259049A priority patent/AU2003259049A1/en
Priority to EP03788347A priority patent/EP1529126A4/fr
Priority to JP2004529271A priority patent/JP2005535787A/ja
Publication of WO2004016829A2 publication Critical patent/WO2004016829A2/fr
Publication of WO2004016829A3 publication Critical patent/WO2004016829A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10PGENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
    • H10P14/00Formation of materials, e.g. in the shape of layers or pillars
    • H10P14/40Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
    • H10P14/46Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a liquid
    • H10P14/47Electrolytic deposition, i.e. electroplating; Electroless plating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/38Electroplating: Baths therefor from solutions of copper
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/12Semiconductors
    • C25D7/123Semiconductors first coated with a seed layer or a conductive layer
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/40Forming printed elements for providing electric connections to or between printed circuits
    • H05K3/42Plated through-holes or plated via connections
    • H05K3/423Plated through-holes or plated via connections characterised by electroplating method

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Manufacturing Of Printed Wiring (AREA)
  • Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)

Abstract

L'invention concerne des solutions de cuivrage électrolytique, des procédés permettant d'utiliser ces solutions et des produits formés à l'aide de ces procédés et de ces solutions. Ces solutions contiennent des alcanesulfonates de cuivre et des acides alcanesulfoniques libres, l'acide libre ayant une concentration comprise entre 0,05 et 2,50 M environ. Ces solutions sont destinées à la métallisation de tranchées ou de trous d'interconnexion, de trous débouchants ou de microtrous d'interconnexion de l'ordre du micron.
PCT/US2003/024747 2002-08-16 2003-08-08 Solutions de cuivrage electrolytique Ceased WO2004016829A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA002465363A CA2465363A1 (fr) 2002-08-16 2003-08-08 Solutions de cuivrage electrolytique
AU2003259049A AU2003259049A1 (en) 2002-08-16 2003-08-08 Electrolytic copper plating solutions
EP03788347A EP1529126A4 (fr) 2002-08-16 2003-08-08 Solutions de cuivrage electrolytique
JP2004529271A JP2005535787A (ja) 2002-08-16 2003-08-08 電解銅めっき液

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US40395402P 2002-08-16 2002-08-16
US60/403,954 2002-08-16
US10/620,042 2003-07-15
US10/620,042 US20040045832A1 (en) 1999-10-14 2003-07-15 Electrolytic copper plating solutions

Publications (2)

Publication Number Publication Date
WO2004016829A2 WO2004016829A2 (fr) 2004-02-26
WO2004016829A3 true WO2004016829A3 (fr) 2004-04-29

Family

ID=31891409

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2003/024747 Ceased WO2004016829A2 (fr) 2002-08-16 2003-08-08 Solutions de cuivrage electrolytique

Country Status (8)

Country Link
US (1) US20040045832A1 (fr)
EP (1) EP1529126A4 (fr)
JP (1) JP2005535787A (fr)
CN (1) CN1592800A (fr)
AU (1) AU2003259049A1 (fr)
CA (1) CA2465363A1 (fr)
TW (1) TWI285687B (fr)
WO (1) WO2004016829A2 (fr)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10311575B4 (de) * 2003-03-10 2007-03-22 Atotech Deutschland Gmbh Verfahren zum elektrolytischen Metallisieren von Werkstücken mit Bohrungen mit einem hohen Aspektverhältnis
JP4238051B2 (ja) * 2003-03-11 2009-03-11 日本ペイント株式会社 カチオン電着塗料組成物及びカチオン電着塗料組成物の安定化方法
JP2005272874A (ja) * 2004-03-23 2005-10-06 Sumitomo Bakelite Co Ltd 回路基板の製造方法
TW200632147A (fr) 2004-11-12 2006-09-16
JP4704761B2 (ja) * 2005-01-19 2011-06-22 石原薬品株式会社 電気銅メッキ浴、並びに銅メッキ方法
US20060231409A1 (en) * 2005-03-31 2006-10-19 Tdk Corporation Plating solution, conductive material, and surface treatment method of conductive material
JP4764718B2 (ja) * 2005-12-28 2011-09-07 新光電気工業株式会社 スルーホールの充填方法
US7575666B2 (en) * 2006-04-05 2009-08-18 James Watkowski Process for electrolytically plating copper
US20080110759A1 (en) * 2006-11-14 2008-05-15 Tower Semiconductor Ltd. Self Terminating Overburden Free Plating (STOP) Of Metals On Patterned Wafers
TWI341554B (en) * 2007-08-02 2011-05-01 Enthone Copper metallization of through silicon via
JP2009041097A (ja) * 2007-08-10 2009-02-26 Rohm & Haas Electronic Materials Llc 銅めっき方法
PL2103717T3 (pl) * 2008-02-29 2010-07-30 Atotech Deutschland Gmbh Kąpiel oparta na pirofosforanach do nakładania warstw stopów cyny
US10221496B2 (en) 2008-11-26 2019-03-05 Macdermid Enthone Inc. Copper filling of through silicon vias
US8388824B2 (en) 2008-11-26 2013-03-05 Enthone Inc. Method and composition for electrodeposition of copper in microelectronics with dipyridyl-based levelers
US20100206737A1 (en) * 2009-02-17 2010-08-19 Preisser Robert F Process for electrodeposition of copper chip to chip, chip to wafer and wafer to wafer interconnects in through-silicon vias (tsv)
US20120018310A1 (en) 2009-04-07 2012-01-26 Basf Se Composition for metal plating comprising suppressing agent for void free submicron feature filling
WO2010115756A1 (fr) * 2009-04-07 2010-10-14 Basf Se Composition pour le plaquage de métaux comportant un agent suppresseur de remplissage des fissures submicroniques éliminant les vides
US8262894B2 (en) 2009-04-30 2012-09-11 Moses Lake Industries, Inc. High speed copper plating bath
US8962085B2 (en) * 2009-06-17 2015-02-24 Novellus Systems, Inc. Wetting pretreatment for enhanced damascene metal filling
TWI465609B (zh) * 2009-07-07 2014-12-21 Furukawa Electric Co Ltd An electrolytic copper film, a method for producing the same, and a copper electrolytic solution for manufacturing a copper electrolytic film
EP2483454A2 (fr) * 2009-09-28 2012-08-08 Basf Se Composition de cuivrage électrolytique
WO2011102276A1 (fr) * 2010-02-22 2011-08-25 Jx日鉱日石金属株式会社 Solution aqueuse de sulfonate de cuivre de grande pureté et son procédé de fabrication
KR101705734B1 (ko) 2011-02-18 2017-02-14 삼성전자주식회사 구리 도금 용액 및 이것을 이용한 구리 도금 방법
US9631292B2 (en) 2011-06-01 2017-04-25 Basf Se Composition for metal electroplating comprising an additive for bottom-up filling of though silicon vias and interconnect features
EP2530102A1 (fr) 2011-06-01 2012-12-05 Basf Se Additif et composition pour dépôt électrique métallique comportant un additif pour remplissage ascendant de trous traversant le silicium
CN103361694A (zh) * 2013-08-08 2013-10-23 上海新阳半导体材料股份有限公司 一种用于3d铜互连高深宽比硅通孔技术微孔电镀填铜方法
CN104762643A (zh) * 2014-12-17 2015-07-08 安捷利电子科技(苏州)有限公司 一种通孔、盲孔和线路共镀的镀铜药水
US20180298515A1 (en) * 2015-04-27 2018-10-18 Jcu Corporation Method for managing copper sulfate plating solution
CN108174615B (zh) 2015-09-29 2023-02-17 大日本印刷株式会社 布线构造体制造方法、图案构造体形成方法及压印用模具
JP2017222903A (ja) * 2016-06-15 2017-12-21 公立大学法人大阪府立大学 ハロゲンフリーまたは低ハロゲン電解穴埋め銅めっき浴
EP3516096A4 (fr) * 2016-09-22 2020-10-21 MacDermid Enthone Inc. Électrodéposition de cuivre en microélectronique
CN106757191B (zh) * 2016-11-23 2019-10-01 苏州昕皓新材料科技有限公司 一种具有高择优取向的铜晶体颗粒及其制备方法
TWI647342B (zh) * 2017-08-03 2019-01-11 國家中山科學研究院 Copper-silver two-component metal plating liquid for semiconductor wires and plating method
KR102641595B1 (ko) * 2017-09-04 2024-02-27 바스프 에스이 평탄화 제제를 포함하는 금속 전기 도금용 조성물
CN108914171B (zh) * 2018-07-19 2020-05-19 广东工业大学 一种加速铜沉积添加剂及其制备方法和应用
CN110983389B (zh) * 2019-12-31 2020-11-13 广州三孚新材料科技股份有限公司 一种钢铁件无氰碱性电镀铜液及其制备方法
CN113279026B (zh) * 2021-04-25 2022-09-02 厦门理工学院 一种用于铜箔盲孔填孔的药水
CN116856022B (zh) * 2023-07-05 2024-02-20 诺博环保科技(中山)有限公司 一种电镀用合金添加剂及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2525943A (en) * 1947-09-24 1950-10-17 Standard Oil Co Copper plating bath and process
DE4338148A1 (de) * 1993-11-04 1995-05-11 Atotech Deutschland Gmbh Wäßrige alkansulfonsaure Lösung zur Kupferabscheidung
JPH10310881A (ja) * 1997-05-12 1998-11-24 Toppan Printing Co Ltd 銅系金属材料のエッチング方法
US6605204B1 (en) * 1999-10-14 2003-08-12 Atofina Chemicals, Inc. Electroplating of copper from alkanesulfonate electrolytes

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2252942A (en) * 1938-07-01 1941-08-19 Clyde M Mourer Metal spray gun
US3770598A (en) * 1972-01-21 1973-11-06 Oxy Metal Finishing Corp Electrodeposition of copper from acid baths
DE2204326C3 (de) * 1972-01-26 1981-07-09 Schering Ag Berlin Und Bergkamen, 1000 Berlin Wäßriges saures Bad zur galvanischen Abscheidung von glänzenden und duktilen Kupferüberzügen
US3956084A (en) * 1972-12-14 1976-05-11 M & T Chemicals Inc. Electrodeposition of copper
US4374709A (en) * 1980-05-01 1983-02-22 Occidental Chemical Corporation Process for plating polymeric substrates
US4376685A (en) * 1981-06-24 1983-03-15 M&T Chemicals Inc. Acid copper electroplating baths containing brightening and leveling additives
US4555315A (en) * 1984-05-29 1985-11-26 Omi International Corporation High speed copper electroplating process and bath therefor
US4673469A (en) * 1984-06-08 1987-06-16 Mcgean-Rohco, Inc. Method of plating plastics
US4673459A (en) * 1985-06-18 1987-06-16 Kamyr, Inc. Radial configuration of evaporator heating elements and method
US5068013A (en) * 1988-08-23 1991-11-26 Shipley Company Inc. Electroplating composition and process
US5051154A (en) * 1988-08-23 1991-09-24 Shipley Company Inc. Additive for acid-copper electroplating baths to increase throwing power
US5174886A (en) * 1991-02-22 1992-12-29 Mcgean-Rohco, Inc. High-throw acid copper plating using inert electrolyte
US5385661A (en) * 1993-09-17 1995-01-31 International Business Machines Corporation Acid electrolyte solution and process for the electrodeposition of copper-rich alloys exploiting the phenomenon of underpotential deposition
DE19545231A1 (de) * 1995-11-21 1997-05-22 Atotech Deutschland Gmbh Verfahren zur elektrolytischen Abscheidung von Metallschichten
US6270601B1 (en) * 1998-11-02 2001-08-07 Coorstek, Inc. Method for producing filled vias in electronic components
US6444110B2 (en) * 1999-05-17 2002-09-03 Shipley Company, L.L.C. Electrolytic copper plating method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2525943A (en) * 1947-09-24 1950-10-17 Standard Oil Co Copper plating bath and process
DE4338148A1 (de) * 1993-11-04 1995-05-11 Atotech Deutschland Gmbh Wäßrige alkansulfonsaure Lösung zur Kupferabscheidung
JPH10310881A (ja) * 1997-05-12 1998-11-24 Toppan Printing Co Ltd 銅系金属材料のエッチング方法
US6605204B1 (en) * 1999-10-14 2003-08-12 Atofina Chemicals, Inc. Electroplating of copper from alkanesulfonate electrolytes

Also Published As

Publication number Publication date
TWI285687B (en) 2007-08-21
AU2003259049A8 (en) 2004-03-03
WO2004016829A2 (fr) 2004-02-26
CN1592800A (zh) 2005-03-09
CA2465363A1 (fr) 2004-02-26
EP1529126A4 (fr) 2006-07-05
TW200415263A (en) 2004-08-16
AU2003259049A1 (en) 2004-03-03
JP2005535787A (ja) 2005-11-24
EP1529126A2 (fr) 2005-05-11
US20040045832A1 (en) 2004-03-11

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