WO2006012152A3 - Catalyseur pour la deshydrogenation de l'ethylbenzene en styrene, elabore avec un precurseur hautement pur du fer - Google Patents

Catalyseur pour la deshydrogenation de l'ethylbenzene en styrene, elabore avec un precurseur hautement pur du fer Download PDF

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Publication number
WO2006012152A3
WO2006012152A3 PCT/US2005/022096 US2005022096W WO2006012152A3 WO 2006012152 A3 WO2006012152 A3 WO 2006012152A3 US 2005022096 W US2005022096 W US 2005022096W WO 2006012152 A3 WO2006012152 A3 WO 2006012152A3
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WO
WIPO (PCT)
Prior art keywords
catalyst
high purity
dehydrogenation
iron precursor
purity iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2005/022096
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English (en)
Other versions
WO2006012152A2 (fr
Inventor
Dennis J Smith
Robert J O'brien
X D Hu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sued Chemie Inc
Original Assignee
Sued Chemie Inc
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Publication date
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Application filed by Sued Chemie Inc filed Critical Sued Chemie Inc
Priority to EP05763223A priority Critical patent/EP1768779A4/fr
Priority to JP2007518244A priority patent/JP5231803B2/ja
Publication of WO2006012152A2 publication Critical patent/WO2006012152A2/fr
Publication of WO2006012152A3 publication Critical patent/WO2006012152A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B01J37/0226—Oxidation of the substrate, e.g. anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne un procédé de production d'un catalyseur destiné à la déshydrogénation de l'éthylbenzène en styrène. Le catalyseur de l'invention comprend un métal hautement pur et au moins un promoteur sous forme d'oxydes solides, d'hydrates d'oxydes, d'hydroxydes, d'hydroxycarbonates ou de métaux. Ce catalyseur s'élabore selon un procédé qui implique l'élaboration d'au moins un précurseur hautement pur du fer avec ou sans matière support additionnelle, et qui utilise une quantité nominale d'eau dans la production du catalyseur. Les granulés de catalyseur élaborés avec le précurseur hautement pur du métal sont sensiblement exempts de contaminants soufrés ou chlorurés.
PCT/US2005/022096 2004-06-24 2005-06-22 Catalyseur pour la deshydrogenation de l'ethylbenzene en styrene, elabore avec un precurseur hautement pur du fer Ceased WO2006012152A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP05763223A EP1768779A4 (fr) 2004-06-24 2005-06-22 Catalyseur pour la deshydrogenation de l'ethylbenzene en styrene, elabore avec un precurseur hautement pur du fer
JP2007518244A JP5231803B2 (ja) 2004-06-24 2005-06-22 高純度鉄先駆体で作成されるエチルベンゼンからスチレンへの脱水素化のための触媒

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/876,150 2004-06-24
US10/876,150 US7271126B2 (en) 2002-05-15 2004-06-24 Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor

Publications (2)

Publication Number Publication Date
WO2006012152A2 WO2006012152A2 (fr) 2006-02-02
WO2006012152A3 true WO2006012152A3 (fr) 2006-09-21

Family

ID=33452929

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/022096 Ceased WO2006012152A2 (fr) 2004-06-24 2005-06-22 Catalyseur pour la deshydrogenation de l'ethylbenzene en styrene, elabore avec un precurseur hautement pur du fer

Country Status (9)

Country Link
US (1) US7271126B2 (fr)
EP (1) EP1768779A4 (fr)
JP (1) JP5231803B2 (fr)
KR (1) KR20070039886A (fr)
CN (1) CN1997448A (fr)
AR (1) AR051547A1 (fr)
RU (1) RU2007102580A (fr)
TW (1) TW200616713A (fr)
WO (1) WO2006012152A2 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2002309821B8 (en) * 2002-05-15 2008-07-17 Sud-Chemie Ip Gmbh & Co. Kg Fischer-Tropsch catalyst prepared with a high purity iron precursor
EP2097167A2 (fr) * 2006-12-12 2009-09-09 Shell Internationale Research Maatschappij B.V. Procédé de préparation de catalyseur
US8259894B2 (en) * 2006-12-14 2012-09-04 Hitachi, Ltd. Method of suppressing deposition of radioactive isotope
CN102209588B (zh) * 2008-11-07 2013-11-06 南方化学触媒株式会社 在高浓度co2的存在下具有高性能的烷基芳香族化合物的脱氢催化剂及其制造方法以及使用该催化剂的脱氢方法
WO2010114096A1 (fr) * 2009-04-03 2010-10-07 日本たばこ産業株式会社 Catalyseur de réduction de mono-oxyde de carbone pour article à fumer, et son procédé de production
US20110004037A1 (en) * 2009-07-02 2011-01-06 Uop Llc Use of Mixed Activity Dehydrogenation Catalyst Following Oxidative Reheat
US9248436B2 (en) * 2010-08-26 2016-02-02 Basf Se Highly active shift catalysts
WO2012107718A2 (fr) 2011-02-07 2012-08-16 Oxford Catalysts Limited Catalyseurs
JP6335788B2 (ja) * 2011-12-22 2018-05-30 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 炭化水素の脱水素化のための触媒
GB201214122D0 (en) 2012-08-07 2012-09-19 Oxford Catalysts Ltd Treating of catalyst support
US10336667B2 (en) * 2014-05-09 2019-07-02 Basf Se Catalyst for dehydrogenating hydrocarbons
BR102016022962B1 (pt) * 2016-10-03 2021-10-26 Petróleo Brasileiro S.A. - Petrobras Processo de preparação de um catalisador de ferro-cromo promovido com platina, e, catalisador composto de ferro-cromo promovido com platina
CN107159204A (zh) * 2017-06-14 2017-09-15 江苏金洲粮油食品有限公司 一种乙苯制苯乙烯的脱氢反应催化剂及其制备方法
CN120019877B (zh) * 2023-11-20 2026-01-27 中国石油化工股份有限公司 脱氢催化剂及其制备方法和应用和氧化烷基苯脱氢的方法

Citations (9)

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US4343724A (en) * 1979-10-01 1982-08-10 Uop Inc. Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein
US4478954A (en) * 1983-05-23 1984-10-23 Standard Oil Company (Indiana) Synthesis gas reaction
US4499204A (en) * 1984-01-03 1985-02-12 Exxon Research & Engineering Co. Leached catalyst for ammonia synthesis
US4933313A (en) * 1987-10-21 1990-06-12 Mitsubishi Kasei Corporation Catalyst for conversion of carbon monoxide
US5935898A (en) * 1995-09-12 1999-08-10 Basf Aktiengesellschaft Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production
US5962757A (en) * 1994-12-14 1999-10-05 Shell Oil Company Dehydrogenation catalyst and process
US6183658B1 (en) * 1996-04-10 2001-02-06 Institut Für Neue Materialien Gem. Gmbh Process for preparing agglomerate-free nanoscalar iron oxide particles with a hydrolysis resistant coating
US6242379B1 (en) * 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts

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US3892897A (en) * 1972-10-02 1975-07-01 Corning Glass Works Process for making base metal titanate catalytic device
JPS57130548A (en) * 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
JPS6128454A (ja) * 1984-07-17 1986-02-08 シ−ビ−エムエム・インタ−ナシヨナル・リミタ−ダ 排ガス中の窒素酸化物除去用触媒
FR2624846B1 (fr) * 1987-12-16 1990-05-04 Atochem Composition a base d'un oxyde de structure spinelle, son application comme catalyseur et procede pour l'obtenir
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JP3786437B2 (ja) * 1994-06-06 2006-06-14 ズードケミー触媒株式会社 エチルベンゼン脱水素触媒及びその製造法
US5863856A (en) * 1997-04-22 1999-01-26 Exxon Research And Engineering Company Preparation of high activity catalysts the catalysts and their use
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PL209993B1 (pl) * 1998-04-01 2011-11-30 Süd Chemie Inc Katalizator odwodorniania dla strumienia alkiloaromatycznego i sposób odwodorniania strumienia alkiloaromatycznego
ITMI20020567A1 (it) * 2002-03-18 2003-09-18 Sud Chemie S R L Processo per la preparazione di ossidi di ferro
WO2003097236A1 (fr) * 2002-05-15 2003-11-27 Süd-Chemie AG Catalyseur fischer-tropsch prepare au moyen d'un precurseur du fer de grande purete
US7037876B2 (en) * 2002-05-15 2006-05-02 Sud-Chemie Inc. High temperature shift catalyst prepared with a purity iron precursor
AU2002309821B8 (en) * 2002-05-15 2008-07-17 Sud-Chemie Ip Gmbh & Co. Kg Fischer-Tropsch catalyst prepared with a high purity iron precursor

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3518208A (en) * 1966-04-26 1970-06-30 Girdler Suedchemie Katalysator Catalyst for the water gas shift reaction
US4343724A (en) * 1979-10-01 1982-08-10 Uop Inc. Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein
US4478954A (en) * 1983-05-23 1984-10-23 Standard Oil Company (Indiana) Synthesis gas reaction
US4499204A (en) * 1984-01-03 1985-02-12 Exxon Research & Engineering Co. Leached catalyst for ammonia synthesis
US4933313A (en) * 1987-10-21 1990-06-12 Mitsubishi Kasei Corporation Catalyst for conversion of carbon monoxide
US5962757A (en) * 1994-12-14 1999-10-05 Shell Oil Company Dehydrogenation catalyst and process
US5935898A (en) * 1995-09-12 1999-08-10 Basf Aktiengesellschaft Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production
US6183658B1 (en) * 1996-04-10 2001-02-06 Institut Für Neue Materialien Gem. Gmbh Process for preparing agglomerate-free nanoscalar iron oxide particles with a hydrolysis resistant coating
US6242379B1 (en) * 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts

Also Published As

Publication number Publication date
JP5231803B2 (ja) 2013-07-10
US7271126B2 (en) 2007-09-18
WO2006012152A2 (fr) 2006-02-02
KR20070039886A (ko) 2007-04-13
EP1768779A4 (fr) 2012-04-18
CN1997448A (zh) 2007-07-11
TW200616713A (en) 2006-06-01
AR051547A1 (es) 2007-01-24
RU2007102580A (ru) 2008-07-27
EP1768779A2 (fr) 2007-04-04
JP2008504120A (ja) 2008-02-14
US20040235652A1 (en) 2004-11-25

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