WO2006050903A3 - Katalysator zur herstellung von kohlenstoffnanoröhrchen durch zersetzung von gasförmigen kohlenstoffverbindungen an einem heterogenen katalysator - Google Patents

Katalysator zur herstellung von kohlenstoffnanoröhrchen durch zersetzung von gasförmigen kohlenstoffverbindungen an einem heterogenen katalysator Download PDF

Info

Publication number
WO2006050903A3
WO2006050903A3 PCT/EP2005/011925 EP2005011925W WO2006050903A3 WO 2006050903 A3 WO2006050903 A3 WO 2006050903A3 EP 2005011925 W EP2005011925 W EP 2005011925W WO 2006050903 A3 WO2006050903 A3 WO 2006050903A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
decomposition
carbon nanotubes
heterogeneous catalyst
producing carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2005/011925
Other languages
English (en)
French (fr)
Other versions
WO2006050903A2 (de
Inventor
Sigurd Buchholz
Daniel Gordon Duff
Volker Michele
Leslaw Mleczko
Christian Muennich
Reiner Rudolf
Aurel Wolf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer Technology Services GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Technology Services GmbH filed Critical Bayer Technology Services GmbH
Priority to CN200580046507XA priority Critical patent/CN101142020B/zh
Priority to EP05816390A priority patent/EP1812159A2/de
Priority to US11/719,152 priority patent/US9409779B2/en
Priority to KR1020077010697A priority patent/KR101292489B1/ko
Priority to JP2007540559A priority patent/JP5702043B2/ja
Priority to TW095104720A priority patent/TW200730245A/zh
Publication of WO2006050903A2 publication Critical patent/WO2006050903A2/de
Publication of WO2006050903A3 publication Critical patent/WO2006050903A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/158—Carbon nanotubes
    • C01B32/16—Preparation
    • C01B32/162—Preparation characterised by catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10—Magnesium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8898—Manganese, technetium or rhenium containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B82B3/0004—Apparatus specially adapted for the manufacture or treatment of nanostructural devices or systems or methods for manufacturing the same
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/127—Carbon filaments; Apparatus specially adapted for the manufacture thereof by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
    • H10K85/221—Carbon nanotubes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/60—Organic compounds having low molecular weight
    • H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/34—Length
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2202/00—Structure or properties of carbon nanotubes
    • C01B2202/20—Nanotubes characterized by their properties
    • C01B2202/36—Diameter

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Thermal Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Mathematical Physics (AREA)
  • Theoretical Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Catalysts (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von Kohlenstoffnanoröhrchen, insbesondere solcher mit einem Durchmesser von 3-150 nm und einem Aspektverhältnis Länge: Durchmesser (L:D) > 100 durch Zersetzung von Kohlenwasserstoffen an einem heterogenen Katalysator, der Mn, Co, bevorzugt auch Molybdän, sowie ein inertes Trägermaterial enthält sowie den Katalysator und die Kohlenstoffnanoröhrchen selbst und deren Verwendung.
PCT/EP2005/011925 2004-11-13 2005-11-08 Katalysator zur herstellung von kohlenstoffnanoröhrchen durch zersetzung von gasförmigen kohlenstoffverbindungen an einem heterogenen katalysator Ceased WO2006050903A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN200580046507XA CN101142020B (zh) 2004-11-13 2005-11-08 用于通过在非均相催化剂上分解气态碳化合物而制备碳纳米管的催化剂
EP05816390A EP1812159A2 (de) 2004-11-13 2005-11-08 Katalysator zur herstellung von kohlenstoffnanoröhrchen durch zersetzung von gasförmigen kohlenstoffverbindungen an einem heterogenen katalysator
US11/719,152 US9409779B2 (en) 2004-11-13 2005-11-08 Catalyst for producing carbon nanotubes by means of the decomposition of gaseous carbon compounds on a heterogeneous catalyst
KR1020077010697A KR101292489B1 (ko) 2004-11-13 2005-11-08 불균질 촉매 상 기체 탄소 화합물의 분해에 의한 탄소나노튜브의 제조용 촉매
JP2007540559A JP5702043B2 (ja) 2004-11-13 2005-11-08 不均一触媒でガス状炭素化合物を分解することによりカーボンナノチューブを製造するための触媒
TW095104720A TW200730245A (en) 2004-11-13 2006-02-13 Catalyst for producing carbon nanotubules by decomposition of gaseous carbon compouds at a heterogeneous catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004054959.1 2004-11-13
DE102004054959A DE102004054959A1 (de) 2004-11-13 2004-11-13 Katalysator zur Herstellung von Kohlenstoffnanoröhrchen durch Zersetzung von gas-förmigen Kohlenverbindungen an einem heterogenen Katalysator

Publications (2)

Publication Number Publication Date
WO2006050903A2 WO2006050903A2 (de) 2006-05-18
WO2006050903A3 true WO2006050903A3 (de) 2006-09-08

Family

ID=35788213

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2005/011925 Ceased WO2006050903A2 (de) 2004-11-13 2005-11-08 Katalysator zur herstellung von kohlenstoffnanoröhrchen durch zersetzung von gasförmigen kohlenstoffverbindungen an einem heterogenen katalysator

Country Status (8)

Country Link
US (1) US9409779B2 (de)
EP (1) EP1812159A2 (de)
JP (1) JP5702043B2 (de)
KR (1) KR101292489B1 (de)
CN (1) CN101142020B (de)
DE (1) DE102004054959A1 (de)
TW (1) TW200730245A (de)
WO (1) WO2006050903A2 (de)

Families Citing this family (84)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006007147A1 (de) 2006-02-16 2007-08-23 Bayer Technology Services Gmbh Verfahren zur kontinuierlichen Herstellung von Katalysatoren
DE102006035773A1 (de) 2006-08-01 2008-02-07 Bayer Technology Services Gmbh Verfahren zur Herstellung von Kohlenstoffnanorörchen-Polymer-Mischungen mittels Gasphasenpolymerisation
JP4197729B2 (ja) 2006-12-21 2008-12-17 昭和電工株式会社 炭素繊維および炭素繊維製造用触媒
DE102007029008A1 (de) 2007-06-23 2008-12-24 Bayer Materialscience Ag Verfahren zur Herstellung eines leitfähigen Polymerverbundwerkstoffs
DE102007046160A1 (de) * 2007-09-27 2009-04-02 Bayer Materialscience Ag Verfahren zur Herstellung eines Katalysators für die Herstellung von Kohlenstoffnanoröhrchen
DE102007058992A1 (de) * 2007-12-07 2009-06-10 Bayer Materialscience Ag Verfahren zur Herstellung eines leitfähigen Polycarbonatverbundmaterials
DE102008004135B4 (de) * 2008-01-11 2014-03-06 H.C. Starck Gmbh Katalysatorpulver
DE102008020135A1 (de) * 2008-04-22 2009-10-29 Bayer Materialscience Ag Reaktionsharz auf Basis eines ungesättigten Polyesters, radikalisch härtbaren Vinylverbindungen und Kohlenstoffnanoröhrchen
US8591858B2 (en) 2008-05-01 2013-11-26 Honda Motor Co., Ltd. Effect of hydrocarbon and transport gas feedstock on efficiency and quality of grown single-walled nanotubes
US9174847B2 (en) 2008-05-01 2015-11-03 Honda Motor Co., Ltd. Synthesis of high quality carbon single-walled nanotubes
JP5649269B2 (ja) 2008-06-18 2015-01-07 昭和電工株式会社 カーボンナノファイバー、その製造方法及び用途
JP5566628B2 (ja) * 2008-06-18 2014-08-06 昭和電工株式会社 炭素繊維の製造方法
JP5420982B2 (ja) * 2008-06-18 2014-02-19 昭和電工株式会社 炭素繊維及び炭素繊維製造用触媒
DE102008031579A1 (de) * 2008-07-03 2010-01-07 Bayer Materialscience Ag Ein hocheffizientes Gasphasenverfahren zur Modifizierung und Funktionalisierung von Kohlenstoff-Nanofasern mit Salpetersäuredampf
EP2151830A1 (de) 2008-08-08 2010-02-10 pp-mid GmbH Polymerformkörper mit leitfähigen Strukturen auf der Oberfläche, sowie Verfahren zu dessen Herstellung
DE102008061051A1 (de) 2008-12-08 2010-06-10 Pp-Mid Gmbh Leiterplatten-Anordnung und leitfähige Klebstoffe zum Verbinden von Bauteilen mit der Leiterplatte sowie Verfahren zu deren Herstellung
US20110134617A1 (en) * 2008-08-08 2011-06-09 Pp-Mid Gmbh Polymer molded bodies and printed circuit board arrangement and method for the production thereof
DE102008048459A1 (de) 2008-09-23 2010-03-25 Pp-Mid Gmbh Polymerformkörper mit leitfähigen Strukturen auf der Oberfläche, sowie Verfahren zu dessen Herstellung
DE102009011538A1 (de) 2009-03-03 2010-09-09 Pp-Mid Gmbh Leiterplatten-Anordnung, sowie Verfahren zu deren Herstellung
DE102008038524A1 (de) 2008-08-20 2010-02-25 Bayer Materialscience Ag Antistatische oder elektrisch leitfähige Polyurethane und ein Verfahren zu deren Herstellung
CA2734568A1 (en) * 2008-08-20 2010-02-25 Bayer Materialscience Ag Method for producing composite materials having reduced resistance and comprising carbon nanotubes
DE602008006421D1 (de) 2008-11-06 2011-06-01 Clariant Finance Bvi Ltd Verfahren zur Herstellung von organischen polymerischen Profilen
EP2184324A1 (de) 2008-11-06 2010-05-12 Clariant International Ltd. Zusammensetzungen mit Propylen-Olefin-Copolymerwachsen und Kohlennanoröhrchen
HUE030729T2 (en) * 2008-11-06 2017-05-29 Clariant Int Ltd Composition containing propylene olefin copolymer waxes and carbon black
KR100976174B1 (ko) * 2009-02-13 2010-08-16 금호석유화학 주식회사 얇은 다중벽 탄소나노튜브 제조용 촉매조성물 및 이의 제조방법
EP2351705B1 (de) 2009-03-05 2014-04-30 Showa Denko K.K. Kohlefaseragglomerate und herstellungsverfahren dafür
DE102009012673A1 (de) 2009-03-13 2010-09-16 Bayer Materialscience Ag Formkörper aus Kohlenstoffnanoteilchen-Polymermischungen mit Gradienteneigenschaft der elektrischen Volumenleitfähigkeit
EP2228414A1 (de) 2009-03-13 2010-09-15 Bayer MaterialScience AG UV-härtbare, verschleißfeste und antistatische Beschichtung, die mit Kohlenstoffnanoröhrchen gefüllt ist
EP2228343A1 (de) 2009-03-13 2010-09-15 Bayer MaterialScience AG Von Wasserdampf unterstützte Ozonolyse von Kohlenstoffnanoröhrchen
EP2228406A1 (de) 2009-03-13 2010-09-15 Bayer MaterialScience AG Verbesserte mechanische Eigenschaften von Epoxid, das mit funktionalisierten Kohlenstoffnanoröhrchen gefüllt ist
DE102009012674A1 (de) 2009-03-13 2010-09-16 Bayer Materialscience Ag Polyurethanmassen mit Kohlenstoffnanoröhrchen
DE102009012675A1 (de) 2009-03-13 2010-09-16 Bayer Materialscience Ag Verfahren zur Dispergierung graphitartiger Nanoteilchen
DE102009013418A1 (de) 2009-03-18 2010-09-23 Bayer Technology Services Gmbh Verfahren zur Dispersion von Nanopartikeln in fluiden Medien
EP2411328B1 (de) 2009-03-26 2019-07-24 Northeastern University Kohlenstoffnanostrukturen aus der pyrolyse organischer materialien
ES3065468T3 (en) 2009-04-17 2026-05-06 Seerstone Llc Method for producing solid carbon by reducing carbon oxides
DE102009024340A1 (de) 2009-06-09 2010-12-16 Bayer Materialscience Ag Hochfließfähige Polymerzusammensetzung und Verfahren zu ihrer Herstellung
KR101089570B1 (ko) * 2009-07-07 2011-12-05 금호석유화학 주식회사 겉보기 밀도를 조절시킨 탄소나노튜브 제조용 촉매
WO2011009071A1 (en) * 2009-07-17 2011-01-20 Southwest Nanotechnologies, Inc. Catalyst and methods for producing multi-wall carbon nanotubes
DE102009038464A1 (de) * 2009-08-21 2011-02-24 Bayer Materialscience Ag Kohlenstoffnanoröhrchen-Agglomerat
DE102009040047A1 (de) 2009-09-04 2011-03-17 Bayer Materialscience Ag Verfahren zur Einarbeitung von Feststoffen in Polymere
CN102712764A (zh) 2009-11-18 2012-10-03 拜耳材料科技股份有限公司 基于聚合物和碳纳米管的复合材料、其制备方法以及其用途
KR101018660B1 (ko) * 2009-12-22 2011-03-04 금호석유화학 주식회사 다중벽 탄소나노튜브 제조용 촉매조성물
DE102010005560A1 (de) 2010-01-22 2011-07-28 Bayer MaterialScience AG, 51373 Herstellung von CNT
DE102010008173A1 (de) 2010-02-16 2012-03-01 Bayer Materialscience Aktiengesellschaft Herstellung von Kohlenstoffnanoröhrchen
WO2012075499A1 (en) 2010-12-03 2012-06-07 Northeastern University Method and device for fuel and power generation by clean combustion of organic waste material
EP3000849B1 (de) 2010-12-08 2018-04-04 Haydale Graphene Industries PLC Graphitnanoplättchen, verbundstoffe damit, herstellung und verwendung
EP2500376A1 (de) 2011-03-17 2012-09-19 Basf Se Antistatische oder elektrisch leitfähige Polyurethane
DE102011105760A1 (de) * 2011-06-15 2012-12-20 Cutec-Institut Gmbh Mischoxidkatalysator, sowie Verfahren zu dessen Herstellung
KR101431953B1 (ko) * 2012-01-11 2014-08-19 주식회사 엘지화학 카본나노튜브용 균질 담지 촉매의 제조방법
KR101424910B1 (ko) * 2012-01-11 2014-07-31 주식회사 엘지화학 카본나노튜브 및 그 제조방법
NO2749379T3 (de) 2012-04-16 2018-07-28
MX354526B (es) 2012-04-16 2018-03-07 Seerstone Llc Metodos y sistemas para capturar y secuestrar carbono y para reducir la masa de oxidos de carbono en una corriente de gas de desechos.
US9796591B2 (en) 2012-04-16 2017-10-24 Seerstone Llc Methods for reducing carbon oxides with non ferrous catalysts and forming solid carbon products
EP2838839B1 (de) 2012-04-16 2020-08-12 Seerstone LLC Verfahren zur herstellung von festem kohlenstoff durch reduzierung von kohlenstoffoxiden
WO2013158158A1 (en) 2012-04-16 2013-10-24 Seerstone Llc Methods for treating an offgas containing carbon oxides
US9896341B2 (en) 2012-04-23 2018-02-20 Seerstone Llc Methods of forming carbon nanotubes having a bimodal size distribution
JP6284934B2 (ja) 2012-07-12 2018-02-28 シーアストーン リミテッド ライアビリティ カンパニー カーボンナノチューブを含む固体炭素生成物およびそれを形成する方法
US10815124B2 (en) 2012-07-12 2020-10-27 Seerstone Llc Solid carbon products comprising carbon nanotubes and methods of forming same
CN107215882A (zh) 2012-07-13 2017-09-29 赛尔斯通股份有限公司 用于形成氨和固体碳产物的方法和系统
US9779845B2 (en) 2012-07-18 2017-10-03 Seerstone Llc Primary voltaic sources including nanofiber Schottky barrier arrays and methods of forming same
EP2700740A3 (de) 2012-08-24 2014-03-19 Showa Denko Kabushiki Kaisha Kohlenstofffasern, Katalysator für die Herstellung von Kohlenstofffasern.
US9506194B2 (en) 2012-09-04 2016-11-29 Ocv Intellectual Capital, Llc Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media
WO2014085378A1 (en) 2012-11-29 2014-06-05 Seerstone Llc Reactors and methods for producing solid carbon materials
EP3129133B1 (de) 2013-03-15 2024-10-09 Seerstone LLC Systeme zur herstellung von festem kohlenstoff durch reduzierung von kohlenstoffoxiden
WO2014151138A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Reactors, systems, and methods for forming solid products
EP3129321B1 (de) 2013-03-15 2021-09-29 Seerstone LLC Elektroden mit nanostrukturiertem kohlenstoff
WO2014150944A1 (en) 2013-03-15 2014-09-25 Seerstone Llc Methods of producing hydrogen and solid carbon
EP3113880A4 (de) 2013-03-15 2018-05-16 Seerstone LLC Kohlenoxidreduktion mit intermetallischen und carbidkatalysatoren
WO2014188439A1 (en) 2013-05-24 2014-11-27 Hindustan Petroleum Corporation Ltd. Catalytic decomposition of lower hydrocarbons to produce carbon oxides free hydrogen and bamboo shaped carbon nanotubes
KR20160021239A (ko) 2013-06-14 2016-02-24 바스프 에스이 전기 전도성 열가소성 폴리우레탄으로부터 제조된 가열 가능한 성형품
DE102013214229A1 (de) 2013-07-19 2015-01-22 Bayer Materialscience Ag Verfahren zur Herstellung eines effizienten Katalysators für die Produktion mehrwandiger Kohlenstoffnanoröhrchen, mehrwandiges Kohlenstoffnanoröhrchen und Kohlenstoffnanoröhrchenpulver
JP6237225B2 (ja) * 2013-12-26 2017-11-29 東洋インキＳｃホールディングス株式会社 カーボンナノチューブ合成用触媒
EP3089940B1 (de) 2013-12-30 2019-07-10 Indian Oil Corporation Limited Verfahren zur gleichzeitigen herstellung eines kohlenstoffnanoröhrchens und eines produktgases aus rohöl und dessen produkte
JP6278727B2 (ja) * 2014-02-04 2018-02-14 住友化学株式会社 共沈物の製造方法およびリチウム含有複合酸化物の製造方法
CN103965389B (zh) * 2014-05-13 2016-09-21 清华大学 碳纳米管-高分子复合材料的气相聚合生产方法及装置
WO2018022999A1 (en) 2016-07-28 2018-02-01 Seerstone Llc. Solid carbon products comprising compressed carbon nanotubes in a container and methods of forming same
US10995000B2 (en) 2016-10-19 2021-05-04 Vanderbilt University Nanostructured carbon materials and methods of making and use thereof
CN107134579B (zh) * 2017-04-17 2020-03-17 中山市卡耐特塑料有限公司 一种用于正极导电剂的碳材料的制备方法
JP6778707B2 (ja) * 2017-05-23 2020-11-04 インディアン オイル コーポレーション リミテッド 形態制御されたｃｎｔを生成するための多重金属触媒組成物およびそのプロセス
KR102303667B1 (ko) * 2017-10-31 2021-09-16 에스케이이노베이션 주식회사 탄소 나노 튜브 합성용 촉매 및 탄소 나노 튜브의 제조 방법
US11181043B2 (en) 2019-09-30 2021-11-23 General Electric Company Apparatuses and methods for generating carbon particles and exhaust gas used by gas turbine systems
EP4392166A1 (de) * 2021-08-27 2024-07-03 Johnson Matthey Public Limited Company Verfahren zur behandlung eines abgases und hlk-system
US20250368573A1 (en) 2023-05-25 2025-12-04 Blue Evolution Inc. Ecofriendly biopolymer admixture for cement and concrete applications
US20250197609A1 (en) 2023-12-13 2025-06-19 Blue Evolution, Inc. Ecofriendly, biodegradable biological polysaccharide composition for packaging materials

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3701822A (en) * 1970-06-11 1972-10-31 Chemical Construction Corp Process and catalyst for treating combustion exhaust gas
US20030148097A1 (en) * 2002-01-08 2003-08-07 Futaba Corporation Method for preparing nano-carbon fiber and nano-carbon fiber
WO2004011178A1 (en) * 2002-07-26 2004-02-05 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4058571A (en) * 1973-03-24 1977-11-15 Bayer Aktiengesellschaft Continuous process for the production of d,l'menthol
JPS5946133A (ja) 1982-09-06 1984-03-15 Yoshinobu Takegami 還元触媒
JPH04323101A (ja) * 1991-04-23 1992-11-12 Hitachi Ltd 脱臭装置を備えた生ごみ容器
JPH06129613A (ja) * 1992-10-20 1994-05-13 Matsushita Electric Ind Co Ltd 触媒燃焼装置
CA2224690C (en) 1995-06-16 2007-06-05 Shell Canada Limited Catalyst and process for the preparation of hydrocarbons
DE69939329D1 (de) * 1998-11-03 2008-09-25 Univ Rice William M Gasphasenabscheidund und wachstum von einwändigen kohlenstoffnanoröhren aus kohlenstoffmonoxid unter hochdruck
EP1054036A1 (de) * 1999-05-18 2000-11-22 Fina Research S.A. Verstärkte Polymere
US20030091496A1 (en) * 2001-07-23 2003-05-15 Resasco Daniel E. Method and catalyst for producing single walled carbon nanotubes
JP3912583B2 (ja) * 2001-03-14 2007-05-09 三菱瓦斯化学株式会社 配向性カーボンナノチューブ膜の製造方法
AUPR421701A0 (en) 2001-04-04 2001-05-17 Commonwealth Scientific And Industrial Research Organisation Process and apparatus for the production of carbon nanotubes
CN1141250C (zh) * 2001-05-25 2004-03-10 清华大学 一种流化床连续化制备碳纳米管的方法及其反应装置
JP2003012939A (ja) * 2001-07-03 2003-01-15 Toray Ind Inc カーボン含有樹脂組成物、成形材料および成形体
JP3782993B2 (ja) * 2001-11-28 2006-06-07 国立大学法人名古屋大学 中空状ナノファイバーの製造法
JP4020410B2 (ja) * 2001-12-28 2007-12-12 大研化学工業株式会社 炭素物質製造用触媒
JP2004018290A (ja) * 2002-06-13 2004-01-22 Mitsubishi Chemical Engineering Corp 炭素質微細繊維状体の粒状凝集体
GB0214383D0 (en) * 2002-06-21 2002-07-31 Isis Innovation Catalyst
JP3804594B2 (ja) 2002-08-02 2006-08-02 日本電気株式会社 触媒担持基板およびそれを用いたカーボンナノチューブの成長方法ならびにカーボンナノチューブを用いたトランジスタ
WO2004035883A2 (en) * 2002-10-17 2004-04-29 Nexen Nano Tech Co., Ltd Fibrous nano-carbon and preparation method thereof
JP4659367B2 (ja) * 2003-02-19 2011-03-30 パナソニック株式会社 電池用電極およびその製造法
US7235159B2 (en) * 2003-09-17 2007-06-26 Molecular Nanosystems, Inc. Methods for producing and using catalytic substrates for carbon nanotube growth
DE602004027656D1 (de) * 2003-12-15 2010-07-22 Resasco Rheniumkatalysatoren und verfahren zur herstellung von einwandigen kohlenstoffnanoröhren
US20060078489A1 (en) * 2004-09-09 2006-04-13 Avetik Harutyunyan Synthesis of small and narrow diameter distributed carbon single walled nanotubes
US7998899B2 (en) * 2007-11-27 2011-08-16 Shell Oil Company Catalyst with support structure

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3701822A (en) * 1970-06-11 1972-10-31 Chemical Construction Corp Process and catalyst for treating combustion exhaust gas
US20030148097A1 (en) * 2002-01-08 2003-08-07 Futaba Corporation Method for preparing nano-carbon fiber and nano-carbon fiber
WO2004011178A1 (en) * 2002-07-26 2004-02-05 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Synthesis of metal nanoparticle compositions from metallic and ethynyl compounds

Also Published As

Publication number Publication date
TW200730245A (en) 2007-08-16
CN101142020A (zh) 2008-03-12
JP2008519679A (ja) 2008-06-12
WO2006050903A2 (de) 2006-05-18
DE102004054959A1 (de) 2006-05-18
US20090140215A1 (en) 2009-06-04
CN101142020B (zh) 2012-05-02
KR101292489B1 (ko) 2013-08-01
US9409779B2 (en) 2016-08-09
JP5702043B2 (ja) 2015-04-15
KR20070084180A (ko) 2007-08-24
EP1812159A2 (de) 2007-08-01

Similar Documents

Publication Publication Date Title
TW200730245A (en) Catalyst for producing carbon nanotubules by decomposition of gaseous carbon compouds at a heterogeneous catalyst
WO2005075341A3 (fr) Procede d'obtention de nanotubes de carbone sur des supports et composites les renfermant
WO2005065100A3 (en) Rhenium catalysts and methods for production of single-walled carbon nanotubes
WO2006093601A3 (en) Uniform single walled carbon nanotube network
WO2003095362A3 (en) Method and apparatus for producing single-wall carbon nanotubes
WO2004052973A3 (en) Synthesis of coiled carbon nanotubes by microwave chemical vapor deposition
AU2003211943A1 (en) Process for producing single-walled carbon nanotube, single-walled carbon nanotube, and composition containing single-walled carbon nanotube
AU2003303947A1 (en) Method for making single-wall carbon nanotubes using supported catalysts
WO2007024242A3 (en) Synthesis of small and narrow diameter distributed carbon single-walled nanotubes
WO2006091277A8 (en) Methods for growing long carbon single-walled nanotubes
WO2008016388A3 (en) Method and apparatus for growth of high quality carbon single-walled nanotubes
WO2005085130A3 (en) Single, multi-walled, functionalized and doped carbon nanotubes and composites thereof
WO2006004599A3 (en) Methods for preparing single-walled carbon nanotubes
WO2006060168A3 (en) Method for preparing supported catalysts from metal loaded carbon nanotubes
WO2008136347A1 (ja) 単層カーボンナノチューブ分散液、及び単層カーボンナノチューブ分散液の製造方法
WO2004046102A3 (en) Novel graphite nanocatalysts
WO2008016390A3 (en) Catalyst for the growth of carbon single-walled nanotubes
WO2006130150A9 (en) Functionalized single walled carbon nanotubes
WO2003048038A3 (en) Method and catalyst for producing carbon nanotubes
WO2006135378A3 (en) Method and apparatus for hydrogen production from greenhouse gas saturated carbon nanotubes and synthesis of carbon nanostructures therefrom
WO2004065294A8 (en) Systems and methods for producing single-walled carbon nanotubes (swnts) on a substrate
AU2003213407A1 (en) Dna nanocage by self-organization of dna and process for producing the same, and dna nanotube and molecule carrier using the same
WO2005019104A3 (en) Controlled nanotube fabrication and uses
WO2003002456A3 (fr) Procede de fabrication selective de nanotubes de carbone ordonne en lit fluidise
SG126710A1 (en) Carbon nanotubes fabrication and hydrogen production

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KN KP KR KZ LC LK LR LS LT LU LV LY MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2005816390

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 3350/DELNP/2007

Country of ref document: IN

WWE Wipo information: entry into national phase

Ref document number: 1020077010697

Country of ref document: KR

WWE Wipo information: entry into national phase

Ref document number: 2007540559

Country of ref document: JP

WWE Wipo information: entry into national phase

Ref document number: 200580046507.X

Country of ref document: CN

WWP Wipo information: published in national office

Ref document number: 2005816390

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 11719152

Country of ref document: US