WO2007083473A1 - Composition durcissable par un rayonnement actif, encre durcissable par un rayonnement actif et procédé de formation d'image utilisant celle-ci - Google Patents

Composition durcissable par un rayonnement actif, encre durcissable par un rayonnement actif et procédé de formation d'image utilisant celle-ci Download PDF

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Publication number
WO2007083473A1
WO2007083473A1 PCT/JP2006/325366 JP2006325366W WO2007083473A1 WO 2007083473 A1 WO2007083473 A1 WO 2007083473A1 JP 2006325366 W JP2006325366 W JP 2006325366W WO 2007083473 A1 WO2007083473 A1 WO 2007083473A1
Authority
WO
WIPO (PCT)
Prior art keywords
group
ray curable
actinic ray
curable composition
ink
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2006/325366
Other languages
English (en)
Japanese (ja)
Inventor
Wataru Ishikawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Konica Minolta Medical and Graphic Inc
Original Assignee
Konica Minolta Medical and Graphic Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Konica Minolta Medical and Graphic Inc filed Critical Konica Minolta Medical and Graphic Inc
Priority to JP2007554833A priority Critical patent/JPWO2007083473A1/ja
Publication of WO2007083473A1 publication Critical patent/WO2007083473A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382—Contact thermal transfer or sublimation processes
    • B41M5/38235—Contact thermal transfer or sublimation processes characterised by transferable colour-forming materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing

Definitions

  • the photopolymerization initiator is an iodonium salt or a sodium salt having a sulfone salt power, and is a photoacid generator, and the photopolymerization initiator is contained in an amount of 1 to 10% by mass. 6.
  • the actinic ray curable composition according to any one of 2 to 5, which is contained below.
  • An image forming method in which the actinic ray curable ink according to 12 or 13 is jetted onto a recording material from an inkjet recording head, and printing is performed on the recording material.
  • An image forming method comprising irradiating actinic rays for 0.001 to 1.0 seconds after ink has landed.
  • FIG. 2 is a top view showing another example of the configuration of the main part of the ink jet recording apparatus applicable to the present invention.
  • Examples of the monomer having a hydroxyl group include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 3-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth). There are atarylates, N-methylolacrylamide, allylic alcohols, etc.
  • Monomers having a tertiary amino group include dimethylaminoethyl (meth) acrylate, jetylaminoethyl (meth) acrylate, dimethylaminopropyl (meth). Arc And rilamide.
  • Examples of compounds having an ethylenically unsaturated bond capable of radical polymerization include unsaturated carboxylic acids such as acrylic acid, methacrylic acid, itaconic acid, crotonic acid, isocrotonic acid, maleic acid, and salts and esters thereof. , Urethane, amide anhydride, acrylonitrile, styrene, and various radically polymerizable compounds such as various unsaturated polyesters, unsaturated polyethers, unsaturated polyamides, and unsaturated urethanes.
  • an alkylene group represented by the following general formula (21) is preferably used as an example of the branched alkylene group having 1 to 12 carbon atoms.
  • An example of a compound having two oxetane rings includes a compound represented by the following general formula (28).
  • R 1U represents a lower alkyl group such as a methyl group, an ethyl group, or a propyl group.
  • p is an integer of 1 10.
  • Butanolinoresininoreethenole, hexanediol divinyl ether, cyclohexane Di- or tri-butyl ether compounds such as dimethanol divinyl ether and trimethylolpropane trivinyl ether, ethyl vinyl ether, n -butyl vinyl ether, isobutyl vinyl ether, octadecyl vinyl ether, cyclohexyl vinyl ether, hydroxybutynole vinylino Tenoré, 2-Ethinorehexinolevinoleateol, Cyclohexanedimethanol monovinyl ether, n-Propyl vinyl ether, Isopropyl vinyl ether, Isopropyl ether o Propylene carbonate, Dodecyl vinyl ether, Diethylene glycol monobutyl ether, Octadecyl vinyl ether And monobuyl ether compounds such as
  • the average particle diameter of the pigment particles is 0.08 to 0.5 ⁇ m.
  • the maximum particle diameter is 0.3 to: LO / zm, preferably 0.3.
  • the selection of the pigment, the dispersant and the dispersion medium, the dispersion conditions and the filtration conditions are appropriately set so as to be ⁇ 3 m.
  • the cost of recording materials such as packaging costs and production costs, and the production of prints It is more advantageous to use a long (web) recording material in terms of efficiency and compatibility with various size prints.
  • the actinic ray curable ink of the present invention is ejected and drawn on a recording material by an inkjet recording method, and then the ink is cured by irradiating active rays such as ultraviolet rays. U, which is the preferred method.
  • the total ink film thickness after the ink has landed on the recording material and cured by irradiation with actinic rays is preferably 2 to 25 ⁇ m.
  • the total ink film thickness is currently over 25 m.
  • the force recording material is thin and is often a plastic material. In addition to curling of the recorded material, it is not only a problem of wrinkles, but also the strain of the entire printed matter. V If there is a problem with the texture, it is preferable to eject ink with an excessive film thickness.
  • the actinic ray is applied for a period of 0.001 seconds to 1.0 seconds after the ink landing as the actinic ray irradiation condition, more preferably 0.001. Seconds to 0.5 seconds. In order to form a high-definition image, it is particularly important that the irradiation timing is as early as possible.
  • the head carriage 2 is installed on the upper side of the recording material P, and a plurality of inkjet recording heads 3 to be described later are arranged on the recording material P according to the number of colors used for image printing, and the discharge ports are arranged on the lower side. Place and store.
  • the head carriage 2 is installed in the main body of the recording apparatus 1 in such a manner that it can reciprocate in the Y direction in FIG. 1, and reciprocates in the Y direction in FIG. 1 by driving the head scanning means.
  • the irradiation means 4 is installed on both sides of the head carriage 2 so as to be fixed substantially parallel to the recording material P.
  • Black pigment C. I. Pigment Black 7 (Mitsubishi Chemical Corporation, # 52)
  • the physical properties of the obtained cured product (formed image) were evaluated according to the methods shown below. Each evaluation was determined by an average value of each characteristic of an image formed with each color ink.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Optics & Photonics (AREA)
  • Polyethers (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Epoxy Resins (AREA)
  • Ink Jet (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention concerne une composition durcissable par un rayonnement actif qui permet de former un film image résistant ayant une sensibilité élevée et une flexibilité élevée. L'invention concerne également une encre durcissable par un rayonnement actif utilisant une telle composition durcissable par un rayonnement actif et un procédé de formation d'image. La composition durcissable par un rayonnement actif contient un initiateur de photopolymérisation et un composé polymérisable par photopolymérisation. Cette composition durcissable par un rayonnement actif est caractérisée en ce qu'elle contient en plus un polymère acrylique et en ce que le composé polymérisable par photopolymérisation est composé d'un monomère polymérisable par polymérisation cationique.
PCT/JP2006/325366 2006-01-17 2006-12-20 Composition durcissable par un rayonnement actif, encre durcissable par un rayonnement actif et procédé de formation d'image utilisant celle-ci Ceased WO2007083473A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007554833A JPWO2007083473A1 (ja) 2006-01-17 2006-12-20 活性光線硬化型組成物、活性光線硬化型インク及びそれを用いた画像形成方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-008542 2006-01-17
JP2006008542 2006-01-17

Publications (1)

Publication Number Publication Date
WO2007083473A1 true WO2007083473A1 (fr) 2007-07-26

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2006/325366 Ceased WO2007083473A1 (fr) 2006-01-17 2006-12-20 Composition durcissable par un rayonnement actif, encre durcissable par un rayonnement actif et procédé de formation d'image utilisant celle-ci

Country Status (2)

Country Link
JP (1) JPWO2007083473A1 (fr)
WO (1) WO2007083473A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008045145A (ja) * 2007-11-02 2008-02-28 Toyo Ink Mfg Co Ltd 活性エネルギー線硬化型インクジェットインキ
JP2009542833A (ja) * 2006-07-05 2009-12-03 セリコル リミテッド プリント用インク
JP2010013557A (ja) * 2008-07-03 2010-01-21 Konica Minolta Ij Technologies Inc カチオン重合性インクジェットインク組成物及びその製造方法
JP2010235914A (ja) * 2009-03-11 2010-10-21 Toyo Ink Mfg Co Ltd インキ組成物およびそれを用いた硬化物
KR20120110038A (ko) * 2011-03-28 2012-10-09 스미또모 가가꾸 가부시키가이샤 포토레지스트 조성물
JP2013249357A (ja) * 2012-05-31 2013-12-12 Ricoh Co Ltd 光重合性インクジェットインク、インクカートリッジ、インクジェット印刷装置
JP2014040592A (ja) * 2013-09-10 2014-03-06 Dnp Fine Chemicals Co Ltd 活性エネルギー線硬化型インクジェット記録用インク組成物
WO2016151904A1 (fr) * 2015-03-24 2016-09-29 富士フイルム株式会社 Dispersion aqueuse de particules de gel, procédé de production de cette dernière, et procédé de formation d'image
JP2017160434A (ja) * 2010-11-22 2017-09-14 セイコーエプソン株式会社 インクジェット記録方法、インクジェット記録装置
US10029483B2 (en) 2012-04-25 2018-07-24 Seiko Epson Corporation Ink jet recording method, ultraviolet-ray curable ink, and ink jet recording apparatus
JP2019056044A (ja) * 2017-09-20 2019-04-11 富士ゼロックス株式会社 造形物製造用インク組成物、造形物製造用インク組成物を製造する方法、造形物および造形物製造装置
US10569571B2 (en) 2012-03-28 2020-02-25 Seiko Epson Corporation Ink jet recording method, ultraviolet curable ink, and ink jet recording apparatus
US10583649B2 (en) 2012-04-27 2020-03-10 Seiko Epson Corporation Ink jet recording method and ink jet recording apparatus

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004522813A (ja) * 2000-11-09 2004-07-29 スリーエム イノベイティブ プロパティズ カンパニー インクジェット用途に有利に使用される、制限量の溶媒を組み入れたインクおよび他の組成物
JP2005060519A (ja) * 2003-08-12 2005-03-10 Konica Minolta Medical & Graphic Inc インクジェット用インク及びそれを用いた記録方法
JP2005060490A (ja) * 2003-08-11 2005-03-10 Konica Minolta Medical & Graphic Inc インク、画像形成方法、印刷物及び記録装置
JP2006028405A (ja) * 2004-07-20 2006-02-02 Fuji Photo Film Co Ltd インク組成物及びそれを用いたインクジェット記録方法
JP2006232987A (ja) * 2005-02-24 2006-09-07 Toshiba Tec Corp 粉体分散体および顔料分散体

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004522813A (ja) * 2000-11-09 2004-07-29 スリーエム イノベイティブ プロパティズ カンパニー インクジェット用途に有利に使用される、制限量の溶媒を組み入れたインクおよび他の組成物
JP2005060490A (ja) * 2003-08-11 2005-03-10 Konica Minolta Medical & Graphic Inc インク、画像形成方法、印刷物及び記録装置
JP2005060519A (ja) * 2003-08-12 2005-03-10 Konica Minolta Medical & Graphic Inc インクジェット用インク及びそれを用いた記録方法
JP2006028405A (ja) * 2004-07-20 2006-02-02 Fuji Photo Film Co Ltd インク組成物及びそれを用いたインクジェット記録方法
JP2006232987A (ja) * 2005-02-24 2006-09-07 Toshiba Tec Corp 粉体分散体および顔料分散体

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009542833A (ja) * 2006-07-05 2009-12-03 セリコル リミテッド プリント用インク
JP2014205839A (ja) * 2006-07-05 2014-10-30 セリコル リミテッド プリント用インク
US8952078B2 (en) 2006-07-05 2015-02-10 Sericol Limited Printing ink
JP2008045145A (ja) * 2007-11-02 2008-02-28 Toyo Ink Mfg Co Ltd 活性エネルギー線硬化型インクジェットインキ
JP2010013557A (ja) * 2008-07-03 2010-01-21 Konica Minolta Ij Technologies Inc カチオン重合性インクジェットインク組成物及びその製造方法
JP2010235914A (ja) * 2009-03-11 2010-10-21 Toyo Ink Mfg Co Ltd インキ組成物およびそれを用いた硬化物
JP2017160434A (ja) * 2010-11-22 2017-09-14 セイコーエプソン株式会社 インクジェット記録方法、インクジェット記録装置
KR20120110038A (ko) * 2011-03-28 2012-10-09 스미또모 가가꾸 가부시키가이샤 포토레지스트 조성물
KR101949124B1 (ko) * 2011-03-28 2019-02-19 스미또모 가가꾸 가부시키가이샤 포토레지스트 조성물
US10894430B2 (en) 2012-03-28 2021-01-19 Seiko Epson Corporation Ink jet recording method, ultraviolet curable ink, and ink jet recording apparatus
US11813843B2 (en) 2012-03-28 2023-11-14 Seiko Epson Corporation Ink jet recording method, ultraviolet curable ink, and ink jet recording apparatus
US10569571B2 (en) 2012-03-28 2020-02-25 Seiko Epson Corporation Ink jet recording method, ultraviolet curable ink, and ink jet recording apparatus
US11077677B2 (en) 2012-04-25 2021-08-03 Seiko Epson Corporation Ink jet recording method, ultraviolet-ray curable ink, and ink jet recording apparatus
US10029483B2 (en) 2012-04-25 2018-07-24 Seiko Epson Corporation Ink jet recording method, ultraviolet-ray curable ink, and ink jet recording apparatus
US10625519B2 (en) 2012-04-25 2020-04-21 Seiko Epson Corporation Ink jet recording method, ultraviolet-ray curable ink, and ink jet recording apparatus
US10583649B2 (en) 2012-04-27 2020-03-10 Seiko Epson Corporation Ink jet recording method and ink jet recording apparatus
JP2013249357A (ja) * 2012-05-31 2013-12-12 Ricoh Co Ltd 光重合性インクジェットインク、インクカートリッジ、インクジェット印刷装置
JP2014040592A (ja) * 2013-09-10 2014-03-06 Dnp Fine Chemicals Co Ltd 活性エネルギー線硬化型インクジェット記録用インク組成物
US10723827B2 (en) 2015-03-24 2020-07-28 Fujifilm Corporation Water dispersion of gel particles, producing method thereof, and image forming method
WO2016151904A1 (fr) * 2015-03-24 2016-09-29 富士フイルム株式会社 Dispersion aqueuse de particules de gel, procédé de production de cette dernière, et procédé de formation d'image
JP2019056044A (ja) * 2017-09-20 2019-04-11 富士ゼロックス株式会社 造形物製造用インク組成物、造形物製造用インク組成物を製造する方法、造形物および造形物製造装置

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