WO2008142849A1 - 熱膨張性微小球の製造方法およびその応用 - Google Patents

熱膨張性微小球の製造方法およびその応用 Download PDF

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Publication number
WO2008142849A1
WO2008142849A1 PCT/JP2008/001198 JP2008001198W WO2008142849A1 WO 2008142849 A1 WO2008142849 A1 WO 2008142849A1 JP 2008001198 W JP2008001198 W JP 2008001198W WO 2008142849 A1 WO2008142849 A1 WO 2008142849A1
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WO
WIPO (PCT)
Prior art keywords
production
thermally expandable
expandable beads
salt
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/001198
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English (en)
French (fr)
Inventor
Hiroki Naito
Satoshi Kawanami
Katsushi Miki
Ikuo Yosejima
Kenichi Kitano
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Matsumoto Yushi Seiyaku Co Ltd
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Matsumoto Yushi Seiyaku Co Ltd
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Application filed by Matsumoto Yushi Seiyaku Co Ltd filed Critical Matsumoto Yushi Seiyaku Co Ltd
Priority to JP2009515084A priority Critical patent/JP4386962B2/ja
Priority to EP08751716A priority patent/EP2151456B1/en
Priority to CN2008800169332A priority patent/CN101679537B/zh
Priority to US12/594,317 priority patent/US8206826B2/en
Priority to KR1020097022567A priority patent/KR101406022B1/ko
Publication of WO2008142849A1 publication Critical patent/WO2008142849A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/14—Polymerisation; cross-linking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C08F2/20—Suspension polymerisation with the aid of macromolecular dispersing agents
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2984—Microcapsule with fluid core [includes liposome]
    • Y10T428/2985—Solid-walled microcapsule from synthetic polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2984—Microcapsule with fluid core [includes liposome]
    • Y10T428/2985—Solid-walled microcapsule from synthetic polymer
    • Y10T428/2987—Addition polymer from unsaturated monomers only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2989—Microcapsule with solid core [includes liposome]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Polymerisation Methods In General (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

　膨張倍率が高く、しかも、熱膨張させた場合に優れた繰り返し圧縮耐久性を有する中空微粒子となる熱膨張性微小球の製造方法およびその応用を提供する。 　熱膨張性微小球の製造方法は、熱可塑性樹脂からなる外殻と、それに内包され且つ前記熱可塑性樹脂の軟化点以下の沸点を有する発泡剤とから構成される熱膨張性微小球の製造方法であって、酸素原子を含有するアルミニウム塩および／またはその水和物、および、カルボン酸（塩）基およびホスホン酸（塩）基から選ばれた親水性官能基が置換したアルキル基が窒素原子と結合した構造を少なくとも１つ有する分子量１０００以上のポリアルキレンイミン類から選ばれた少なくとも１種の水溶性化合物の存在下、重合性成分と前記発泡剤とを分散させた水性分散媒中で、前記重合性成分を重合させる工程を含む製造方法である。
PCT/JP2008/001198 2007-05-21 2008-05-14 熱膨張性微小球の製造方法およびその応用 Ceased WO2008142849A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2009515084A JP4386962B2 (ja) 2007-05-21 2008-05-14 熱膨張性微小球の製造方法およびその応用
EP08751716A EP2151456B1 (en) 2007-05-21 2008-05-14 Process for production of thermally expandable beads and application thereof
CN2008800169332A CN101679537B (zh) 2007-05-21 2008-05-14 热膨胀性微球的制备方法及其应用
US12/594,317 US8206826B2 (en) 2007-05-21 2008-05-14 Method for producing heat-expandable microspheres and application thereof
KR1020097022567A KR101406022B1 (ko) 2007-05-21 2008-05-14 열팽창성 미소구의 제조방법 및 그 응용

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-134009 2007-05-21
JP2007134009 2007-05-21

Publications (1)

Publication Number Publication Date
WO2008142849A1 true WO2008142849A1 (ja) 2008-11-27

Family

ID=40031568

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/001198 Ceased WO2008142849A1 (ja) 2007-05-21 2008-05-14 熱膨張性微小球の製造方法およびその応用

Country Status (6)

Country Link
US (1) US8206826B2 (ja)
EP (1) EP2151456B1 (ja)
JP (1) JP4386962B2 (ja)
KR (1) KR101406022B1 (ja)
CN (1) CN101679537B (ja)
WO (1) WO2008142849A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008291067A (ja) * 2007-05-22 2008-12-04 Matsumoto Yushi Seiyaku Co Ltd 熱膨張性微小球の製造方法
JP2011032626A (ja) * 2009-07-08 2011-02-17 Toyota Boshoku Corp 繊維成形体の製造方法及び熱膨張性カプセル配合体
JP2011195813A (ja) * 2010-02-25 2011-10-06 Matsumoto Yushi Seiyaku Co Ltd 熱膨張性微小球、中空微粒子、その製造方法および用途
CN102459492A (zh) * 2009-06-09 2012-05-16 松本油脂制药株式会社 热膨胀性微球和热膨胀性微球的制备方法及其应用
JP2016130308A (ja) * 2015-01-09 2016-07-21 松本油脂製薬株式会社 セラミック組成物用造孔材およびその用途
JP2018145441A (ja) * 2018-06-14 2018-09-20 積水化学工業株式会社 マスターバッチ及び発泡成形体
WO2019124233A1 (ja) * 2017-12-21 2019-06-27 松本油脂製薬株式会社 樹脂組成物、成形体、及び熱膨張性微小球

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JP5269485B2 (ja) * 2008-05-30 2013-08-21 ユニ・チャーム株式会社 凹凸模様を有する嵩高紙及びその製造方法
JP5269486B2 (ja) * 2008-05-30 2013-08-21 ユニ・チャーム株式会社 凹凸模様を有する嵩高紙及びその製造方法
US9663626B2 (en) 2012-01-25 2017-05-30 Matsumoto Yushi-Seiyaku Co., Ltd. Heat-expandable microspheres, process for producing the same, and application thereof
KR102014742B1 (ko) * 2012-06-10 2019-08-27 롬 앤드 하아스 컴패니 혼합염 현탁 중합방법 및 그로부터 제조된 수지 및 촉매
AU2013317851B2 (en) * 2012-09-20 2017-04-13 Encapsys, Llc Spray drying microcapsules
KR102258220B1 (ko) * 2013-12-26 2021-06-01 마쓰모토유시세이야쿠 가부시키가이샤 열팽창성 미소구의 제조방법 및 그 이용
KR101923096B1 (ko) * 2014-02-25 2019-02-27 자동차부품연구원 열팽창 마이크로 캡슐 및 그 제조방법
CN104689772B (zh) * 2015-03-06 2017-08-11 天津大学 多酚化学启发制备高分子微囊的方法
CN105647088A (zh) * 2016-04-07 2016-06-08 清远南方新特材料研究院有限公司 一种导热塑料及其制备方法
CN109414838A (zh) 2016-07-01 2019-03-01 戈拉工业公司 形成具有硬质外壳的可膨胀泡沫团粒的方法和设备
CN109294393A (zh) * 2018-09-19 2019-02-01 宝华（黄山）新材料技术有限公司 一种微发泡环氧粉末涂料及其制作方法
CN110551248A (zh) * 2018-12-19 2019-12-10 南京人天环保科技有限公司 一种粒径可控的热膨胀性微球制备方法
CN109473039A (zh) * 2018-12-28 2019-03-15 厦门天马微电子有限公司 显示模组和显示装置
CN109647299B (zh) * 2019-01-18 2021-05-25 唐山开滦化工科技有限公司 一种导电型可膨胀微胶囊及其制备方法
JP7338185B2 (ja) 2019-03-20 2023-09-05 株式会社リコー 感熱記録媒体
CN111755688A (zh) * 2019-03-29 2020-10-09 住友橡胶工业株式会社 硫系活性物质
CN109847664B (zh) * 2019-04-09 2021-11-12 贵州师范大学 一种导电热膨胀型微胶囊及其制备方法
CN112480325B (zh) * 2020-12-02 2022-05-27 辽宁石油化工大学 一种酚醛树脂-丙烯酰胺复合微球及其制备方法和应用
CN114685843B (zh) * 2020-12-29 2024-04-12 洛阳尖端技术研究院 热膨胀微珠、包含其的可反复热剥离压敏胶、反光膜及制备方法
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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008291067A (ja) * 2007-05-22 2008-12-04 Matsumoto Yushi Seiyaku Co Ltd 熱膨張性微小球の製造方法
EP2441814A4 (en) * 2009-06-09 2015-03-04 Matsumoto Yushi Seiyaku Kk HOT EXPANSIBLE MICROSPHERE, PROCESS FOR PRODUCING SAME, AND USE THEREOF
CN102459492A (zh) * 2009-06-09 2012-05-16 松本油脂制药株式会社 热膨胀性微球和热膨胀性微球的制备方法及其应用
EP2529830A3 (en) * 2009-06-09 2014-10-29 Matsumoto Yushi-Seiyaku Co., Ltd. Heat-expandable microspheres and a method of making heat-expandable microspheres and application thereof
CN102459492B (zh) * 2009-06-09 2014-11-26 松本油脂制药株式会社 热膨胀性微球和热膨胀性微球的制备方法及其应用
US9126178B2 (en) 2009-06-09 2015-09-08 Matsumoto Yushi-Seiyaku Co., Ltd. Heat-expandable microspheres and a method of making heat-expandable microspheres and application thereof
JP2011032626A (ja) * 2009-07-08 2011-02-17 Toyota Boshoku Corp 繊維成形体の製造方法及び熱膨張性カプセル配合体
JP2011195813A (ja) * 2010-02-25 2011-10-06 Matsumoto Yushi Seiyaku Co Ltd 熱膨張性微小球、中空微粒子、その製造方法および用途
JP2016130308A (ja) * 2015-01-09 2016-07-21 松本油脂製薬株式会社 セラミック組成物用造孔材およびその用途
WO2019124233A1 (ja) * 2017-12-21 2019-06-27 松本油脂製薬株式会社 樹脂組成物、成形体、及び熱膨張性微小球
JPWO2019124233A1 (ja) * 2017-12-21 2019-12-19 松本油脂製薬株式会社 樹脂組成物、成形体、及び熱膨張性微小球
US11773237B2 (en) 2017-12-21 2023-10-03 Matsumoto Yushi-Seiyaku Co., Ltd. Resin composition, molded article and heat-expandable microspheres
JP2018145441A (ja) * 2018-06-14 2018-09-20 積水化学工業株式会社 マスターバッチ及び発泡成形体

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EP2151456A1 (en) 2010-02-10
EP2151456B1 (en) 2012-07-11
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