WO2009021710A3 - Verfahren und anlage zur herstellung von synthesegas aus biogas - Google Patents

Verfahren und anlage zur herstellung von synthesegas aus biogas Download PDF

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Publication number
WO2009021710A3
WO2009021710A3 PCT/EP2008/006614 EP2008006614W WO2009021710A3 WO 2009021710 A3 WO2009021710 A3 WO 2009021710A3 EP 2008006614 W EP2008006614 W EP 2008006614W WO 2009021710 A3 WO2009021710 A3 WO 2009021710A3
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WIPO (PCT)
Prior art keywords
biogas
oxygen
gas
oxidation
synthethis
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Ceased
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PCT/EP2008/006614
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English (en)
French (fr)
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WO2009021710A2 (de
Inventor
Lothar Guenther
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DGE Dr Ing Guenther Engineering GmbH
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DGE Dr Ing Guenther Engineering GmbH
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Application filed by DGE Dr Ing Guenther Engineering GmbH filed Critical DGE Dr Ing Guenther Engineering GmbH
Priority to CN2008801065839A priority Critical patent/CN101801842B/zh
Priority to BRPI0815478-3A2A priority patent/BRPI0815478A2/pt
Priority to US12/673,239 priority patent/US8187568B2/en
Priority to EP08785493A priority patent/EP2188210A2/de
Publication of WO2009021710A2 publication Critical patent/WO2009021710A2/de
Publication of WO2009021710A3 publication Critical patent/WO2009021710A3/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
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    • B01D53/1456—Removing acid components
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  • Preparation Of Compounds By Using Micro-Organisms (AREA)

Abstract

Die Erfindung bezieht sich auf ein Verfahren zur Herstellung von Synthesegas aus Biogas und eine zur Durchführung des Verfahrens geeignete Anlage. Ausgehend von den Nachteilen des bekannten Standes der Technik soll ein Verfahren geschaffen werden, das sich durch eine wirtschaftlichere Prozessführung und eine höhere Ausbeute auszeichnet. Hierzu wird als Lösung vorgeschlagen, dass vor der katalytischen Umwandlung des Biogases aus diesem Schwefelwasserstoff und Kohlendioxid in getrennten Reinigungsstufen nahezu vollständig abgetrennt werden, wobei Schwefelwasserstoff biologisch durch Zugabe von Sauerstoff und/oder sauerstoffhaltigem Oxidationsmittel entfernt wird. Der Sauerstoff oder das Oxidationsmittel werden so dosiert, dass im gereinigten Biogas (Methangas) ein Sauerstoffüberschuss von mindestens 1,0 Vol.-% enthalten ist. Das Biogas wird ohne Entfeuchtung verdichtet, erwärmt und mit überhitztem Dampf versetzt. Bedingt durch den Sauerstoffüberschuss wird während des Reformingprozesses zusätzlich Wärmeenergie durch eine exotherme Oxidation von im Biogas enthaltenem Sauerstoff mit Wasserstoff im Katalysatorbett erzeugt, zur endothermen Umsetzung von Methan zu Synthesegas.
PCT/EP2008/006614 2007-08-16 2008-08-12 Verfahren und anlage zur herstellung von synthesegas aus biogas Ceased WO2009021710A2 (de)

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CN2008801065839A CN101801842B (zh) 2007-08-16 2008-08-12 用于从生物气生产合成气的方法和设备
BRPI0815478-3A2A BRPI0815478A2 (pt) 2007-08-16 2008-08-12 Processo e instalação para produção de gás sintético a partir de biogás
US12/673,239 US8187568B2 (en) 2007-08-16 2008-08-12 Method and plant for the production of synthesis gas from biogas
EP08785493A EP2188210A2 (de) 2007-08-16 2008-08-12 Verfahren und anlage zur herstellung von synthesegas aus biogas

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CN101801842B (zh) 2013-07-31
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WO2009021710A2 (de) 2009-02-19
BRPI0815478A2 (pt) 2015-02-10
US20110175032A1 (en) 2011-07-21
DE102007038760B3 (de) 2009-01-02
US8187568B2 (en) 2012-05-29

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