WO2012105731A1 - Matériau d'alliage de cuivre pour l'eau de mer et son procédé de préparation - Google Patents

Matériau d'alliage de cuivre pour l'eau de mer et son procédé de préparation Download PDF

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Publication number
WO2012105731A1
WO2012105731A1 PCT/KR2011/003449 KR2011003449W WO2012105731A1 WO 2012105731 A1 WO2012105731 A1 WO 2012105731A1 KR 2011003449 W KR2011003449 W KR 2011003449W WO 2012105731 A1 WO2012105731 A1 WO 2012105731A1
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Prior art keywords
seawater
alloy material
copper alloy
weight
copper
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PCT/KR2011/003449
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English (en)
Inventor
In Dal Kim
Dong Woo Lee
Dae Hyun Kim
Young Chul Choi
Dae Hyun Ju
Ji Hoon Lee
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Poongsan Corp
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Poongsan Corp
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Application filed by Poongsan Corp filed Critical Poongsan Corp
Priority to CN2011800664967A priority Critical patent/CN103403201A/zh
Priority to JP2013552452A priority patent/JP5911891B2/ja
Priority to EP11857456.5A priority patent/EP2670875B1/fr
Priority to AU2011357615A priority patent/AU2011357615A1/en
Publication of WO2012105731A1 publication Critical patent/WO2012105731A1/fr
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C9/00—Alloys based on copper
    • C22C9/04—Alloys based on copper with zinc as the next major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon

Definitions

  • the present invention relates to a copper alloy material for use in the seawater, a method for preparing the same and a structure manufactured from the same for use in the seawater. More specifically, the present invention relates to a copper alloy material for use in the seawater comprising 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni) and the remainder of copper (Cu), a method for preparing the same and a structure manufactured from the same for use in the seawater.
  • the copper alloy material for use in the seawater further comprises, in an amount of 1% by weight or less, at least one element selected from the group consisting of Sn, Al, Si, Co, Fe, P, Mg, Pb and Ca.
  • an aquaculture net made of iron hereinafter, referred to as an iron net
  • an aquaculture net made of a chemical fiber hereinafter, referred to as a chemical fiber net
  • marine organisms such as shellfish or algae are readily adhered to the net and the mesh of the net is clogged, causing a deterioration in flow of tidewater, thus limiting supply of oxygen or water-in nutrients to the farm, and thus causing a deterioration in production efficiency and aquaculture yield.
  • the aquaculture net requires superior strength, since it should be resilient to certain unforeseen circumstances such as tides of seawater and typhoons.
  • the chemical fiber net has a disadvantage of low strength, as compared to the metal net.
  • metal nets require sufficient corrosion resistance to seawater, since they are inevitably exposed to ionic components such as salts present in the seawater.
  • conventional metal nets are readily corroded by seawater.
  • other metal nets made of a metal-containing material have economic efficiency problems due to high cost. For this reason, metal nets are preferably made of a material which can be manufactured at a low cost.
  • Aquaculture nets made of a copper alloy material under recently developed under such a circumference can prevent adhesion of marine organisms thereto due to anti-fouling property derived from silver and copper ions, thus reducing clogging the mesh of the aquaculture net and thereby somewhat solving the high-cost problem caused by deterioration in production efficiency or yield of cultured fish.
  • copper alloys which satisfy the requirements of sufficient strength, corrosion resistance to seawater and anti-fouling property and are made of a cheap material.
  • Korean Laid-open Patent Publication No. 1993-0019841 discloses a copper alloy material based on Cu-Al-Ni, which has an insufficient strength for use as a structure for use in the seawater, and low economic efficiency, due to use of relatively expensive nickel (Ni).
  • Korean Laid-open Patent Publication No. 1999-002539 discloses a copper alloy material based on Cu-Al-Zn-Mn-Fe in which aluminum is present in an amount of 5% to 5.3% by weight and zinc is present in an amount of 10% to 20% by weight, thus making it difficult to secure sufficient processability, and in which iron is present in an amount of 2% to 4% by weight, thus making it difficult to secure sufficient corrosion resistance.
  • An object of the present invention devised to solve the problem lies on a copper alloy material for use in the seawater which has superior mechanical properties including sufficient strength, superior ductility and low brittleness, and exhibits high corrosion resistance to seawater and anti-fouling property.
  • Another object of the present invention devised to solve the problem lies on a method for preparing the copper alloy material and a structure for use in the seawater manufactured by the copper alloy material.
  • the object of the present invention can be achieved by providing a copper alloy material for use in the seawater comprising 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni) and the remainder of copper (Cu).
  • the copper alloy material further comprises, in an amount of 1% by weight or less, at least one element selected from the group consisting of Sn, Al, Si, Co, Fe, P, Mg, Pb and Ca.
  • a method for preparing a copper alloy material for seawater comprising: producing an ingot comprising 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni) and the remainder of copper (Cu); annealing the ingot at 600°C to 900°C for 30 minutes to 12 hours, followed by hot extruding and drawing; quenching the resulting product, followed by cold drawing; annealing the resulting product at 500°C to 800°C for 30 minutes to 12 hours; and cold drawing the resulting product.
  • the copper alloy material may further comprise, in an amount of 1% by weight or less, at least one element selected from the group consisting of Sn, Al, Si, Co, Fe, P, Mg, Pb and Ca.
  • Final cold drawing ratio may be 10% to 90%.
  • a structure for seawater manufactured from a copper alloy material for seawater comprising 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni) and the remainder of copper (Cu).
  • the structure for seawater may be an aquaculture net.
  • the present invention provides a copper alloy material for seawater which has superior mechanical properties and exhibits superior high anti-fouling property and corrosion resistance to seawater. Further, the present invention provides a method for preparing the copper alloy material.
  • FIG. 1 shows results observed with an optical microscope after dezincification test using, as samples, copper alloy specimens of Examples and Comparative Examples according to the present invention.
  • FIGS. 2 and 3 show results of seawater immersion test using, as samples, copper alloy material specimens of Examples and Comparative Examples according to the present invention.
  • FIG. 2 is an image showing variation in the seawater, caused by copper ions eluted from copper alloys after immersion for 20 days.
  • FIG. 3 shows color observation results of specimens after immersion for 20 days.
  • Example #1 means test results of the sample prepared in Example 1
  • Example #6 means test results of the sample prepared in Example 6
  • Comparative Example #1 means test results for the sample of Comparative Example 1
  • Comparative Example #2 means test results for the sample of Comparative Example 2.
  • copper alloy material for seawater or “copper alloy material for use in the seawater,” as used herein, refers to a copper alloy material which is partially or entirely immersed in the seawater for a long period and, for example, a fish net for aquaculture.
  • the present invention is directed to a copper alloy material for seawater comprising 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni) and the remainder of copper (Cu).
  • zinc (Zn) is present in an amount of 25% to 40% by weight, based on the weight of the copper alloy material.
  • Zinc improves the strength and hardness of the copper alloy material obtained by alloying a copper metal and enhances heat resistance.
  • the second phase, beta ( ⁇ ) phase when zinc is less than 25% by weight, sufficient hardness cannot be secured and economic efficiency decreases due to an increased amount of copper with respect to zinc, and when zinc exceeds 40% by weight, the second phase, beta ( ⁇ ) phase, indicating brittleness of materials in the obtained copper alloy material, increases and ductility is thus deteriorated, thus causing problems, such as cracking during processing.
  • zinc is preferably present in an amount of 35% to 40% by weight.
  • manganese (Mn) is present in an amount of 0.5% to 10% by weight, based on the weight of the copper alloy material.
  • the second phase, beta ( ⁇ ) phase increases and ductility is thus deteriorated, as the content of zinc in the copper alloy material increases.
  • manganese reduces deterioration in ductility.
  • the content of manganese is less than 0.5% by weight, reduction of ductility through addition of manganese is insufficient, and when the content exceeds 10% by weight, the materials are brittle.
  • nickel is present in an amount of 0.1% to 5% by weight, based on the weight of the copper alloy material. Nickel improves hardness of the obtained copper alloy material. When the content of nickel is less than 0.1% by weight, hardness is not sufficiently improved, and when the content of nickel exceeds 5% by weight, hardness improvement is slowed. Although nickel is added in an amount of 5% by weight or higher, considerable improvement in hardness cannot be obtained. Accordingly, as the amount of nickel increases, economic efficiency is considerably deteriorated.
  • copper (Cu) is a main component.
  • the copper is present in an amount of the remainder, except for which the afore-mentioned other components are present in amounts defined above.
  • the copper alloy material for seawater may further comprise, in an amount of 1% by weight or less, at least one element selected from the group consisting of Sn, Al, Si, Co, Fe, P, Mg, Pb and Ca.
  • the copper content is decreased in an amount corresponding to the content of the further added element.
  • the further added element exhibits effects, comparable to the copper alloy material of the present invention, without causing in deterioration in hardness and softening resistance of the copper alloy material and having a negative effect on corrosion resistance to seawater and eluted amount of ions.
  • the copper alloy material may further comprise trace impurities in an amount that does not effect characteristics of the copper alloy material.
  • the copper alloy material for seawater may further comprise trace impurities of at least one selected from the group consisting of As, Ti, S, Cr, Nb and Sb of 0.1% by weight.
  • the impurities may be added during a general process for preparing a copper alloy material and are present in trace amounts, thus having no great effect on the properties of the copper alloy material.
  • the copper alloy material in accordance with the present invention exhibits considerably improved corrosion resistance to seawater when a structure for seawater made of the copper alloy material is used in the seawater, compared with a conventional copper alloy material in which a corrosion promoter is readily produced by seawater.
  • the eluted amount of copper ions in the copper alloy material should be 60% or higher, based on the eluted amount of copper ions of pure copper, in order to impart sufficient anti-fouling property to the structure for seawater manufactured from the copper alloy material.
  • the eluted amount of copper ions of copper alloy material is 60% or less of the eluted amount of copper ions of pure copper, the pollution prevention effects cannot be sufficiently realized.
  • the amount of copper ions eluted from the copper alloy material in the seawater should be 415.8 mg/m2/day or more, in order to secure sufficient antibacterial properties, since the amount of copper ions eluted from pure copper in the seawater is about 693 mg/m2/day.
  • the copper alloy material in accordance with the present invention exhibits an amount of eluted copper ions which is 60% or more of copper ions eluted from pure copper.
  • the strength of the copper alloy material according to the present invention may be evaluated in terms of hardness and softening resistance.
  • the hardness of the copper alloy material may vary depending on the percentage reduction in thickness after annealed in the preparation process.
  • the copper alloy material according to the present invention has a hardness ranging from 120 to 160 Hv when processed at a percentage reduction in thickness of about 10% to 30%, immediately after annealing. Within the range defined above, the copper alloy material has a sufficient strength required for the structure for sea water such as aquaculture nets.
  • the softening resistance may be evaluated from a hardness measured after the copper alloy material is reduced in thickness to at most 70% due to an increased processing ratio, placed in a annealing furnace at 400°C and maintained for 30 minutes. The hardness should be within a range from about 95 to about 120 Hv.
  • the copper alloy material for seawater according to the present invention is prepared by the method comprising: producing an ingot from 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni) and the remainder of copper (Cu); annealing the ingot at 600°C to 900°C for 30 minutes to 12 hours, followed by hot extruding and drawing; quenching the resulting product to room temperature, followed by cold drawing; annealing the resulting product at 500°C to 800°C for 30 minutes to 12 hours; and cold drawing the resulting product.
  • Zn zinc
  • Mn manganese
  • Ni nickel
  • Cu copper
  • an ingot is produced by mold casting 25% to 40% by weight of zinc (Zn), 0.5% to 10% by weight of manganese (Mn), 0.1% to 5% by weight of nickel (Ni), and the remainder of copper (Cu).
  • the ingot may further comprise 1% by weight or less of at least one selected from the group consisting of Sn, Al, Si, Co, Fe, P, Mg, Pb and Ca.
  • the ingot thus obtained is annealed in a continuous annealing furnace at a temperature of 600°C to 900°C for 30 minutes to 12 hours, hot-extruded and drawn in a linear or rod shape.
  • a continuous annealing furnace at a temperature of 600°C to 900°C for 30 minutes to 12 hours, hot-extruded and drawn in a linear or rod shape.
  • the annealing is performed at 600°C or lower, sufficient effects of annealing cannot be obtained, recrystallization in the metal structure is difficult and excessive hot load occurs.
  • the annealing is performed at 900°C or higher, coarse structures are formed and abnormal structures are thus produced in the metal structure.
  • the annealing is performed for 30 minutes or less, softening of metal structures is not sufficient, and when the annealing is performed for 12 hours, disadvantageously, metal structures are excessively softened and production efficiency is deteriorated.
  • the annealed product is quenched to room temperature of about 21°C to about 30°C and is then cold drawn.
  • the resulting product is annealed at 500°C to 800°C for 30 minutes to 12 hours.
  • the annealing may be carried out in a bell or batch annealing furnace.
  • the annealing temperature ranges from 500°C to 800°C, since the product annealed once in the previous step is recrystallized at a relatively low temperature.
  • annealing is performed at 500°C or lower, recrystallization in the metal structure is disadvantageously difficult, and when the annealing is performed at 800°C or higher, coarse structures are grown, abnormal structures are thus generated, and production efficiency is deteriorated to the excessively high temperature.
  • the annealing is performed for 30 minutes or less, softening of metal structures is not sufficient, and when annealing is performed for 12 hours or longer, disadvantageously, metal structures are excessively softened and production efficiency is deteriorated.
  • the resulting product is cold drawn.
  • a drawing ratio ranges from 10% to 90%.
  • the drawing ratio is lower than 10%, sufficient mechanical strength cannot be secured, and when the drawing ratio exceeds 90%, a percentage cold reduction in thickness disadvantageously reaches a limit due to the excessive processing ratio.
  • the annealing and cold drawing steps may be repeated.
  • an ingot with a chemical composition shown in the following Table 1 was prepared and annealed at 600°C for 6 hours, hot-extruded and drawn to a thickness of 1.5 mm.
  • the resulting product was quenched to room temperature, cold-drawn and annealed at 600°C for one hour.
  • the resulting specimen was cut and then cold drawn at a percentage reduction in thickness of at most 30% after immediately annealing, to obtain a final sample.
  • the sample of Comparative Example 1 was a brass product (UR30) commercially available from Mitsubishi (Japan) and the sample of Comparative Example 2 was a brass (alloy of copper and zinc in a ratio of 6:4), and the sample of Comparative Example 3 was pure copper.
  • the material subjected to reduction in thickness at an increased processing ratio that is, at a percentage (at most 70%) was placed in a furnace at 400°C, held for 30 minutes and removed.
  • the decrease in hardness of the material was measured using a micro Vickers hardness tester. The results are shown in Table 2. As can be seen from Table 2, the samples of Examples 1 to 14 fall within the range of about 98 to 119 Hv.
  • KS D9502 salt water spray test was performed to evaluate corrosion resistance to seawater and salt water prepared by dissolving sodium chloride in distilled water was used.
  • the specimens were placed in a salt water spray tester, sprayed for 24 hours at an interval of several hours and removed. Corrosion of the specimen was observed. The results are shown in Table 2. The notation is based on ⁇ : good, ⁇ : insufficient and X: bad, in accordance with a naked eye examination standard.
  • the respective specimens were immersed in a beaker containing 200 ml of seawater for 24 hours and the amount of eluted copper ions was measured. The results are shown in Table 2.
  • the amount of eluted copper ions was 693 mg/m2/day and 60% of the amount of eluted copper ions was 415.8 mg/m2/day.
  • 60% of the amount of eluted copper ions for pure copper was 415.8 mg/m2/day or more, which indicates that the samples can provide sufficient anti-bioattachment.
  • Example 1 to 14 exhibited considerably superior dezincification and good corrosion resistance to seawater, as compared to the samples of Comparative Examples 1 to 3. Further, in the samples of Examples 1 to 14, 60% of the amount of eluted copper ions for pure copper was 415.8 mg/m2/day or more, which indicates that the samples satisfy the requirements for anti-bioattachment.
  • FIG. 3 shows color observation results of specimens after immersed for 20 days. As can be seen from FIG. 3, the sample of Example 1 and the sample of Example 6 were not greatly varied, as compared to prior to immersion, while the sample of Comparative Example 1 turned blue and the sample of Comparative Example 2 was partially corroded and turned gray.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Farming Of Fish And Shellfish (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Extrusion Of Metal (AREA)

Abstract

La présente invention concerne un matériau d'alliage de cuivre pour l'eau de mer comprenant de 25 % à 40 % en poids de zinc (Zn), de 0,5 % à 10 % en poids de manganèse (Mn), de 0,1 % à 5 % en poids de nickel (Ni) et le complément de cuivre (Cu), un procédé de préparation dudit matériau, et une structure pour l'eau de mer fabriquée à partir de celui-ci. De plus, le matériau d'alliage de cuivre pour l'eau de mer comprend en outre, en une quantité de 1 % en poids tout au plus, au moins un élément choisi dans le groupe constitué de Sn, Al, Si, Co, Fe, P, Mg, Pb et Ca.
PCT/KR2011/003449 2011-02-01 2011-05-11 Matériau d'alliage de cuivre pour l'eau de mer et son procédé de préparation Ceased WO2012105731A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN2011800664967A CN103403201A (zh) 2011-02-01 2011-05-11 用于海水的铜合金材料及其制备方法
JP2013552452A JP5911891B2 (ja) 2011-02-01 2011-05-11 海水用銅合金材及びその製造方法
EP11857456.5A EP2670875B1 (fr) 2011-02-01 2011-05-11 Matériau d'alliage de cuivre pour l'eau de mer et son procédé de préparation
AU2011357615A AU2011357615A1 (en) 2011-02-01 2011-05-11 Copper alloy material for seawater and method for preparing same

Applications Claiming Priority (2)

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KR1020110009997A KR101260912B1 (ko) 2011-02-01 2011-02-01 해수용 동합금재 및 이의 제조 방법
KR10-2011-0009997 2011-02-01

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WO2012105731A1 true WO2012105731A1 (fr) 2012-08-09

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EP (1) EP2670875B1 (fr)
JP (1) JP5911891B2 (fr)
KR (1) KR101260912B1 (fr)
CN (1) CN103403201A (fr)
AU (1) AU2011357615A1 (fr)
CL (1) CL2013002197A1 (fr)
WO (1) WO2012105731A1 (fr)

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KR101519075B1 (ko) * 2013-12-03 2015-05-21 (주)신동 전자기파 차폐용 철동합금 선재 또는 봉재와 그 제조방법
CN103757480B (zh) * 2014-01-10 2016-05-11 滁州学院 一种耐海水腐蚀复杂白铜合金材料及其制备方法
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WO2018088721A1 (fr) * 2016-11-08 2018-05-17 주식회사 대창 Alliage de cuivre pour filet pour poisson de pisciculture présentant une résistance à la corrosion améliorée et son procédé de fabrication
KR101796191B1 (ko) 2017-01-17 2017-11-09 주식회사 풍산 항균성, 내변색성 및 성형성이 우수한 동합금재 및 이의 제조방법
CN107460367B (zh) * 2017-08-29 2019-08-09 河南科技大学 一种耐含砂海水腐蚀磨损的铜合金及其制备方法
KR102616847B1 (ko) * 2019-03-27 2023-12-26 주식회사 대창 양식 어망용 동합금 선재
CN110863123A (zh) * 2019-11-29 2020-03-06 常熟市常氏瓶钳有限公司 一种制造瓶钳的铜合金配方
KR102265115B1 (ko) * 2021-02-24 2021-06-15 주식회사 풍산 내식성 및 내변색성이 우수한 Cu-Zn계 합금 및 이의 제조 방법
CN114107728B (zh) * 2021-10-11 2023-03-24 中铝洛阳铜加工有限公司 一种耐海洋腐蚀的深远海水产养殖用铜合金材料
CN118086716B (zh) * 2024-04-22 2024-07-16 中铝科学技术研究院有限公司 海洋养殖用铜合金丝材、其制备方法及应用

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4631171A (en) * 1985-05-16 1986-12-23 Handy & Harman Copper-zinc-manganese-nickel alloys
KR19990002539A (ko) * 1997-06-20 1999-01-15 민병권 내후성 및 내해수부식성이 우수한 구리합금 조성물
KR20000077017A (ko) * 1999-05-05 2000-12-26 올린 코포레이션 황금빛을 띠는 구리 합금
US20090022620A1 (en) * 2007-06-28 2009-01-22 Kai Weber Copper-zinc alloy, production method and use
US20100061884A1 (en) * 2008-09-10 2010-03-11 Pmx Industries Inc. White-colored copper alloy with reduced nickel content

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB868276A (en) 1958-10-18 1961-05-17 Eugen Vaders Improvements in or relating to bearing metal alloys
US3778236A (en) * 1972-03-29 1973-12-11 Olin Corp Plated copper base alloy article
JPS5952223B2 (ja) * 1979-04-23 1984-12-18 三菱マテリアル株式会社 養殖生け「す」用銅合金
JPS59159957A (ja) 1983-02-28 1984-09-10 Mitsubishi Metal Corp 耐海水腐食性および熱間加工性にすぐれた高強度Ｃｕ合金
JPS63100144A (ja) * 1986-05-23 1988-05-02 Nippon Mining Co Ltd 耐食性に優れた銅合金
JPS63213628A (ja) * 1987-03-02 1988-09-06 Nippon Mining Co Ltd ヒユ−ズ用銅合金
JPH06184679A (ja) * 1992-12-18 1994-07-05 Mitsui Mining & Smelting Co Ltd 電気部品用銅合金
JP3311606B2 (ja) * 1996-10-15 2002-08-05 三宝伸銅工業株式会社 銅基合金
JP3280250B2 (ja) * 1996-11-26 2002-04-30 三宝伸銅工業株式会社 魚類用養殖網及び魚類養殖用生簀
DE19802246C1 (de) * 1998-01-22 1999-07-29 Wieland Werke Ag Verwendung einer Kupfer-Zink-Nickel-Mangan-Aluminium-Legierung
DK1777305T3 (da) 2004-08-10 2011-01-03 Mitsubishi Shindo Kk Støbning af kobberbaselegering med raffinerede krystalkorn
DE102009032371A1 (de) * 2009-07-08 2011-01-13 Berkenhoff Gmbh Zusatzwerkstoff zum Löten von Stahlblechen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4631171A (en) * 1985-05-16 1986-12-23 Handy & Harman Copper-zinc-manganese-nickel alloys
KR19990002539A (ko) * 1997-06-20 1999-01-15 민병권 내후성 및 내해수부식성이 우수한 구리합금 조성물
KR20000077017A (ko) * 1999-05-05 2000-12-26 올린 코포레이션 황금빛을 띠는 구리 합금
US20090022620A1 (en) * 2007-06-28 2009-01-22 Kai Weber Copper-zinc alloy, production method and use
US20100061884A1 (en) * 2008-09-10 2010-03-11 Pmx Industries Inc. White-colored copper alloy with reduced nickel content

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AU2011357615A1 (en) 2013-08-01
CN103403201A (zh) 2013-11-20
EP2670875A4 (fr) 2014-08-13
KR20120088978A (ko) 2012-08-09
EP2670875B1 (fr) 2016-11-02
JP2014506627A (ja) 2014-03-17
JP5911891B2 (ja) 2016-04-27
CL2013002197A1 (es) 2014-02-28
KR101260912B1 (ko) 2013-05-06
EP2670875A1 (fr) 2013-12-11

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