Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
  • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
  • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
  • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
  • C10B47/28—Other processes
  • C10B47/32—Other processes in ovens with mechanical conveying means
  • C10B47/44—Other processes in ovens with mechanical conveying means with conveyor-screws
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E50/00—Technologies for the production of fuel of non-fossil origin
  • Y02E50/10—Biofuels, e.g. bio-diesel

Definitions

• the subject of the invention is a device for biomass carbonisation intended for use in the power industry for the generation of heat and electricity, and for the production of charcoal.
• Polish patent description No. 206503 discloses a device for biomass carbonisation, which consists of a vertical reactor with a vertical retort and with openings along the perimeter and along the entire length of a combustion chamber, and facing the combustion chamber that transfers the gases from the retort to the combustion chamber, with a variable speed screw conveyor that moves the mixture towards the bottom part of the reactor, with an air installed tangentially in a wall of the bottom part of the combustion chamber, and with an outlet for process gas or exhaust gas and a bottom closure of the retort located outside the reactor and equipped with a piece for outputting carbonised fuel, or with a piece for feeding carbonised fuel to other devices that utilise the fuel.
• a bottom closure of the retort is a device for mechanical fragmentation of carbonised fuel installed at the end of the screw conveyor inside the reactor and with a piece for outputting carbonised fuel through a slot along the perimeter of the cone of the device for mechanical fragmentation of the fuel towards the walls of the combustion chamber, and subsequently into the top part of the combustion chamber and the outlet.
• Polish patent description No. 207596 discloses a device for biomass carbonisation consisting of a vertical reactor with a cylindrical vertical drying and heating column, and a combustion chamber. Inside the drying and heating column, a mixer for raising and mixing biomass is installed. Under the bottom part of the drying and heating column, there is a cone- shaped grate, under which a scraper is installed for scraping carbonised biomass from the cone-shaped grate. Under the combustion chamber, a chamber for cooling carbonised biomass and an outlet for the evacuation of the finished product from the device are installed.
• the solutions known in the prior art are not suitable for processing biomass with high moisture content, and require its pre-drying in a dryer. This may give rise to significant issues with the interactions between an external dryer and a reactor for biomass carbonisation relating to adequate performance of both devices, and to the control of the temperature of biomass downstream at a dryer outlet and at the inlet of a carbonising reactor.
• the solutions known in the prior art also do not protect the surface of a reactor from detrimental influence of tar.
• coal obtained from biomass by applying solutions known in the prior art could be used only for combustion, and could not be used in the chemical industry due to insufficient carbon content.
• the device according to the invention comprises a tray at the top part of the device hermetically connected with the inside of the device, inside the device there is a vertical retort i.e. a metal tube with a length preferably from 1 to 15 metres, most preferably 6 metres, with inner diameter preferably from 400 to 1000 mm, most preferably 600 mm, through which biomass is conveyed vertically in the downward direction.
• a vertical retort i.e. a metal tube with a length preferably from 1 to 15 metres, most preferably 6 metres, with inner diameter preferably from 400 to 1000 mm, most preferably 600 mm, through which biomass is conveyed vertically in the downward direction.
• an inner tube with an outer diameter preferably from 200 to 800 mm, most preferably 400 mm, onto which an augered strip is attached.
• the inner tube preferably is attached to the top part of the device in a swivelling manner.
• the augered strip is inclined at an angle from 30° to 60° relative to the lateral plane of the inner tube, preferably at an angle of 45°.
• the inclination of the augered strip improves the contact surface of biomass with the inner surface of the retort.
• the inclination of the augered strip between 30° and 60° is preferable due to the flow of the gases generated during the drying and degassing of biomass.
• the pitch of the auger ensures that the biomass on the surface of the auger biomass does not move spontaneously.
• the ratio of the outer diameter of the inner tube with the auger to the inner diameter of the retort should be between 0.5 and 0.8, preferably 0.667.
• the biomass conveyed by the auger inside the vertical retort with a length between 1 and 15 metres, preferably 6 metres is heated, dried, degassed, and undergoes partial carbonisation.
• the retort is finished with a cylindrical element comprising a set of connected parallel bars forming a palisade-like shape. This element positively affects the heating of the biomass leaving the vertical retort and the outflow of gases from inside the retort into a vortex combustion chamber located beneath the inner tube. Some biomass may move through gaps between the bars into the vortex combustion chamber. At the top of the retort there are openings through which water vapour escapes into the combustion chamber.
• the vortex combustion chamber has a cylinder shape, and its side walls are equipped with tangent nozzles that supply air for the combustion of the gases generated during biomass degassing. It is preferable that the air supply nozzles are placed at four locations distributed evenly along the perimeter of the vortex combustion chamber, and it is preferable that the nozzles are placed on several levels, preferably on 4 levels.
• the diameter of the vortex combustion chamber is larger than the outside diameter of the retort, preferably 1.2 to 4 times larger, preferably 2 times larger.
• the height of the vortex combustion chamber preferably is from 0.5 to 3 diameters of the vortex combustion chamber, preferably 1.5. Under the retort and the cylindrical element, there is a cone for redirecting the flow of biomass from vertical to horizontal.
• the diameter of the base of the cone preferably is from 0.6 to 0.9 of the inner diameter of vortex combustion chamber, most preferably 0.85.
• the angle between the base of the cone and the slant height that determines the side surface of the cone is between 10 and 45°, preferably 20°.
• Above the surface of the cone there is a mixer for raking and flipping the biomass on the cone.
• the mixer should preferably be equipped with 2 to 8 arms arranged so as to ensure proper mixing and raking of biomass, preferably 4 arms.
• the retort is equipped on its outer surface with an additional auger that extends the duration of the exhaust gas stay in the vicinity of the retort.
• the auger strip outside the retort is inclined at an angle from 30° to 60° relative to the lateral plane of the outer tube, preferably at an angle of 45°.
• the diameter of the flue is between 1.3 and 2.2 times the outer diameter of the retort, most preferably 1.7.
• the length of the flue corresponds to the length of the retort.
• the exhaust gases that leave the flue are directed into a cyclone and subsequently into an afterburn chamber for afterburning.
• the carbonised biomass in the vortex combustion chamber moves along the surface of the cone and flows into the bottom part of the reactor, which is cylindrical and its cross-section preferably changes to square along the way. Any remaining gases and tars are removed from the carbonised biomass, which stays and moves downwards in a ceramic chamber intended to be located under the cone. The obtained gases flow in the vertical direction and escape through an opening in the cone, whereas the tars may be carbonised on the biocoal grains located above.
• the cylindrical part is equipped with at least two levels of tubes with openings facing down and the sides intended for adding water vapour or other additives to the hot biocoal to activate it, and to control the carbonisation ratio and temperature.
• These tubes are spaced horizontally preferably by 100 to 200 mm, most preferably 150 mm, and the distance between the levels is preferably between 100 and 200 mm, most preferably 150 mm.
• the tubes located at the respective levels can be arranged perpendicular to each other or in parallel and moved by half the distance between the tubes at a level.
• the openings in the tubes located along their length can be spaced by 50 to 200 mm, preferably by 100 mm.
• the diameter of the openings should be sufficient to enable the flow of water vapour at a speed from 0.5 to 5 m/s, preferably 2 m/s.
• the system has a "V" shape so as to enable the discharge of the product from the device.
• This shape is preferable due to minimum risk of product jamming.
• the heat exchange surface is increased, which is necessary for the purposes of cooling.
• This element may be designed as a bunded structure with water.
• the process of biomass carbonisation in the device according to the invention involves feeding fragmented biomass from the tray to the inside of the reactor, where the biomass is heat-dried, degassed and carbonised.
• the device is equipped with systems for the control of the flow of the biomass fed to the inside of the reactor.
• the fed biomass is conveyed vertically with an auger in the downward direction inside a metal retort.
• the biomass conveyed by the auger inside the vertical retort is heated, dried, degassed, and undergoes partial carbonisation.
• Some biomass may move through gaps in the cylindrical element, between the bars, into the vortex combustion chamber.
• Some or all gases generated during biomass of degassing are combusted in the vortex combustion chamber, above the layer of biomass.
• the generated exhaust gases flow through a circular flue in which the retort is located, whose outer surface is equipped with auger coils that extend the duration of the exhaust gas stay in the vicinity of the retort.
• the exhaust gases that leave the flue are directed into a cyclone and subsequently into an afterburn chamber for afterburning.
• the carbonised biomass in the vortex combustion chamber as a result of the combustion of a part of volatile components and the mixing, moves along the surface of the cone and flows into the bottom part of the reactor.
• the product is collected in the bottom part of the device.
• device for biomass carbonisation solves the following issues:
• the device for biomass carbonisation can be used for the carbonisation of biomass with high moisture content, as it is installed inside a reactor of a vertical retort, which dries the biomass.
• the design solutions known in the prior art use dryers as additional elements of the installation. This may give rise to significant issues with the interactions between an external dryer and a reactor for biomass carbonisation relating to adequate performance of both devices, and to the control of the temperature of biomass downstream at a dryer outlet and at the inlet of a carbonising reactor. In specific circumstances the biomass therein may ignite.
• the proposed solution obviates the hazard of biomass ignition in the case of integration of drying and carbonisation within one device, and, in the case of low moisture content of biomass, the inner dryer (i.e. the vertical retort) may also serve as a zone for initial pyrolysis and carbonisation of biomass so as to substantially increase in the biomass carbonisation performance of the entire device.
• the device according to the invention is presented in figures, where fig. 1 presents the diagram of the design of the device for biomass combustion, fig. 2 - the design of the inner tube, and fig. 3 - the design of the vortex combustion chamber.
• the device according to the invention comprises a tray at the top part of the device hermetically connected with the inside of the device.
• a vertical retort 2 i.e. a metal tube with a length of 6 metres, with inner diameter preferably of 600 mm, through which biomass is conveyed vertically in the downward direction.
• an inner tube 13 with an outer diameter of 400 mm, onto which an augered strip 12 is attached.
• the inner tube 13 is attached to the top part of the device in a swivelling manner.
• the augered strip 12 is inclined at an angle of 45° relative to the lateral plane of the inner tube. The inclination of the augered strip 12 improves the contact surface of biomass with the inner surface of the retort 2.
• the inclination of the augered strip 12 of 45° is preferable due to the flow of the gases generated during the drying and degassing of biomass.
• the pitch of the auger 12 ensures that the biomass on the surface of the auger biomass does not move spontaneously.
• the ratio of the outer diameter of the inner tube 13 with the auger 12 to the inner diameter of the retort is 0.667.
• the biomass conveyed by the auger inside the vertical retort 2 with a length of 6 metres is heated, dried, degassed, and undergoes partial carbonisation.
• the retort 2 is finished with a cylindrical element comprising a set of connected parallel bars 7 forming a palisade-like shape.
• This element positively affects the heating of the biomass leaving the vertical retort and the outflow of gases from inside the retort 2 into a vortex combustion chamber 9 located beneath the inner tube 12.
• Some biomass may move through gaps between the bars into the vortex combustion chamber 9.
• the vortex combustion chamber 9 has a cylinder shape, and its side walls are equipped with tangent nozzles 14 that supply air fed from the outside via the duct 6 for the combustion of the gases generated during biomass degassing. It is preferable that the air supply nozzles 14 are placed at four locations distributed evenly along the perimeter of the vortex combustion chamber 9 on 4 levels.
• the diameter of the vortex combustion chamber 9 is two times larger than the outside diameter of the retort 2.
• the height of the vortex combustion chamber 9 is 1.5 of the diameter of the vortex combustion chamber 9.
• the diameter of the base of the cone 10 is 0.85 of the inner diameter of vortex combustion chamber 9.
• the angle between the base of the cone 10 and the slant height that determines the side surface of the cone 10 is 20°.
• Above the surface of the cone 10 there is a mixer for raking and flipping the biomass on the cone 10.
• the mixer 8 is equipped with 4 arms.
• the generated exhaust gases flow through a circular flue 5, in which a retort is installed.
• the flue 5 consists of a brickwork clad on the outside with an insulation layer 4.
• the retort 2 is equipped on its outer surface with an additional auger that extends the duration of the exhaust gas stay in the vicinity of the retort 2.
• the auger strip outside the retort 2 is inclined at an angle of 45° relative to the lateral plane of the outer tube.
• the diameter of the flue is 1.7 times the outer diameter of the retort 2.
• the length of the flue corresponds to the length of the retort 2.
• the exhaust gases that leave the flue are directed into a cyclone and subsequently into an afterburn chamber for afterburning.
• the carbonised biomass 16 in the vortex combustion chamber 9 moves along the surface of the cone 10 and flows into the bottom part of the reactor, which is cylindrical and its cross-section changes to square along the way. Any remaining gases 15 and tars are removed from the carbonised biomass 16 which stays and moves downwards.
• the obtained gases 15 flow in the vertical direction and escape through an opening in the cone 10, whereas the tars may be carbonised on the biocoal grains located above. This protects the inside of the reactor against the harmful effects of tar and simultaneously increases the efficiency of biocoal production.
• the cylindrical part is equipped with two levels of tubes 11 with openings facing down and the sides intended for adding water vapour or other additives to the hot biocoal to activate it, and to control the carbonisation ratio and temperature.
• the tubes 11 are spaced horizontally by 150 mm, and the distance between the levels is 150 mm.
• the tubes 11 located at the respective levels can be arranged perpendicular to each other or in parallel and moved by half the distance between the tubes at a level.
• the openings in the tubes 11 located along their length are spaced by 100 mm.
• the diameter of the openings should be sufficient to enable the flow of water vapour at a speed from 0.5 to 5 m/s.
• In the bottom part of the device there is a system for discharging the product and cooling it at the same time.
• the system has a shape so as to enable the discharge of the product from the device. This shape is preferable due to minimum risk of product jamming.
• the heat exchange surface is increased, which is necessary for the purposes of cooling.
• This element is designed as a bunded structure with water.
• Table 1 summarises the results of the technical and elemental analysis and the obtained product averaged over 6 hours of steady operation of the device according to the invention. 12 samples of raw biomass and biocoal were collected during this period.
• the total moisture of the raw biomass samples generally falls within the range of 33-43%, however, in adverse weather conditions (e.g. rain) and without adequate protection, it can substantially increase and reach as much as above 60%, with corresponds to a moisture level of fresh biomass. Since implementation of autothermal carbonisation of biomass with a moisture content above approximately 30-35% poses difficulties, in this case an upstream dryer of raw material must be installed so that woodchips that are fed into the reactor have a moisture content of approximately 20-30%.
• the moisture content in the product of carbonisation was low ( ⁇ 10%, cf. table 2), which can be most likely attributed to the absorption of ambient humidity by dry biocoal (biocarbon) during cooling;
• the ash content in biomass was very low and amounted to approximately 1-2.5%.
• the ash content in biocoal amounted to approximately 7-12%;
• sample woodchips and biocarbon differed substantially in terms of the estimated content of fixed carbon, with approximately 10-20% for biomass, and 50-80% for biocoal. These substantial differences in the fixed carbon content in the product also point to broad possibilities of controlling and modifying the parameters of a carbonisation process (duration of stay and temperature) with the use of the described device, which enables the adjustment of operational conditions to the fuel;
• the heat of combustion and calorific values of the biocarbon samples were very high amounting to - in the case of calorific value - in the range between 22 and 29.5 J/kg. These values were substantially (by a factor of 2) higher than the calorific values estimated for woodchips in their operational condition, and at the level of black coal of very good quality;

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Materials Engineering (AREA)
• Organic Chemistry (AREA)
• Combustion & Propulsion (AREA)
• Solid Fuels And Fuel-Associated Substances (AREA)
• Processing Of Solid Wastes (AREA)

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Citations (4)

• 2016
  • 2016-06-03 PL PL417430A patent/PL235428B1/pl unknown
• 2017
  • 2017-05-29 WO PCT/PL2017/000057 patent/WO2017209632A1/en not_active Ceased

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