AR018146A1 - Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacion - Google Patents
Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacionInfo
- Publication number
- AR018146A1 AR018146A1 ARP990100943A ARP990100943A AR018146A1 AR 018146 A1 AR018146 A1 AR 018146A1 AR P990100943 A ARP990100943 A AR P990100943A AR P990100943 A ARP990100943 A AR P990100943A AR 018146 A1 AR018146 A1 AR 018146A1
- Authority
- AR
- Argentina
- Prior art keywords
- omega
- hydrogenation
- alpha
- catalyst
- weight
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000011148 porous material Substances 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- CUPCBVUMRUSXIU-UHFFFAOYSA-N [Fe].OOO Chemical class [Fe].OOO CUPCBVUMRUSXIU-UHFFFAOYSA-N 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 235000014413 iron hydroxide Nutrition 0.000 abstract 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 1
- 235000013980 iron oxide Nutrition 0.000 abstract 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 abstract 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical class [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Una masa apropiada como catalizador, que contiene: a) hierro o un compuesto a base de hierro o sus mezclas; b) de 0,001 a 0,3% en peso, con respecto a (a),de un promotor a base de 2, 3, 4 o 5 elementos seleccionados del grupo que comprende aluminio,silicio, circonio, titanio, vanadio; c) de 0 a 1% enpeso, con respecto a (a) de un compuesto a base de un metal alcalino y/o un metal alcalinotérreo, así como d) de 0,001 a 0,3% en peso, conrespecto a a), de manganeso. Un procedimiento para la hidrogenacion de alfa, omega-dinitrilos, en presencia de tales masas como catalizador, y al usode tales masas como catalizador en la hidrogenacion de alfa-omega-dinitrilos. Este procedimiento para la hidrogenacion de alfa, omega-dinitrilos (I) NC-(CH2)n-CN, en donde n es un numero entero de 1 hasta 10, opcionalmente 2, 3, 4, 5 y 6; en alfa, omega-aminonitrilos (II) NC-(CH2)n-NH2, en donde ntiene el significado anterior y/o alfa, omega-diaminas (III) H2N-CH2-(CH2)n-CH2-NH2 en donde n tiene el significado anterior; en presencia delcatalizador, así como catalizadores que permitan hidrogenar de manera simple y economica alfa, omega-dinitrilos con alta selectividad, teniendo elcatalizador una larga duracion. Las masas segun la invencion presentan, preferentemente, una superficie BET de 3 hasta 20 m2/g, un volumen de porostotal de 0,05 hasta 0,2 ml/g, un diámetro de poros medio de 0,03 hasta 0,1 micrones y una proporcion en volumen de poros en la region de 0,01 hasta0,1 micrones del 50 hasta 70%.Los porcentajes en peso indicados en (b) y (d) se refieren a los elementos, los porcentajes indicados en (c) a losoxidos de los metales alcalinos y alcalinotérreos. Estas indicaciones se refieren al componente (a). El componente (a) consta en un 90 hasta 100% enpeso, preferentemente en un 92 hasta 99% en peso, con respecto a (a), de oxidos de hierro, hidroxidos de hierro, oxihidroxidos de hierro o sus mezclas.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19809687A DE19809687A1 (de) | 1998-03-06 | 1998-03-06 | Hydrierkatalysator |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR018146A1 true AR018146A1 (es) | 2001-10-31 |
Family
ID=7859988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP990100943A AR018146A1 (es) | 1998-03-06 | 1999-03-05 | Masa apropiada como catalizador, procedimiento para la hidrogenacion de alfa, omega-dinitrilos en presencia de dicha masa y uso de dicha masa comocatalizador de hidrogenacion |
Country Status (27)
| Country | Link |
|---|---|
| US (3) | US6297394B1 (es) |
| EP (1) | EP1071653B1 (es) |
| JP (1) | JP2002505192A (es) |
| KR (1) | KR100553283B1 (es) |
| CN (1) | CN1185205C (es) |
| AR (1) | AR018146A1 (es) |
| AT (1) | ATE247623T1 (es) |
| AU (1) | AU2835699A (es) |
| BG (1) | BG64753B1 (es) |
| BR (1) | BR9908505A (es) |
| CA (1) | CA2322185C (es) |
| CZ (1) | CZ294316B6 (es) |
| DE (2) | DE19809687A1 (es) |
| EA (1) | EA003285B1 (es) |
| ES (1) | ES2207184T3 (es) |
| HU (1) | HUP0101241A3 (es) |
| ID (1) | ID25619A (es) |
| MY (1) | MY122207A (es) |
| NO (1) | NO317588B1 (es) |
| PL (1) | PL342900A1 (es) |
| PT (1) | PT1071653E (es) |
| SI (1) | SI1071653T1 (es) |
| SK (1) | SK12382000A3 (es) |
| TR (1) | TR200002588T2 (es) |
| TW (1) | TW518252B (es) |
| UA (1) | UA66841C2 (es) |
| WO (1) | WO1999044984A1 (es) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10151559A1 (de) * | 2001-10-23 | 2003-04-30 | Basf Ag | Als Katalysator geeignete Masse |
| DE10151558A1 (de) * | 2001-10-23 | 2003-04-30 | Basf Ag | Als Katalysatorvorstufe geeignete oxidische Masse |
| RU2295386C2 (ru) * | 2003-03-07 | 2007-03-20 | Алексей Юрьевич Кочетков | Гетерогенный катализатор окисления неорганических и/или органических соединений на керамическом носителе |
| DE10321788A1 (de) * | 2003-05-14 | 2004-12-09 | Basf Ag | Polyamide |
| US7339080B2 (en) | 2003-09-10 | 2008-03-04 | Basf Aktiengesellschaft | Method for the production of diaminoxylene by continuous hydrogenation of liquid phthalonitrile |
| FR2878848B1 (fr) * | 2004-12-07 | 2007-01-05 | Rhodia Chimie Sa | Procede de fabrication de composes dinitriles |
| WO2007014901A1 (de) | 2005-08-02 | 2007-02-08 | Basf Se | Verfahren zur herstellung von xylylendiamin durch kontinuierliche hydrierung von phthalodinitril |
| WO2007019390A2 (en) | 2005-08-03 | 2007-02-15 | Ccmi Corporation | Enhancement of surface-active solid-phase heterogeneous catalysts |
| JP4670603B2 (ja) * | 2005-11-18 | 2011-04-13 | 株式会社デンソー | 触媒用粒子およびその製造方法 |
| US8031804B2 (en) * | 2006-04-24 | 2011-10-04 | Parkervision, Inc. | Systems and methods of RF tower transmission, modulation, and amplification, including embodiments for compensating for waveform distortion |
| US8063239B2 (en) | 2006-05-09 | 2011-11-22 | Basf Se | Process for preparing aminoalkylnitriles and diamines from such nitriles |
| US7709541B2 (en) * | 2006-07-14 | 2010-05-04 | Headwaters Technology Innovation, Llc | Fischer-Tropsch catalysts incorporating promoter for increasing yields of C5+ hydrocarbons and methods for making and using same |
| EP1900428B1 (en) | 2006-08-09 | 2016-01-06 | Mitsubishi Gas Chemical Company, Inc. | Production method of primary amines and catalysts for producing primary amines |
| EP2114857B1 (de) | 2007-03-01 | 2013-01-09 | Basf Se | Verfahren zur herstellung von tetraethylenpentaamin |
| EP2537835B1 (de) | 2007-03-01 | 2014-04-30 | Basf Se | Neues Verfahren zur Herstellung von TETA über EDDN |
| KR20090122437A (ko) | 2007-03-01 | 2009-11-30 | 바스프 에스이 | 비처리된 aan으로부터의 에틸렌아민의 제조 방법 |
| JP5393486B2 (ja) | 2007-03-01 | 2014-01-22 | ビーエーエスエフ ソシエタス・ヨーロピア | トリエチレンテトラアミンの製造方法 |
| EP2132165B1 (de) * | 2007-03-01 | 2014-04-23 | Basf Se | Verfahren zur herstellung von ethylendiamin |
| KR101589316B1 (ko) * | 2007-09-17 | 2016-01-27 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 가스 스트림에 함유된 황 화합물의 접촉 환원에 유용한 촉매 조성물 및 이 조성물의 제조 및 사용 방법 |
| CA2746006C (en) | 2008-12-08 | 2016-01-26 | Reinier Crous | Olefin selective ft catalyst composition and preparation thereof |
| EP2193841A1 (en) * | 2008-12-08 | 2010-06-09 | Sasol Technology (Proprietary) Limited | Hydrocarbon synthesis catalyst and process with improved selectivity to short chain products |
| CN102803213B (zh) | 2009-06-18 | 2015-05-13 | 巴斯夫欧洲公司 | 甲基取代的teta化合物 |
| US9012638B2 (en) | 2011-08-31 | 2015-04-21 | Basf Se | Process for preparing EDDN and/or EDMN by conversion of FACH and EDA |
| WO2013030254A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta und/oder deta |
| EP2751067A1 (de) | 2011-08-31 | 2014-07-09 | Basf Se | Verfahren zur aufarbeitung von reaktionsausträgen aus der hydrierung von eddn bzw. edmn |
| WO2013030161A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von edfa und/oder edmfa mit hcn |
| WO2013030144A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn, edmn, teta und deta |
| WO2013030249A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von aminen durch hydrierung von nitrilen |
| WO2013030287A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn durch umsetzung von fach und eda |
| WO2013030023A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie ein verfahren zur herstellung von deta und/oder teta |
| WO2013030259A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von teta |
| US9096497B2 (en) | 2011-08-31 | 2015-08-04 | Basf Se | Process for preparing EDDN and EDMN |
| US8952156B2 (en) | 2011-08-31 | 2015-02-10 | Basf Se | Process for working up reaction outputs from the hydrogenation of EDDN or EDMN |
| WO2013030255A1 (de) | 2011-08-31 | 2013-03-07 | Basf Se | Verfahren zur herstellung von eddn und/oder edmn sowie verfahren zur herstellung von deta und/oder teta |
| US8946459B2 (en) | 2011-08-31 | 2015-02-03 | Basf Se | Process for preparing EDDN and/or EDMN by reacting EDFA and/or EDMFA with HCN |
| JP2014527538A (ja) | 2011-08-31 | 2014-10-16 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Eddnおよび/またはedmnを製造する方法 |
| JP2014529617A (ja) | 2011-08-31 | 2014-11-13 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | Edfaおよび/またはedmfaおよびdetaおよび/またはtetaの製造方法 |
| CN105073712B (zh) | 2013-01-30 | 2017-09-22 | 巴斯夫欧洲公司 | 2,6‑双(氨基甲基)哌啶衍生物 |
| EP2961731B1 (de) | 2013-02-28 | 2017-02-01 | Basf Se | Verfahren zur herstellung von eda unter verwendung von so2-freier blausäure |
| WO2014131674A2 (en) | 2013-03-01 | 2014-09-04 | Basf Se | Amine composition |
| US9776175B2 (en) * | 2013-03-19 | 2017-10-03 | Korea Institute Of Energy Research | Iron-based catalyst and method for preparing the same and use thereof |
| CN108779060B (zh) | 2016-02-16 | 2022-01-28 | 英威达纺织(英国)有限公司 | 用于选择性腈加氢的促进剂 |
| US20190218341A1 (en) | 2016-09-19 | 2019-07-18 | Basf Se | Method for the preparation of polyamines from dinitriles and/or amino nitriles |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE848654C (de) | 1950-08-19 | 1952-09-08 | Basf Ag | Verfahren zur Herstellung von partiellen Hydrierungsprodukten des Adipinsaeuredinitrils |
| CA915707A (en) | 1969-07-11 | 1972-11-28 | Du Pont Of Canada Limited | Hydrogenation of adiponitrile |
| BE758035A (fr) * | 1969-10-29 | 1971-04-26 | Halcon International Inc | Procede de couplage par reduction de composes organiques halogenes |
| NL7408053A (nl) | 1973-09-12 | 1975-03-14 | Ici Ltd | Hydrogeneringskatalysator en werkwijze voor de bereiding daarvan. |
| US4064172A (en) | 1973-09-12 | 1977-12-20 | Imperial Chemical Industries Limited | Hexamethylene diamine by hydrogenation of adiponitrile in presence of an activated iron oxide catalyst |
| GB1486890A (en) | 1973-09-12 | 1977-09-28 | Ici Ltd | Catalysts and their use in hydrogenation |
| US4282381A (en) | 1980-08-21 | 1981-08-04 | E. I. Du Pont De Nemours And Company | Process for purifying hexamethylenediamine |
| JPH0820666B2 (ja) * | 1987-02-24 | 1996-03-04 | 旭光学工業株式会社 | フアインダ−装置 |
| DE4446893A1 (de) | 1994-12-27 | 1996-07-04 | Basf Ag | Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen |
| DE19533484A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| JP2001503026A (ja) | 1996-09-10 | 2001-03-06 | ビーエーエスエフ アクチェンゲゼルシャフト | 脂肪族α,ω―アミノニトリルの製造方法 |
| DE10151559A1 (de) * | 2001-10-23 | 2003-04-30 | Basf Ag | Als Katalysator geeignete Masse |
-
1998
- 1998-03-06 DE DE19809687A patent/DE19809687A1/de not_active Withdrawn
-
1999
- 1999-02-23 SI SI9930440T patent/SI1071653T1/xx unknown
- 1999-02-23 CN CNB998037192A patent/CN1185205C/zh not_active Ceased
- 1999-02-23 US US09/622,773 patent/US6297394B1/en not_active Expired - Lifetime
- 1999-02-23 CZ CZ20003237A patent/CZ294316B6/cs not_active IP Right Cessation
- 1999-02-23 ID IDW20001721A patent/ID25619A/id unknown
- 1999-02-23 KR KR1020007009834A patent/KR100553283B1/ko not_active Expired - Fee Related
- 1999-02-23 JP JP2000534529A patent/JP2002505192A/ja not_active Withdrawn
- 1999-02-23 BR BR9908505-4A patent/BR9908505A/pt not_active Application Discontinuation
- 1999-02-23 TR TR2000/02588T patent/TR200002588T2/xx unknown
- 1999-02-23 HU HU0101241A patent/HUP0101241A3/hu unknown
- 1999-02-23 UA UA2000105672A patent/UA66841C2/uk unknown
- 1999-02-23 CA CA002322185A patent/CA2322185C/en not_active Expired - Fee Related
- 1999-02-23 ES ES99908940T patent/ES2207184T3/es not_active Expired - Lifetime
- 1999-02-23 PT PT99908940T patent/PT1071653E/pt unknown
- 1999-02-23 AT AT99908940T patent/ATE247623T1/de not_active IP Right Cessation
- 1999-02-23 DE DE59906684T patent/DE59906684D1/de not_active Expired - Lifetime
- 1999-02-23 EP EP99908940A patent/EP1071653B1/de not_active Expired - Lifetime
- 1999-02-23 WO PCT/EP1999/001150 patent/WO1999044984A1/de not_active Ceased
- 1999-02-23 SK SK1238-2000A patent/SK12382000A3/sk unknown
- 1999-02-23 PL PL99342900A patent/PL342900A1/xx unknown
- 1999-02-23 EA EA200000894A patent/EA003285B1/ru not_active IP Right Cessation
- 1999-02-23 AU AU28356/99A patent/AU2835699A/en not_active Abandoned
- 1999-03-05 AR ARP990100943A patent/AR018146A1/es unknown
- 1999-03-05 MY MYPI99000815A patent/MY122207A/en unknown
- 1999-03-05 TW TW088103356A patent/TW518252B/zh not_active IP Right Cessation
-
2000
- 2000-09-05 NO NO20004424A patent/NO317588B1/no unknown
- 2000-09-18 BG BG104773A patent/BG64753B1/bg unknown
-
2001
- 2001-05-08 US US09/851,214 patent/US6852669B2/en not_active Expired - Fee Related
-
2004
- 2004-02-12 US US10/776,544 patent/US7091153B2/en not_active Expired - Fee Related
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