AT515486B1 - Verfahren - Google Patents

Verfahren Download PDF

Info

Publication number: AT515486B1
Authority: AT; Austria
Prior art keywords: catalyst; mixture; black liquor; feo; hydrogen donor
Prior art date: 2014-02-24

Application number

ATA50139/2014A

Other languages

German (de)

English (en)

Other versions

AT515486A1 (de

Inventor

Dipl Ing Dr Schwaiger Nikolaus

Dipl Ing Feiner Roland

Dipl Ing Pucher Hannes

Original Assignee

Technische Universität Graz

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2014-02-24

Filing date

2014-02-24

Publication date

2017-05-15

2014-02-24 Application filed by Technische Universität Graz filed Critical Technische Universität Graz

2014-02-24 Priority to ATA50139/2014A priority Critical patent/AT515486B1/de

2015-02-24 Priority to PCT/AT2015/050050 priority patent/WO2015123714A1/fr

2015-09-15 Publication of AT515486A1 publication Critical patent/AT515486A1/de

2017-05-15 Application granted granted Critical

2017-05-15 Publication of AT515486B1 publication Critical patent/AT515486B1/de

Links

238000000034 method Methods 0.000 title claims abstract description 58
239000003054 catalyst Substances 0.000 claims abstract description 28
239000000203 mixture Substances 0.000 claims abstract description 22
239000000852 hydrogen donor Substances 0.000 claims abstract description 18
238000002156 mixing Methods 0.000 claims abstract description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
238000010438 heat treatment Methods 0.000 claims abstract description 3
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetraline Natural products C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 claims description 29
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 14
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 12
229910052717 sulfur Inorganic materials 0.000 claims description 11
239000011593 sulfur Substances 0.000 claims description 11
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 8
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 4
XXPBFNVKTVJZKF-UHFFFAOYSA-N 9,10-dihydrophenanthrene Chemical class C1=CC=C2CCC3=CC=CC=C3C2=C1 XXPBFNVKTVJZKF-UHFFFAOYSA-N 0.000 claims description 4
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 claims description 4
235000019253 formic acid Nutrition 0.000 claims description 4
IEECXTSVVFWGSE-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Fe+3] IEECXTSVVFWGSE-UHFFFAOYSA-M 0.000 claims description 4
229910000462 iron(III) oxide hydroxide Inorganic materials 0.000 claims description 4
229910021519 iron(III) oxide-hydroxide Inorganic materials 0.000 claims description 4
WPCIUCNVWJNRCD-UHFFFAOYSA-N 4,5-dihydropyrene Chemical class C1=CC=C2CCC3=CC=CC4=CC=C1C2=C34 WPCIUCNVWJNRCD-UHFFFAOYSA-N 0.000 claims description 2
150000003839 salts Chemical class 0.000 claims description 2
125000005329 tetralinyl group Chemical group C1(CCCC2=CC=CC=C12)* 0.000 claims description 2
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
239000000463 material Substances 0.000 description 24
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 16
229910052799 carbon Inorganic materials 0.000 description 16
239000003575 carbonaceous material Substances 0.000 description 16
238000005984 hydrogenation reaction Methods 0.000 description 12
229910052739 hydrogen Inorganic materials 0.000 description 10
239000001257 hydrogen Substances 0.000 description 10
241000294754 Macroptilium atropurpureum Species 0.000 description 9
239000007787 solid Substances 0.000 description 9
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
229920002678 cellulose Polymers 0.000 description 8
239000001913 cellulose Substances 0.000 description 8
229920005610 lignin Polymers 0.000 description 8
238000004519 manufacturing process Methods 0.000 description 8
239000003245 coal Substances 0.000 description 7
239000007788 liquid Substances 0.000 description 7
150000001875 compounds Chemical class 0.000 description 6
229920005611 kraft lignin Polymers 0.000 description 6
239000007789 gas Substances 0.000 description 5
229930195733 hydrocarbon Natural products 0.000 description 5
150000002430 hydrocarbons Chemical class 0.000 description 5
239000002904 solvent Substances 0.000 description 5
239000000047 product Substances 0.000 description 4
239000007858 starting material Substances 0.000 description 4
239000002023 wood Substances 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
239000003921 oil Substances 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
238000005303 weighing Methods 0.000 description 3
239000004215 Carbon black (E152) Substances 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
229920002488 Hemicellulose Polymers 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001722 carbon compounds Chemical class 0.000 description 2
238000009826 distribution Methods 0.000 description 2
238000004880 explosion Methods 0.000 description 2
239000000446 fuel Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000000543 intermediate Substances 0.000 description 2
238000000197 pyrolysis Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003464 sulfur compounds Chemical class 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
239000002028 Biomass Substances 0.000 description 1
229910002588 FeOOH Inorganic materials 0.000 description 1
241001251054 Formica truncorum Species 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
INILCLIQNYSABH-UHFFFAOYSA-N cobalt;sulfanylidenemolybdenum Chemical compound [Mo].[Co]=S INILCLIQNYSABH-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000029087 digestion Effects 0.000 description 1
239000000386 donor Substances 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000000295 fuel oil Substances 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
239000003077 lignite Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
239000003863 metallic catalyst Substances 0.000 description 1
239000011368 organic material Substances 0.000 description 1
NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000002699 waste material Substances 0.000 description 1
229910006299 γ-FeOOH Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
- C10G1/086—Characterised by the catalyst used
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/42—Hydrogen of special source or of special composition

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

ATA50139/2014A 2014-02-24 2014-02-24 Verfahren AT515486B1 (de)

Priority Applications (2)

Application Number	Priority Date	Filing Date	Title
ATA50139/2014A AT515486B1 (de)	2014-02-24	2014-02-24	Verfahren
PCT/AT2015/050050 WO2015123714A1 (fr)	2014-02-24	2015-02-24	Procédé de liquéfaction d'une matière carbonée

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
ATA50139/2014A AT515486B1 (de)	2014-02-24	2014-02-24	Verfahren

Publications (2)

Publication Number	Publication Date
AT515486A1 AT515486A1 (de)	2015-09-15
AT515486B1 true AT515486B1 (de)	2017-05-15

Family

ID=52726910

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ATA50139/2014A AT515486B1 (de)	2014-02-24	2014-02-24	Verfahren

Country Status (2)

Country	Link
AT (1)	AT515486B1 (fr)
WO (1)	WO2015123714A1 (fr)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3611340A1 (de) *	1986-04-04	1987-10-08	Faix Oskar Dipl Holzw Dr	Verfahren zur erzeugung von niedrigviskosen, niedermolekularen, hexanloeslichen leicht- und mitteloelen durch katalytische druckhydrierung von lignocellulosischer biomasse

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4409089A (en) *	1980-08-14	1983-10-11	Mobil Oil Corporation	Coal liquefaction and resid processing with lignin
JPS59136135A (ja) *	1983-01-26	1984-08-04	Hokkaido Daigaku	石炭直接液化法
CN1240811C (zh)	2002-03-29	2006-02-08	华东理工大学	生物质快速裂解油的加氢处理方法
EP2348091B1 (fr) *	2010-01-12	2012-12-05	IFP Energies nouvelles	Procédé d'hydroliquéfaction directe de biomasse comprenant deux etapes d'hydroconversion en lit bouillonnant

2014
- 2014-02-24 AT ATA50139/2014A patent/AT515486B1/de not_active IP Right Cessation
2015
- 2015-02-24 WO PCT/AT2015/050050 patent/WO2015123714A1/fr not_active Ceased

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3611340A1 (de) *	1986-04-04	1987-10-08	Faix Oskar Dipl Holzw Dr	Verfahren zur erzeugung von niedrigviskosen, niedermolekularen, hexanloeslichen leicht- und mitteloelen durch katalytische druckhydrierung von lignocellulosischer biomasse

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Berl, E. et al., Coal Hydrogenation. Natural bituminous coal; artificial cellulose coal and its bitumen and residual portion. Industrial and Engineering Chemistry (1941), 33, 672-674. Columbus, Ohio, USA: Chemical Abstacts, Vol. 35, the abstract No. 26372. *
Huadong University of Science and Technology, Peop. Rep. China. Process for hydrogenation of rapidly cracked oil from biomass. Faming Zhuanli Shenqing, 5pp. Columbus, Ohio, USA: Chemical Abstacts, Vol. 140, 15 September 2003, the abstract No. 29308. *
Segimoto, Y. et al., Hydrous mild hydrolysis of cellulose and red pine. Hydrogenation of solid products. Segitan Kagaku Kaigi Happyo Ronbunshu (1994), 31st, 60-62. Columbus, Ohio, USA: Chemical Abstacts, Vol. 125, 16 August 1996, the abstract No. 486585. *

Also Published As

Publication number	Publication date
WO2015123714A1 (fr)	2015-08-27
AT515486A1 (de)	2015-09-15

Legal Events

Date	Code	Title	Description
2019-10-15	MM01	Lapse because of not paying annual fees	Effective date: 20190224

Publication	Publication Date	Title
EP2445990B1 (fr)	2026-03-04	Transformation thermochimique de biomasse
Breunig et al.	2018	Direct liquefaction of lignin and lignin rich biomasses by heterogenic catalytic hydrogenolysis
EP1489157B1 (fr)	2008-08-13	Procédé pour convertir de déchets et matières premières contenant de l'huile ou de la graisse en un mélange contenant des hydrocarbures
EP2445991B1 (fr)	2026-03-04	Procédé de bioraffinerie
WO2009037281A2 (fr)	2009-03-26	Procédé d'hydrogénolyse de lignine sur des carbures de métaux de transition
DE1768567A1 (de)	1971-11-18	Kohlehydrierverfahren
DE2613122A1 (de)	1976-10-14	Verfluessigung und entschwefelung von kohle unter verwendung von synthesegas
AT515486B1 (de)	2017-05-15	Verfahren
DE3045847A1 (de)	1982-07-22	Verfahren zur herstellung von hydrierten aromaten und deren verwendung
DE102014202803B4 (de)	2017-02-23	Verfahren zur Herstellung flüssiger und/oder fester Kohlenwasserstoffverbindungen
DE102013009885A1 (de)	2014-07-10	Verfahren zur Herstellung von Synthesegas aus Steinkohle
EP3636729B1 (fr)	2021-11-24	Procédé de fabrication de charbon à coke
CN108079995B (zh)	2021-04-06	一种组合催化剂及应用
EP3037503A1 (fr)	2016-06-29	Procédé de fabrication et d'utilisation d'un mélange d'hydrocarbures
DE2930032A1 (de)	1981-01-29	Verfahren zur herstellung von festen, fluessigen und gasfoermigen kohlenwasserstoffen durch katalytische hydrierung von kohlenwasserstoffhaltiger biomasse
DE1017724B (de)	1957-10-17	Verfahren zur hydrierenden Raffination von Kohlenwasserstoffen oder Kohlenwasserstofffraktionen mit Wasserstoff enthaltenden Gasen und in Gegenwart von schwefelfesten Katalysatoren
WO2012013735A1 (fr)	2012-02-02	Composition contenant un catalyseur et de la lignine, et utilisation de ladite composition pour la production d'une composition aromatique
WO2011138355A2 (fr)	2011-11-10	Procédé de production de cellulose et d'au moins une matière valorisable organique liquide ou liquéfiable avec recyclage des effluents gazeux
DE716470C (de)	1942-01-21	Verfahren zur Druckhydrierung von kohlenstoffhaltigen Stoffen
CN112745875B (zh)	2023-05-05	一种生物质热解油的加工方法
DE3013066C2 (de)	1982-10-14	Verfahren zum Inlösungbringen von Kohle oder Torf
DE303893C (de)	1919-12-04	Verfahren zur Herstellung von fl}ssigen organischen Verbindungen aus Steinkohle u. dgl.
DE102022133257A1 (de)	2024-06-20	Verfahren zur Herstellung von Synthesegas und Industrieruß aus aluminiumhaltigen Verbundverpackungen
DD281407A5 (de)	1990-08-08	Verfahren zur herstellung von pyrolysebriketts aus braunkohlen
DE1002903B (de)	1957-02-21	Verfahren zur Umwandlung von Kohlenwasserstoffen von Gasoeltyp in verhaeltnismaessig leichtere Kohlenwasserstoffprodukte