ATE405535T1 - Verfahren zur herstellung von phenol und methylethylketon - Google Patents

Verfahren zur herstellung von phenol und methylethylketon

Info

Publication number
ATE405535T1
ATE405535T1 AT05770053T AT05770053T ATE405535T1 AT E405535 T1 ATE405535 T1 AT E405535T1 AT 05770053 T AT05770053 T AT 05770053T AT 05770053 T AT05770053 T AT 05770053T AT E405535 T1 ATE405535 T1 AT E405535T1
Authority
AT
Austria
Prior art keywords
produce
producing phenol
butylbenzene
hydroperoxide
sec
Prior art date
Application number
AT05770053T
Other languages
English (en)
Inventor
Jane Cheng
John Buchanan
Doron Levin
Michael Steckel
Jihad Dakka
James Stokes
John Robbins
Jon Stanat
Charles Smith
Jose Santiesteban
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Application granted granted Critical
Publication of ATE405535T1 publication Critical patent/ATE405535T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C409/00—Peroxy compounds
    • C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
    • C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
    • C07C409/08—Compounds containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT05770053T 2004-08-13 2005-08-05 Verfahren zur herstellung von phenol und methylethylketon ATE405535T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60166104P 2004-08-13 2004-08-13

Publications (1)

Publication Number Publication Date
ATE405535T1 true ATE405535T1 (de) 2008-09-15

Family

ID=34956214

Family Applications (1)

Application Number Title Priority Date Filing Date
AT05770053T ATE405535T1 (de) 2004-08-13 2005-08-05 Verfahren zur herstellung von phenol und methylethylketon

Country Status (10)

Country Link
US (1) US7799956B2 (de)
EP (1) EP1778605B1 (de)
JP (1) JP5051898B2 (de)
KR (1) KR101116523B1 (de)
CN (1) CN101006033B (de)
AT (1) ATE405535T1 (de)
DE (1) DE602005009207D1 (de)
ES (1) ES2313385T3 (de)
TW (1) TWI376361B (de)
WO (1) WO2006015826A1 (de)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7829062B2 (en) 2006-02-14 2010-11-09 Exxonmobil Chemical Patent Inc. Method of preparing a molecular sieve composition
TW200744986A (en) * 2006-02-14 2007-12-16 Exxonmobil Chemical Patents Inc Process for producing phenol and methyl ethyl ketone
EP1984315A1 (de) * 2006-02-14 2008-10-29 Exxonmobil Chemical Patents Inc. Verfahren zur herstellung von phenol und methylethylketon
WO2007094938A1 (en) 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. An mcm-22 family molecular sieve composition
WO2007094937A1 (en) 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. A process for manufacturing mcm-22 family molecular sieves
WO2007093359A1 (en) * 2006-02-14 2007-08-23 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
TW200744985A (en) * 2006-02-14 2007-12-16 Exxonmobil Chemical Patents Inc Process for producing sec-butylbenzene
US7959899B2 (en) 2006-07-28 2011-06-14 Exxonmobil Chemical Patents Inc. Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions
US7417003B2 (en) 2006-12-29 2008-08-26 Uop Llc Solid acid catalyst and process for decomposition of cumene hydroperoxide
CA2675264C (en) * 2007-02-09 2013-04-02 Exxonmobil Chemical Patents Inc. Improved alkylaromatic production process
TW200846312A (en) * 2007-02-22 2008-12-01 Exxonmobil Chem Patents Inc Oxidation of sec-butylbenzene and production of phenol and methyl ethyl ketone
WO2008101616A1 (en) * 2007-02-22 2008-08-28 Exxonmobil Chemical Patents Inc. Production of alkylaromatic compounds
TW200904789A (en) 2007-04-19 2009-02-01 Exxonmobil Chem Patents Inc Process for oxidizing alkylaromatic compounds
US7692046B2 (en) 2007-06-21 2010-04-06 Exxonmobil Chemical Patents Inc. Heterogeneous arylalkyl oxidation promoter
US8470289B2 (en) 2007-07-16 2013-06-25 Exxonmobil Chemical Patents Inc. Manganese oxides and their use in the oxidation of alkanes
US7985883B2 (en) 2007-07-16 2011-07-26 Exxonmobil Chemical Patents Inc. Process for oxidizing alkylaromatic compounds
CN101784507A (zh) 2007-08-22 2010-07-21 埃克森美孚化学专利公司 仲丁基苯的制备方法
CN101687784B (zh) 2007-08-22 2014-11-12 埃克森美孚化学专利公司 烃的氧化
US8398955B2 (en) 2007-10-26 2013-03-19 Exxonmobil Chemical Patents Inc. Method of preparing a molecular sieve composition
EP2098498A1 (de) 2008-03-04 2009-09-09 ExxonMobil Chemical Patents Inc. Selektive Oligomerisierung von Isobuten
WO2009058531A1 (en) 2007-10-31 2009-05-07 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
KR101257988B1 (ko) 2007-10-31 2013-04-24 엑손모빌 케미칼 패턴츠 인코포레이티드 탄화수소의 산화
WO2009067331A2 (en) 2007-11-16 2009-05-28 Exxonmobil Chemical Patents Inc. Catalyst regeneration process
KR101123499B1 (ko) * 2008-02-12 2012-06-12 엑손모빌 케미칼 패턴츠 인코포레이티드 사이클로헥실벤젠의 제조방법
WO2010014404A1 (en) 2008-07-28 2010-02-04 Exxonmobil Chemical Patents Inc. Process of making alkylaromatics using emm-13
EP2334601B1 (de) 2008-07-28 2019-01-30 ExxonMobil Chemical Patents Inc. Herstellungsverfahren von alkylaromatischen verbindungen unter verwendung von molekularsiebzusammensetzung emm-12
CN102112397B (zh) 2008-07-28 2016-12-21 埃克森美孚化学专利公司 一种新型分子筛组合物emm‑12、其制备方法和使用方法
JP5548686B2 (ja) 2008-07-28 2014-07-16 エクソンモービル・ケミカル・パテンツ・インク 新規なモレキュラーシーブ組成物emm−13、その製造方法およびその使用プロセス
US20110092742A1 (en) * 2008-08-26 2011-04-21 Dakka Jihad M Process for Producing Alkylbenzene Hydroperoxides
US8440864B2 (en) * 2008-10-10 2013-05-14 Exxonmobil Chemical Patents Inc. Process for producing sec-butylbenzene
US8461397B2 (en) 2008-10-10 2013-06-11 Exxonmobil Chemical Patents Inc. Oxidation of hydrocarbons
US8445730B2 (en) 2008-10-10 2013-05-21 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2010042269A1 (en) 2008-10-10 2010-04-15 Exxonmobil Chemical Patents Inc. Process for producing phenol and methyl ethyl ketone
KR20110086162A (ko) 2008-12-15 2011-07-27 엑손모빌 케미칼 패턴츠 인코포레이티드 알킬방향족 화합물의 산화
US20100160704A1 (en) * 2008-12-19 2010-06-24 Robert Schmidt Alkylation of aromatics with high activity catalyst
EP2401248B1 (de) 2009-02-26 2016-04-20 ExxonMobil Chemical Patents Inc. Verfahren zur herstellung von phenol
CN106117099A (zh) 2009-08-28 2016-11-16 埃克森美孚化学专利公司 烃的氧化
US8518847B2 (en) * 2009-09-30 2013-08-27 Uop Llc Aromatic alkylation catalyst
WO2012145030A1 (en) 2011-04-19 2012-10-26 Exxonmobil Chemical Patents Inc. Process for producing phenol
WO2012036825A1 (en) 2010-09-14 2012-03-22 Exxonmobil Chemical Patents Inc. Oxidation of cyclohexylbenzene
WO2012036824A1 (en) 2010-09-14 2012-03-22 Exxonmobil Chemical Patents Inc. Oxidation of alkylbenzenes and cycloalkylbenzenes
US9388102B2 (en) 2011-04-19 2016-07-12 Exxonmobil Chemical Patents Inc. Process for producing phenol
CN103492072B (zh) * 2011-04-19 2016-01-20 埃克森美孚化学专利公司 苯酚的制备方法
WO2013052217A2 (en) 2011-10-07 2013-04-11 Exxonmobil Chemical Patents Inc. Mixed metal oxide catalysts and use thereof
CN103102240B (zh) * 2011-11-14 2015-02-25 中国石油化工股份有限公司 一种仲丁基苯的合成方法
CN102826980B (zh) * 2012-09-04 2014-10-15 华东理工大学 2,3-丁二醇气相脱水制备甲乙酮的方法
US9452965B2 (en) 2012-09-17 2016-09-27 Exxonmobil Chemical Patents Inc. Process for producing phenol and/or cyclohexanone from cyclohexylbenzene
US9272974B2 (en) 2012-09-17 2016-03-01 Exxonmobil Chemical Patents Inc. Process for producing phenol and/or cyclohexanone from cyclohexylbenzene
CN103739437B (zh) * 2012-10-17 2015-10-21 中国石油化工股份有限公司 用于混合碳四和苯生产非苯芳烃的方法
CN107922289B (zh) 2015-09-07 2021-01-26 沙特基础工业全球技术有限公司 使用混合烯烃流股作为烷基化剂生产枯烯和/或仲丁苯的方法
CN105251529B (zh) * 2015-11-25 2017-09-12 广东工业大学 一种负载型催化剂及其制备方法与催化长链烷基酚的合成方法
CN109180437A (zh) 2018-09-06 2019-01-11 常州大学 管式连续流反应器中过氧化氢异丙苯分解制备苯酚的方法
CN114057620B (zh) * 2020-08-04 2025-12-30 中国石油化工股份有限公司 环戊烯制备过氧化氢环戊基苯的方法和系统

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2584103A (en) * 1949-07-16 1952-02-05 Universal Oil Prod Co Alkylation of aromatic hydrocarbons
SU265349A1 (ru) 1968-08-03 1976-10-05 Институт Органической Химии Им.Н.Д. Зелинского Способ получени втор-бутилбензола
JPS4880524A (de) * 1972-01-10 1973-10-29
US3819735A (en) * 1972-02-04 1974-06-25 Union Carbide Corp Alkylation catalyst and process of alkylating benzene
SU417405A1 (ru) 1972-05-26 1974-02-28 Я. И. Исаков, М. Миначев, Я. Т. Эйдус, А. Л. Лапидус , В. П. Калинин Способ совместного получения этилбензола и вторичного бутилбензола
US4051191A (en) * 1977-01-03 1977-09-27 Uop Inc. Solid phosphoric acid catalyzed alkylation of aromatic hydrocarbons
SU1245564A1 (ru) 1982-06-24 1986-07-23 Ордена Трудового Красного Знамени Институт Нефтехимических Процессов Им.Ю.Г.Мамедалиева Способ получени вторичного бутилбензола
US4490566A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4490565A (en) * 1983-05-06 1984-12-25 Mobil Oil Corporation Production of phenol
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US4992606A (en) * 1988-10-06 1991-02-12 Mobil Oil Corp. Process for preparing short chain alkyl aromatic compounds
JP2797609B2 (ja) * 1989-04-25 1998-09-17 住友化学工業株式会社 sec―ブチルベンゼンの製造方法
CA2015191A1 (en) * 1989-04-25 1990-10-25 Kazuhiro Yamauchi Process for production of sec-butylbenzene
JP2884820B2 (ja) * 1990-09-10 1999-04-19 住友化学工業株式会社 sec−ブチルベンゼンの製造法
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5545788A (en) * 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
US5183945A (en) * 1991-11-18 1993-02-02 Exxon Research And Engineering Company Catalytic production of aryl alkyl hydroperoxides by manganese complexes
JP3225605B2 (ja) * 1992-07-14 2001-11-05 住友化学工業株式会社 フェノール及びメチルエチルケトンの製造方法
TW226011B (de) * 1991-12-26 1994-07-01 Sumitomo Chemical Co
JPH05229972A (ja) * 1991-12-26 1993-09-07 Sumitomo Chem Co Ltd フェノール及びメチルエチルケトンの製造方法
JP3089779B2 (ja) * 1991-12-26 2000-09-18 住友化学工業株式会社 フェノール及びメチルエチルケトンの製造方法
US5177283A (en) * 1992-02-03 1993-01-05 Uop Hydrocarbon conversion process
JPH06256238A (ja) * 1993-03-05 1994-09-13 Sumitomo Chem Co Ltd フェノール及びメチルエチルケトンの製造方法
JP3367056B2 (ja) * 1992-07-07 2003-01-14 住友化学工業株式会社 フェノール及びメチルエチルケトンの製造方法
US5362697A (en) * 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US5336820A (en) * 1993-08-11 1994-08-09 Mobil Oil Corporation Process for the alkylation of benzene-rich gasoline
WO1996004225A1 (fr) * 1994-08-03 1996-02-15 Asahi Kasei Kogyo Kabushiki Kaisha PROCEDE D'ALKYLATION EN PHASE LIQUIDE D'HYDROCARBURES AROMATIQUES AU MOYEN DE LA β-ZEOLITHE
US5504256A (en) * 1995-03-10 1996-04-02 Exxon Research And Engineering Company Catalytic production of aryl alkyl hydroperoxides by polynuclear transition metal aggregates (LAW229)
US6162416A (en) * 1996-07-12 2000-12-19 Uop Llc Zeolite beta and its use in aromatic alkylation
CN1105093C (zh) * 1996-08-20 2003-04-09 陶氏化学公司 制备烷基化苯的方法
WO1998009928A2 (en) * 1996-09-06 1998-03-12 Exxon Chemical Patents Inc. Alkylation process using zeolite beta
US6051521A (en) * 1998-08-25 2000-04-18 Mobil Oil Corporation Method of producing an aromatics alkylation catalyst
US6169215B1 (en) * 1999-03-25 2001-01-02 Mobil Oil Corporation Production of phenol
US6169216B1 (en) * 1999-04-22 2001-01-02 Mobil Oil Corporation Production of phenol
US6297406B1 (en) * 1999-08-03 2001-10-02 Mobil Oil Corporation Production of phenol
DE19946888A1 (de) 1999-09-30 2001-04-05 Phenolchemie Gmbh & Co Kg Verfahren zur Herstellung von Phenol, Aceton und Methylethylketon
US6410804B1 (en) * 1999-12-21 2002-06-25 Exxon Mobil Oil Corporation Production of phenol using reactive distillation
DE10015874A1 (de) * 2000-03-30 2001-10-11 Creavis Tech & Innovation Gmbh Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol
JP2002282698A (ja) 2001-03-29 2002-10-02 Mitsui Chemicals Inc 固体に担持したn−ヒドロキシフタルイミド触媒

Also Published As

Publication number Publication date
KR20070057173A (ko) 2007-06-04
WO2006015826A1 (en) 2006-02-16
US7799956B2 (en) 2010-09-21
EP1778605A1 (de) 2007-05-02
EP1778605B1 (de) 2008-08-20
KR101116523B1 (ko) 2012-02-28
DE602005009207D1 (de) 2008-10-02
CN101006033A (zh) 2007-07-25
JP5051898B2 (ja) 2012-10-17
JP2008509178A (ja) 2008-03-27
CN101006033B (zh) 2011-10-12
TW200619180A (en) 2006-06-16
TWI376361B (en) 2012-11-11
US20080086018A1 (en) 2008-04-10
ES2313385T3 (es) 2009-03-01

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