ATE448237T1 - Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben - Google Patents

Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben

Info

Publication number
ATE448237T1
ATE448237T1 AT02770191T AT02770191T ATE448237T1 AT E448237 T1 ATE448237 T1 AT E448237T1 AT 02770191 T AT02770191 T AT 02770191T AT 02770191 T AT02770191 T AT 02770191T AT E448237 T1 ATE448237 T1 AT E448237T1
Authority
AT
Austria
Prior art keywords
transition metal
same
metal complex
catalyst
polymerization
Prior art date
Application number
AT02770191T
Other languages
English (en)
Inventor
Hidenori Hanaoka
Eiji Yoshikawa
Yuka Imamoto
Original Assignee
Sumitomo Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2001279524A external-priority patent/JP3928394B2/ja
Priority claimed from JP2001337582A external-priority patent/JP3928408B2/ja
Priority claimed from JP2001337581A external-priority patent/JP3960011B2/ja
Priority claimed from JP2001354234A external-priority patent/JP3960018B2/ja
Priority claimed from JP2001366248A external-priority patent/JP3960027B2/ja
Priority claimed from JP2001368236A external-priority patent/JP3960028B2/ja
Application filed by Sumitomo Chemical Co filed Critical Sumitomo Chemical Co
Application granted granted Critical
Publication of ATE448237T1 publication Critical patent/ATE448237T1/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/45—Monoamines
    • C07C211/48—N-alkylated amines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/43—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton
    • C07C211/44—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring
    • C07C211/52—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/72—Hydrazones
    • C07C251/86—Hydrazones having doubly-bound carbon atoms of hydrazone groups bound to carbon atoms of six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/50—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton to carbon atoms of non-condensed six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/34—Monohydroxylic alcohols containing six-membered aromatic rings and other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/56—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds
    • C07C45/57—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom
    • C07C45/59—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds from heterocyclic compounds with oxygen as the only heteroatom in five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
    • C07C47/548—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings having unsaturation outside the six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/794—Ketones containing a keto group bound to a six-membered aromatic ring having unsaturation outside an aromatic ring
    • C07C49/798—Ketones containing a keto group bound to a six-membered aromatic ring having unsaturation outside an aromatic ring containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
    • C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
    • C07D317/10—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings
    • C07D317/14—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 not condensed with other rings with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D317/18—Radicals substituted by singly bound oxygen or sulfur atoms
    • C07D317/20—Free hydroxyl or mercaptan
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/06—Systems containing only non-condensed rings with a five-membered ring
    • C07C2601/10—Systems containing only non-condensed rings with a five-membered ring the ring being unsaturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
    • C07C2602/04—One of the condensed rings being a six-membered aromatic ring
    • C07C2602/08—One of the condensed rings being a six-membered aromatic ring the other ring being five-membered, e.g. indane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT02770191T 2001-09-14 2002-09-12 Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben ATE448237T1 (de)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP2001279524A JP3928394B2 (ja) 2001-09-14 2001-09-14 置換シクロペンタジエンおよびその製造方法
JP2001337582A JP3928408B2 (ja) 2001-11-02 2001-11-02 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
JP2001337581A JP3960011B2 (ja) 2001-11-02 2001-11-02 置換シクロペンタジエンおよびその製造方法
JP2001354234A JP3960018B2 (ja) 2001-11-20 2001-11-20 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
JP2001366248A JP3960027B2 (ja) 2001-11-30 2001-11-30 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
JP2001368236A JP3960028B2 (ja) 2001-12-03 2001-12-03 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
PCT/JP2002/009314 WO2003024983A1 (en) 2001-09-14 2002-09-12 Transition metal complex, catalyst for olefin polymerization, and process for producing olefin polymer with the same

Publications (1)

Publication Number Publication Date
ATE448237T1 true ATE448237T1 (de) 2009-11-15

Family

ID=27555000

Family Applications (1)

Application Number Title Priority Date Filing Date
AT02770191T ATE448237T1 (de) 2001-09-14 2002-09-12 Übergangsmetallkomplex, katalysator für die polymerisierung von olefinen und verfahren zur herstellung von olefinpolymeren unter anwendung desselben

Country Status (6)

Country Link
US (3) US7439379B2 (de)
EP (1) EP1426379B1 (de)
CN (1) CN100357303C (de)
AT (1) ATE448237T1 (de)
DE (1) DE60234353D1 (de)
WO (1) WO2003024983A1 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100789241B1 (ko) 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
KR100789242B1 (ko) 2005-07-08 2008-01-02 주식회사 엘지화학 전이금속 화합물, 이를 포함하는 촉매 조성물 및 이를이용한 올레핀 중합
WO2011142735A1 (en) 2010-05-13 2011-11-17 Chevron Phillips Chemical Company Lp Method and system for forming a precursor compound for non-bridged unsymmetric polyolefin polymerization catalyst
US8013177B2 (en) 2009-05-14 2011-09-06 Chevron Phillips Chemical Company Lp Method and system for forming a precursor compound for non-bridged unsymmetric polyolefin polymerization catalyst
WO2013161833A1 (ja) * 2012-04-26 2013-10-31 三井化学株式会社 オレフィン重合体の製造方法
EP2801578B1 (de) 2013-05-08 2017-01-04 Arlanxeo Netherlands B.V. Metallkomplex mit einem überbrückten Cyclopentadienylamidinligand
EP2801579B1 (de) * 2013-05-08 2016-10-19 Arlanxeo Netherlands B.V. Metall-Komplex mit einer Lewis-Base-Liganden
EP2816051B1 (de) * 2013-06-19 2015-11-04 Scg Chemicals Co. Ltd. Katalysator für die Olefinpolymerisation, Verfahren zur dessen Herstellung sowie dessen Verwendung
EP2902420B1 (de) * 2014-01-29 2019-06-12 Arlanxeo Netherlands B.V. Metallkomplex mit einem zyklischen amidinliganden
CN107417729A (zh) * 2017-08-15 2017-12-01 吉林大学 含苄胺基侧臂单茂金属铬(iv)配合物及其用途
CN111620914B (zh) * 2020-07-09 2021-03-19 吉林大学 含中性苄杂原子配位基侧臂单茂四价过渡金属配合物及其用途
CN114105814B (zh) * 2021-11-29 2024-02-02 万华化学集团股份有限公司 一种配体及其制备方法、烯烃聚合催化剂及其制备方法、应用

Family Cites Families (10)

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Publication number Priority date Publication date Assignee Title
US5621126A (en) 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5637660A (en) * 1995-04-17 1997-06-10 Lyondell Petrochemical Company Polymerization of α-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety
JP3378436B2 (ja) 1995-07-14 2003-02-17 住友化学工業株式会社 遷移金属錯体からなるオレフィン重合用触媒成分、該触媒成分を含有するオレフィン重合用触媒、およびオレフィン重合体の製造方法
KR100414757B1 (ko) * 1995-07-14 2004-06-04 스미또모 가가꾸 고오교오 가부시끼가이샤 전이금속착체,그것의제조방법,그전이금속착체를함유하는올레핀중합촉매,및올레핀중합체의제조방법
EP0852230B1 (de) * 1995-08-31 2001-12-05 Sumitomo Chemical Company Limited Übergangsmetallkomplexe, katalysatoren für die olefinpolymerisation und verfahren zur herstellung von olefinpolymeren
IT1298616B1 (it) * 1998-03-10 2000-01-12 Enichem Spa Complesso metallocenico pontato per la (co) polimerizzazione delle olefine
DE69916535T2 (de) * 1998-07-09 2005-05-12 Sumitomo Chemical Co. Ltd. Verfahren zur Herstellung eines Titankomplexes
SG99905A1 (en) * 2000-06-21 2003-11-27 Sumitomo Chemical Co Transition metal compound, catalyst for addition polymerization, and process for producing addition polymer
DE10057009A1 (de) * 2000-11-17 2002-05-29 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen

Also Published As

Publication number Publication date
US7732643B2 (en) 2010-06-08
EP1426379A1 (de) 2004-06-09
CN100357303C (zh) 2007-12-26
US7671226B2 (en) 2010-03-02
WO2003024983A1 (en) 2003-03-27
US20090054607A1 (en) 2009-02-26
US20040242410A1 (en) 2004-12-02
DE60234353D1 (de) 2009-12-24
CN1578783A (zh) 2005-02-09
EP1426379B1 (de) 2009-11-11
US20100048933A1 (en) 2010-02-25
US7439379B2 (en) 2008-10-21
EP1426379A4 (de) 2007-07-25

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