ATE464312T1 - Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen - Google Patents
Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinenInfo
- Publication number
- ATE464312T1 ATE464312T1 AT04803537T AT04803537T ATE464312T1 AT E464312 T1 ATE464312 T1 AT E464312T1 AT 04803537 T AT04803537 T AT 04803537T AT 04803537 T AT04803537 T AT 04803537T AT E464312 T1 ATE464312 T1 AT E464312T1
- Authority
- AT
- Austria
- Prior art keywords
- transition metal
- metal compound
- organometallic transition
- polyolefins
- biscyclopentadienylligand
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
- C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
- C07C13/547—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered
- C07C13/553—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings at least one ring not being six-membered, the other rings being at the most six-membered with an indacene or hydrogenated indacene ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/06—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members
- C07C2603/10—Ortho- or ortho- and peri-condensed systems containing three rings containing at least one ring with less than six ring members containing five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10358082A DE10358082A1 (de) | 2003-12-10 | 2003-12-10 | Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen |
| US54166804P | 2004-02-03 | 2004-02-03 | |
| PCT/EP2004/013827 WO2005058916A2 (en) | 2003-12-10 | 2004-12-06 | Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and preparation of polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE464312T1 true ATE464312T1 (de) | 2010-04-15 |
Family
ID=34672618
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT04803537T ATE464312T1 (de) | 2003-12-10 | 2004-12-06 | Organometallische übergangsmetallverbindung, biscyclopentadienylligandensystem, katalysatorsystem und herstellung von polyolefinen |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7452949B2 (de) |
| EP (1) | EP1692144B1 (de) |
| JP (1) | JP4823071B2 (de) |
| CN (1) | CN100473669C (de) |
| AT (1) | ATE464312T1 (de) |
| BR (1) | BRPI0417550B1 (de) |
| DE (1) | DE10358082A1 (de) |
| ES (1) | ES2341453T3 (de) |
| RU (1) | RU2362779C2 (de) |
| WO (1) | WO2005058916A2 (de) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| US8178636B2 (en) | 2004-05-04 | 2012-05-15 | Basell Polyolefine Gmbh | Process for the preparation of atactic 1-butene polymers |
| DE102004027332A1 (de) * | 2004-06-04 | 2005-12-22 | Basell Polyolefine Gmbh | Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen |
| DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
| PL1858907T3 (pl) * | 2005-03-18 | 2009-04-30 | Basell Polyolefine Gmbh | Metalocenowe związki |
| US7803887B2 (en) | 2005-03-18 | 2010-09-28 | Basell Polyolefine Gmbh | Metallocene compounds |
| WO2006100258A1 (en) * | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerization of olefins |
| AU2006226366A1 (en) * | 2005-03-23 | 2006-09-28 | Basell Polyolefine Gmbh | Process for the polymerizatio of olefins |
| EP1877453A1 (de) * | 2005-05-03 | 2008-01-16 | Basell Polyolefine GmbH | Verfahren zur polymerisation von alpha-olefinen |
| WO2006120177A2 (en) | 2005-05-11 | 2006-11-16 | Basell Poliolefine Itatia S.R.L. | Polymerization process for preparing polyolefin blends |
| KR20080024128A (ko) * | 2005-06-13 | 2008-03-17 | 바젤 폴리올레핀 게엠베하 | 프로필렌의 공중합 방법 |
| BRPI0617253A2 (pt) * | 2005-10-14 | 2016-04-19 | Basell Polyolefine Gmbh | sistemas catalisadores híbridos suportados sobre halogeneto de magnésio |
| ATE526337T1 (de) | 2006-03-17 | 2011-10-15 | Basell Polyolefine Gmbh | Metallocenverbindungen |
| WO2007116034A1 (en) * | 2006-04-12 | 2007-10-18 | Basell Polyolefine Gmbh | Metallocene compounds |
| US8785575B2 (en) * | 2006-04-21 | 2014-07-22 | Basell Polyolefine Gmbh | Process for the preparation of ethylene propylene copolymers |
| WO2007122098A1 (en) * | 2006-04-21 | 2007-11-01 | Basell Polyolefine Gmbh | Process for the preparation of ethylene copolymers |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| JP5461409B2 (ja) * | 2007-10-04 | 2014-04-02 | バーゼル・ポリオレフィン・ゲーエムベーハー | 触媒ペーストの製造法およびその生成物 |
| EP2203486B9 (de) * | 2007-10-25 | 2012-08-01 | Lummus Novolen Technology Gmbh | Racemoselektive synthese von ansa-metallocen-verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und -copolymere |
| JP5409294B2 (ja) * | 2008-12-17 | 2014-02-05 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| WO2011061151A1 (en) | 2009-11-17 | 2011-05-26 | Basell Polyolefine Gmbh | Ethylene copolymers |
| EP2402354B1 (de) | 2010-07-01 | 2016-03-02 | Borealis AG | Verfahren zur Polymerisierung von Olefinen unter Verwendung von Gruppe-4-Metallocenen als Katalisatoren |
| EP2402353B1 (de) | 2010-07-01 | 2018-04-25 | Borealis AG | Gruppe-4-Metallocene als Katalysatoren zur Olefinpolymerisation |
| JP5966321B2 (ja) * | 2010-11-19 | 2016-08-10 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| EP2573091A1 (de) | 2011-09-23 | 2013-03-27 | Lummus Novolen Technology Gmbh | Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen |
| JP5880000B2 (ja) * | 2011-12-14 | 2016-03-08 | 日本ポリプロ株式会社 | メタロセン錯体およびオレフィンの重合方法 |
| EP2676972A1 (de) | 2012-06-19 | 2013-12-25 | Basell Polyolefine GmbH | Verfahren zum Erhalt einer Polyolefinzusammensetzung |
| EP2722344B1 (de) | 2012-10-18 | 2017-03-22 | Borealis AG | Polymerisationsverfahren |
| EP2722346A1 (de) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisationsverfahren und Katalysator |
| ES2711081T3 (es) | 2012-10-18 | 2019-04-30 | Borealis Ag | Catalizador para la polimerización de olefinas |
| CN104755511B (zh) | 2012-10-31 | 2016-12-28 | 埃克森美孚化学专利公司 | 丙烯共聚物组合物及其制备方法 |
| WO2014096171A1 (en) | 2012-12-21 | 2014-06-26 | Borealis Ag | Catalyst |
| EP2746301B1 (de) | 2012-12-21 | 2018-05-30 | Borealis AG | Katalysator |
| EP2746289B1 (de) | 2012-12-21 | 2017-09-27 | Borealis AG | Katalysatoren |
| EP3022236B1 (de) | 2013-07-17 | 2017-11-15 | ExxonMobil Chemical Patents Inc. | Verfahren mit substituierten metallocenkatalysatoren und produkte daraus |
| JP2016531978A (ja) | 2013-07-17 | 2016-10-13 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 置換メタロセン触媒 |
| EP3022235B1 (de) | 2013-07-17 | 2020-04-08 | ExxonMobil Chemical Patents Inc. | Metallocene und katalysatorzusammensetzungen daraus |
| EP3022233B1 (de) | 2013-07-17 | 2019-05-01 | ExxonMobil Chemical Patents Inc. | Cyclopropyl-substituierte metallocenkatalysatoren |
| US9938364B2 (en) | 2013-07-17 | 2018-04-10 | Exxonmobil Chemical Patents Inc. | Substituted metallocene catalysts |
| WO2015009472A1 (en) | 2013-07-17 | 2015-01-22 | Exxonmobil Chemcal Patents Inc. | Metallocenes and catalyst compositions derived therefrom |
| CN103980395B (zh) * | 2014-04-30 | 2016-08-24 | 中国科学院化学研究所 | 一种可用于3d打印的超高分子量无规聚丙烯树脂及其制备方法和应用 |
| KR101580591B1 (ko) | 2014-06-10 | 2015-12-28 | 주식회사 엘지화학 | 프로필렌계 엘라스토머 |
| EP2995629B1 (de) | 2014-09-12 | 2018-03-07 | Borealis AG | Verfahren zur Herstellung von Propylencopolymeren in Gasphase |
| KR20170068474A (ko) | 2014-09-12 | 2017-06-19 | 보레알리스 아게 | 프로필렌의 코폴리머의 제조 공정 |
| EP3225610B1 (de) * | 2014-11-26 | 2021-09-29 | Sumitomo Chemical Company, Limited | Verfahren zur herstellung von polymeren mittels kupplungsreaktionen |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| EP3303422B1 (de) | 2015-06-05 | 2021-03-17 | ExxonMobil Chemical Patents Inc. | Herstellung von heterophasischen polymeren in gas- oder schlämmephase |
| US10759886B2 (en) | 2015-06-05 | 2020-09-01 | Exxonmobil Chemical Patents Inc. | Single reactor production of polymers in gas or slurry phase |
| WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US9803037B1 (en) * | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
| US11059918B2 (en) | 2016-05-27 | 2021-07-13 | Exxonmobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
| KR101846412B1 (ko) | 2016-12-06 | 2018-05-18 | 한화케미칼 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
| JP7130649B2 (ja) | 2016-12-29 | 2022-09-05 | ボレアリス エージー | 触媒 |
| JP6984128B2 (ja) * | 2016-12-29 | 2021-12-17 | 日本ポリエチレン株式会社 | ポリエチレン樹脂の製造方法並びに当該方法により製造されたポリエチレン樹脂を用いた太陽電池封止材および太陽電池モジュール |
| KR102065719B1 (ko) | 2017-01-25 | 2020-01-13 | 주식회사 엘지화학 | 혼성 담지 촉매 |
| WO2019072695A1 (en) | 2017-10-11 | 2019-04-18 | Basell Polyolefine Gmbh | CATALYST SUPPORTED SYSTEM |
| US11001657B2 (en) | 2017-10-25 | 2021-05-11 | Exxonmobil Chemical Patents Inc. | Unbridged indacenyl metallocenes |
| US11214631B2 (en) * | 2017-11-14 | 2022-01-04 | Exxonmobil Chemical Patents Inc. | (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight |
| WO2019099250A1 (en) * | 2017-11-14 | 2019-05-23 | Exxonmobil Chemical Patents Inc. | (di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight |
| US11130827B2 (en) | 2017-11-14 | 2021-09-28 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and articles made therefrom |
| KR102530448B1 (ko) | 2019-03-13 | 2023-05-08 | 주식회사 엘지화학 | 전이 금속 화합물 및 이를 포함하는 촉매 조성물 |
| JP7278653B2 (ja) * | 2019-06-11 | 2023-05-22 | エルジー・ケム・リミテッド | プロピレン－エチレンランダム共重合体 |
| KR102524952B1 (ko) * | 2019-06-13 | 2023-04-24 | 주식회사 엘지화학 | 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법 |
| WO2020251265A1 (ko) | 2019-06-13 | 2020-12-17 | 주식회사 엘지화학 | 혼성 담지 메탈로센 촉매 및 이를 이용한 폴리프로필렌의 제조 방법 |
| WO2021034459A1 (en) | 2019-08-22 | 2021-02-25 | Exxonmobil Chemical Patents Inc. | Isotactic propylene homopolymers and copolymers produced with c1 symmetric metallocene catalysts |
| US11472828B2 (en) | 2019-10-11 | 2022-10-18 | Exxonmobil Chemical Patents Inc. | Indacene based metallocene catalysts useful in the production of propylene polymers |
| EP4043470B1 (de) * | 2020-07-16 | 2024-11-06 | Lg Chem, Ltd. | Übergangsmetallverbindung und katalysatorzusammensetzung damit |
| US20230416418A1 (en) | 2020-11-23 | 2023-12-28 | Exxonmobil Chemical Patents Inc. | Metallocene polypropylene prepared using aromatic solvent-free supports |
| US20250002617A1 (en) | 2021-09-02 | 2025-01-02 | ExxonMobil Technology and Engineering Company | C1 symmetric metallocene catalysts tailored for production of vinyl-terminated polypropylene oligomers and macromonomers |
| CN115160470B (zh) * | 2022-07-18 | 2023-06-30 | 宁夏清研高分子新材料有限公司 | 一种tpx聚合物的制备方法、催化剂及其制备方法 |
| CN121843955A (zh) | 2023-07-14 | 2026-04-10 | 北欧化工有限责任公司 | 用于烯烃聚合的催化剂 |
| WO2025051400A1 (en) | 2023-09-07 | 2025-03-13 | Borealis Ag | Methods of producing metallocene catalyst components |
| WO2025016568A1 (en) | 2023-07-14 | 2025-01-23 | Borealis Ag | Metallocenes for the manufacture of polypropylene |
| CN121532401A (zh) | 2023-07-14 | 2026-02-13 | 北欧化工有限责任公司 | 用于制造聚丙烯的茂金属 |
| EP4743473A1 (de) | 2023-07-14 | 2026-05-20 | Borealis Gmbh | Katalysatoren für die olefinpolymerisation |
| WO2026041323A1 (en) | 2024-08-19 | 2026-02-26 | Basell Poliolefine Italia S.R.L. | Polypropylene composition having good thermal and optical properties |
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| CA2193882C (en) | 1994-06-24 | 2005-07-26 | Anthony Nicholas Speca | Polymerization catalyst systems, their production and use |
| EP0728773B1 (de) | 1995-02-21 | 1998-11-04 | Mitsubishi Chemical Corporation | Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren |
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| KR100405780B1 (ko) | 1996-04-22 | 2004-03-30 | 닛뽕폴리올레핀가부시키가이샤 | 폴리올레핀제조용촉매및폴리올레핀의제조방법 |
| JPH10265588A (ja) * | 1997-01-24 | 1998-10-06 | Mitsui Chem Inc | オレフィン系共重合体製収縮フィルム |
| US5789634A (en) | 1997-02-05 | 1998-08-04 | Boulder Scientific Company | Coupling reactions of 2-substituted, 7-haloindenes with aryl substituents to produce metallocene catalyst intermediates |
| US6492539B1 (en) | 1997-03-07 | 2002-12-10 | Basell Polypropylen Gmbh | Preparation of preparing substituted indanones |
| AU7332398A (en) | 1997-03-07 | 1998-09-29 | Targor Gmbh | Method for producing olefin polymers with a higher melting point |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| EP2192151A1 (de) * | 1997-08-19 | 2010-06-02 | Idemitsu Kosan Co., Ltd. | Nukleierte Propylenpolymerzusammensetzungen und Filme daraus |
| DE19808253A1 (de) * | 1998-02-27 | 1999-09-02 | Aventis Res & Tech Gmbh & Co | Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen |
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| DE19816154A1 (de) * | 1998-04-09 | 1999-10-21 | Bernhard Rieger | Lineare isotaktische Polymere, Verfahren zu ihrer Herstellung und deren Verwendung sowie eine Katalysatorkombination |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| BR9906934B1 (pt) | 1998-11-25 | 2010-08-24 | composto, catalisador, processo para preparar uma poliolefina, e, uso de um catalisador. | |
| CN1590422A (zh) | 1999-12-23 | 2005-03-09 | 巴塞尔聚烯烃有限公司 | 过渡金属化合物，配体体系，催化剂体系及其在烯烃的聚合反应和共聚反应中的用途 |
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-
2003
- 2003-12-10 DE DE10358082A patent/DE10358082A1/de not_active Withdrawn
-
2004
- 2004-12-06 EP EP04803537A patent/EP1692144B1/de not_active Revoked
- 2004-12-06 WO PCT/EP2004/013827 patent/WO2005058916A2/en not_active Ceased
- 2004-12-06 JP JP2006543449A patent/JP4823071B2/ja not_active Expired - Lifetime
- 2004-12-06 ES ES04803537T patent/ES2341453T3/es not_active Expired - Lifetime
- 2004-12-06 RU RU2006124537/04A patent/RU2362779C2/ru active
- 2004-12-06 US US10/581,985 patent/US7452949B2/en not_active Expired - Lifetime
- 2004-12-06 BR BRPI0417550A patent/BRPI0417550B1/pt not_active IP Right Cessation
- 2004-12-06 CN CNB2004800363141A patent/CN100473669C/zh not_active Expired - Fee Related
- 2004-12-06 AT AT04803537T patent/ATE464312T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2341453T3 (es) | 2010-06-21 |
| JP2007513906A (ja) | 2007-05-31 |
| RU2362779C2 (ru) | 2009-07-27 |
| CN1890272A (zh) | 2007-01-03 |
| US20070155919A1 (en) | 2007-07-05 |
| WO2005058916A2 (en) | 2005-06-30 |
| BRPI0417550B1 (pt) | 2015-10-27 |
| RU2006124537A (ru) | 2008-01-20 |
| JP4823071B2 (ja) | 2011-11-24 |
| CN100473669C (zh) | 2009-04-01 |
| EP1692144B1 (de) | 2010-04-14 |
| DE10358082A1 (de) | 2005-07-14 |
| EP1692144A2 (de) | 2006-08-23 |
| WO2005058916A3 (en) | 2005-11-03 |
| US7452949B2 (en) | 2008-11-18 |
| BRPI0417550A (pt) | 2007-03-27 |
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