ATE461943T1 - Polymerlatex mit hervorragender schlagzähigkeit und hervorragendem pulverfliessverhalten und herstellungsverfahren dafür - Google Patents
Polymerlatex mit hervorragender schlagzähigkeit und hervorragendem pulverfliessverhalten und herstellungsverfahren dafürInfo
- Publication number
- ATE461943T1 ATE461943T1 AT04808617T AT04808617T ATE461943T1 AT E461943 T1 ATE461943 T1 AT E461943T1 AT 04808617 T AT04808617 T AT 04808617T AT 04808617 T AT04808617 T AT 04808617T AT E461943 T1 ATE461943 T1 AT E461943T1
- Authority
- AT
- Austria
- Prior art keywords
- polymer latex
- impact resistance
- unit
- seed
- production process
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2989—Microcapsule with solid core [includes liposome]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR20030100081 | 2003-12-30 | ||
| PCT/KR2004/003488 WO2005063826A1 (en) | 2003-12-30 | 2004-12-29 | Polymer latex having excellent impact-resistance and powder flow property and method for preparing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE461943T1 true ATE461943T1 (de) | 2010-04-15 |
Family
ID=36808422
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT04808617T ATE461943T1 (de) | 2003-12-30 | 2004-12-29 | Polymerlatex mit hervorragender schlagzähigkeit und hervorragendem pulverfliessverhalten und herstellungsverfahren dafür |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8048524B2 (de) |
| EP (1) | EP1699828B1 (de) |
| JP (1) | JP4625021B2 (de) |
| KR (1) | KR100789108B1 (de) |
| CN (1) | CN100469796C (de) |
| AT (1) | ATE461943T1 (de) |
| DE (1) | DE602004026219D1 (de) |
| WO (1) | WO2005063826A1 (de) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060235131A1 (en) * | 2005-04-15 | 2006-10-19 | Hughes Kathleen A | Process for preparing aqueous dispersions of multistage emulsion polymers |
| KR100708986B1 (ko) * | 2005-05-16 | 2007-04-18 | 주식회사 엘지화학 | 다층구조의 그라프트 공중합체 및 그 제조방법 |
| KR100832356B1 (ko) * | 2005-10-25 | 2008-05-26 | 주식회사 엘지화학 | 아크릴계 공중합체와 그 제조방법, 및 이를 이용한 수지조성물 |
| EP1992664B1 (de) * | 2006-02-16 | 2013-08-28 | Kaneka Corporation | Thermoplastische harzzusammensetzung |
| KR100815995B1 (ko) * | 2006-06-08 | 2008-03-21 | 제일모직주식회사 | 저온 및 상온 내충격성과 착색성 및 내후성이 우수한asa 그라프트 공중합체 및 이를 포함한 열가소성 수지조성물 |
| KR100871318B1 (ko) * | 2007-05-29 | 2008-12-01 | 이봉규 | 콘크리트 개질제용 카르복실레이트 스티렌 부타디엔합성라텍스의 제조방법 |
| EP2042530A1 (de) * | 2007-09-26 | 2009-04-01 | Eliokem | Kautschukartiges Polymer mit niedrigem Druckverformungsrest |
| KR101691567B1 (ko) * | 2008-02-08 | 2016-12-30 | 라인 케미 라이나우 게엠베하 | 가수 분해 저항성인 폴리아마이드-엘라스토머 혼합물과, 이로부터 제조된 성형품 및 이들의 용도 |
| KR100943961B1 (ko) * | 2008-05-16 | 2010-02-26 | 제일모직주식회사 | 내후성 열가소성 수지 조성물 |
| KR101268660B1 (ko) * | 2009-09-22 | 2013-05-29 | 주식회사 엘지화학 | 분무 건조 방식을 이용한 열가소성 폴리에스테르 수지용 충격 보강제의 제조방법, 이로부터 제조된 충격 보강제 및 이를 포함하는 열가소성 폴리에스테르 수지 조성물 |
| BR112013027682B1 (pt) * | 2011-08-23 | 2020-10-27 | Rohm And Haas Company | composição de polímero em multi-estágio, película e placa polarizadora |
| KR101620665B1 (ko) | 2013-04-26 | 2016-05-23 | 제일모직주식회사 | 열가소성 수지 조성물 및 이를 포함하는 성형품 |
| CN103421265B (zh) * | 2013-04-26 | 2014-12-10 | 彭朕财 | 透明pmma增韧剂 |
| WO2014204071A1 (ko) * | 2013-06-19 | 2014-12-24 | 주식회사 엘지화학 | 다층 코어-쉘 구조의 고무질 중합체 라텍스, 이의 제조방법 및 이를 포함하는 아크릴로니트릴-부타디엔-스티렌 그라프트 공중합체 |
| IN2014DN06810A (de) * | 2013-06-19 | 2015-05-22 | Lg Chemical Ltd | |
| CA2945996C (en) * | 2014-04-16 | 2022-07-19 | Arkema Inc. | Use of high rubber impact modifiers in thermoplastic formulations |
| KR101666273B1 (ko) * | 2014-06-13 | 2016-10-24 | 주식회사 엘지화학 | 스티렌-부타디엔계 라텍스 및 그 제조방법 |
| EP3194160B1 (de) * | 2014-08-22 | 2020-04-15 | Arkema, Inc. | Verfahren zur herstellung von leeren latexpartikeln |
| BR112017003443B1 (pt) | 2014-08-22 | 2021-10-13 | Arkema Inc | Processo para formar partículas de látex com espaço vazio |
| CN104448112B (zh) * | 2014-11-11 | 2016-06-08 | 河北工业大学 | 尼龙6低温增韧改性用功能化聚丙烯酸酯复合乳液的制备方法 |
| KR101957854B1 (ko) * | 2015-05-13 | 2019-03-14 | 주식회사 엘지화학 | 아크릴계 가공조제 및 이를 포함하는 염화비닐계 수지 조성물 |
| US20180223026A1 (en) * | 2015-07-31 | 2018-08-09 | Rohm And Haas Company | Oligomer seed for synthesis of unimodal acrylic bead particles |
| GB201609160D0 (en) * | 2016-05-25 | 2016-07-06 | Croda Europ Ltd | Polymeric coating compositions |
| KR102049890B1 (ko) * | 2016-11-01 | 2019-11-28 | 주식회사 엘지화학 | 충격강도가 향상된 abs계 그라프트 공중합체의 제조방법 및 이를 포함하는 abs계 사출성형품의 제조방법 |
| KR102044364B1 (ko) | 2016-11-11 | 2019-11-13 | 주식회사 엘지화학 | 열가소성 수지 및 열가소성 수지 조성물 |
| WO2018088677A1 (ko) * | 2016-11-11 | 2018-05-17 | (주) 엘지화학 | 열가소성 수지 및 열가소성 수지 조성물 |
| KR102280689B1 (ko) * | 2017-07-28 | 2021-07-22 | 주식회사 엘지화학 | 코어-쉘 공중합체, 이의 제조방법 및 이를 포함하는 열가소성 수지 조성물 |
| KR101988293B1 (ko) * | 2017-12-22 | 2019-06-12 | 금호석유화학 주식회사 | 고무질 중합체 라텍스의 제조방법 |
| JP7263077B2 (ja) * | 2019-03-27 | 2023-04-24 | 株式会社カネカ | 塩化ビニル系樹脂組成物用流動性改良剤、塩化ビニル系樹脂組成物および塩化ビニル系樹脂成形体 |
| US12398263B2 (en) | 2019-11-25 | 2025-08-26 | Lg Chem, Ltd. | Graft copolymer and method for preparing same |
| CN112876623B (zh) * | 2021-01-18 | 2023-04-07 | 万华化学(四川)有限公司 | 一种abs接枝胶乳的制备方法及制备的abs树脂 |
| CN114805693A (zh) * | 2022-04-01 | 2022-07-29 | 威海金合思化工有限公司 | 一种高流动性丙烯酸酯类增韧剂及其合成方法 |
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| JPS5023067B1 (de) * | 1970-07-17 | 1975-08-05 | ||
| JPS4940635B1 (de) * | 1970-12-26 | 1974-11-02 | ||
| JPS5230996B2 (de) * | 1972-05-15 | 1977-08-11 | ||
| JPS5023067A (de) | 1973-06-29 | 1975-03-12 | ||
| GB1541569A (en) * | 1975-10-22 | 1979-03-07 | Ici Ltd | Treament of a liquid by circulation and gas contacting |
| US4278576A (en) | 1978-12-05 | 1981-07-14 | Rohm And Haas Company | Isolation and improvement of impact modifier polymer powders |
| DE3006804A1 (de) * | 1980-02-23 | 1981-09-10 | Bayer Ag, 5090 Leverkusen | Kerbschlagzaehe polymerisate mit verbesserter witterungsbestaendigkeit |
| JPS592704B2 (ja) * | 1980-10-23 | 1984-01-20 | 呉羽化学工業株式会社 | 塩化ビニル系樹脂組成物 |
| CA1261094A (en) * | 1983-09-14 | 1989-09-26 | Surendra H. Agarwal | Flexible thermoplastic polyester compositions |
| JPS61211A (ja) * | 1984-06-13 | 1986-01-06 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂の製造方法 |
| JPS62236850A (ja) * | 1986-04-08 | 1987-10-16 | Takeda Chem Ind Ltd | ポリカ−ボネ−ト樹脂組成物 |
| JP2980735B2 (ja) * | 1990-05-11 | 1999-11-22 | 武田薬品工業株式会社 | 多層構造重合体、これを含む熱可塑性樹脂組成物及びその成形品 |
| DE4223202A1 (de) * | 1992-07-15 | 1994-01-20 | Basf Ag | Teilchenförmiges Pfropfcopolymerisat |
| JP3260486B2 (ja) * | 1993-06-18 | 2002-02-25 | 鐘淵化学工業株式会社 | 耐ブロッキング性の改良された合成樹脂粉末を製造する方法 |
| JP2501015B2 (ja) * | 1993-12-06 | 1996-05-29 | 三菱レイヨン株式会社 | 耐衝撃性、耐候性、熱可塑性樹脂組成物 |
| KR0160333B1 (ko) | 1994-10-24 | 1999-01-15 | 박원배 | 투명성 및 가공성이 우수한 사출성형용 아크릴계 충격보강제의 제조방법 |
| JP3212471B2 (ja) * | 1995-02-21 | 2001-09-25 | 積水化学工業株式会社 | 塩化ビニル系樹脂 |
| EP0745622A1 (de) * | 1995-05-24 | 1996-12-04 | Imperial Chemical Industries Plc | Schlagfeste (Meth)acrylpolymere |
| KR100380551B1 (ko) | 1996-02-02 | 2003-07-18 | 주식회사 엘지화학 | 라텍스입자파우더를 이용한 진공단열재의 제조방법 |
| JPH11140140A (ja) * | 1997-09-02 | 1999-05-25 | Sekisui Chem Co Ltd | 塩化ビニル系グラフト樹脂の製造方法及び塩化ビニル系グラフト樹脂組成物 |
| KR19990060688A (ko) * | 1997-12-31 | 1999-07-26 | 김충세 | 내후성 및 내충격성이 향상된 아크릴계 충격보강제의 제조방법 |
| US6130290A (en) | 1998-04-29 | 2000-10-10 | Rohm And Haas Company | Impact modifier for amorphous aromatic polyester |
| DE69943227D1 (de) | 1998-09-09 | 2011-04-07 | Rohm & Haas | Ein Verfahren zur Herstellung einer Kernschalen-schlagmodifizierten Emulsion |
| JP2000344841A (ja) * | 1999-06-04 | 2000-12-12 | Mitsubishi Rayon Co Ltd | グラフト共重合体とその製造方法並びに樹脂組成物 |
| TWI231305B (en) | 2000-10-25 | 2005-04-21 | Rohm & Haas | High rubber impact modifier powders |
| KR100601088B1 (ko) * | 2003-01-03 | 2006-07-14 | 주식회사 엘지화학 | 우수한 분말 흐름성을 갖는 고 고무성 충격보강제와 이의 제조방법 및 이를 포함하는 염화비닐수지 |
| KR100727235B1 (ko) | 2005-04-01 | 2007-06-11 | 주식회사 엘지화학 | 아크릴계 충격보강제 및 그 제조방법 |
-
2004
- 2004-12-29 JP JP2006546839A patent/JP4625021B2/ja not_active Expired - Fee Related
- 2004-12-29 EP EP04808617A patent/EP1699828B1/de not_active Expired - Lifetime
- 2004-12-29 AT AT04808617T patent/ATE461943T1/de not_active IP Right Cessation
- 2004-12-29 WO PCT/KR2004/003488 patent/WO2005063826A1/en not_active Ceased
- 2004-12-29 KR KR1020040114900A patent/KR100789108B1/ko not_active Expired - Fee Related
- 2004-12-29 US US11/023,502 patent/US8048524B2/en not_active Expired - Lifetime
- 2004-12-29 DE DE602004026219T patent/DE602004026219D1/de not_active Expired - Lifetime
- 2004-12-29 CN CNB2004800396605A patent/CN100469796C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US8048524B2 (en) | 2011-11-01 |
| KR100789108B1 (ko) | 2007-12-26 |
| EP1699828A1 (de) | 2006-09-13 |
| CN1902233A (zh) | 2007-01-24 |
| EP1699828B1 (de) | 2010-03-24 |
| WO2005063826A1 (en) | 2005-07-14 |
| DE602004026219D1 (de) | 2010-05-06 |
| JP2007517105A (ja) | 2007-06-28 |
| JP4625021B2 (ja) | 2011-02-02 |
| EP1699828A4 (de) | 2008-07-02 |
| US20050203247A1 (en) | 2005-09-15 |
| KR20050069908A (ko) | 2005-07-05 |
| CN100469796C (zh) | 2009-03-18 |
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