ATE462731T1 - Katalysatorzusammensetzung zur olefinpolymerisierung - Google Patents

Katalysatorzusammensetzung zur olefinpolymerisierung

Info

Publication number
ATE462731T1
ATE462731T1 AT06758705T AT06758705T ATE462731T1 AT E462731 T1 ATE462731 T1 AT E462731T1 AT 06758705 T AT06758705 T AT 06758705T AT 06758705 T AT06758705 T AT 06758705T AT E462731 T1 ATE462731 T1 AT E462731T1
Authority
AT
Austria
Prior art keywords
olefin polymerization
catalyst composition
combining
catalyst system
intermediate composition
Prior art date
Application number
AT06758705T
Other languages
English (en)
Inventor
Thorsten Sell
Joerg Schottek
Nicola Stefanie Paczkowski
Andreas Winter
Original Assignee
Novolen Tech Holdings Cv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novolen Tech Holdings Cv filed Critical Novolen Tech Holdings Cv
Application granted granted Critical
Publication of ATE462731T1 publication Critical patent/ATE462731T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AT06758705T 2005-05-17 2006-04-27 Katalysatorzusammensetzung zur olefinpolymerisierung ATE462731T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/130,925 US7232869B2 (en) 2005-05-17 2005-05-17 Catalyst composition for olefin polymerization
PCT/US2006/016114 WO2006124231A1 (en) 2005-05-17 2006-04-27 Catalyst composition for olefin polymerization

Publications (1)

Publication Number Publication Date
ATE462731T1 true ATE462731T1 (de) 2010-04-15

Family

ID=36829739

Family Applications (1)

Application Number Title Priority Date Filing Date
AT06758705T ATE462731T1 (de) 2005-05-17 2006-04-27 Katalysatorzusammensetzung zur olefinpolymerisierung

Country Status (11)

Country Link
US (2) US7232869B2 (de)
EP (1) EP1882000B1 (de)
JP (1) JP2008545821A (de)
KR (1) KR101190758B1 (de)
CN (1) CN101384624B (de)
AT (1) ATE462731T1 (de)
BR (1) BRPI0610163A2 (de)
DE (1) DE602006013300D1 (de)
ES (1) ES2342106T3 (de)
TW (1) TW200710110A (de)
WO (1) WO2006124231A1 (de)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
PT2099832T (pt) 2006-12-14 2019-06-27 Grace W R & Co Ativadores de catalisador, processos para preparação dos mesmos, e sua utilização em catalisadores e polimerização de olefinas
JP5598856B2 (ja) * 2007-10-25 2014-10-01 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー
EP2203486B9 (de) * 2007-10-25 2012-08-01 Lummus Novolen Technology Gmbh Racemoselektive synthese von ansa-metallocen-verbindungen, ansa-metallocen-verbindungen, diese enthaltende katalysatoren, verfahren zur herstellung eines olefinpolymers durch verwendung der katalysatoren und olefinhomopolymere und -copolymere
EP2172493A1 (de) 2008-10-02 2010-04-07 Total Petrochemicals Research Feluy Aktivierungsträger auf Basis von perfluorierten Borsäuren
JP2012513463A (ja) * 2008-12-31 2012-06-14 ルムス・ノボレン・テクノロジー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 新たなメタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー
WO2012055797A1 (en) 2010-10-28 2012-05-03 Lummus Novolen Technology Gmbh Nonwoven and yarn polypropylene with additivation
WO2012071205A2 (en) * 2010-11-22 2012-05-31 Albemarle Corporation Activator compositions, their preparation, and their use in catalysis
EP2573091A1 (de) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen
US9260538B2 (en) * 2012-02-08 2016-02-16 Reliance Industries Limited Immobilization of single site catalyst on inorganic oxide support for preparation of UHMWPE
EP2824107B1 (de) 2012-05-08 2017-01-18 Lg Chem, Ltd. Ansa-metallocen-verbindung und verfahren zur herstellung eines geträgerten katalysators damit
KR101584350B1 (ko) * 2013-04-08 2016-01-13 한화케미칼 주식회사 대전 방지제를 포함하는 메탈로센 촉매 시스템 및 이를 이용한 폴리올레핀의 제조 방법
FR3039431B1 (fr) * 2015-07-29 2019-05-31 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et d'un ligand de type phosphine complexe au nickel et son utilisation dans un procede d'oligomerisation des olefines
FR3042989A1 (fr) * 2015-10-30 2017-05-05 Ifp Energies Now Nouvelle composition catalytique a base de nickel en presence d'un activateur specifique et son utilisation dans un procede d'oligomerisation des olefines
FR3045414B1 (fr) * 2015-12-18 2019-12-27 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et de ligand de type phosphine et d'une base de lewis et son utilisation dans un procede d'oligomerisation des olefines
CN108786919B (zh) * 2017-05-05 2020-07-21 中国石油化工股份有限公司 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法
CN108786918B (zh) * 2017-05-05 2020-07-24 中国石油化工股份有限公司 负载型茂金属催化剂及其制备方法和应用和丙烯酸甲酯的制备方法
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
CN111212856B (zh) 2017-10-31 2023-03-24 埃克森美孚化学专利公司 来自在脂肪族溶剂中原位形成负载的铝氧烷的无甲苯的二氧化硅负载的单中心茂金属催化剂
KR102301666B1 (ko) * 2017-12-22 2021-09-14 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조 방법, 상기 제조 방법으로 제조된 혼성 담지 메탈로센 촉매, 및 이를 이용하는 폴리올레핀의 제조 방법
KR102431269B1 (ko) 2018-11-02 2022-08-10 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
US11352375B2 (en) 2018-12-28 2022-06-07 Braskem S.A. Auxiliaries for olefin polymerization process
US11866522B2 (en) 2018-12-28 2024-01-09 Braskem S.A. Process for introducing catalyst in a polymerization process
CN115368490B (zh) * 2021-05-20 2023-11-28 中国科学技术大学 硼烷助催化剂、合成方法及其应用
CN121021585A (zh) * 2025-10-28 2025-11-28 洛阳常龙新材料科技有限公司 一种第一代Grubbs催化剂的制备方法

Family Cites Families (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3127133A1 (de) * 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4530914A (en) * 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US4937299A (en) * 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
DE3508887A1 (de) * 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) * 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
DE3751694T2 (de) 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
DE3726067A1 (de) * 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
DE3808268A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5120867A (en) * 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3907964A1 (de) * 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5239022A (en) * 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5436305A (en) * 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
DE4120009A1 (de) * 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
TW300901B (de) * 1991-08-26 1997-03-21 Hoechst Ag
EP0537686B1 (de) 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
EP0549900B1 (de) * 1991-11-30 1996-08-21 Hoechst Aktiengesellschaft Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5932669A (en) * 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
TW309523B (de) * 1991-11-30 1997-07-01 Hoechst Ag
TW318184B (de) * 1991-11-30 1997-10-21 Hoechst Ag
US5830821A (en) * 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
EP0574597B2 (de) * 1992-06-13 2002-06-26 Basell Polyolefine GmbH Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl
TW294669B (de) * 1992-06-27 1997-01-01 Hoechst Ag
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
JP3293927B2 (ja) 1993-02-19 2002-06-17 三菱化学株式会社 α‐オレフィン重合用触媒成分およびそれを用いたα‐オレフィン重合体の製造法
DE69408989T2 (de) 1993-05-25 1998-11-05 Exxon Chemical Patents Inc Metallocen-katalysatorsysteme auf einem träger für die olefinpolymerisation, ihre herstellung und verwendung
DE69431222T2 (de) * 1993-06-07 2003-04-17 Mitsui Chemicals, Inc. Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
CA2125247C (en) * 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
JP3423378B2 (ja) * 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4406109A1 (de) 1994-02-25 1995-08-31 Witco Gmbh Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen
CA2193882C (en) * 1994-06-24 2005-07-26 Anthony Nicholas Speca Polymerization catalyst systems, their production and use
CA2195879C (en) 1994-08-03 2001-01-09 John Flexer Walzer Jr. Supported ionic catalyst composition
US6124230A (en) * 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6140432A (en) * 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
US5635437A (en) * 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
DE19544828A1 (de) * 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US5678812A (en) * 1996-02-14 1997-10-21 R. R. Donnelley & Sons Company Bindery apparatus with gathering conveyors and a method of make-ready
CA2243519A1 (en) 1996-03-04 1997-09-12 Exxon Chemical Patents, Inc. Stable metallocene catalyst systems
HU223533B1 (hu) * 1996-06-17 2004-08-30 Exxonmobil Chemical Patents Inc. Vegyes átmenetifém katalizátor-rendszer olefinek polimerizálására
ATE200785T1 (de) 1996-07-04 2001-05-15 Basf Ag Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
AU733813B2 (en) 1996-11-15 2001-05-24 Montell Technology Company B.V. Heterocyclic metallocenes and polymerization catalysts
DE69722902T2 (de) * 1996-12-09 2004-05-19 Mitsubishi Chemical Corp. Katalysator für Alpha-Olefinpolymerisation
EP0985674B1 (de) * 1997-01-21 2003-04-23 Mitsubishi Chemical Corporation Organische verbindungen enthaltend silizium oder germanium, übergangsmetallkomplexe, katalysatoren für alpha-olefin polymerisation und verfahren zur herstellung von alpha-olefinpolymeren
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6100214A (en) * 1997-06-05 2000-08-08 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
US6228795B1 (en) * 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
DE19733017A1 (de) * 1997-07-31 1999-02-04 Hoechst Ag Chemische Verbindung
DE19757540A1 (de) 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE19804970A1 (de) * 1998-02-07 1999-08-12 Aventis Res & Tech Gmbh & Co Katalysatorsystem
JP4116148B2 (ja) * 1998-06-08 2008-07-09 三菱化学株式会社 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
EP1109839B1 (de) 1998-08-26 2003-05-21 ExxonMobil Chemical Patents Inc. Hochwirksame geträgerte katalysatorzusammensetzungen
DE19903306A1 (de) * 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
DE19917985A1 (de) 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
CN1590422A (zh) * 1999-12-23 2005-03-09 巴塞尔聚烯烃有限公司 过渡金属化合物,配体体系,催化剂体系及其在烯烃的聚合反应和共聚反应中的用途
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
US6376411B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) * 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380334B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) * 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) * 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
SG96700A1 (en) * 2001-09-27 2003-06-16 Sumitomo Chemical Co Catalyst component for addition polymerization, process for producing catalyst for addition polymerization and process for producing addition polymer
US7141637B2 (en) 2001-11-30 2006-11-28 Basell Polyolefine Gmbh Metallocene compounds and process for the preparation of propylene polymers
JP2005529185A (ja) 2002-06-12 2005-09-29 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 遷移金属化合物の製造方法、および得られた化合物をオレフィンの重合および共重合のための触媒組成物において使用する方法
US7618912B2 (en) * 2002-07-15 2009-11-17 Basell Polyolefine Gmbh Preparation of supported catalyst systems
WO2004007569A1 (en) 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of catalyst systems
SG130016A1 (en) * 2002-09-24 2007-03-20 Sumitomo Chemical Co Modified particle, catalyst component for addition polymerization, catalyst for addition polymerization and process for producing addition polymer
US7592402B2 (en) * 2004-04-30 2009-09-22 Sumitomo Chemical Company, Limited Process for producing modified particle; carrier; catalyst component for addition polymerization; process for producing catalyst for addition polymerization; and process for producing addition polymer

Also Published As

Publication number Publication date
WO2006124231A1 (en) 2006-11-23
EP1882000A1 (de) 2008-01-30
ES2342106T3 (es) 2010-07-01
DE602006013300D1 (de) 2010-05-12
US20060264587A1 (en) 2006-11-23
EP1882000B1 (de) 2010-03-31
TW200710110A (en) 2007-03-16
US7468416B2 (en) 2008-12-23
KR20080033906A (ko) 2008-04-17
BRPI0610163A2 (pt) 2010-06-01
JP2008545821A (ja) 2008-12-18
CN101384624B (zh) 2012-07-04
KR101190758B1 (ko) 2012-10-12
US7232869B2 (en) 2007-06-19
CN101384624A (zh) 2009-03-11
US20070249799A1 (en) 2007-10-25

Similar Documents

Publication Publication Date Title
DE602006013300D1 (de) Katalysatorzusammensetzung zur olefinpolymerisierung
ATE516311T1 (de) Trialkylaluminium-behandelter träger
EA201200700A1 (ru) Технология приготовления системы твердофазного металлоценового катализатора без носителя и ее использование при полимеризации олефинов
DE602005002130D1 (de) Metallorganisches gerüstmaterial, herstellung und verwendung
EA200970605A1 (ru) Ингибиторы mapk/erk-киназ
ATE544788T1 (de) Verbesserte saure aktivator-träger und katalysatoren für die olefinpolymerisation
MX337111B (es) Activadores de catalitizador de aluminoxano que contienen agentes carbocationes y uso de los mismos en catalizadores de poliolefina.
JP2006521436A5 (de)
ATE400591T1 (de) Polymerisationsverfahren
EA201071434A1 (ru) Высокоактивные катализаторы циглера-натта, способ получения катализаторов и их использование
MY160247A (en) Catalyst support used for olefin polymerization and preparing method and application thereof
DE602007006011D1 (de) Katalysatorzusammensetzung zur (co)polymerisierung von propylen
WO2006110234A3 (en) Propylene polymer catalyst donor component
TW200740874A (en) Palladium catalyzed polymerization reaction
WO2006096621A3 (en) Propylene polymer catalyst donor component
DK1501507T3 (da) Tetrahydropyranyl-cyclopentyl-tertrahydropyridopyrindin-modulatorer af kemokin-receptor-aktivitet
TW200602387A (en) A polymer and a process for producing the same
DE502006006249D1 (de) Synthese von phenylsubstituierten polyfluoranthenen und ihre verwendung
ATE420918T1 (de) Sauerstoffbarriereformulierungen
WO2008036591A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
TW200745758A (en) Base soluble polymers for photoresist compositions
ATE507270T1 (de) Antiadhäsive beschichtung von bauteilen zur verhinderung von ölkohleanbackungen
BRPI0512310A (pt) compostos quìmicos
WO2008011267A3 (en) Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
ATE500210T1 (de) Verfahren zur telomerisation von nicht cyclischen olefinen

Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification

Ref document number: 1882000

Country of ref document: EP