ATE475467T1 - Verfahren zur wiedergewinnung von katalysatoren aus hydrocyanierungsproduktgemischen - Google Patents

Verfahren zur wiedergewinnung von katalysatoren aus hydrocyanierungsproduktgemischen

Info

Publication number
ATE475467T1
ATE475467T1 AT04700629T AT04700629T ATE475467T1 AT E475467 T1 ATE475467 T1 AT E475467T1 AT 04700629 T AT04700629 T AT 04700629T AT 04700629 T AT04700629 T AT 04700629T AT E475467 T1 ATE475467 T1 AT E475467T1
Authority
AT
Austria
Prior art keywords
diphosphite
containing compounds
organic
saturated
disclosed
Prior art date
Application number
AT04700629T
Other languages
English (en)
Inventor
Scott Jackson
Ronald Mckinney
Original Assignee
Invista Tech Sarl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Invista Tech Sarl filed Critical Invista Tech Sarl
Application granted granted Critical
Publication of ATE475467T1 publication Critical patent/ATE475467T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0426—Counter-current multistage extraction towers in a vertical or sloping position
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/04—Solvent extraction of solutions which are liquid
    • B01D11/0446—Juxtaposition of mixers-settlers
    • B01D11/0457—Juxtaposition of mixers-settlers comprising rotating mechanisms, e.g. mixers, mixing pumps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT04700629T 2003-01-08 2004-01-07 Verfahren zur wiedergewinnung von katalysatoren aus hydrocyanierungsproduktgemischen ATE475467T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/338,567 US6936171B2 (en) 2003-01-08 2003-01-08 Process for catalyst recovery from hydrocyanation product mixtures
PCT/US2004/000375 WO2004062765A1 (en) 2003-01-08 2004-01-07 Process for catalyst recovery from hydrocyanation product mixtures

Publications (1)

Publication Number Publication Date
ATE475467T1 true ATE475467T1 (de) 2010-08-15

Family

ID=32710978

Family Applications (1)

Application Number Title Priority Date Filing Date
AT04700629T ATE475467T1 (de) 2003-01-08 2004-01-07 Verfahren zur wiedergewinnung von katalysatoren aus hydrocyanierungsproduktgemischen

Country Status (8)

Country Link
US (1) US6936171B2 (de)
EP (1) EP1581323B1 (de)
CN (1) CN100386128C (de)
AT (1) ATE475467T1 (de)
DE (1) DE602004028336D1 (de)
MY (1) MY135238A (de)
TW (1) TW200417412A (de)
WO (1) WO2004062765A1 (de)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6906218B2 (en) * 2002-12-18 2005-06-14 Invista North America S.A.R.L. Cyclohexane derivatives and methods for their preparation
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
FR2854892B1 (fr) 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
DE102004050935A1 (de) * 2004-10-18 2006-04-20 Basf Ag Extraktion von Nickel(0)-Komplexen aus Nitrilgemischen mit verminderter Mulmbildung
WO2007109005A2 (en) 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
KR20090006177A (ko) * 2006-04-07 2009-01-14 바스프 에스이 니트릴 혼합물로부터 니켈(０) 착물 및 인-함유 리간드의 분리 방법
US7709673B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7659422B2 (en) * 2006-07-14 2010-02-09 Invista North America S.A.R.L. Hydrocyanation process with reduced yield losses
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7709674B2 (en) 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
WO2009091771A2 (en) 2008-01-15 2009-07-23 Invista Technologies S.A R.L Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
ES2542430T3 (es) 2010-07-07 2015-08-05 Invista Technologies S.À.R.L. Proceso para hacer nitrilos
EP2794047B1 (de) 2011-12-21 2021-04-14 INVISTA Textiles (U.K.) Limited Regelung des extraktionslösungsmittels zur verminderung stabiler emulsionen
JP2015512862A (ja) 2011-12-21 2015-04-30 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
US9133223B2 (en) 2011-12-21 2015-09-15 Invista North America S.A.R.L. Extraction solvent control for reducing stable emulsions
KR20150035479A (ko) 2011-12-21 2015-04-06 인비스타 테크놀러지스 에스.에이 알.엘. 안정한 에멀젼을 감소시키기 위한 추출 용매 제어
EP3010615B1 (de) 2013-06-20 2022-09-28 INVISTA Textiles (U.K.) Limited Verfahren zur rückgewinnung von diphosphonithaltigen verbindungen mittels eines mehrstufigen gegenstrom-flüssig-flüssig-extraktors mit misch-absetzer und rückführung der schweren phase
EP3010617B1 (de) 2013-06-20 2022-11-30 INVISTA Textiles (U.K.) Limited Steuerung eines extraktionslösungsmittels zur reduzierung stabiler emulsionen
WO2014205188A1 (en) 2013-06-20 2014-12-24 Invista North America S.A.R.L. Extraction solvent control for reducing stable emulsions
WO2014205195A1 (en) * 2013-06-20 2014-12-24 Invista Technologies S.A.R.L. Extraction solvent control for reducing stable emulsions
US9676800B2 (en) 2013-06-20 2017-06-13 Invista North America S.A.R.L. Extraction solvent control for reducing stable emulsions
US10759741B2 (en) 2013-07-17 2020-09-01 Invista North America S.A R.L. Separating a solvent from a nickel catalyst by distillation
CN103408178B (zh) * 2013-08-22 2015-07-22 太原理工大学 从hpf焦化脱硫废液中回收脱硫催化剂的工艺
US9914700B2 (en) 2014-06-27 2018-03-13 Invista North America S.A R.L. Enhanced extraction of impurities from mixture comprising nitriles
CN107207406B (zh) 2014-06-27 2019-12-03 英威达纺织（英国）有限公司 用增强的液-液萃取制造腈的整合方法
CN113044904B (zh) * 2021-05-10 2022-06-03 中国科学院过程工程研究所 协同萃取煤化工废水中难降解污染物和酚的萃取剂及方法
CN119390607B (zh) * 2024-09-27 2025-11-25 中国天辰工程有限公司 一种氢氰化反应方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496215A (en) * 1965-11-23 1970-02-17 Du Pont Hydrocyanation of olefins using selected nickel phosphite catalysts
GB1112539A (en) * 1965-11-26 1968-05-08 Du Pont Preparation of organic nitriles
US3496217A (en) * 1967-05-23 1970-02-17 Du Pont Hydrocyanation of olefins
US3773609A (en) 1970-09-19 1973-11-20 Chisso Corp Process for preparing film of crystalline propylene polymer having good heat sealability at low temperature
US3766241A (en) * 1971-05-26 1973-10-16 Du Pont Removal of metal cations from solution in nitriles
US3773809A (en) * 1972-06-28 1973-11-20 Du Pont Separation of organic phosphorus compounds and their metal complexes from organic nitriles in the hydrocyanation of olefins
US4387056A (en) * 1981-04-16 1983-06-07 E. I. Du Pont De Nemours And Company Process for separating zero-valent nickel species from divalent nickel species
CA2177135C (en) * 1993-11-23 2005-04-26 Wilson Tam Processes and catalyst compositions for hydrocyanation of monoolefins
US5512695A (en) * 1994-04-14 1996-04-30 E. I. Du Pont De Nemours And Company Bidentate phosphite and nickel catalyst compositions for hydrocyanation of monoolefins
US5543536A (en) * 1994-04-26 1996-08-06 E. I. Du Pont De Nemours And Company Monodentate phosphite and nickel catalyst composition for monoolefin hydrocyanation
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
TW315370B (de) * 1994-10-07 1997-09-11 Du Pont
US5523453A (en) * 1995-03-22 1996-06-04 E. I. Du Pont De Nemours And Company Process for hydrocyanation
US5693843A (en) * 1995-12-22 1997-12-02 E. I. Du Pont De Nemours And Company Process for hydrocyanation of diolefins and isomerization of nonconjugated 2 alkyl-3-monoalkenenitriles
ZA986374B (en) * 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
US5959135A (en) * 1997-07-29 1999-09-28 E. I. Du Pont De Nemours And Company Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions thereof
MY124170A (en) * 1997-07-29 2006-06-30 Invista Tech Sarl Hydrocyanation processes and multidentate phosphite ligand and nickel catalyst compositions therefor
ZA986369B (en) * 1997-07-29 2000-01-17 Du Pont Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles.
US5847191A (en) * 1997-07-29 1998-12-08 E. I. Du Pont De Nemours And Company Process for the hydrocyanation of monoolefins using bidentate phosphite ligands and zero-valent nickel
US6048996A (en) * 1999-08-26 2000-04-11 E. I. Du Pont De Nemours And Company Insoluble promoters for nickel-catalyzed hydrocyanation of monoolefins
US6307107B1 (en) * 1999-09-20 2001-10-23 E.I. Du Pont De Nemours And Company Hydroformylation of acyclic monoethylenically unsaturated compounds to corresponding terminal aldehydes
DE19953058A1 (de) 1999-11-03 2001-05-10 Basf Ag Phosphite
US6660876B2 (en) * 2001-11-26 2003-12-09 E. I. Du Pont De Nemours And Company Phosphorus-containing compositions and their use in hydrocyanation, isomerization and hydroformylation reactions

Also Published As

Publication number Publication date
EP1581323A1 (de) 2005-10-05
US6936171B2 (en) 2005-08-30
EP1581323A4 (de) 2008-07-02
TW200417412A (en) 2004-09-16
EP1581323B1 (de) 2010-07-28
US20040140263A1 (en) 2004-07-22
CN1723067A (zh) 2006-01-18
CN100386128C (zh) 2008-05-07
DE602004028336D1 (de) 2010-09-09
WO2004062765A1 (en) 2004-07-29
MY135238A (en) 2008-03-31

Similar Documents

Publication Publication Date Title
ATE475467T1 (de) Verfahren zur wiedergewinnung von katalysatoren aus hydrocyanierungsproduktgemischen
RU2315751C2 (ru) Способ получения и выделения динитрилов
Mele et al. Fine chemicals and new hybrid materials from cardanol
ES2258547T3 (es) Procedimiento para la separacion de isomeros de pentenonitrilo.
ATE555083T1 (de) Verfahren zur herstellung von dinitril
DE602004005580D1 (de) Verfahren zur herstellung eines nickel/phosphor-ligand-katalysators
KR100734798B1 (ko) 불포화 화합물의 시안화수소화 방법
ATE513801T1 (de) Verfahren zur synthese von propargylatierten aminoindanderivativen
MXPA05009364A (es) Resinas fenolicas de rosina y usos relacionados con las mismas.
US7385096B2 (en) Process for producing 1,2-diol
ATE274490T1 (de) Verfahren zur hydrierung von dinitrilen zu aminonitrilen
Majhi et al. Solvent‐free synthesis of α‐aminonitriles from aldehydes, amines and trimethylsilyl cyanide catalyzed by thallium (III) chloride tetrahydrate
ATE440831T1 (de) Verfahren zur herstellung von ungesättigten lactonen
CN114787124B (zh) 制备丙烯腈二聚体的方法
EP3066070A1 (de) Katalytische hydrierung zur herstellung von aminen aus amidacetalen, keten-n, o-acetalen oder esterimiden
JP6023067B2 (ja) ビアセチル含有量が低減されたメチルメタクリレートを製造する方法
EP1072584A1 (de) An harz gebundene aminderivate und verfahren zur herstellung einer beta-aminocarbonylverbindung in der festphase
TH67174A (th) กระบวนการสำหรับการนำกลับคืนตัวเร่งปฏิกิริยาจากส่วนผสมผลผลิตไฮโดรไซยาเนชั่น
DE102016116130A1 (de) Verfahren zur Herstellung chiraler Aminonitrile
Schmid Catalytic formylation of amines with dense carbon dioxide
TH84971A (th) สารผสมฟอสไฟต์ประเภทโพลิเมอร์ และการทำไฮโดรไซยาเนชันของสารประกอบอินทรีย์ไม่อิ่มตัว และการทำไอโซเมอไรเซชันของไนไทรล์ไม่อิ่มตัว
TH72061A (th) กระบวนการของไฮโดรไซยาเนชันของอนุพันธ์ของคาร์บอกซิลิกแอซิดที่ไม่อิ่มตัว

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties