ATE513608T1 - Verfahren zum entfernen von wasserstoffcyanid und ameisensäure aus synthesegas - Google Patents

Verfahren zum entfernen von wasserstoffcyanid und ameisensäure aus synthesegas

Info

Publication number
ATE513608T1
ATE513608T1 AT07724334T AT07724334T ATE513608T1 AT E513608 T1 ATE513608 T1 AT E513608T1 AT 07724334 T AT07724334 T AT 07724334T AT 07724334 T AT07724334 T AT 07724334T AT E513608 T1 ATE513608 T1 AT E513608T1
Authority
AT
Austria
Prior art keywords
hydrogencyanide
removal
formic acid
synthesis gas
synthesis
Prior art date
Application number
AT07724334T
Other languages
English (en)
Inventor
Karsten Pedersen
Ib Dybkjaer
Poul Nielsen
Jesper Nerlov
Original Assignee
Haldor Topsoe As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38370425&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ATE513608(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Haldor Topsoe As filed Critical Haldor Topsoe As
Application granted granted Critical
Publication of ATE513608T1 publication Critical patent/ATE513608T1/de

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8671—Removing components of defined structure not provided for in B01D53/8603 - B01D53/8668
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8678—Removing components of undefined structure
    • B01D53/8681—Acidic components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/104—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/106—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20769—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AT07724334T 2006-04-28 2007-04-18 Verfahren zum entfernen von wasserstoffcyanid und ameisensäure aus synthesegas ATE513608T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200600606 2006-04-28
PCT/EP2007/003397 WO2007124865A1 (en) 2006-04-28 2007-04-18 Process for the removal of hydrogen cyanide and formic acid from synthesis gas

Publications (1)

Publication Number Publication Date
ATE513608T1 true ATE513608T1 (de) 2011-07-15

Family

ID=38370425

Family Applications (1)

Application Number Title Priority Date Filing Date
AT07724334T ATE513608T1 (de) 2006-04-28 2007-04-18 Verfahren zum entfernen von wasserstoffcyanid und ameisensäure aus synthesegas

Country Status (14)

Country Link
US (1) US8623303B2 (de)
EP (1) EP2015860B1 (de)
CN (1) CN101484230B (de)
AR (1) AR060674A1 (de)
AT (1) ATE513608T1 (de)
AU (1) AU2007245907B2 (de)
BR (1) BRPI0711075B1 (de)
CA (1) CA2650844C (de)
EA (1) EA013870B1 (de)
MX (1) MX2008013754A (de)
MY (1) MY148621A (de)
TW (1) TWI439316B (de)
WO (1) WO2007124865A1 (de)
ZA (1) ZA200809252B (de)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7892324B2 (en) * 2007-10-10 2011-02-22 General Electric Company Systems and methods for carbon dioxide capture
MX2010004517A (es) * 2007-10-26 2010-06-02 Haldor Topsoe As Proceso para la reduccion en la cantidad de compuestos de azufre, cianuro de hidrogeno y acido formico en un gas de sintesis.
CN101269297B (zh) * 2008-05-21 2011-09-14 昆明理工大学 一种工业废气中氰化氢的催化氧化净化方法
JP5006855B2 (ja) * 2008-09-24 2012-08-22 本田技研工業株式会社 排ガス浄化触媒及びこれを用いた排ガス浄化フィルタ
US8974759B2 (en) * 2011-11-28 2015-03-10 Coskata, Inc. Processes for selectively reducing the concentration of hydrogen cyanide in syngas
JP2013170091A (ja) * 2012-02-20 2013-09-02 Toyo Eng Corp 合成ガスの製造方法
CN104549305A (zh) * 2014-12-23 2015-04-29 昆明理工大学 一种水解氰化氢催化剂的制备方法及应用
US10260005B2 (en) * 2016-08-05 2019-04-16 Greyrock Technology LLC Catalysts, related methods and reaction products
CA3036953A1 (en) 2016-10-07 2018-04-12 Haldor Topsoe A/S A process for low temperature gas cleaning with ozone and a catalytic bag filter for use in the process
CN109569588B (zh) * 2017-09-28 2021-11-30 中国石油化工股份有限公司 含氰废气催化氧化催化剂及其制备方法
CN110354649A (zh) * 2019-06-29 2019-10-22 上海二十冶建设有限公司 空分装置中分子筛吸附器内吸附剂的移除方法
CN112675867B (zh) * 2020-11-02 2023-06-13 中国人民解放军陆军防化学院 一种用于高效消除氰化氢的催化材料的制备方法
CN116920601A (zh) * 2023-06-20 2023-10-24 宁夏滨泽新能源科技有限公司 一种净化含氰化氢工业尾气的系统及方法

Family Cites Families (16)

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JPS535065A (en) 1976-07-05 1978-01-18 Nitto Chem Ind Co Ltd Treatment of exhaust gas containing hydrocyanic acid
DE2655321C3 (de) * 1976-12-07 1979-12-20 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von rußarmen und schwefelfreien Verbrennungsgasen
DE2733105B1 (de) * 1977-07-22 1979-01-18 Basf Ag Verfahren zur Herstellung von Synthesegasen durch partielle Oxidation
DE3243206A1 (de) * 1982-11-23 1984-05-24 Basf Ag, 6700 Ludwigshafen Verfahren zur reinigung von co und/oder co(pfeil abwaerts)2(pfeil abwaerts) enthaltenden gasen
EP0293546A3 (de) * 1987-02-11 1989-06-07 Ammonia Casale S.A. System zur Verbesserung der Reaktorleistungsfähigkeit der exothermischen Ammoniaksynthese
US4810475A (en) * 1987-08-18 1989-03-07 Shell Oil Company Removal of HCN, and HCN and COS, from a substantially chloride-free gaseous stream
JP2812486B2 (ja) * 1989-05-15 1998-10-22 大阪瓦斯株式会社 炭化水素の水蒸気改質方法
DE69215345T2 (de) * 1991-12-30 1997-03-13 Texaco Development Corp Behandlung von Synthesegas
US5587348A (en) * 1995-04-19 1996-12-24 Phillips Petroleum Company Alkyne hydrogenation catalyst and process
US6107353A (en) * 1995-08-08 2000-08-22 Exxon Research And Engineering Company Cyanide and ammonia removal from synthesis gas
US6162373A (en) * 1995-10-03 2000-12-19 Exxon Research And Engineering Company Removal of hydrogen cyanide from synthesis gas (Law322)
KR100319922B1 (ko) * 1999-03-05 2002-01-09 이형도 디젤엔진 배기가스 정화용 촉매
DE60320531T2 (de) * 2002-02-18 2009-06-10 Haldor Topsoe A/S Verfahren zur selektiven entfernung von schwefelverbindungen aus synthesegas
MY137042A (en) * 2002-06-14 2008-12-31 Chevron Phillips Chemical Co Hydrogenation palladium-silver catalyst and methods
CN1729139A (zh) * 2002-12-20 2006-02-01 本田技研工业株式会社 用于氢产生的催化剂配方
JP3855994B2 (ja) * 2003-12-25 2006-12-13 日産自動車株式会社 触媒及びその製造方法

Also Published As

Publication number Publication date
EP2015860A1 (de) 2009-01-21
AR060674A1 (es) 2008-07-02
BRPI0711075B1 (pt) 2017-12-12
WO2007124865A1 (en) 2007-11-08
AU2007245907B2 (en) 2011-02-10
ZA200809252B (en) 2010-02-24
MX2008013754A (es) 2009-01-09
US8623303B2 (en) 2014-01-07
EP2015860B1 (de) 2011-06-22
EA200802196A1 (ru) 2009-04-28
MY148621A (en) 2013-05-15
CN101484230B (zh) 2012-12-26
CN101484230A (zh) 2009-07-15
TWI439316B (zh) 2014-06-01
EA013870B1 (ru) 2010-08-30
CA2650844A1 (en) 2007-11-08
CA2650844C (en) 2014-01-14
BRPI0711075A2 (pt) 2011-08-23
TW200744737A (en) 2007-12-16
US20090074643A1 (en) 2009-03-19
AU2007245907A1 (en) 2007-11-08

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