EA200802196A1 - Способ удаления цианистого водорода и муравьиной кислоты из синтез-газа - Google Patents

Способ удаления цианистого водорода и муравьиной кислоты из синтез-газа

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Publication number
EA200802196A1
EA200802196A1 EA200802196A EA200802196A EA200802196A1 EA 200802196 A1 EA200802196 A1 EA 200802196A1 EA 200802196 A EA200802196 A EA 200802196A EA 200802196 A EA200802196 A EA 200802196A EA 200802196 A1 EA200802196 A1 EA 200802196A1
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EA
Eurasian Patent Office
Prior art keywords
formic acid
synthesis gas
hydrogen
cyanic
group
Prior art date
Application number
EA200802196A
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English (en)
Other versions
EA013870B1 (ru
Inventor
Карстен Педерзен
Иб Дибкайер
Поль Эрик Хойлунд Нильзен
Йеспер Нерлоф
Original Assignee
Хальдор Топсёэ А/С
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Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38370425&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EA200802196(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Хальдор Топсёэ А/С filed Critical Хальдор Топсёэ А/С
Publication of EA200802196A1 publication Critical patent/EA200802196A1/ru
Publication of EA013870B1 publication Critical patent/EA013870B1/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8671—Removing components of defined structure not provided for in B01D53/8603 - B01D53/8668
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8678—Removing components of undefined structure
    • B01D53/8681—Acidic components
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/104—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/106—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/206—Rare earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20761—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20769—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/408—Cyanides, e.g. hydrogen cyanide (HCH)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ каталитического удаления цианистого водорода, муравьиной кислоты и производных муравьиной кислоты из синтез-газа, включающего эти компоненты, моноксид углерода и водород, который заключается в приведении синтез-газа в контакт с катализатором, включающим один или несколько металлов, выбранных из группы, включающей серебро, золото, медь, палладий, платину и их смеси, и нанесенных на носитель, включающий по меньшей мере один из оксидов металлов, выбранных из группы, состоящей из скандия, иттрия, лантана, церия, титана, циркония, алюминия, цинка, хрома и молибдена.
EA200802196A 2006-04-28 2007-04-18 Способ удаления цианистого водорода и муравьиной кислоты из синтез-газа EA013870B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200600606 2006-04-28
PCT/EP2007/003397 WO2007124865A1 (en) 2006-04-28 2007-04-18 Process for the removal of hydrogen cyanide and formic acid from synthesis gas

Publications (2)

Publication Number Publication Date
EA200802196A1 true EA200802196A1 (ru) 2009-04-28
EA013870B1 EA013870B1 (ru) 2010-08-30

Family

ID=38370425

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200802196A EA013870B1 (ru) 2006-04-28 2007-04-18 Способ удаления цианистого водорода и муравьиной кислоты из синтез-газа

Country Status (14)

Country Link
US (1) US8623303B2 (ru)
EP (1) EP2015860B1 (ru)
CN (1) CN101484230B (ru)
AR (1) AR060674A1 (ru)
AT (1) ATE513608T1 (ru)
AU (1) AU2007245907B2 (ru)
BR (1) BRPI0711075B1 (ru)
CA (1) CA2650844C (ru)
EA (1) EA013870B1 (ru)
MX (1) MX2008013754A (ru)
MY (1) MY148621A (ru)
TW (1) TWI439316B (ru)
WO (1) WO2007124865A1 (ru)
ZA (1) ZA200809252B (ru)

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US7892324B2 (en) * 2007-10-10 2011-02-22 General Electric Company Systems and methods for carbon dioxide capture
BRPI0818853B1 (pt) * 2007-10-26 2018-11-21 Haldor Topsoe A/S processos para a redução na quantidade de compostos de enxofre, cianeto de hidrogênio, ácido fórmico e derivados de ácido fórmico em gás de síntese, para a preparação de metanol, éter dimetílico e/ou hidrocarbonetos em forma gasosa ou líquida a partir de gás de síntese, e, para apreparação de hidrocarbonetos em forma líquida a partir de gás de síntese
CN101269297B (zh) * 2008-05-21 2011-09-14 昆明理工大学 一种工业废气中氰化氢的催化氧化净化方法
JP5006855B2 (ja) * 2008-09-24 2012-08-22 本田技研工業株式会社 排ガス浄化触媒及びこれを用いた排ガス浄化フィルタ
US8974759B2 (en) * 2011-11-28 2015-03-10 Coskata, Inc. Processes for selectively reducing the concentration of hydrogen cyanide in syngas
JP2013170091A (ja) * 2012-02-20 2013-09-02 Toyo Eng Corp 合成ガスの製造方法
CN104549305A (zh) * 2014-12-23 2015-04-29 昆明理工大学 一种水解氰化氢催化剂的制备方法及应用
US10260005B2 (en) * 2016-08-05 2019-04-16 Greyrock Technology LLC Catalysts, related methods and reaction products
CN109803746A (zh) 2016-10-07 2019-05-24 托普索公司 用臭氧进行低温气体清洁的方法和用于该方法的催化袋式过滤器
CN109569588B (zh) * 2017-09-28 2021-11-30 中国石油化工股份有限公司 含氰废气催化氧化催化剂及其制备方法
CN110354649A (zh) * 2019-06-29 2019-10-22 上海二十冶建设有限公司 空分装置中分子筛吸附器内吸附剂的移除方法
CN112675867B (zh) * 2020-11-02 2023-06-13 中国人民解放军陆军防化学院 一种用于高效消除氰化氢的催化材料的制备方法
CN116920601A (zh) * 2023-06-20 2023-10-24 宁夏滨泽新能源科技有限公司 一种净化含氰化氢工业尾气的系统及方法

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Also Published As

Publication number Publication date
US8623303B2 (en) 2014-01-07
MY148621A (en) 2013-05-15
ZA200809252B (en) 2010-02-24
ATE513608T1 (de) 2011-07-15
EA013870B1 (ru) 2010-08-30
CA2650844A1 (en) 2007-11-08
MX2008013754A (es) 2009-01-09
WO2007124865A1 (en) 2007-11-08
BRPI0711075A2 (pt) 2011-08-23
CA2650844C (en) 2014-01-14
CN101484230A (zh) 2009-07-15
EP2015860A1 (en) 2009-01-21
TW200744737A (en) 2007-12-16
AU2007245907A1 (en) 2007-11-08
CN101484230B (zh) 2012-12-26
BRPI0711075B1 (pt) 2017-12-12
AU2007245907B2 (en) 2011-02-10
US20090074643A1 (en) 2009-03-19
EP2015860B1 (en) 2011-06-22
AR060674A1 (es) 2008-07-02
TWI439316B (zh) 2014-06-01

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