BR9915221A - Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono - Google Patents
Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbonoInfo
- Publication number
- BR9915221A BR9915221A BR9915221-5A BR9915221A BR9915221A BR 9915221 A BR9915221 A BR 9915221A BR 9915221 A BR9915221 A BR 9915221A BR 9915221 A BR9915221 A BR 9915221A
- Authority
- BR
- Brazil
- Prior art keywords
- carbon
- passages
- reformer
- walls
- compaction
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
- B01J19/0026—Avoiding carbon deposits
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/0085—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction promoting uninterrupted fluid flow, e.g. by filtering out particles in front of the catalyst layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
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- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/382—Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
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- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/384—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts with external heating of the catalyst
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
- C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
- C01B3/32—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
- C01B3/34—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
- C01B3/386—Catalytic partial combustion
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- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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- B01J2219/00245—Avoiding undesirable reactions or side-effects
- B01J2219/00247—Fouling of the reactor or the process equipment
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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- B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
- B01J2219/0218—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components of ceramic
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/02—Apparatus characterised by their chemically-resistant properties
- B01J2219/0204—Apparatus characterised by their chemically-resistant properties comprising coatings on the surfaces in direct contact with the reactive components
- B01J2219/0236—Metal based
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
- C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0816—Heating by flames
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1005—Arrangement or shape of catalyst
- C01B2203/1011—Packed bed of catalytic structures, e.g. particles, packing elements
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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- C01B2203/1041—Composition of the catalyst
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- C01B2203/1052—Nickel or cobalt catalysts
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- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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- C01B2203/1241—Natural gas or methane
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- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/1604—Starting up the process
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Fuel Cell (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
''CONJUNTO DE REFORMADOR DE VAPOR DE GáS COMBUSTìVEL HIDROCARBONETO, E, PROCESSO PARA FORMAR UM COMPONENTE RESISTENTE à DEPOSIçãO DE CARBONO'' Um conjunto de reformador de gás combustivel para uso em usina de energia de célula de combustível inclui passagens de gás combustível (2), que contém uma compactação de alumina em partículas (12) em que uma mistura de corrente de vapor - combustível hidrocarboneto vaporizada é aquecida. As paredes (4) das passagens (2) tem um revestimento de alumina que protege as paredes (4) da corrosão. O revestimento (4) e compactação (12) são sobrepostos por uma camada de óxido de metal alcalino-terroso que limita o acúmulo de carbono sobre as superfícies das paredes (4) e evita o entupimento prematuro das passagens (2). A camada limitadora do acúmulo de carbono é formada em componentes das passagens do reformador por aplicação de uma suspensão à base d'água de compostos de metal alcalino-terroso para as superfícies da passagem do reformador, e então secagem da suspensão para solidificar a mesma. O material de compactação revestido (14) é operativo para converter qualquer carbono livre restante na corrente de gás para dióxido de carbono, ou monóxido de cabono, assim ainda limitando a deposição de carbono no conjunto.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/190,855 US6258330B1 (en) | 1998-11-10 | 1998-11-10 | Inhibition of carbon deposition on fuel gas steam reformer walls |
| PCT/US1999/026558 WO2000029092A1 (en) | 1998-11-10 | 1999-11-10 | Inhibition of carbon deposition on fuel gas steam reformer walls |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9915221A true BR9915221A (pt) | 2001-07-24 |
Family
ID=22703076
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9915221-5A BR9915221A (pt) | 1998-11-10 | 1999-11-10 | Conjunto de reformador de vapor de gás combustìvel hidrocarboneto, e, processo para formar um componente resistente à deposição de carbono |
| BR9915190-1A BR9915190A (pt) | 1998-11-10 | 1999-11-10 | Conjunto de reformador de gás combustìvel de hidrocarboneto |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9915190-1A BR9915190A (pt) | 1998-11-10 | 1999-11-10 | Conjunto de reformador de gás combustìvel de hidrocarboneto |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6258330B1 (pt) |
| EP (2) | EP1140322B1 (pt) |
| JP (2) | JP2002529359A (pt) |
| KR (2) | KR100563182B1 (pt) |
| CN (2) | CN1170623C (pt) |
| AU (2) | AU2843000A (pt) |
| BR (2) | BR9915221A (pt) |
| DE (1) | DE69941093D1 (pt) |
| ID (1) | ID29948A (pt) |
| WO (2) | WO2000029092A1 (pt) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020182132A1 (en) * | 2000-10-04 | 2002-12-05 | Lesieur Roger R. | Fuel gas reformer assemblage |
| US6767376B1 (en) | 2000-11-10 | 2004-07-27 | Sofco-Efs Holdings, L.L.C. | Selectively controllable modular auto-thermal reformer and method for same |
| US6759016B2 (en) * | 2000-11-30 | 2004-07-06 | Ballard Power Systems Inc. | Compact multiple tube steam reformer |
| US20020108308A1 (en) * | 2001-02-13 | 2002-08-15 | Grieve Malcolm James | Temperature/reaction management system for fuel reformer systems |
| US7025903B2 (en) | 2001-02-15 | 2006-04-11 | Delphi Technologies, Inc. | Reformer system process |
| US20040028604A1 (en) * | 2001-10-03 | 2004-02-12 | Haruo Watanabe | Method for recovering hydrogen from resin waste, process for producing hydrogen from resin waste, and apparatus for producing hydrogen from resin waste |
| AU2003208176B2 (en) * | 2002-03-04 | 2008-12-11 | Chaozhou Three-Circle (Group) Co., Ltd. | Solid oxide fuel cell |
| AUPS087502A0 (en) | 2002-03-04 | 2002-03-28 | Ceramic Fuel Cells Limited | Solid oxide fuel cell |
| US20030188475A1 (en) * | 2002-03-29 | 2003-10-09 | Shabbir Ahmed | Dynamic fuel processor with controlled declining temperatures |
| US20030223926A1 (en) * | 2002-04-14 | 2003-12-04 | Edlund David J. | Steam reforming fuel processor, burner assembly, and methods of operating the same |
| EP1516663A3 (en) * | 2002-04-14 | 2006-03-22 | IdaTech, LLC. | Steam reformer with burner |
| DE10313527A1 (de) * | 2003-03-26 | 2004-10-14 | Basf Ag | Verfahren zur Durchführung einer Hochtemperaturreaktion, Reaktor zur Durchführung des Verfahrens, Verfahren zum Scale-Up eines Reaktors sowie Verwendung |
| DE10313529A1 (de) * | 2003-03-26 | 2004-10-14 | Basf Ag | Reaktor für Hochtemperaturreaktionen und Verwendung |
| JP4998932B2 (ja) * | 2004-12-21 | 2012-08-15 | 三菱化工機株式会社 | メタノール改質装置 |
| JP4799995B2 (ja) * | 2005-10-20 | 2011-10-26 | 東京瓦斯株式会社 | 水蒸気改質器 |
| KR100993468B1 (ko) | 2009-02-05 | 2010-11-09 | 삼성에스디아이 주식회사 | 자동 점화형 자열 개질기 및 이를 구비하는 연료전지 시스템 |
| JP5423180B2 (ja) * | 2009-06-26 | 2014-02-19 | パナソニック株式会社 | 水素生成装置 |
| AT513931B1 (de) * | 2013-02-04 | 2017-03-15 | Avl List Gmbh | Reformereinheit für Brennstoffzellensystem |
| ITMI20131564A1 (it) * | 2013-09-23 | 2015-03-24 | Rivoira S P A | Sistema per la generazione di endogas |
| KR101518204B1 (ko) * | 2015-01-30 | 2015-05-11 | 주식회사 한중엔시에스 | 예열기가 병합된 연료전지용 다채널 직립형 개질기 |
| CN109195696B (zh) * | 2016-04-12 | 2022-04-26 | 俄亥俄州立创新基金会 | 从含碳燃料化学循环生产合成气 |
| NL2017215B1 (nl) | 2016-07-22 | 2018-01-30 | Green Vision Holding Bv | Apparaat voor het omzetten van een voedingsgas in productgas |
| EP3296255A1 (de) | 2016-09-14 | 2018-03-21 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Reformerrohr mit strukturiertem katalysator und verbessertem wärmehaushalt |
| EP3532430B1 (en) * | 2016-10-25 | 2020-07-01 | Technip France | Catalyst tube for reforming |
| WO2019027972A1 (en) | 2017-07-31 | 2019-02-07 | Ohio State Innovation Foundation | REACTOR SYSTEM WITH UNEQUAL OPERATING PRESSURE OF REACTOR ASSEMBLY |
| WO2020033500A1 (en) | 2018-08-09 | 2020-02-13 | Ohio State Innovation Foundation | Systems, methods and materials for hydrogen sulfide conversion |
| CA3125491A1 (en) | 2019-01-17 | 2020-07-23 | Ohio State Innovation Foundation | Systems, methods and materials for stable phase syngas generation |
| US11453626B2 (en) | 2019-04-09 | 2022-09-27 | Ohio State Innovation Foundation | Alkene generation using metal sulfide particles |
| EP3772372A1 (en) | 2019-08-05 | 2021-02-10 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for preventing fluidizazion in an upward-flow catalytic fixed bed reactor |
| EP4010115A4 (en) | 2019-08-19 | 2023-07-19 | Ohio State Innovation Foundation | IMMOBILIZED METAL OXIDE NANOPARTICLES ON A MESOPOROUS SUPPORT |
| WO2021046156A1 (en) | 2019-09-03 | 2021-03-11 | Ohio State Innovation Foundation | Redox reaction facilitated carbon dioxide capture from flue gas and conversion to carbon monoxide |
| EP4164786A4 (en) | 2020-06-29 | 2024-07-10 | Ohio State Innovation Foundation | SYSTEMS AND METHODS FOR HIGH REAGENT CONVERSION BY MULTIPLE SEPARATION FOR REAGENT FLOW REGULATION |
| CN111849563B (zh) * | 2020-07-30 | 2025-01-07 | 中冶焦耐(大连)工程技术有限公司 | 一种干式多通道煤气净化塔及其工作方法 |
| CN112054227B (zh) * | 2020-09-15 | 2021-11-26 | 上海捷氢科技有限公司 | 氢燃料电池车的氢气利用装置和方法 |
Family Cites Families (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB472629A (en) * | 1936-01-24 | 1937-09-24 | Distillers Co Yeast Ltd | Improvements in process and apparatus for carrying out exothermic reactions |
| JPS496824Y1 (pt) * | 1968-02-01 | 1974-02-18 | ||
| US3760933A (en) * | 1969-04-03 | 1973-09-25 | Martin Marietta Corp | Apparatus for rapidly coating surfaces with wet, particulate materials |
| DE2046324A1 (de) * | 1970-09-19 | 1972-03-23 | Berger, Heinz, 3470 Höxter | Vorrichtung zur Vernichtung der schädlichen Anteile der Abgase von Verbrennungsmotoren |
| US3791143A (en) * | 1971-11-10 | 1974-02-12 | Engelhard Min & Chem | Process and apparatus |
| FR2374946A1 (fr) * | 1976-12-22 | 1978-07-21 | United Technologies Corp | Appareil pour la mise en oeuvre de reactions catalytiques endothermiques |
| CA1095696A (en) * | 1976-12-22 | 1981-02-17 | Richard F. Buswell | Catalytic reaction apparatus |
| JPS5469105A (en) * | 1977-11-10 | 1979-06-02 | Genhiru Rubuobuichi Sutoriaru | Thermal decomposition of hydrocarbons |
| JPS55158170A (en) * | 1979-05-25 | 1980-12-09 | Ngk Spark Plug Co | High speed cutting ceramic tool |
| JPS5684789A (en) * | 1979-12-13 | 1981-07-10 | Toyo Eng Corp | High-temperature treatment of hydrocarbon-containing material |
| JPS5736784A (en) * | 1980-08-16 | 1982-02-27 | Mitsui Toatsu Chem Inc | Method of effectively utilizing exhaust gas in fuel-cell power generation device, and system for that |
| JPS5827787A (ja) * | 1981-08-10 | 1983-02-18 | Matsushita Electric Ind Co Ltd | カ−ボン抑制方法 |
| JPS58156350A (ja) * | 1982-03-12 | 1983-09-17 | Matsushita Electric Ind Co Ltd | 排ガス浄化装置 |
| US4451578A (en) * | 1982-04-26 | 1984-05-29 | United Technologies Corporation | Iron oxide catalyst for steam reforming |
| JPS6183602A (ja) * | 1984-09-29 | 1986-04-28 | Toshiba Corp | 改質装置 |
| JPS62132995A (ja) * | 1985-12-06 | 1987-06-16 | Toyo Eng Corp | 炭化水素高温処理用複層耐熱材料 |
| GB8629497D0 (en) * | 1986-12-10 | 1987-01-21 | British Petroleum Co Plc | Apparatus |
| US4820314A (en) * | 1987-02-11 | 1989-04-11 | International Fuel Cells Corporation | Fuel cell power plant reformer |
| US5070072A (en) * | 1987-05-04 | 1991-12-03 | Eastman Kodak Company | Conductive articles and processes for their preparation |
| JPH01315332A (ja) * | 1988-06-14 | 1989-12-20 | Mitsubishi Electric Corp | 反応装置 |
| JP2567055B2 (ja) * | 1988-08-31 | 1996-12-25 | 株式会社東芝 | 燃料改質装置 |
| JP2818171B2 (ja) * | 1988-09-09 | 1998-10-30 | 東洋シーシーアイ株式会社 | 炭化水素の水蒸気改質反応用触媒及びその製造方法 |
| US4900712A (en) | 1988-09-30 | 1990-02-13 | Prototech Company | Catalytic washcoat and method of preparation of the same |
| JPH02132764A (ja) * | 1988-11-14 | 1990-05-22 | Hitachi Ltd | 溶融炭酸塩型燃料電池 |
| JPH0431243Y2 (pt) * | 1989-03-02 | 1992-07-28 | ||
| US5266281A (en) * | 1989-09-16 | 1993-11-30 | Xytel Technologies Partnership | Catalytic reactor |
| DE69222633T2 (de) * | 1991-03-08 | 1998-04-23 | Chevron Chemical Co., San Francisco, Calif. | Reformierungsverfahren mit niedrigem schwefelgehalt |
| US5805973A (en) * | 1991-03-25 | 1998-09-08 | General Electric Company | Coated articles and method for the prevention of fuel thermal degradation deposits |
| JPH0593239A (ja) * | 1991-09-30 | 1993-04-16 | Kubota Corp | 炭化水素類の熱分解・改質反応用管 |
| JPH05245379A (ja) * | 1992-03-03 | 1993-09-24 | Tokyo Gas Co Ltd | サイクリック式ガス化触媒及びその製造方法 |
| US5888292A (en) * | 1992-04-27 | 1999-03-30 | Stellar Materials | Bonded aggregate composition and binders for the same |
| US5254318A (en) * | 1992-07-20 | 1993-10-19 | Stone & Webster Engineering Corporation | Lined reformer tubes for high pressure reformer reactors |
| JPH06111838A (ja) * | 1992-09-30 | 1994-04-22 | Toshiba Corp | 改質器、改質システム、及び燃料電池システム |
| JP3322933B2 (ja) * | 1993-03-05 | 2002-09-09 | 株式会社東芝 | 燃料改質器 |
| JP3409894B2 (ja) * | 1993-11-17 | 2003-05-26 | トヨタ自動車株式会社 | 排ガス浄化用触媒及び排ガス浄化方法 |
| GB9403198D0 (en) * | 1994-02-19 | 1994-04-13 | Rolls Royce Plc | A solid oxide fuel cell stack |
| US5470360A (en) * | 1994-03-10 | 1995-11-28 | International Fuel Cells Corporation | Fuel cell power plant reformer burner gas flow control system |
| JP3579155B2 (ja) * | 1995-01-18 | 2004-10-20 | 東芝セラミックス株式会社 | 焼成用道具材 |
| EP0728831B1 (de) * | 1995-02-17 | 2000-07-12 | Linde Aktiengesellschaft | Verfahren zum Spalten von Kohlenwasserstoffen und Vorrichtung |
| US5846915A (en) * | 1995-10-26 | 1998-12-08 | Clearwater, Inc. | Delayed breaking of gelled hydrocarbon fracturing fluid |
| US5733347A (en) * | 1995-12-27 | 1998-03-31 | International Fuel Cells Corp. | Compact fuel gas reformer assemblage |
| JPH10306362A (ja) * | 1997-04-28 | 1998-11-17 | Nippon Steel Hardfacing Co Ltd | 溶融金属に対する耐食性および耐剥離性が優れた複合溶射皮膜を形成した溶融金属浴用部材 |
-
1998
- 1998-11-10 US US09/190,855 patent/US6258330B1/en not_active Expired - Lifetime
-
1999
- 1999-11-10 AU AU28430/00A patent/AU2843000A/en not_active Abandoned
- 1999-11-10 CN CNB998144657A patent/CN1170623C/zh not_active Expired - Fee Related
- 1999-11-10 EP EP99969258A patent/EP1140322B1/en not_active Expired - Lifetime
- 1999-11-10 AU AU21486/00A patent/AU2148600A/en not_active Abandoned
- 1999-11-10 BR BR9915221-5A patent/BR9915221A/pt active Search and Examination
- 1999-11-10 DE DE69941093T patent/DE69941093D1/de not_active Expired - Lifetime
- 1999-11-10 KR KR1020017005739A patent/KR100563182B1/ko not_active Expired - Fee Related
- 1999-11-10 BR BR9915190-1A patent/BR9915190A/pt active Search and Examination
- 1999-11-10 JP JP2000582133A patent/JP2002529359A/ja active Pending
- 1999-11-10 KR KR1020017005861A patent/KR100599893B1/ko not_active Expired - Fee Related
- 1999-11-10 JP JP2000580738A patent/JP2002529895A/ja active Pending
- 1999-11-10 WO PCT/US1999/026558 patent/WO2000029092A1/en not_active Ceased
- 1999-11-10 WO PCT/US1999/026885 patent/WO2000027518A1/en not_active Ceased
- 1999-11-10 CN CN99813115A patent/CN1120214C/zh not_active Expired - Fee Related
- 1999-11-10 ID IDW00200101208A patent/ID29948A/id unknown
- 1999-11-10 EP EP99965796A patent/EP1148939B1/en not_active Expired - Lifetime
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| EP1140322A1 (en) | 2001-10-10 |
| US6258330B1 (en) | 2001-07-10 |
| AU2148600A (en) | 2000-05-29 |
| EP1140322B1 (en) | 2011-07-13 |
| JP2002529359A (ja) | 2002-09-10 |
| CN1325319A (zh) | 2001-12-05 |
| KR100563182B1 (ko) | 2006-03-27 |
| KR100599893B1 (ko) | 2006-07-13 |
| CN1170623C (zh) | 2004-10-13 |
| EP1148939B1 (en) | 2009-07-08 |
| CN1330570A (zh) | 2002-01-09 |
| BR9915190A (pt) | 2001-08-14 |
| ID29948A (id) | 2001-10-25 |
| EP1140322A4 (en) | 2005-01-19 |
| DE69941093D1 (de) | 2009-08-20 |
| JP2002529895A (ja) | 2002-09-10 |
| WO2000029092A1 (en) | 2000-05-25 |
| KR20010110296A (ko) | 2001-12-12 |
| WO2000027518A1 (en) | 2000-05-18 |
| KR20010089430A (ko) | 2001-10-06 |
| AU2843000A (en) | 2000-06-05 |
| EP1148939A4 (en) | 2005-01-19 |
| CN1120214C (zh) | 2003-09-03 |
| EP1148939A1 (en) | 2001-10-31 |
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