BRPI0406992A - Processo para oxidar parcialmente o propeno a ácido acrìlico em fase gasosa sob catálise heterogênea - Google Patents

Processo para oxidar parcialmente o propeno a ácido acrìlico em fase gasosa sob catálise heterogênea

Info

Publication number
BRPI0406992A
BRPI0406992A BR0406992-7A BRPI0406992A BRPI0406992A BR PI0406992 A BRPI0406992 A BR PI0406992A BR PI0406992 A BRPI0406992 A BR PI0406992A BR PI0406992 A BRPI0406992 A BR PI0406992A
Authority
BR
Brazil
Prior art keywords
acrylic acid
reaction
fixed catalyst
specific
propylene
Prior art date
Application number
BR0406992-7A
Other languages
English (en)
Inventor
Martin Dieterle
Jochen Petzoldt
Klaus Joachim M Ller-Engel
Hans Martan
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BRPI0406992A publication Critical patent/BRPI0406992A/pt
Publication of BRPI0406992B1 publication Critical patent/BRPI0406992B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"PROCESSO PARA OXIDAR PARCIALMENTE O PROPENO A áCIDO ACRìLICO EM FASE GASOSA SOB CATáLISE HETEROGêNEA". é divulgado um método para oxidação parcial em fase gasosa catalisada heterogeneamente do propeno a ácido acrílico, de acordo com a qual uma especificamente composta mistura gasosa de reação inicial contendo propeno e oxigênio é oxidada em um primeiro leito fixo de catalisador possuindo uma constante ou crescente atividade volume-específica na direção do fluxo em um primeiro estágio de reação. A mistura gasosa resultante do primeiro estágio de reação, a qual contém acroleína, é então oxidada em um segundo leito fixo de catalisador que possui uma crescente atividade volume-específica na direção do fluxo em um segundo estágio de reação. Os corpos moldados do catalisador, de ambos os leitos fixos de catalisador, possuem uma conformação anular e são respectivamente providos com uma composição de óxido de multimetais específica.
BRPI0406992-7B1A 2003-03-25 2004-03-20 Processo para oxidar parcialmente o propeno a ácido acrílico em fase gasosa sob catálise heterogênea BRPI0406992B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10313209.0 2003-03-25
DE10313209A DE10313209A1 (de) 2003-03-25 2003-03-25 Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure
PCT/EP2004/002931 WO2004085368A2 (de) 2003-03-25 2004-03-20 Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propen zu acrylsäure

Publications (2)

Publication Number Publication Date
BRPI0406992A true BRPI0406992A (pt) 2006-01-10
BRPI0406992B1 BRPI0406992B1 (pt) 2015-03-03

Family

ID=31197654

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0406992-7B1A BRPI0406992B1 (pt) 2003-03-25 2004-03-20 Processo para oxidar parcialmente o propeno a ácido acrílico em fase gasosa sob catálise heterogênea

Country Status (8)

Country Link
US (2) US7019168B2 (pt)
EP (1) EP1611078A2 (pt)
KR (1) KR101011065B1 (pt)
CN (1) CN100347144C (pt)
BR (1) BRPI0406992B1 (pt)
DE (1) DE10313209A1 (pt)
MY (1) MY140688A (pt)
WO (1) WO2004085368A2 (pt)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10313209A1 (de) * 2003-03-25 2004-03-04 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure
BRPI0413440A (pt) 2003-08-14 2006-10-17 Basf Ag processo para a preparação de (met) acroleìna e/ou de ácido (met) acrìlico por oxidação parcial em fase gasosa catalisada heterogeneamente
DE10353954A1 (de) 2003-11-18 2005-06-09 Basf Ag Verfahren zur Herstellung von Acrolein durch heterogen katalysierte partielle Gasphasenoxidation von Propen
CN1980878B (zh) * 2004-07-01 2010-09-29 巴斯福股份公司 通过丙烯的非均相催化部分气相氧化而制备丙烯醛、丙烯酸或其混合物的方法
KR101188502B1 (ko) * 2004-07-01 2012-10-08 바스프 에스이 프로판으로부터 아크롤레인, 아크릴산, 또는 이들의혼합물의 제조 방법
KR101206583B1 (ko) * 2004-07-01 2012-11-29 바스프 에스이 프로필렌의 불균질 촉매화 부분 기상 산화에 의한아크릴산의 제조 방법
US8431743B2 (en) 2004-07-01 2013-04-30 Basf Aktiengesellschaft Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene
DE102005062010A1 (de) * 2005-12-22 2007-06-28 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
DE102005062026A1 (de) * 2005-12-22 2007-06-28 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
US7897813B2 (en) * 2006-07-19 2011-03-01 Nippon Shokubai Co., Ltd. Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
DE102007004961A1 (de) 2007-01-26 2008-07-31 Basf Se Verfahren zur Herstellung von Katalysatorformkörpern, deren Aktivmasse ein Multielementoxid ist
DE102007025869A1 (de) 2007-06-01 2008-07-03 Basf Se Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett
JP4277921B2 (ja) * 2007-06-05 2009-06-10 セイコーエプソン株式会社 アクチュエータ、光スキャナおよび画像形成装置
DE102007028333A1 (de) 2007-06-15 2008-12-18 Basf Se Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors
DE102008040093A1 (de) 2008-07-02 2008-12-18 Basf Se Verfahren zur Herstellung eines ringähnlichen oxidischen Formkörpers
DE102008040094A1 (de) 2008-07-02 2009-01-29 Basf Se Verfahren zur Herstellung eines oxidischen geometrischen Formkörpers
DE102008042060A1 (de) 2008-09-12 2009-06-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042064A1 (de) 2008-09-12 2010-03-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
DE102008042061A1 (de) 2008-09-12 2010-03-18 Basf Se Verfahren zur Herstellung von geometrischen Katalysatorformkörpern
WO2010038676A1 (ja) * 2008-09-30 2010-04-08 株式会社日本触媒 アクリル酸製造用の触媒および該触媒を用いたアクリル酸の製造方法
CN102076411B (zh) * 2008-09-30 2013-02-13 株式会社日本触媒 用于制备丙烯醛和/或丙烯酸的催化剂以及使用了该催化剂的丙烯醛和/或丙烯酸的制备方法
DE102008054586A1 (de) 2008-12-12 2010-06-17 Basf Se Verfahren zur kontinuierlichen Herstellung von geometrischen Katalysatorformkörpern K
DE102009047291A1 (de) 2009-11-30 2010-09-23 Basf Se Verfahren zur Herstellung von (Meth)acrolein durch heterogen katalysierte Gasphasen-Partialoxidation
DE102010040923A1 (de) 2010-09-16 2012-03-22 Basf Se Verfahren zur Herstellung von Acrylsäure aus Ethanol und Formaldehyd
DE102010048405A1 (de) 2010-10-15 2011-05-19 Basf Se Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein
DE102011076931A1 (de) 2011-06-03 2012-12-06 Basf Se Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base
DE102011084040A1 (de) 2011-10-05 2012-01-05 Basf Se Mo, Bi und Fe enthaltende Multimetalloxidmasse
DE102011079035A1 (de) 2011-07-12 2013-01-17 Basf Se Mo, Bi und Fe enthaltende Multimetalloxidmassen
CN103796752A (zh) 2011-07-12 2014-05-14 巴斯夫欧洲公司 含Mo、Bi和Fe的多金属氧化物物质
DE102012204436A1 (de) 2012-03-20 2012-10-04 Basf Se Thermisches Trennverfahren
DE102013202048A1 (de) 2013-02-07 2013-04-18 Basf Se Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist
KR101554318B1 (ko) 2013-05-24 2015-09-18 주식회사 엘지화학 아크롤레인 및 아크릴산 제조용 촉매와 이의 제조 방법
AR098595A1 (es) 2013-12-06 2016-06-01 Shell Int Research Deshidrogenación oxidativa de alcanos y/u oxidación de alquenos
DE102015209638A1 (de) 2015-05-27 2016-07-07 Basf Se Verfahren zur Herstellung eines Bismut und Wolfram enthaltenden Multielementoxids durch Co-Präzipitation
JP6799582B2 (ja) * 2015-08-24 2020-12-16 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ モノマー生成で使用するための材料の不活性度を決定する方法
WO2017035055A1 (en) * 2015-08-24 2017-03-02 Rohm And Haas Company Method of determining the inertness of materials for use in monomer production
DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
KR20230002897A (ko) 2020-04-21 2023-01-05 바스프 에스이 원소 Mo, W, V 및 Cu를 함유하는 촉매 활성 다원소 산화물의 제조 방법
EP3805194A1 (en) 2020-09-25 2021-04-14 Basf Se Method for producing a multimetal oxide catalyst under gas-tight conditions
WO2022090019A1 (de) 2020-10-29 2022-05-05 Basf Se Verfahren zur herstellung eines schalenkatalysators
WO2024037905A1 (de) 2022-08-16 2024-02-22 Basf Se Verfahren zur herstellung von vollkatalysatorformkörpern zur gasphasenoxidation eines alkens und/oder eines alkohols zu einem α,β-ungesättigtem aldehyd und/oder einer α,β-ungesättigten carbonsäure
CN120322292A (zh) 2022-12-07 2025-07-15 巴斯夫欧洲公司 用于制造含钼、钨、钒、铜和锑元素的催化活性多元素氧化物的方法
WO2025125092A1 (de) 2023-12-14 2025-06-19 Basf Se Verfahren zur herstellung eines die elemente mo, w, v, cu und sb enthaltenden katalytisch aktiven multielementoxids
WO2025172145A1 (de) 2024-02-16 2025-08-21 Basf Se Anorganische faser-haltiger multi-element-vollkatalysatorformkörper zur herstellung von ungesättigten aldehyden und ungesättigten carbonsäuren; dessen herstellungsverfahren sowie verwendung in der gasphasenoxidation
WO2025176520A1 (de) 2024-02-23 2025-08-28 Basf Se Verfahren zur herstellung eines ethylenisch ungesättigten aldehyds und/oder einer ethylenisch ungesättigten carbonsäure an einem katalysatorfestbett eines rohrbündelreaktors
WO2026017456A1 (de) 2024-07-15 2026-01-22 Basf Se Verfahren zur herstellung eines katalysators umfassend eine wasserbehandlung

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CA1299193C (en) 1986-07-17 1992-04-21 Gordon Gene Harkreader Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
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MY121878A (en) * 1999-03-10 2006-02-28 Basf Ag Method for the catalytic gas-phase oxidation of propene into acrylic acid
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US6620968B1 (en) 1999-11-23 2003-09-16 Rohm And Haas Company High hydrocarbon space velocity process for preparing unsaturated aldehydes and acids
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DE10313209A1 (de) * 2003-03-25 2004-03-04 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure

Also Published As

Publication number Publication date
KR20050115308A (ko) 2005-12-07
CN100347144C (zh) 2007-11-07
EP1611078A2 (de) 2006-01-04
WO2004085368A3 (de) 2004-11-04
BRPI0406992B1 (pt) 2015-03-03
US7019168B2 (en) 2006-03-28
CN1764628A (zh) 2006-04-26
DE10313209A1 (de) 2004-03-04
WO2004085368A2 (de) 2004-10-07
US20060135813A1 (en) 2006-06-22
KR101011065B1 (ko) 2011-01-25
MY140688A (en) 2010-01-15
US20040191953A1 (en) 2004-09-30

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Legal Events

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B15K Others concerning applications: alteration of classification

Free format text: A CLASSIFICACAO ANTERIOR ERA: C07C 57/05

Ipc: C07C 51/25 (2006.01), C07C 57/04 (2006.01)

B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 03/03/2015, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 19A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2714 DE 10-01-2023 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.