BRPI0419176B8 - composição de catalisadores de organocromo/metaloceno combinados para produzir resinas bimodais, método de fazer uma composição de catalisador e método de polimerizar olefinas - Google Patents

composição de catalisadores de organocromo/metaloceno combinados para produzir resinas bimodais, método de fazer uma composição de catalisador e método de polimerizar olefinas

Info

Publication number
BRPI0419176B8
BRPI0419176B8 BRPI0419176A BRPI0419176A BRPI0419176B8 BR PI0419176 B8 BRPI0419176 B8 BR PI0419176B8 BR PI0419176 A BRPI0419176 A BR PI0419176A BR PI0419176 A BRPI0419176 A BR PI0419176A BR PI0419176 B8 BRPI0419176 B8 BR PI0419176B8
Authority
BR
Brazil
Prior art keywords
organochrome
composition
combined
metallocene catalysts
making
Prior art date
Application number
BRPI0419176A
Other languages
English (en)
Inventor
Elizabeth A Benham
Gil R Hawley
Joel L Martin
Kathy S Collins
Max P Mcdaniel
Michael Jensen
Original Assignee
Chevron Phillips Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co filed Critical Chevron Phillips Chemical Co
Publication of BRPI0419176A publication Critical patent/BRPI0419176A/pt
Publication of BRPI0419176B1 publication Critical patent/BRPI0419176B1/pt
Publication of BRPI0419176B8 publication Critical patent/BRPI0419176B8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/01—Cp or analog bridged to a non-Cp X neutral donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63925—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

catalisadores de organocromo/metaloceno combinados para produzir resinas bimodais. esta invenção se refere ao campo de composições de catalisador de polimerização de olefina, e métodos para polimerização e co-polimerização de olefinas, incluindo métodos de polimerização utilizando uma composição de catalisador suportada. em um aspecto, a presente invenção abrange um catalisador compreendendo o produto de contato de pelo menos um composto de metaloceno, pelo menos um composto de organocromo, pelo menos um óxido sólido quimicamente tratado, e pelo menos um composto de organoalumínio.
BRPI0419176A 2004-11-04 2004-11-04 composição de catalisadores de organocromo/metaloceno combinados para produzir resinas bimodais, método de fazer uma composição de catalisador e método de polimerizar olefinas BRPI0419176B8 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2004/036650 WO2006052232A1 (en) 2004-11-04 2004-11-04 Organochromium/ metallocene combination catalyst for producing bimodal resins

Publications (3)

Publication Number Publication Date
BRPI0419176A BRPI0419176A (pt) 2007-12-18
BRPI0419176B1 BRPI0419176B1 (pt) 2015-04-14
BRPI0419176B8 true BRPI0419176B8 (pt) 2016-09-13

Family

ID=34959597

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0419176A BRPI0419176B8 (pt) 2004-11-04 2004-11-04 composição de catalisadores de organocromo/metaloceno combinados para produzir resinas bimodais, método de fazer uma composição de catalisador e método de polimerizar olefinas

Country Status (10)

Country Link
EP (1) EP1807456B1 (pt)
JP (1) JP2008519092A (pt)
CN (1) CN101080424B (pt)
AU (1) AU2004324873B2 (pt)
BR (1) BRPI0419176B8 (pt)
CA (1) CA2585199C (pt)
EG (1) EG26351A (pt)
ES (1) ES2395009T3 (pt)
MX (1) MX2007005413A (pt)
WO (1) WO2006052232A1 (pt)

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US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US20070254800A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
DE102007014621A1 (de) 2007-03-23 2008-09-25 Innogel Ag Verfahren zur Herstellung von Molekulargewichtsverteilungen mit kurzkettigem Anteil mittels Post-Reaktor Extrusion
SG10201403259SA (en) 2009-06-16 2014-10-30 Chevron Phillips Chemical Co Oligomerization of alpha olefins using metallocene-ssa catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends
EP2526131B1 (en) 2010-01-22 2014-04-16 Basell Polyolefine GmbH Ultra-high molecular weight polyethylene
EP2640757A4 (en) * 2010-11-19 2014-07-30 Exxonmobil Chem Patents Inc METHODS FOR PRODUCING POLYOLEFINS HAVING MULTIMODAL MOLECULAR WEIGHT DISTRIBUTION
US9725530B2 (en) * 2012-04-20 2017-08-08 East China University Of Science And Technology Supported metal oxide double active center polyethylene catalyst, process for preparing the same and use thereof
KR101483247B1 (ko) 2013-04-23 2015-01-16 주식회사 엘지화학 폴리올레핀 중합용 촉매의 제조 방법 및 폴리올레핀 제조방법
US10246528B2 (en) * 2014-01-09 2019-04-02 Chevron Phillips Chemical Company Lp Chromium (III) catalyst systems with activator-supports
GB201408616D0 (en) * 2014-05-15 2014-06-25 Scg Chemicals Co Ltd Solid-supported catalyst, use of the same and process for producing polymers
WO2015191290A1 (en) * 2014-06-13 2015-12-17 Exxonmobil Chemical Patents Inc. Multiple catalyst system and polymerization process for use thereof
US9422382B2 (en) 2014-06-13 2016-08-23 Exxonmobil Chemical Patents Inc. Multiple catalyst system and polymerization process for use thereof
KR101653356B1 (ko) 2014-10-17 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
KR101653357B1 (ko) 2014-11-06 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
WO2016093678A1 (ko) * 2014-12-12 2016-06-16 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법
US10329363B2 (en) 2015-03-23 2019-06-25 Exxonmobil Chemical Patents Inc. Group 6 transition metal catalyst compound and use thereof
US10618989B2 (en) * 2015-04-20 2020-04-14 Exxonmobil Chemical Patents Inc. Polyethylene composition
WO2017069854A1 (en) 2015-10-22 2017-04-27 Exxonmobil Chemical Patents Inc. Catalysts for the formation of multimodal polymers
CN110878130B (zh) * 2018-09-06 2023-04-07 中国石油化工股份有限公司 负载型铬和茂双金属催化剂、其制备方法及其应用
CN112552434B (zh) * 2019-09-25 2022-08-02 中国石油天然气股份有限公司 一种多中心负载型催化剂及其制备方法与应用
CN112552437B (zh) * 2019-09-25 2022-12-02 中国石油天然气股份有限公司 一种铬钼双中心负载型催化剂及其制备方法与应用
CN116139890A (zh) * 2023-04-24 2023-05-23 北京宇极科技发展有限公司 一种硼元素造孔的高比表面积铬基催化剂和高比例z-含氟烯烃/e-含氟烯烃的制备方法

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Also Published As

Publication number Publication date
WO2006052232A1 (en) 2006-05-18
EG26351A (en) 2013-08-26
BRPI0419176A (pt) 2007-12-18
CA2585199C (en) 2013-01-08
AU2004324873A1 (en) 2006-05-18
BRPI0419176B1 (pt) 2015-04-14
EP1807456B1 (en) 2012-07-11
WO2006052232A9 (en) 2008-02-07
CN101080424B (zh) 2011-11-09
AU2004324873B2 (en) 2011-08-11
MX2007005413A (es) 2007-07-13
CA2585199A1 (en) 2006-05-18
JP2008519092A (ja) 2008-06-05
ES2395009T3 (es) 2013-02-07
CN101080424A (zh) 2007-11-28
EP1807456A1 (en) 2007-07-18

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