ES2250736T3 - Elastomeros termoplasticos y procedimiento para fabricarlos. - Google Patents
Elastomeros termoplasticos y procedimiento para fabricarlos.Info
- Publication number
- ES2250736T3 ES2250736T3 ES02796151T ES02796151T ES2250736T3 ES 2250736 T3 ES2250736 T3 ES 2250736T3 ES 02796151 T ES02796151 T ES 02796151T ES 02796151 T ES02796151 T ES 02796151T ES 2250736 T3 ES2250736 T3 ES 2250736T3
- Authority
- ES
- Spain
- Prior art keywords
- elastomeric copolymer
- thermoplastic
- gas
- phase
- elastomeros
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/005—Drying oils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Laminated Bodies (AREA)
Abstract
Un procedimiento para producir una composición de elastómero termoplástico, comprendiendo dicho procedimiento: sintetizar un copolímero elastomérico polimerizando etileno, una a-olefina y, opcionalmente, un monómero de dieno dentro de la fase gaseosa en presencia de un dispersante de negro de carbón para así producir un copolímero elastomérico en fase gaseosa que tiene negro de carbón dispersado; mezclar el copolímero elastomérico en fase gaseosa con un polímero termoplástico para formar una mezcla del copolímero elastomérico y del polímero termoplástico; y vulcanizar dinámicamente el copolímero elastomérico en fase gaseosa dentro de la mezcla del copolímero elastomérico y del polímero termoplástico. en el que dicho copolímero elastomérico en fase gaseosa tiene una viscosidad de Mooney (ML (1+4 a 125ºC)) de 80 a 450.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US34909902P | 2002-01-15 | 2002-01-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2250736T3 true ES2250736T3 (es) | 2006-04-16 |
Family
ID=23370897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES02796151T Expired - Lifetime ES2250736T3 (es) | 2002-01-15 | 2002-12-26 | Elastomeros termoplasticos y procedimiento para fabricarlos. |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US7868082B2 (es) |
| EP (1) | EP1419183B2 (es) |
| JP (1) | JP5216182B2 (es) |
| KR (1) | KR20040082370A (es) |
| CN (1) | CN1308357C (es) |
| AT (2) | ATE312123T1 (es) |
| AU (1) | AU2002360862A1 (es) |
| BR (1) | BR0212486A (es) |
| CA (1) | CA2451079A1 (es) |
| CZ (1) | CZ2004577A3 (es) |
| DE (2) | DE60228507D1 (es) |
| ES (1) | ES2250736T3 (es) |
| IL (1) | IL162889A0 (es) |
| MX (1) | MXPA04002355A (es) |
| TW (1) | TW200424223A (es) |
| WO (1) | WO2003059963A1 (es) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7868082B2 (en) | 2002-01-15 | 2011-01-11 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomers and process for making same |
| US7737205B2 (en) | 2003-07-28 | 2010-06-15 | Dow Global Technologies Inc | Thermoplastic vulcanizates and process to prepare them |
| DE602004024215D1 (de) * | 2003-09-17 | 2009-12-31 | Exxonmobil Chem Patents Inc | Ellungsverfahren dafür |
| CN101027357B (zh) * | 2004-07-27 | 2012-07-11 | 陶氏环球技术有限责任公司 | 热塑性硫化橡胶及其制备方法 |
| US20060235107A1 (en) * | 2005-04-15 | 2006-10-19 | 3M Innovative Properties Company | Method of reusing flexible mold and microstructure precursor composition |
| US7622528B2 (en) * | 2005-06-27 | 2009-11-24 | Exxonmobil Chemical Patents Inc. | Process for preparing thermoplastic elastomers by dynamic vulcanization |
| US20070112139A1 (en) * | 2005-11-14 | 2007-05-17 | Ellul Maria D | Peroxide-cured thermoplastic vulcanizates and process for making the same |
| US7655727B2 (en) | 2005-12-09 | 2010-02-02 | Exxonmobil Chemical Patents Inc. | Method for preparing thermoplastic vulcanizates with improved extrusion surfaces |
| US8039526B2 (en) * | 2006-04-05 | 2011-10-18 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates including nanoclays and processes for making the same |
| CN101583476A (zh) * | 2006-04-19 | 2009-11-18 | 陶氏环球技术公司 | 在挤出机中共混材料的方法,制品和材料预混合 |
| RU2009102825A (ru) * | 2006-06-29 | 2010-08-10 | Дау Глобал Текнолоджиз, Инк. (Us) | Термопластичные изделия и способы их получения с использованием улучшенной маточной смеси |
| US8178625B2 (en) * | 2006-08-01 | 2012-05-15 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate composition |
| WO2008134173A1 (en) * | 2007-05-01 | 2008-11-06 | Advanced Elastomer Systems, L.P. | Method for preparing thermoplastic vulcanizates |
| JP5244371B2 (ja) * | 2007-11-15 | 2013-07-24 | 鬼怒川ゴム工業株式会社 | 熱可塑性エラストマー組成物および製造方法 |
| US8709316B2 (en) * | 2008-03-14 | 2014-04-29 | Dow Global Technologies Llc | Process for shaping polymeric articles |
| US9234093B2 (en) * | 2008-03-31 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizates |
| US8524793B2 (en) | 2008-06-18 | 2013-09-03 | Dow Global Technologies, Llc | Interpolymer compositions of ethylene, α-olefin and nonconjugated polyene, methods of making the same, and foam and articles prepared from the same |
| CN102197078B (zh) | 2008-08-28 | 2013-12-11 | 陶氏环球技术有限责任公司 | 用于注射吹塑的方法和组合物 |
| ES2495993T3 (es) * | 2010-05-13 | 2014-09-18 | Unilever N.V. | Tubo moldeado por inyección |
| RU2014138063A (ru) | 2012-02-21 | 2016-04-10 | Шлюмбергер Холдингз Лимитед | Волоконно-армированный эластомерный статор |
| US10071522B2 (en) | 2012-07-10 | 2018-09-11 | U.S. Farathane Corporation | Roof ditch molding process incorporating conformed shaping features in a molding fixture |
| US8955896B2 (en) * | 2012-07-10 | 2015-02-17 | U.S. Farathane Corporation | Tri-extruded roof ditch molding with hard and soft components including associated fastener system and method for heat forming the roof ditch molding |
| US10179435B2 (en) | 2012-07-10 | 2019-01-15 | U.S. Farathane Corporation | Roof ditch molding assembly and process with heated air assist |
| US10196508B2 (en) | 2014-10-24 | 2019-02-05 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate compositions |
| FR3062446B1 (fr) * | 2017-02-02 | 2020-07-31 | Tristone Flowtech Solutions Tfs | Conduite de circulation de fluide pour vehicule automobile, son procede de fabrication et son utilisation en tant que tuyau de refroidissement de fluide moteur de vehicule automobile |
| US10508179B2 (en) | 2017-02-28 | 2019-12-17 | Exxonmobil Chemical Patents Inc. | Thermoplastic vulcanizate prepared with oil-extended, bimodal metallocene-synthesized EPDM |
| WO2019013899A1 (en) | 2017-07-13 | 2019-01-17 | Exxonmobil Chemical Patents Inc. | POLYESTER COMPOSITIONS AND PROCESS FOR PRODUCING ARTICLES THEREFROM |
| WO2020005442A1 (en) * | 2018-06-29 | 2020-01-02 | Dow Global Technologies Llc | Thermoplastic vulcanizates modified polypropylene for subsea insulation |
| EP4176005A1 (en) * | 2020-07-02 | 2023-05-10 | Celanese International Corporation | Thermoplastic vulcanizate compositions containing metallocene multimodal copolymer rubber and processes for making same |
| JP2024534483A (ja) * | 2021-09-22 | 2024-09-20 | アランセオ・ネザーランズ・ベー・フェー | エチレン-α-オレフィン-非共役ジエンコポリマー及びポリマー鎖あたり高いジエン含量を有するそのブレンド |
| WO2023076448A1 (en) * | 2021-10-29 | 2023-05-04 | Celanese International Corporation | Extruder systems and processes thereof |
| WO2025059983A1 (zh) * | 2023-09-21 | 2025-03-27 | 无锡金通高纤股份有限公司 | 连续动态热交联聚烯烃弹性纤维及其制造方法 |
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| US5470900A (en) * | 1992-04-03 | 1995-11-28 | Sumitomo Chemical Company, Limited | Powder molding process using a thermoplastic elastomer powder |
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| EP0889090A1 (en) | 1997-07-04 | 1999-01-07 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomer vulcanizate |
| CA2334533A1 (en) | 1998-06-08 | 1999-12-16 | Advanced Elastomer Systems, L.P. | Polypropylene thermoplastic elastomer compositions having improved processing properties and physical property balance |
| US6214903B1 (en) * | 1998-06-16 | 2001-04-10 | Union Carbide Chemicals & Plastics Technology Corporation | Post-reactor process for treating polymers prepared in a gas phase polymerization in the presence of an inert particulate material |
| US6011128A (en) * | 1998-06-17 | 2000-01-04 | Union Carbide Chemicals & Plastics Technology Corporation | Process for conditioning a gas-phase reactor to produce an ethylene-propylene or ethylene-propylene-diene rubber |
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-
2002
- 2002-12-26 US US10/481,375 patent/US7868082B2/en not_active Expired - Lifetime
- 2002-12-26 KR KR10-2004-7000615A patent/KR20040082370A/ko not_active Withdrawn
- 2002-12-26 CA CA002451079A patent/CA2451079A1/en not_active Abandoned
- 2002-12-26 DE DE60228507T patent/DE60228507D1/de not_active Expired - Lifetime
- 2002-12-26 DE DE60207870T patent/DE60207870T3/de not_active Expired - Lifetime
- 2002-12-26 EP EP02796151A patent/EP1419183B2/en not_active Expired - Lifetime
- 2002-12-26 IL IL16288902A patent/IL162889A0/xx unknown
- 2002-12-26 ES ES02796151T patent/ES2250736T3/es not_active Expired - Lifetime
- 2002-12-26 MX MXPA04002355A patent/MXPA04002355A/es unknown
- 2002-12-26 AU AU2002360862A patent/AU2002360862A1/en not_active Abandoned
- 2002-12-26 CN CNB028153219A patent/CN1308357C/zh not_active Expired - Fee Related
- 2002-12-26 BR BR0212486-6A patent/BR0212486A/pt not_active Application Discontinuation
- 2002-12-26 JP JP2003560063A patent/JP5216182B2/ja not_active Expired - Fee Related
- 2002-12-26 CZ CZ2004577A patent/CZ2004577A3/cs unknown
- 2002-12-26 AT AT02796151T patent/ATE312123T1/de not_active IP Right Cessation
- 2002-12-26 AT AT05107223T patent/ATE405594T1/de not_active IP Right Cessation
- 2002-12-26 WO PCT/US2002/041908 patent/WO2003059963A1/en not_active Ceased
-
2003
- 2003-12-26 TW TW092137163A patent/TW200424223A/zh unknown
-
2005
- 2005-10-26 US US11/259,019 patent/US7696276B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP5216182B2 (ja) | 2013-06-19 |
| AU2002360862A1 (en) | 2003-07-30 |
| DE60207870T2 (de) | 2006-08-17 |
| ATE312123T1 (de) | 2005-12-15 |
| US20040171758A1 (en) | 2004-09-02 |
| EP1419183A4 (en) | 2004-09-22 |
| CA2451079A1 (en) | 2003-07-24 |
| JP2005514497A (ja) | 2005-05-19 |
| CN1538976A (zh) | 2004-10-20 |
| KR20040082370A (ko) | 2004-09-24 |
| WO2003059963A1 (en) | 2003-07-24 |
| US20060052538A1 (en) | 2006-03-09 |
| MXPA04002355A (es) | 2004-06-29 |
| US7696276B2 (en) | 2010-04-13 |
| EP1419183A1 (en) | 2004-05-19 |
| TW200424223A (en) | 2004-11-16 |
| CZ2004577A3 (cs) | 2004-11-10 |
| BR0212486A (pt) | 2004-08-24 |
| DE60207870D1 (de) | 2006-01-12 |
| US7868082B2 (en) | 2011-01-11 |
| DE60207870T3 (de) | 2011-12-15 |
| ATE405594T1 (de) | 2008-09-15 |
| IL162889A0 (en) | 2005-11-20 |
| CN1308357C (zh) | 2007-04-04 |
| EP1419183B1 (en) | 2005-12-07 |
| EP1419183B2 (en) | 2011-02-02 |
| DE60228507D1 (de) | 2008-10-02 |
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