BRPI0505407A - processo para preparação de álcoois a partir de olefinas por meio de hidroformilação e hidrogenação - Google Patents
processo para preparação de álcoois a partir de olefinas por meio de hidroformilação e hidrogenaçãoInfo
- Publication number
- BRPI0505407A BRPI0505407A BRPI0505407-9A BRPI0505407A BRPI0505407A BR PI0505407 A BRPI0505407 A BR PI0505407A BR PI0505407 A BRPI0505407 A BR PI0505407A BR PI0505407 A BRPI0505407 A BR PI0505407A
- Authority
- BR
- Brazil
- Prior art keywords
- hydrogenation
- cobalt
- hydroformylation
- olefins
- organic phase
- Prior art date
Links
- 238000005984 hydrogenation reaction Methods 0.000 title abstract 4
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 150000001298 alcohols Chemical class 0.000 title abstract 2
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 239000012074 organic phase Substances 0.000 abstract 3
- -1 aliphatic alcohols Chemical class 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000001868 cobalt Chemical class 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000001869 cobalt compounds Chemical class 0.000 abstract 1
- XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical class [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 abstract 1
- 229910000001 cobalt(II) carbonate Inorganic materials 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA PREPARAçãO DE áLCOOIS A PARTIR DE OLEFINAS POR MEIO DE HIDROFORMILAçãO E HIDROGENAçãO". A presente invenção refere-se a um processo para preparação de álcoois alifáticos com 7 até 25 átomos de carbono, abrangendo as etapas: a) hidroformilação catalisada com cobalto de olefinas com 7 até 24 átomos de carbono, b) tratamento da mistura de hidroformilação com gases contendo oxigênio em presença de soluções aquosas ácidas de sal de cobalto(II), c) separação da mistura de b) em uma fase aquosa contendo sais de cobalto e uma fase orgânica contendo os aldeídos alifáticos e d) hidrogenação da fase orgânica contendo aldeído, sendo que a fase orgânica de c) é tratada com um agente de adsorção antes da hidrogenação d) para separação de compostos de cobalto.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004059292A DE102004059292A1 (de) | 2004-12-09 | 2004-12-09 | Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0505407A true BRPI0505407A (pt) | 2006-09-12 |
| BRPI0505407B1 BRPI0505407B1 (pt) | 2016-01-19 |
Family
ID=35911332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0505407A BRPI0505407B1 (pt) | 2004-12-09 | 2005-12-07 | processo para preparação de álcoois a partir de olefinas por meio de hidroformilação e hidrogenação |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7154012B2 (pt) |
| EP (1) | EP1669337B1 (pt) |
| JP (1) | JP5382978B2 (pt) |
| CN (1) | CN100450985C (pt) |
| BR (1) | BRPI0505407B1 (pt) |
| DE (2) | DE102004059292A1 (pt) |
| SG (1) | SG123664A1 (pt) |
| TW (1) | TWI392665B (pt) |
Families Citing this family (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10058383A1 (de) | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
| AU2002327859B2 (en) * | 2001-09-26 | 2007-08-09 | Evonik Degussa Gmbh | Phthalic acid alkylester mixtures with controlled viscosity |
| DE10149348A1 (de) | 2001-10-06 | 2003-04-10 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefin mit Palladiumcarbenverbindungen |
| DE10220801A1 (de) * | 2002-05-10 | 2003-11-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Rhodium-katalysierten Hydroformylierung von Olefinen unter Reduzierung der Rhodiumverluste |
| DE10225565A1 (de) | 2002-06-10 | 2003-12-18 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen |
| CN1290814C (zh) | 2002-08-31 | 2006-12-20 | 奥克森诺奥勒芬化学股份有限公司 | 通过烯属不饱和化合物的加氢甲酰基化制备醛的方法,该方法在环状碳酸酯存在的条件下由未改性的金属配合物催化 |
| RU2337090C2 (ru) | 2002-08-31 | 2008-10-27 | Оксено Олефинхеми Гмбх | Способ гидроформилирования олефиновых соединений в присутствии циклических эфиров угольной кислоты |
| DE10257499A1 (de) | 2002-12-10 | 2004-07-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Olefinen durch katalytische Spaltung von 1-Alkoxyalkanen |
| DE10329042A1 (de) * | 2003-06-27 | 2005-01-13 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 1-Octen aus Crack-C4 |
| DE10359628A1 (de) * | 2003-12-18 | 2005-07-21 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Herstellung von 1-Olefinen aus 2-Hydroxyalkanen |
| DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
| DE10360772A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Organoacylphosphiten |
| DE102004033410A1 (de) * | 2004-02-14 | 2005-09-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen |
| DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
| DE102004021128A1 (de) * | 2004-04-29 | 2005-11-24 | Oxeno Olefinchemie Gmbh | Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator |
| DE102005036039A1 (de) | 2004-08-28 | 2006-03-02 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von 2,7-Octadienylderivaten |
| DE102004063673A1 (de) * | 2004-12-31 | 2006-07-13 | Oxeno Olefinchemie Gmbh | Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas |
| DE102005035816A1 (de) * | 2005-07-30 | 2007-02-01 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten |
| DE102005042464A1 (de) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
| DE102006040432A1 (de) * | 2006-08-29 | 2008-03-20 | Oxeno Olefinchemie Gmbh | Katalysator und Verfahren zur Herstellung von Isoolefinen |
| DE102007041380A1 (de) * | 2007-08-31 | 2009-03-05 | Evonik Oxeno Gmbh | Hydrierkatalysator und Verfahren zur Herstellung von Alkoholen durch Hydrierung von Carbonylverbindungen |
| WO2010079018A1 (en) * | 2009-01-08 | 2010-07-15 | Exxonmobil Chemical Patents Inc. | Improvements in or relating to alcohols |
| KR101206214B1 (ko) * | 2009-01-16 | 2012-12-03 | 주식회사 엘지화학 | 올레핀으로부터의 알코올을 제조하는 시스템 |
| DE102009001230A1 (de) | 2009-02-27 | 2010-09-02 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung und teilweiser Rückführung von Übergangsmetallen bzw. deren katalytisch wirksamen Komplexverbindungen aus Prozessströmen |
| KR101896721B1 (ko) | 2009-07-23 | 2018-09-07 | 에보닉 피브레 게엠베하 | 중합 용액으로 제조된 폴리이미드 막 |
| DE102009047351A1 (de) | 2009-12-01 | 2011-06-09 | Evonik Goldschmidt Gmbh | Komposit-Siliconmembranen mit hoher Trennwirkung |
| DE102010029924A1 (de) | 2010-06-10 | 2011-12-15 | Evonik Oxeno Gmbh | Verfahren zur Regenerierung von gebrauchten Hydrierkatalysatoren |
| DE102012202779A1 (de) | 2012-02-23 | 2013-08-29 | Evonik Oxeno Gmbh | Verfahren und Vorrichtung zur technischen Hydroformylierung von Isobuten und zum Auftrennen des Produktgemisches |
| WO2014056736A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung |
| DE102012223572A1 (de) | 2012-12-18 | 2014-06-18 | Evonik Industries Ag | Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren |
| KR101403823B1 (ko) * | 2013-02-13 | 2014-06-03 | 주식회사 엘지화학 | 올레핀으로부터의 알코올을 제조하는 장치 |
| DE102013203117A1 (de) | 2013-02-26 | 2014-08-28 | Evonik Industries Ag | Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen |
| US9375679B2 (en) | 2013-08-30 | 2016-06-28 | Haldex Brake Products Corporation | Air dryer assembly with manifold system |
| DE102014107374A1 (de) * | 2014-05-26 | 2015-11-26 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Entfernung von Metallen aus hochsiedenden Kohlenwasserstofffraktionen |
| JP7194629B2 (ja) * | 2019-03-29 | 2022-12-22 | 日揮触媒化成株式会社 | ニッケル触媒及びその製造方法 |
| CN115028520B (zh) * | 2021-03-05 | 2024-09-20 | 中国石油化工股份有限公司 | 氢甲酰化反应产物分离方法和氢甲酰化反应分离方法 |
| EP4234525B1 (de) | 2022-02-25 | 2024-01-31 | Evonik Operations GmbH | Verfahren zur hydrierung von aldehyden in mindestens zwei hydrierstufen |
| EP4234527B1 (de) | 2022-02-25 | 2024-01-31 | Evonik Operations GmbH | Verfahren zur hydrierung von c9-aldehyden in mindestens zwei hydrierstufen |
| EP4234528A1 (de) | 2022-02-25 | 2023-08-30 | Evonik Operations GmbH | Verfahren zur hydrierung von c13-aldehyden in mindestens zwei hydrierstufen |
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| US1387657A (en) * | 1921-03-31 | 1921-08-16 | Dennison Mfg Co | Tag |
| GB1387657A (en) | 1972-08-25 | 1975-03-19 | Davy Powergas Ltd | Hydroformylation process |
| JPS5841830A (ja) | 1981-09-07 | 1983-03-11 | Nissan Chem Ind Ltd | オキソ法によるアルコ−ルの製造方法 |
| US4670401A (en) * | 1985-01-25 | 1987-06-02 | Monell Chemical Senses Center | Axillary androstenol and dehydroepiandrosterone as fertile period onset indicators |
| US4931403A (en) * | 1985-01-25 | 1990-06-05 | Monell Chemical Senses Center | Axillary androstenol and dehydroepiandrosterone as fertile period onset indicators |
| JPS63196537A (ja) * | 1987-02-10 | 1988-08-15 | Kansai Coke & Chem Co Ltd | ヒドロホルミル化化合物の製造法 |
| DE3914817C2 (de) | 1989-05-05 | 1995-09-07 | Huels Chemische Werke Ag | Verfahren zur Oligomerisierung von Olefinen |
| JPH03253523A (ja) * | 1990-03-01 | 1991-11-12 | Mitsubishi Kasei Corp | 第8族貴金属の分離回収法 |
| GB9102513D0 (en) | 1991-02-06 | 1991-03-27 | Exxon Chemical Patents Inc | Hydrocarbon production |
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| DE19654340A1 (de) | 1996-12-24 | 1998-08-06 | Huels Chemische Werke Ag | Verfahren zur Herstellung von höheren Oxo-Alkoholen |
| US5935968A (en) * | 1997-03-17 | 1999-08-10 | Merck & Co., Inc. | Methods for treating polycystic ovary syndrome |
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| DE19842368A1 (de) * | 1998-09-16 | 2000-03-23 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von höheren Oxoalkoholen aus Olefingemischen durch zweistufige Hydroformylierung |
| DE19842370A1 (de) * | 1998-09-16 | 2000-03-23 | Oxeno Oelfinchemie Gmbh | Verfahren zur selektiven Hydrierung von Hydroformylierungsgemischen |
| DE19842369A1 (de) | 1998-09-16 | 2000-03-23 | Oxeno Oelfinchemie Gmbh | Verfahren zur Hydrierung von Hydroformylierungsgemischen |
| DE19842371A1 (de) * | 1998-09-16 | 2000-03-23 | Oxeno Oelfinchemie Gmbh | Verfahren zur Herstellung von höheren Oxo-Alkoholen aus Olefingemischen |
| JP4368454B2 (ja) | 1999-05-31 | 2009-11-18 | 協和発酵ケミカル株式会社 | アルコールの製造法 |
| US6548087B1 (en) * | 1999-07-12 | 2003-04-15 | Frances B. Kent | Nutritional supplement |
| DE19939491A1 (de) | 1999-08-20 | 2001-02-22 | Basf Ag | Kontinuierliches Verfahren zur Hydroformylierung von Olefinen mit 6 bis 20 Kohlenstoffatomen |
| DE10009207A1 (de) | 2000-02-26 | 2001-08-30 | Oxeno Olefinchemie Gmbh | Verbessertes Verfahren zur Hydroformylierung von Olefinen durch Reduzierung der Ameisensäurekonzentration |
| DE10014844B4 (de) * | 2000-03-24 | 2005-09-22 | Celanese Chemicals Europe Gmbh | Verfahren zur Wiedergewinnung von Rhodium aus den Produkten der Hydroformylierung |
| DE10034360A1 (de) * | 2000-07-14 | 2002-01-24 | Oxeno Olefinchemie Gmbh | Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen |
| DE10062448A1 (de) | 2000-12-14 | 2002-06-20 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydrierung von Hydroformylierungsgemischen |
| DE10135906A1 (de) * | 2001-07-24 | 2003-02-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von höheren Olefinen mit Kobaltverbindungen als Katalysator |
| DE10227995A1 (de) | 2002-03-15 | 2003-09-25 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen |
| CN100503542C (zh) * | 2002-03-15 | 2009-06-24 | 奥克森诺奥勒芬化学股份有限公司 | 烯烃的加氢甲酰基化方法 |
-
2004
- 2004-12-09 DE DE102004059292A patent/DE102004059292A1/de not_active Withdrawn
-
2005
- 2005-09-30 SG SG200506358A patent/SG123664A1/en unknown
- 2005-10-13 DE DE502005000856T patent/DE502005000856D1/de not_active Expired - Lifetime
- 2005-10-13 EP EP05109524A patent/EP1669337B1/de not_active Expired - Lifetime
- 2005-12-02 TW TW094142558A patent/TWI392665B/zh active
- 2005-12-07 BR BRPI0505407A patent/BRPI0505407B1/pt not_active IP Right Cessation
- 2005-12-08 US US11/296,310 patent/US7154012B2/en not_active Expired - Fee Related
- 2005-12-08 CN CNB2005101294592A patent/CN100450985C/zh not_active Expired - Fee Related
- 2005-12-09 JP JP2005356573A patent/JP5382978B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7154012B2 (en) | 2006-12-26 |
| CN100450985C (zh) | 2009-01-14 |
| JP2006160745A (ja) | 2006-06-22 |
| CN1817833A (zh) | 2006-08-16 |
| EP1669337A1 (de) | 2006-06-14 |
| JP5382978B2 (ja) | 2014-01-08 |
| EP1669337B1 (de) | 2007-06-13 |
| SG123664A1 (en) | 2006-07-26 |
| TWI392665B (zh) | 2013-04-11 |
| BRPI0505407B1 (pt) | 2016-01-19 |
| TW200633962A (en) | 2006-10-01 |
| DE502005000856D1 (de) | 2007-07-26 |
| DE102004059292A1 (de) | 2006-06-14 |
| US20060129004A1 (en) | 2006-06-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B25D | Requested change of name of applicant approved |
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