BRPI0602678A - aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalìtico fluido em baixa severidade e processo de preparo do mesmo - Google Patents

aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalìtico fluido em baixa severidade e processo de preparo do mesmo

Info

Publication number
BRPI0602678A
BRPI0602678A BRPI0602678-8A BRPI0602678A BRPI0602678A BR PI0602678 A BRPI0602678 A BR PI0602678A BR PI0602678 A BRPI0602678 A BR PI0602678A BR PI0602678 A BRPI0602678 A BR PI0602678A
Authority
BR
Brazil
Prior art keywords
additive
maximization
low
additives
molecules
Prior art date
Application number
BRPI0602678-8A
Other languages
English (en)
Inventor
Lam Yiu Lau
Raquel Bastiani
Claudia Maria De Macer Batiata
Original Assignee
Petroleo Brasileiro Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa filed Critical Petroleo Brasileiro Sa
Priority to BRPI0602678-8A priority Critical patent/BRPI0602678B1/pt
Priority to US11/714,117 priority patent/US7691768B2/en
Priority to ES07252799.7T priority patent/ES2654862T3/es
Priority to EP07252799.7A priority patent/EP1878491B1/en
Priority to PT72527997T priority patent/PT1878491T/pt
Publication of BRPI0602678A publication Critical patent/BRPI0602678A/pt
Publication of BRPI0602678B1 publication Critical patent/BRPI0602678B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

ADITIVO PARA MAXIMIZAçãO DE GLP E PROPENO ADEQUADO A OPERAçãO DA UNIDADE DE CRAQUEAMENTO CATALìTICO FLUIDO EM BAIXA SEVERIDADE E PROCESSO DE PREPARO DO MESMO A presente invenção diz respeito a um processo para preparação e modificação de aditivos, a base de zeólita com alta relação sílica-alumina (SAR) como a ZSM-5, com a finalidade de aumentar os rendimento de propeno e GLP, em operações de FCC de baixa severidade, que visam maximizar a produção de destilados médios de baixa aromaticidade e minimizar o craqueamento de moléculas na faixa do LCO. Os aditivos desenvolvidos nesta patente garantem o aumenta do rendimento de olefinas leves sem alterar o rendimento e a qualidade do LCO produzido, diferentemente dos aditivos produzidos por outros processos encontradas no estado-da-técnica. O processo inovador compreende as ações surpreendentes das terras-raras (RE) nos sítios ativos da zeólita, que de um lado bloqueiam parcialmente seus poros e, assim, dificultam o craqueamento de moléculas da faixa dos destilados médios, que ocorre preferencialmente a baixas temperaturas de reação, e de outro lado conserva sítios restantes bastante ativos, o suficiente para craquear moléculas menores na faixa de gasolina, garantindo um aumento global em olefinas leves e permitindo que o aditivo desenvolvido possa ser utilizado industrialmente em operações de maximização de destilados médios na unidade de FCC. Esse novo aditivo pode ser obtido a partir da modificação de qualquer aditivo comercial a base de zeólita do tipo ZSM-5.
BRPI0602678-8A 2006-07-14 2006-07-14 Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo BRPI0602678B1 (pt)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BRPI0602678-8A BRPI0602678B1 (pt) 2006-07-14 2006-07-14 Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo
US11/714,117 US7691768B2 (en) 2006-07-14 2007-03-06 Additive to maximize GLP and propene suitable for use in low-severity operations of a fluid catalytic cracking unit and its preparatory process
ES07252799.7T ES2654862T3 (es) 2006-07-14 2007-07-13 Aditivo para maximizar GLP y propileno adecuado para su uso en operaciones de baja gravedad de una unidad de craqueo catalítico fluido y su proceso de preparación
EP07252799.7A EP1878491B1 (en) 2006-07-14 2007-07-13 Additive to maximize glp and propene suitable for use in low-severity operations of a fluid catalytic cracking unit its preparatory process
PT72527997T PT1878491T (pt) 2006-07-14 2007-07-13 Aditivo para maximizar glp e propeno adequados para uso em operações de severidade baixa de uma unidade de craqueamento catalítico em leito fluidizado e seu processo preparação

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0602678-8A BRPI0602678B1 (pt) 2006-07-14 2006-07-14 Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo

Publications (2)

Publication Number Publication Date
BRPI0602678A true BRPI0602678A (pt) 2008-03-04
BRPI0602678B1 BRPI0602678B1 (pt) 2015-09-01

Family

ID=38650105

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0602678-8A BRPI0602678B1 (pt) 2006-07-14 2006-07-14 Aditivo para maximização de glp e propeno adequado a operação da unidade de craqueamento catalítico fluido em baixa severidade e processo de preparo do mesmo

Country Status (5)

Country Link
US (1) US7691768B2 (pt)
EP (1) EP1878491B1 (pt)
BR (1) BRPI0602678B1 (pt)
ES (1) ES2654862T3 (pt)
PT (1) PT1878491T (pt)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015054757A1 (pt) * 2013-10-17 2015-04-23 Petróleo Brasileiro S.A.-Petrobras Processo de craqueamento catalítico fluido para a maximização de destilados médios

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI0705179B1 (pt) * 2007-10-10 2016-10-11 Petróleo Brasileiro S A Petrobras aditivo para maximizar olefinas leves em fcc e processo para preparação do mesmo
WO2010014606A2 (en) 2008-07-28 2010-02-04 Intercat, Inc. Composition and methods for preferentially increasing yields of one or more selected hydrocarbon products
BRPI0803617A2 (pt) * 2008-09-19 2010-06-15 Petroleo Brasileiro Sa Aditivo com sistema múltiplo de zeólitas e método de preparo
BRPI0805566B1 (pt) 2008-12-18 2018-02-14 Petróleo Brasileiro S/A - Petrobras Processo integrado para a fabricação de olefinas e intermediários para a produção de amônia e uréia
US9284492B2 (en) 2012-05-25 2016-03-15 Saudi Arabian Oil Company Catalyst for enhanced propylene in fluidized catalytic cracking
EP2877281B1 (en) 2012-07-24 2021-08-18 Indian Oil Corporation Ltd Catalyst composition for fluid catalytic cracking, process for preparing the same and use thereof
CN104229824B (zh) * 2013-06-18 2016-11-02 中国石油天然气股份有限公司 一种酸碱耦合制备等级孔zsm-5分子筛的方法
JP6032219B2 (ja) * 2014-01-24 2016-11-24 トヨタ自動車株式会社 運転支援装置
EP3277779A4 (en) * 2015-03-31 2018-09-26 Hindustan Petroleum Corporation Ltd. Fluid catalytic cracking process
EP3135373A1 (en) * 2015-08-24 2017-03-01 INDIAN OIL CORPORATION Ltd. Preparation and composition of a fluid catalytic cracking catalyst additive with lower phosphate content for enhanced lpg yield
CN108365230B (zh) * 2018-01-04 2020-10-27 中国科学院大学 活性位点与空气电极结构结合的普适性制备方法及应用
EP3800232A3 (en) 2019-10-04 2021-06-30 Indian Oil Corporation Limited Fluid catalytic cracking additive composition for enhancing gasoline octane barrel and a process of preparation thereof
CN117399064B (zh) * 2022-07-08 2025-11-18 中国石油天然气股份有限公司 用于废塑料裂解的催化剂及其制备方法与应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4309279A (en) * 1979-06-21 1982-01-05 Mobil Oil Corporation Octane and total yield improvement in catalytic cracking
US4368114A (en) * 1979-12-05 1983-01-11 Mobil Oil Corporation Octane and total yield improvement in catalytic cracking
CA1202295A (en) * 1982-09-28 1986-03-25 Joseph N. Miale Method of producing a zeolite containing occluded multimetalite and the product of such a method
US5179054A (en) * 1987-12-28 1993-01-12 Mobil Oil Corporation Layered cracking catalyst and method of manufacture and use thereof
US4973399A (en) * 1989-11-03 1990-11-27 Mobil Oil Corporation Catalytic cracking of hydrocarbons
CN1034223C (zh) 1993-03-29 1997-03-12 中国石油化工总公司 制取低碳烯烃的裂解催化剂
EP0697247B1 (en) * 1994-07-15 1999-09-29 Shell Internationale Researchmaatschappij B.V. Process for the conversion of hydrocarbonaceous feedstock
CN1156555C (zh) * 2000-08-10 2004-07-07 中国石油化工集团公司 一种催化裂化助剂及其制备方法
JP4112943B2 (ja) * 2002-10-28 2008-07-02 出光興産株式会社 炭化水素の接触分解によるオレフィンの製造方法
DE60319940T2 (de) * 2002-12-10 2008-06-26 Haldor Topsoe A/S Verfahren zur katalytischen Dehydrierung und Katalysator dafür
US7122494B2 (en) * 2003-02-05 2006-10-17 Exxonmobil Chemical Patents Inc. Combined cracking and selective hydrogen combustion for catalytic cracking
US20050227853A1 (en) * 2004-04-02 2005-10-13 Ranjit Kumar Catalyst compositions comprising metal phosphate bound zeolite and methods of using same to catalytically crack hydrocarbons
BRPI0504854A (pt) 2005-10-31 2007-09-18 Petroleo Brasileiro Sa processo de fcc para a maximização de destilados médios

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015054757A1 (pt) * 2013-10-17 2015-04-23 Petróleo Brasileiro S.A.-Petrobras Processo de craqueamento catalítico fluido para a maximização de destilados médios

Also Published As

Publication number Publication date
PT1878491T (pt) 2018-01-11
US7691768B2 (en) 2010-04-06
ES2654862T3 (es) 2018-02-15
US20080015105A1 (en) 2008-01-17
BRPI0602678B1 (pt) 2015-09-01
EP1878491A2 (en) 2008-01-16
EP1878491B1 (en) 2017-11-08
EP1878491A3 (en) 2008-03-05

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 14/07/2006, OBSERVADAS AS CONDICOES LEGAIS.