BRPI0612170A2 - processo para a polimerização de olefinas - Google Patents

processo para a polimerização de olefinas Download PDF

Info

Publication number
BRPI0612170A2
BRPI0612170A2 BRPI0612170-5A BRPI0612170A BRPI0612170A2 BR PI0612170 A2 BRPI0612170 A2 BR PI0612170A2 BR PI0612170 A BRPI0612170 A BR PI0612170A BR PI0612170 A2 BRPI0612170 A2 BR PI0612170A2
Authority
BR
Brazil
Prior art keywords
formula
olefins
optionally
compound
alkyl radical
Prior art date
Application number
BRPI0612170-5A
Other languages
English (en)
Inventor
Eleonora Ciaccia
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BRPI0612170A2 publication Critical patent/BRPI0612170A2/pt
Publication of BRPI0612170B1 publication Critical patent/BRPI0612170B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Processo para a polimerizaçio de olefinas. O presente invento descreve um processo multi-etapas compreendendo as seguintes etapas: etapa a) polimerizar propileno e opcionalmente um ou mais monómeros escolhidos dentre etileno ou a-olefinas de fórmula CH~2~=CHT^1^, em que T^1^ é um radical alquila C~2~-C~10~ na presença de um sistema catalítico suportado em um suporte inerte, compreendendo: i) um ou mais compostos metalocenos de fórmula (I). ii) um alumoxano ou um composto capaz de formar um cátion alquilmetaloceno; e opcionalmente iii) um composto organo metálico; etapa b) contatar, sob condições de polimerização, em fase gasosa, propileno ou etileno com uma ou mais a-olefinas de fórmula CH~2~=CHT, em que T é hidrogênio ou um radical alquila C~1~-C~10~, e opcionalmente com um dieno não conjugado, na presença do polimero obtido na etapa a) e opcionalmente na presença de um composto organoalumínio adicional; desde que não seja produzido um homopolímero; em que o composto de fórmula (I) é descrito no pedido de patente.
BRPI0612170A 2005-03-23 2006-03-22 processo para a polimerização de olefinas BRPI0612170B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP05102357 2005-03-23
US66621705P 2005-03-29 2005-03-29
PCT/EP2006/060957 WO2006100269A1 (en) 2005-03-23 2006-03-22 Process for the polymerizatio of olefins

Publications (2)

Publication Number Publication Date
BRPI0612170A2 true BRPI0612170A2 (pt) 2010-10-19
BRPI0612170B1 BRPI0612170B1 (pt) 2017-02-21

Family

ID=39208705

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0612170A BRPI0612170B1 (pt) 2005-03-23 2006-03-22 processo para a polimerização de olefinas

Country Status (10)

Country Link
US (1) US7728086B2 (pt)
EP (1) EP1861436B1 (pt)
JP (1) JP5294842B2 (pt)
KR (1) KR101289946B1 (pt)
CN (1) CN101146836B (pt)
AU (1) AU2006226366A1 (pt)
BR (1) BRPI0612170B1 (pt)
RU (1) RU2392283C2 (pt)
WO (1) WO2006100269A1 (pt)
ZA (1) ZA200707614B (pt)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
JP5466826B2 (ja) * 2008-02-08 2014-04-09 日本ポリプロ株式会社 プロピレン／エチレン−αオレフィン系ブロック共重合体の製造方法
JP5315114B2 (ja) * 2009-04-03 2013-10-16 日本ポリプロ株式会社 プロピレン系重合体の製造方法及びその方法により製造されるプロピレン系重合体
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
EP3539993A1 (en) 2013-07-17 2019-09-18 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009472A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
KR101580591B1 (ko) 2014-06-10 2015-12-28 주식회사 엘지화학 프로필렌계 엘라스토머
CN105622795B (zh) * 2014-10-28 2019-02-19 中国石油化工股份有限公司 茂金属催化剂组合物及其制备方法
EP3064514B1 (en) 2015-03-02 2018-01-10 Borealis AG C2C3 random copolymer composition with improved balance between sealing initiation temperature and melting point
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10570219B2 (en) 2015-06-05 2020-02-25 Exxonmobil Chemical Patents Inc. Production of heterophasic polymers in gas or slurry phase
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US9738779B2 (en) * 2015-06-05 2017-08-22 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and sequential polymerization
US9725537B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. High activity catalyst supportation
US9920176B2 (en) 2015-06-05 2018-03-20 Exxonmobil Chemical Patents Inc. Single site catalyst supportation
CN107667139A (zh) * 2015-06-05 2018-02-06 埃克森美孚化学专利公司 多相共聚物和序列聚合
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9725569B2 (en) * 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. Porous propylene polymers
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US10077325B2 (en) 2015-06-05 2018-09-18 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10723821B2 (en) 2015-06-05 2020-07-28 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US9803037B1 (en) * 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US11059918B2 (en) 2016-05-27 2021-07-13 Exxonmobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
KR102282288B1 (ko) * 2017-04-06 2021-07-26 에스케이이노베이션 주식회사 공중합체 및 그 제조 방법
WO2019099250A1 (en) 2017-11-14 2019-05-23 Exxonmobil Chemical Patents Inc. (di)silicon bridged metallocenes that produce polyethylene broad molecular weight distribution and molecular weight
US11130827B2 (en) 2017-11-14 2021-09-28 Exxonmobil Chemical Patents Inc. Polyethylene compositions and articles made therefrom
US11214631B2 (en) 2017-11-14 2022-01-04 Exxonmobil Chemical Patents Inc. (Di)silicon bridged metallocenes that produce polyethylene with broad molecular weight distribution and high molecular weight
KR102375854B1 (ko) 2017-11-28 2022-03-17 주식회사 엘지화학 폴리프로필렌 및 그 제조방법
US12065560B2 (en) 2019-06-11 2024-08-20 Lg Chem, Ltd. Propylene-ethylene random copolymer

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4178272A (en) * 1977-03-02 1979-12-11 Eastman Kodak Company Hot-melt adhesvies for bonding polyethylene
DE3474673D1 (en) 1984-08-30 1988-11-24 Mitsui Petrochemical Ind 1-butene polymer and its use
AU6158390A (en) 1989-08-03 1991-03-11 Exxon Chemical Patents Inc. Very high molecular weight polyethylene
JPH0416853A (ja) 1990-05-11 1992-01-21 Citizen Watch Co Ltd 電子写真用感光体
JPH0416851A (ja) 1990-05-11 1992-01-21 Citizen Watch Co Ltd 電子写真用感光体
JPH0416854A (ja) 1990-05-11 1992-01-21 Citizen Watch Co Ltd 電子写真用感光体
JPH0431868A (ja) 1990-05-29 1992-02-04 Citizen Watch Co Ltd 電子写真用感光体
RU2118203C1 (ru) 1990-06-22 1998-08-27 Экксон Кэмикал Пейтентс Инк. Каталитическая система для получения полиолефинов и композиция, используемая для полимеризации олефинов
TW294669B (pt) * 1992-06-27 1997-01-01 Hoechst Ag
KR100314971B1 (ko) * 1993-05-25 2002-07-03 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀중합을위한지지된메탈로센촉매시스템,그의제조방법및용도
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
IT1269837B (it) 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
RU2153507C2 (ru) * 1994-06-24 2000-07-27 Эксон Кемикэл Пейтентс Инк. Каталитическая система для полимеризации олефинов, ее получение и способ полимеризации пропилена
KR100368194B1 (ko) * 1994-10-13 2003-04-03 니혼폴리올레핀 가부시키가이샤 폴리올레핀제조용촉매성분,당해촉매성분을포함하는폴리올레핀제조용촉매및당해촉매존재하의폴리올레핀의제조방법
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
JP3281389B2 (ja) 1995-06-08 2002-05-13 昭和電工株式会社 イオン性化合物およびその化合物を用いたオレフィン重合用触媒
TR199901635T2 (xx) 1996-11-15 2000-02-21 Montell Technology Company Bv Heterosiklik metalosenler ve polimerizasyon kataliz�rleri.
KR100624632B1 (ko) 1997-03-07 2006-09-15 타고르 게엠베하 메탈로센 및 그의 제조 방법
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
EP0980396B2 (en) 1998-03-05 2009-08-19 Basell Poliolefine Italia S.r.l. Polybutene-1 (co)polymers and process for their preparation
JP4031868B2 (ja) 1998-06-19 2008-01-09 株式会社日立コミュニケーションテクノロジー 通信装置、基地局および通信方法
AU1272100A (en) * 1998-11-25 2000-06-13 Targor Gmbh Metallocene monohalogenides
DE19917985A1 (de) 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
BR0014616A (pt) 1999-09-22 2002-06-18 Basell Technology Co Bv Sistema catalìtico e processo para a polimerização de olefinas
IT1314261B1 (it) * 1999-12-03 2002-12-06 Enichem Spa Composti metallocenici pontati, processo per la loro preparazione eloro uso come catalizzatori per la polimerizzazione di olefine.
US6444833B1 (en) * 1999-12-15 2002-09-03 Basell Technology Company Bv Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins
DE19962814A1 (de) 1999-12-23 2001-06-28 Targor Gmbh Neues Katalysatorsystem und dessen Verwendung
DE19962910A1 (de) 1999-12-23 2001-07-05 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen
BRPI0016723B1 (pt) * 1999-12-23 2018-02-27 Basell Polyolefine Gmbh. Metaloceno, sistema catalisador, e, processo para a copolimerização de propileno com etileno
WO2001047939A1 (en) 1999-12-28 2001-07-05 Basell Technology Company B.V. Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
WO2001062764A1 (en) * 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
DE60202524T2 (de) * 2001-05-21 2005-06-30 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
WO2003045964A1 (en) 2001-11-30 2003-06-05 Basell Polyolefine Gmbh Metallocene compounds and process for the preparation of propylene polymers
DE60132827D1 (de) 2001-12-10 2008-03-27 Exxon Chemical Patents Inc Metallocene und von ihnen abgeleitete katalysatorzusammensetzungen
WO2004005360A2 (en) 2002-07-09 2004-01-15 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60318616T2 (de) 2002-12-04 2009-01-08 Basell Polyolefine Gmbh Verfahren zur herstellung von1-buten-polymeren
JP4016851B2 (ja) 2003-02-20 2007-12-05 株式会社村田製作所 モジュール部品
JP4016853B2 (ja) 2003-02-28 2007-12-05 サクサ株式会社 ボタン電話システム、ボタン電話装置およびプログラム
JP4016854B2 (ja) 2003-03-04 2007-12-05 株式会社デンソー 演算増幅回路を有する半導体装置
US7390862B2 (en) * 2003-05-12 2008-06-24 Basell Polyolefine Gmbh Process for polymerizing 1-butene
WO2005023889A1 (en) * 2003-09-11 2005-03-17 Basell Polyolefine Gmbh Multistep process for preparing heterophasic propylene copolymers
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
JP2007528925A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ １−ヘキセンまたは高級α−オレフィンの重合方法
BRPI0508155A (pt) 2004-03-12 2007-08-07 Basell Polyolefine Gmbh sistema catalìtico para a polimerização de olefinas
DE102004027332A1 (de) * 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
RU2410388C2 (ru) 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends

Also Published As

Publication number Publication date
WO2006100269A1 (en) 2006-09-28
RU2007139099A (ru) 2009-04-27
ZA200707614B (en) 2008-10-29
JP5294842B2 (ja) 2013-09-18
KR20070117609A (ko) 2007-12-12
JP2008534706A (ja) 2008-08-28
EP1861436B1 (en) 2014-04-16
BRPI0612170B1 (pt) 2017-02-21
CN101146836A (zh) 2008-03-19
AU2006226366A1 (en) 2006-09-28
US20090259007A1 (en) 2009-10-15
KR101289946B1 (ko) 2013-07-26
RU2392283C2 (ru) 2010-06-20
EP1861436A1 (en) 2007-12-05
US7728086B2 (en) 2010-06-01
CN101146836B (zh) 2011-06-08

Similar Documents

Publication Publication Date Title
BRPI0612170A2 (pt) processo para a polimerização de olefinas
BR0207072A (pt) Processo para a polimerização de olefinas
BRPI0413961A (pt) processo multi-etapas para preparar copolìmeros heterofásicos de propileno
BR112014013764A2 (pt) processo para a produção de polietileno bimodal na presença desse sistema de catalisador
AR070087A1 (es) Proceso para polimerizar polimeros a base de olefinas
ES2479665T3 (es) Procedimiento para la preparación de composiciones de polímeros de propileno, con resistencia al impacto
WO2008014217A3 (en) Fluorenyl catalyst compositions and olefin polymerization process
WO2009091480A3 (en) Production of propylene-based polymers
BR0006002A (pt) Componentes catalìticos catalisadores e processo a polimerização de olefinas.
BR112013008476A2 (pt) sistema de catalisador de metaloceno ligado em ponte com hidrogênio permutável e efeitos de comonômero
CN105377904A (zh) 金属茂和由其衍生的催化剂组合物
WO2011019474A3 (en) Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
BR112014012427A2 (pt) processo para a preparação de um copolímero de etileno
TW200704656A (en) Aminosilane compound, catalyst component and catalyst for olefin polymerization, and process for producing olefin polymer using the same
BRPI0513108A (pt) processo para produzir polìmeros de buteno-1 fracionáveis
BRPI0518520A2 (pt) composiÇÕes de butila vulcanizÁveis por peràxido éteis para artigos de borracha
WO2012134715A3 (en) Branched vinyl terminated polymers and methods for production thereof
EP1857468A4 (en) PROCESS FOR PREPARING A STABILIZED POLYMER
TW200704651A (en) Process for production of propylene copolymers
JP2009504888A5 (pt)
WO2009141831A3 (en) A catalyst system for polymerization of olefins
EP1939229A3 (en) Antistatic composition for polymerization or copolymerization of olefins in the gas phase, olefin polymerization or copolymerization process in the gas phase, and olefin polymer or copolymer thereof
NO20032999D0 (no) Fremgangsmåte til fremstilling av amorfe polyolefiner med höy molekylvekt,for anvendelse som drag-reduserende midler
BR0306719A (pt) Catalisador de polimerização, processo para a polimerização de olefinas, produto e processo para moldagem a sopro
BRPI0518990A2 (pt) componente de catalisador sàlido, catalisador para a polimerizaÇço de olefinas, e, processo para produzir um polÍmero ou copolÍmero de olefina

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]