BRPI0710948A2 - Catalisadores de metal de transição fluorados e formação dos mesmos - Google Patents

Catalisadores de metal de transição fluorados e formação dos mesmos Download PDF

Info

Publication number
BRPI0710948A2
BRPI0710948A2 BRPI0710948-2A BRPI0710948A BRPI0710948A2 BR PI0710948 A2 BRPI0710948 A2 BR PI0710948A2 BR PI0710948 A BRPI0710948 A BR PI0710948A BR PI0710948 A2 BRPI0710948 A2 BR PI0710948A2
Authority
BR
Brazil
Prior art keywords
transition metal
formation
same
inorganic support
support composition
Prior art date
Application number
BRPI0710948-2A
Other languages
English (en)
Inventor
Lopez Margarito
Marin Vladimir
Abbas Razavi
Original Assignee
Fina Technology, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology, Inc. filed Critical Fina Technology, Inc.
Publication of BRPI0710948A2 publication Critical patent/BRPI0710948A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)

Abstract

CATALISADORES DE METAL DE TRANSIÇçO FLUORADOS E FORMAÇçO DOS MESMOS. Sistemas de catalisadores suportados e métodos de formar os mesmos estão geralmente descritos no presente. Os métodos geralmente incluem prover uma composição de suporte inorgânico, em que a composição de suporte inorgânico inclui uma seqüência de ligação selecionada de Si-O-AI-F, F-Si-O-AI, F-Si-O-AI-F e combinações das mesmas, e contatar a composição de suporte inorgânico com um composto de metal de transição para formar um sistema de catalisador suportado, em que o composto de metal de transição é representado pela fórmula [L]~m~M[A]~n~; em que L é um ligante volumoso, A é um grupo de saída, M é um metal de transição e m e n são de tal forma que a uma valência de ligante total corresponde à valência de metal de transição.
BRPI0710948-2A 2006-04-28 2007-04-27 Catalisadores de metal de transição fluorados e formação dos mesmos BRPI0710948A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/413,791 2006-04-28
US11/413,791 US20070255022A1 (en) 2006-04-28 2006-04-28 Fluorinated transition metal catalysts and formation thereof
PCT/US2007/010435 WO2007127465A2 (en) 2006-04-28 2007-04-27 Fluorinated transition metal catalysts and formation thereof

Publications (1)

Publication Number Publication Date
BRPI0710948A2 true BRPI0710948A2 (pt) 2012-03-06

Family

ID=38649035

Family Applications (5)

Application Number Title Priority Date Filing Date
BRPI0711051-0A BRPI0711051A2 (pt) 2006-04-28 2007-04-27 catalisadores de metais de transição fluorados e formação dos mesmos
BRPI0710969-5A BRPI0710969A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados
BRPI0710970-9A BRPI0710970A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados
BRPI0710954-7A BRPI0710954A2 (pt) 2006-04-28 2007-04-27 Processo para a produção de copolímero usando catalisadores de metais de transição fluorados
BRPI0710948-2A BRPI0710948A2 (pt) 2006-04-28 2007-04-27 Catalisadores de metal de transição fluorados e formação dos mesmos

Family Applications Before (4)

Application Number Title Priority Date Filing Date
BRPI0711051-0A BRPI0711051A2 (pt) 2006-04-28 2007-04-27 catalisadores de metais de transição fluorados e formação dos mesmos
BRPI0710969-5A BRPI0710969A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados
BRPI0710970-9A BRPI0710970A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados
BRPI0710954-7A BRPI0710954A2 (pt) 2006-04-28 2007-04-27 Processo para a produção de copolímero usando catalisadores de metais de transição fluorados

Country Status (8)

Country Link
US (6) US20070255022A1 (pt)
EP (5) EP2013242A4 (pt)
JP (5) JP2009535461A (pt)
KR (5) KR20080111041A (pt)
BR (5) BRPI0711051A2 (pt)
CA (5) CA2644744A1 (pt)
MX (5) MX2008011108A (pt)
WO (1) WO2007127465A2 (pt)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1749842A1 (en) * 2005-08-03 2007-02-07 Total Petrochemicals Research Feluy Transition metal complexes supported on activating fluorinated support
US20070255026A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Process for polyolefin production using fluorinated transition metal catalysts having a low pH
US8003739B2 (en) * 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
ES2627289T3 (es) * 2007-08-29 2017-07-27 Albemarle Corporation Activadores de catalizador de aluminoxano derivados de agentes precursores de catión dialquilaluminio y uso de los mismos en catalizadores y polimerización de olefinas
US8138285B2 (en) * 2007-10-26 2012-03-20 Fina Technology, Inc. Fluorinated impregnated catalyst systems and methods of forming the same
JP5134928B2 (ja) 2007-11-30 2013-01-30 浜松ホトニクス株式会社 加工対象物研削方法
EP2235075B1 (en) * 2007-12-28 2012-08-08 Basell Poliolefine Italia S.r.l. Plastic tanks made from random copolymers of propylene and hexene-1
JP5325533B2 (ja) * 2008-10-29 2013-10-23 日本ポリプロ株式会社 プロピレン／エチレン−α−オレフィン系ブロック共重合体用重合触媒及びそれを用いるプロピレン系ブロック共重合体の製造方法
KR101149755B1 (ko) * 2009-01-06 2012-06-01 에스케이종합화학 주식회사 에틸렌-프로필렌-디엔 공중합체 제조방법
MX362816B (es) * 2009-06-16 2019-02-15 Chevron Phillips Chemical Co Lp Oligomerizacion de alfa olefinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
AU2015227408B2 (en) * 2009-06-16 2016-09-29 Chevron Phillips Chemical Company Lp Oligomerization of alpha olefins using metallocene-SSA catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends
KR200457978Y1 (ko) * 2009-11-23 2012-01-16 주식회사 청정에너지 엘이디 조명등
KR101271395B1 (ko) * 2009-12-21 2013-06-05 에스케이종합화학 주식회사 메탈로센 촉매를 이용한 에틸렌과 알파-올레핀의 공중합체를 제조하는 방법
JP5580963B2 (ja) * 2010-02-09 2014-08-27 日本ポリプロ株式会社 溶融紡糸型エレクトロスピニング用プロピレン系樹脂材料及び極細繊維の溶融紡糸方法
AU2011217940B2 (en) * 2010-02-22 2013-10-03 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
US8288487B2 (en) 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
US8993703B2 (en) * 2010-09-06 2015-03-31 Basell Poliolefine Italia S.R.L. Polypropylene-based terpolymers for films
EP2614094B1 (en) * 2010-09-06 2016-09-21 Basell Poliolefine Italia S.r.l. Propylene-based terpolymers for film
JP5606250B2 (ja) * 2010-09-29 2014-10-15 有限会社Ｔｎｅ 亜鉛メッキ鋼板の抵抗溶接方法及び亜鉛メッキ鋼板抵抗溶接用電極チップの再生方法
JP4916590B1 (ja) * 2010-12-01 2012-04-11 株式会社フジクラ 伝送ケーブル用絶縁電線及び伝送ケーブル
JP4916575B1 (ja) * 2010-12-01 2012-04-11 株式会社フジクラ 伝送ケーブル用絶縁電線及び伝送ケーブル
JP4916574B1 (ja) * 2010-12-01 2012-04-11 株式会社フジクラ 伝送ケーブル用絶縁電線及び伝送ケーブル
CN104810086B (zh) * 2010-12-01 2017-04-26 株式会社藤仓 绝缘电线和电缆
EP2759554A1 (en) 2013-01-23 2014-07-30 Total Research & Technology Feluy Process for producing olefin / 3-methyl-1-butene copolymers
EP2810883A1 (en) * 2013-06-06 2014-12-10 Basell Poliolefine Italia S.r.l. Propylene based terpolymer for containers
KR20160097254A (ko) 2013-12-06 2016-08-17 토탈 리서치 앤드 테크놀로지 펠루이 장쇄 분지된 폴리프로필렌
US9303106B1 (en) * 2014-10-17 2016-04-05 Chevron Phillips Chemical Company Lp Processes for preparing solid metallocene-based catalyst systems
EP3585822B1 (en) * 2017-02-21 2025-05-07 NTP Tec, LLC Processes for making polyisobutylene compositions
US11028192B2 (en) 2017-03-27 2021-06-08 Exxonmobil Chemical Patents Inc. Solution process to make ethylene copolymers
KR101959401B1 (ko) 2017-05-18 2019-07-05 주식회사 파나시아 배기가스 처리장치의 배출 세정액 내의 유해가스 제거 시스템 및 방법
CN113201086A (zh) * 2021-04-27 2021-08-03 上海欣鑫化工有限公司 一种聚烯烃共混物的催化剂体系与应用
CN118339205A (zh) * 2021-12-01 2024-07-12 道达尔能源一技术比利时公司 使用双催化剂组合物的聚合工艺

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1009406A3 (fr) * 1995-06-09 1997-03-04 Solvay Methode de regulation de procedes de synthese de produits chimiques.
FI104825B (fi) * 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
JP2001511215A (ja) * 1997-02-07 2001-08-07 エクソン・ケミカル・パテンツ・インク ポリエチレンマクロマーを組み入れるプロピレンポリマー
FR2769245B1 (fr) * 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
US6235918B1 (en) * 1998-07-29 2001-05-22 Northwestern University Supported organometallic catalysts for hydrogenation and Olefin Polymerization
CN1142190C (zh) * 1998-08-26 2004-03-17 埃克森化学专利公司 高活性负载型催化剂组合物
FI991015A0 (fi) * 1999-05-04 1999-05-04 Borealis As Menetelmä alfa-olefiinipolymeerien valmistamiseksi
US6355594B1 (en) * 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6576583B1 (en) * 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
US6723804B1 (en) * 2000-11-03 2004-04-20 Chevron Phillips Chemical Company, Lp Monitoring and control of slurry processes for polymerizing olefins
EP1349881B1 (en) * 2000-12-04 2007-10-17 Univaton Technologies, LLC Polimerization process
US6605675B2 (en) * 2000-12-04 2003-08-12 Univation Technologies, Llc Polymerization process
US6555495B2 (en) * 2000-12-06 2003-04-29 Univation Technologies, Llc Catalyst support method and polymerization with supported catalysts
DE60234067D1 (de) * 2001-04-05 2009-12-03 Japan Polypropylene Corp Katalysator für Olefinpolymerisation und Verfahren zur Olefinpolymerisation
GB0205932D0 (en) * 2002-03-13 2002-04-24 Borealis Tech Oy Homogenising multimodal polymer
TWI300782B (en) * 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts
US6884748B2 (en) * 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
EP1415999B1 (en) * 2002-10-30 2007-12-05 Borealis Technology Oy Process and apparatus for producing olefin polymers
US6900154B2 (en) * 2002-11-26 2005-05-31 Univation Technologies, Llc Methods of forming a supported activated catalyst composition
US6890876B2 (en) * 2002-11-26 2005-05-10 Univation Technologies, Llc Processes for producing fluorided catalysts from nitrogenous metallocenes
US7172987B2 (en) * 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
CA2534836C (en) * 2003-08-22 2012-11-27 Innovene Europe Limited Supported polymerisation catalysts
US6958306B2 (en) * 2003-08-28 2005-10-25 Univation Technologies, Llc Activated catalyst systems from substituted dialuminoxane complexes
US7211536B2 (en) * 2004-10-22 2007-05-01 Fina Technology, Inc. Supported metallocene catalysts and their use in producing stereospecific polymers
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
EP1709091A2 (en) * 2004-01-30 2006-10-11 Total Petrochemicals Research Feluy Activating supports for metallocene catalysis
US7148298B2 (en) * 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
ES2395009T3 (es) * 2004-11-04 2013-02-07 Chevron Phillips Chemical Company Lp Catalizadores de combinación de organocromo/metaloceno para producir resinas bimodales
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof

Also Published As

Publication number Publication date
US20070254801A1 (en) 2007-11-01
CA2643946A1 (en) 2007-11-08
MX2008011108A (es) 2008-09-10
CA2644740A1 (en) 2007-11-08
EP2013245A4 (en) 2009-08-05
CA2644736A1 (en) 2007-11-08
KR20080111041A (ko) 2008-12-22
EP2012920A4 (en) 2009-08-05
JP2009535456A (ja) 2009-10-01
KR20090003314A (ko) 2009-01-09
KR20090004920A (ko) 2009-01-12
US20070255023A1 (en) 2007-11-01
JP2009535457A (ja) 2009-10-01
EP2013244A4 (en) 2009-08-05
CA2644746A1 (en) 2007-11-08
KR20090003313A (ko) 2009-01-09
JP2009535454A (ja) 2009-10-01
EP2013248A2 (en) 2009-01-14
MX2008011107A (es) 2008-09-10
WO2007127465A2 (en) 2007-11-08
US20070255025A1 (en) 2007-11-01
MX2008011106A (es) 2008-09-10
EP2013242A4 (en) 2009-08-05
US20070255024A1 (en) 2007-11-01
US20070255022A1 (en) 2007-11-01
EP2013242A2 (en) 2009-01-14
BRPI0710954A2 (pt) 2012-03-20
MX2008011105A (es) 2008-09-10
BRPI0710969A2 (pt) 2011-05-24
JP2009535460A (ja) 2009-10-01
BRPI0710970A2 (pt) 2011-05-31
MX2008011111A (es) 2008-09-10
US20070255021A1 (en) 2007-11-01
EP2013244A2 (en) 2009-01-14
KR20090004911A (ko) 2009-01-12
EP2013248A4 (en) 2009-08-05
EP2012920A2 (en) 2009-01-14
JP2009535461A (ja) 2009-10-01
EP2013245A2 (en) 2009-01-14
CA2644744A1 (en) 2007-11-08
BRPI0711051A2 (pt) 2011-08-23
WO2007127465A3 (en) 2008-01-31

Similar Documents

Publication Publication Date Title
BRPI0710948A2 (pt) Catalisadores de metal de transição fluorados e formação dos mesmos
BR112014015584A2 (pt) catalisadores de hidrogenação com suportes modificados com cobalto
BR112014017557A8 (pt) reator catalítico de leito fixo contínuo e método de reação catalítica que usa o mesmo
BR112012027385A2 (pt) composição para o controle de doenças de plantas e uso da mesma
PL2300157T3 (pl) Katalizator do odwodorniania węglowodorów
BR112013030226A2 (pt) Catalisadores para acoplamento oxidativo de metano
BRPI0910458A2 (pt) catalisador para preparar acroleína ou ácido acrílico por reação de desidratação de glicerina e método para produzir o mesmo
BRPI0815564B8 (pt) anticorpos que inibem a dimerização de c-met e usos dos mesmos, hibridoma de murino, anticorpo, ácido nucleico isolado, vetor, método para produção de anticorpo, composição, uso e método de diagnóstico in vitro de enfermidades induzidas por uma superexpressão ou subexpressão do receptor de c-met
MY146010A (en) Oligomerisation in the presence of both a tetramerisation catalyst and a further oligomerisation catalyst
BR112014015580A8 (pt) catalisador, catalisador de hidrogenação, processo para produzir etanol e processo de síntese para produzir o catalisador
WO2012019430A8 (zh) 酞嗪酮类衍生物、其制备方法及其在医药上的应用
BR112013011172A2 (pt) compostos antidiabéticos
BR112012012917A2 (pt) anticorpo, ácido nucleico, vetor, célula hospedeira, método para a produção de um anticorpo ou um fragmento do mesmo, composição farmacêutica, método para tratar ou prevenir uma condição médica em um indivíduo, uso de um anticorpo ou fragmento do mesmo, e, métodos in vitro para neutralizar il-10 em uma amostra, in vitro para detectar a presença de il-10 em uma amostra e para diagnosticar lúpus eritematoso sistêmico (sle) em um indivíduo
CO6710898A2 (es) Ligandos fosfina para racciones cataliticas
BRPI0815417A2 (pt) Composições de catalisador modificada para conversão de álcool em alceno
BRPI0507810A (pt) grupo de saìda de fluoroálcool para catalisadores de polimerização de olefina não-metalocenos
EA200802002A1 (ru) Каталитическая система
BRPI0914105A2 (pt) novo ligante bidentado, processo para a carbonilação de compostos etilennicamente insaturados, novo complexo, e, sistemas de catalisador
BRPI0908921A2 (pt) Sistema de reação de síntese para composto de hidrocarboneto, e método de remoção de partículas de catalisador em pó
BR112012029495A2 (pt) catalisador de base sólida
BR112013022674A2 (pt) processo para preparar aminas primárias, e, uso de um catalisador complexo
BR112017022154A2 (pt) método para síntese de complexos de monociclopentadienil de zircônio e háfnio
EP2139870A4 (en) CATALYSER IMMOBILIZATION ON SILICON-DIOXIDE-CONTAINING MESOCELLULAR FOAM BY CLICKING CHEMISTRY
BR112013015072A2 (pt) síntese de cloridrato de metilfenidato à baixa temperatura
BRPI0917752A2 (pt) catalisador para a desidrogenação de alcanos ou substituintes alquila de hidrocarbonetos, processo para a produção do catalisador, e, processo para a desidrogenação de alcanos

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 8A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2308 DE 31/03/2015.