BRPI0710954A2 - Processo para a produção de copolímero usando catalisadores de metais de transição fluorados - Google Patents

Processo para a produção de copolímero usando catalisadores de metais de transição fluorados Download PDF

Info

Publication number
BRPI0710954A2
BRPI0710954A2 BRPI0710954-7A BRPI0710954A BRPI0710954A2 BR PI0710954 A2 BRPI0710954 A2 BR PI0710954A2 BR PI0710954 A BRPI0710954 A BR PI0710954A BR PI0710954 A2 BRPI0710954 A2 BR PI0710954A2
Authority
BR
Brazil
Prior art keywords
transition metal
copolymer
support material
production
metal compound
Prior art date
Application number
BRPI0710954-7A
Other languages
English (en)
Inventor
Abbas Razavi
Marin Vladimir
Lopez Margarito
Original Assignee
Fina Technology, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fina Technology, Inc. filed Critical Fina Technology, Inc.
Priority claimed from PCT/US2007/010316 external-priority patent/WO2007127414A2/en
Publication of BRPI0710954A2 publication Critical patent/BRPI0710954A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22—Halogenating
    • B01J37/26—Fluorinating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/16—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of silicon, germanium, tin, lead, titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2400/00—Characteristics for processes of polymerization
    • C08F2400/02—Control or adjustment of polymerization parameters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)

Abstract

PROCESSO PARA A PRODUçãO DE COPOLìMERO USANDO CATALISADORES DE METAIS DE TRANSIçãO FLUORADOS. A presente invenção refere-se a copolímeros e métodos de formar copolímeros. Os métodos em geral incluem proporcionar um composto de metal de transição representado pela fórmula [L]~ m~M[A]~ n~, em que L é um ligante volumoso incluindo a bisindenila, A é um grupo de saída, M é um metal de transição e m e n são tais que a valência do ligante total corresponda à valência do metal de transição e proporcionar um material de suporte tendo uma seqüência de ligação selecionada a partir de Si-O-AI-F, F-Si-O-AI, F-Si-O-AI-F e combinações dos mesmos. Os métodos adicionalmente incluem contatar o composto de metal de transição com o material de suporte, para formar um sistema de catalisador suportado ativo, em que o contato do composto de metal de transição com o material de suporte ocorre em proximidade ao contato com o monómero, e contatar o sistema de catalisador suportado ativo com uma pluralidade de monómeros, para formar um copolímero de olefina.
BRPI0710954-7A 2006-04-28 2007-04-27 Processo para a produção de copolímero usando catalisadores de metais de transição fluorados BRPI0710954A2 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US11/413,791 2006-04-28
US11/413,791 US20070255022A1 (en) 2006-04-28 2006-04-28 Fluorinated transition metal catalysts and formation thereof
US11/540,181 2006-09-29
US11/540,181 US20070255023A1 (en) 2006-04-28 2006-09-29 Process for copolymer production using fluorinated transition metal catalysts
PCT/US2007/010316 WO2007127414A2 (en) 2006-04-28 2007-04-27 Process for copolymer production using fluorinated transition metal catalysts

Publications (1)

Publication Number Publication Date
BRPI0710954A2 true BRPI0710954A2 (pt) 2012-03-20

Family

ID=38649035

Family Applications (5)

Application Number Title Priority Date Filing Date
BRPI0711051-0A BRPI0711051A2 (pt) 2006-04-28 2007-04-27 catalisadores de metais de transição fluorados e formação dos mesmos
BRPI0710969-5A BRPI0710969A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados
BRPI0710954-7A BRPI0710954A2 (pt) 2006-04-28 2007-04-27 Processo para a produção de copolímero usando catalisadores de metais de transição fluorados
BRPI0710948-2A BRPI0710948A2 (pt) 2006-04-28 2007-04-27 Catalisadores de metal de transição fluorados e formação dos mesmos
BRPI0710970-9A BRPI0710970A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados

Family Applications Before (2)

Application Number Title Priority Date Filing Date
BRPI0711051-0A BRPI0711051A2 (pt) 2006-04-28 2007-04-27 catalisadores de metais de transição fluorados e formação dos mesmos
BRPI0710969-5A BRPI0710969A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados

Family Applications After (2)

Application Number Title Priority Date Filing Date
BRPI0710948-2A BRPI0710948A2 (pt) 2006-04-28 2007-04-27 Catalisadores de metal de transição fluorados e formação dos mesmos
BRPI0710970-9A BRPI0710970A2 (pt) 2006-04-28 2007-04-27 processo para a produção de poliolefina usando catalisadores de metal de transição fluorados

Country Status (8)

Country Link
US (6) US20070255022A1 (pt)
EP (5) EP2013244A4 (pt)
JP (5) JP2009535454A (pt)
KR (5) KR20090004911A (pt)
BR (5) BRPI0711051A2 (pt)
CA (5) CA2644744A1 (pt)
MX (5) MX2008011105A (pt)
WO (1) WO2007127465A2 (pt)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1749842A1 (en) * 2005-08-03 2007-02-07 Total Petrochemicals Research Feluy Transition metal complexes supported on activating fluorinated support
US8003739B2 (en) * 2007-10-17 2011-08-23 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming in-situ heterophasic copolymers and/or varying the xylene solubles content of polyolefins
US20070255026A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Process for polyolefin production using fluorinated transition metal catalysts having a low pH
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
US8354485B2 (en) * 2007-08-29 2013-01-15 Albemarle Corporation Aluminoxane catalyst activators derived from dialkylaluminum cation precursor agents, processes for making same, and use thereof in catalysts and polymerization of olefins
US8138285B2 (en) * 2007-10-26 2012-03-20 Fina Technology, Inc. Fluorinated impregnated catalyst systems and methods of forming the same
JP5134928B2 (ja) 2007-11-30 2013-01-30 浜松ホトニクス株式会社 加工対象物研削方法
CN101910219B (zh) * 2007-12-28 2012-11-21 巴塞尔聚烯烃意大利有限责任公司 从丙烯和己烯-1的无规共聚物制造的塑料罐
JP5325533B2 (ja) * 2008-10-29 2013-10-23 日本ポリプロ株式会社 プロピレン／エチレン−α−オレフィン系ブロック共重合体用重合触媒及びそれを用いるプロピレン系ブロック共重合体の製造方法
KR101149755B1 (ko) * 2009-01-06 2012-06-01 에스케이종합화학 주식회사 에틸렌-프로필렌-디엔 공중합체 제조방법
KR101753549B1 (ko) * 2009-06-16 2017-07-03 셰브론 필립스 케미컬 컴퍼니 엘피 메탈로센-ｓｓａ 촉매시스템을 이용한 알파 올레핀 올리고머화 및 윤활제 블렌드 제조를 위한 생성된 폴리알파올레핀의 용도
AU2015227408B2 (en) * 2009-06-16 2016-09-29 Chevron Phillips Chemical Company Lp Oligomerization of alpha olefins using metallocene-SSA catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends
KR200457978Y1 (ko) * 2009-11-23 2012-01-16 주식회사 청정에너지 엘이디 조명등
KR101271395B1 (ko) * 2009-12-21 2013-06-05 에스케이종합화학 주식회사 메탈로센 촉매를 이용한 에틸렌과 알파-올레핀의 공중합체를 제조하는 방법
JP5580963B2 (ja) * 2010-02-09 2014-08-27 日本ポリプロ株式会社 溶融紡糸型エレクトロスピニング用プロピレン系樹脂材料及び極細繊維の溶融紡糸方法
KR20130026531A (ko) * 2010-02-22 2013-03-13 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 생산물을 생산하기 위한 촉매 시스템 및 이의 사용 방법
US8288487B2 (en) 2010-07-06 2012-10-16 Chevron Phillips Chemical Company Lp Catalysts for producing broad molecular weight distribution polyolefins in the absence of added hydrogen
BR112013005327B1 (pt) * 2010-09-06 2020-01-28 Basell Poliolefine Italia Srl película compreendendo um terpolímero contendo propileno, etileno e 1-hexeno
CN103080155B (zh) * 2010-09-06 2016-05-18 巴塞尔聚烯烃意大利有限责任公司 用于膜的丙烯基三元聚合物
JP5606250B2 (ja) * 2010-09-29 2014-10-15 有限会社Ｔｎｅ 亜鉛メッキ鋼板の抵抗溶接方法及び亜鉛メッキ鋼板抵抗溶接用電極チップの再生方法
JP4916574B1 (ja) * 2010-12-01 2012-04-11 株式会社フジクラ 伝送ケーブル用絶縁電線及び伝送ケーブル
JP4916575B1 (ja) * 2010-12-01 2012-04-11 株式会社フジクラ 伝送ケーブル用絶縁電線及び伝送ケーブル
CN104810086B (zh) * 2010-12-01 2017-04-26 株式会社藤仓 绝缘电线和电缆
JP4916590B1 (ja) * 2010-12-01 2012-04-11 株式会社フジクラ 伝送ケーブル用絶縁電線及び伝送ケーブル
EP2759554A1 (en) 2013-01-23 2014-07-30 Total Research & Technology Feluy Process for producing olefin / 3-methyl-1-butene copolymers
EP2810883A1 (en) * 2013-06-06 2014-12-10 Basell Poliolefine Italia S.r.l. Propylene based terpolymer for containers
KR20160097254A (ko) 2013-12-06 2016-08-17 토탈 리서치 앤드 테크놀로지 펠루이 장쇄 분지된 폴리프로필렌
US9303106B1 (en) * 2014-10-17 2016-04-05 Chevron Phillips Chemical Company Lp Processes for preparing solid metallocene-based catalyst systems
EP3585822B1 (en) * 2017-02-21 2025-05-07 NTP Tec, LLC Processes for making polyisobutylene compositions
US11028192B2 (en) 2017-03-27 2021-06-08 Exxonmobil Chemical Patents Inc. Solution process to make ethylene copolymers
KR101959401B1 (ko) 2017-05-18 2019-07-05 주식회사 파나시아 배기가스 처리장치의 배출 세정액 내의 유해가스 제거 시스템 및 방법
CN113201086A (zh) * 2021-04-27 2021-08-03 上海欣鑫化工有限公司 一种聚烯烃共混物的催化剂体系与应用
JP2024545050A (ja) * 2021-12-01 2024-12-05 トータルエナジーズ・ワンテック・ベルジャム 二元触媒組成物を用いる重合方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE1009406A3 (fr) * 1995-06-09 1997-03-04 Solvay Methode de regulation de procedes de synthese de produits chimiques.
FI104825B (fi) * 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
DE69809192T2 (de) * 1997-02-07 2003-07-24 Exxonmobil Chemical Patents Inc., Baytown Propylenpolymere enthaltend polyethylenmakromonomere
FR2769245B1 (fr) * 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
US6235918B1 (en) * 1998-07-29 2001-05-22 Northwestern University Supported organometallic catalysts for hydrogenation and Olefin Polymerization
US6368999B1 (en) * 1998-08-26 2002-04-09 Exxon Mobil Chemical Patents Inc. Highly active supported catalyst compositions
FI991015A0 (fi) * 1999-05-04 1999-05-04 Borealis As Menetelmä alfa-olefiinipolymeerien valmistamiseksi
US6355594B1 (en) * 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6576583B1 (en) * 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
US6723804B1 (en) * 2000-11-03 2004-04-20 Chevron Phillips Chemical Company, Lp Monitoring and control of slurry processes for polymerizing olefins
AU1790702A (en) * 2000-12-04 2002-06-18 Univaton Technologies Llc Polimerization process
US6605675B2 (en) * 2000-12-04 2003-08-12 Univation Technologies, Llc Polymerization process
US6555495B2 (en) * 2000-12-06 2003-04-29 Univation Technologies, Llc Catalyst support method and polymerization with supported catalysts
EP1247573B1 (en) * 2001-04-05 2009-10-21 Japan Polypropylene Corporation Catalyst for polymerizing olefin and process for polymerizing olefin
GB0205932D0 (en) * 2002-03-13 2002-04-24 Borealis Tech Oy Homogenising multimodal polymer
TWI300782B (en) * 2002-08-29 2008-09-11 Ineos Europe Ltd Supported polymerisation catalysts
US6884748B2 (en) * 2002-09-04 2005-04-26 Univation Technologies, Llc Process for producing fluorinated catalysts
EP1415999B1 (en) * 2002-10-30 2007-12-05 Borealis Technology Oy Process and apparatus for producing olefin polymers
US6890876B2 (en) * 2002-11-26 2005-05-10 Univation Technologies, Llc Processes for producing fluorided catalysts from nitrogenous metallocenes
US6900154B2 (en) * 2002-11-26 2005-05-31 Univation Technologies, Llc Methods of forming a supported activated catalyst composition
US7172987B2 (en) * 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
EP1656394B1 (en) * 2003-08-22 2012-10-03 Ineos Commercial Services UK Limited Supported polymerisation catalysts
US6958306B2 (en) * 2003-08-28 2005-10-25 Univation Technologies, Llc Activated catalyst systems from substituted dialuminoxane complexes
US7211536B2 (en) * 2004-10-22 2007-05-01 Fina Technology, Inc. Supported metallocene catalysts and their use in producing stereospecific polymers
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
CN100487005C (zh) * 2004-01-30 2009-05-13 托塔尔石油化学产品研究弗吕公司 茂金属催化用的活化载体
US7148298B2 (en) * 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
AU2004324873B2 (en) * 2004-11-04 2011-08-11 Chevron Phillips Chemical Company, Lp Organochromium/ metallocene combination catalyst for producing bimodal resins
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof

Also Published As

Publication number Publication date
KR20090004911A (ko) 2009-01-12
BRPI0710969A2 (pt) 2011-05-24
EP2012920A2 (en) 2009-01-14
JP2009535461A (ja) 2009-10-01
US20070255024A1 (en) 2007-11-01
MX2008011106A (es) 2008-09-10
JP2009535460A (ja) 2009-10-01
US20070255022A1 (en) 2007-11-01
KR20090003313A (ko) 2009-01-09
EP2013245A4 (en) 2009-08-05
BRPI0710948A2 (pt) 2012-03-06
EP2013248A2 (en) 2009-01-14
EP2012920A4 (en) 2009-08-05
EP2013242A4 (en) 2009-08-05
CA2644740A1 (en) 2007-11-08
JP2009535454A (ja) 2009-10-01
EP2013242A2 (en) 2009-01-14
CA2644744A1 (en) 2007-11-08
US20070254801A1 (en) 2007-11-01
MX2008011108A (es) 2008-09-10
CA2644736A1 (en) 2007-11-08
JP2009535456A (ja) 2009-10-01
US20070255021A1 (en) 2007-11-01
KR20090004920A (ko) 2009-01-12
MX2008011111A (es) 2008-09-10
EP2013245A2 (en) 2009-01-14
JP2009535457A (ja) 2009-10-01
BRPI0710970A2 (pt) 2011-05-31
CA2644746A1 (en) 2007-11-08
CA2643946A1 (en) 2007-11-08
US20070255023A1 (en) 2007-11-01
EP2013244A4 (en) 2009-08-05
KR20090003314A (ko) 2009-01-09
MX2008011107A (es) 2008-09-10
KR20080111041A (ko) 2008-12-22
WO2007127465A3 (en) 2008-01-31
WO2007127465A2 (en) 2007-11-08
EP2013244A2 (en) 2009-01-14
BRPI0711051A2 (pt) 2011-08-23
EP2013248A4 (en) 2009-08-05
MX2008011105A (es) 2008-09-10
US20070255025A1 (en) 2007-11-01

Similar Documents

Publication Publication Date Title
BRPI0710954A2 (pt) Processo para a produção de copolímero usando catalisadores de metais de transição fluorados
BRPI0500615A (pt) catalisador modificado, e, sistema de catalisador modificado
BRPI0815807A2 (pt) Composição de ativadores de catalisador de aluminoxanos derivados dos agentes precursores do cátion dialquilalumínio, processos para fazer os mesmos, e sua utilização em catalisadores e polimerização de olefinas.
BR112014015584A2 (pt) catalisadores de hidrogenação com suportes modificados com cobalto
BR112014015580A8 (pt) catalisador, catalisador de hidrogenação, processo para produzir etanol e processo de síntese para produzir o catalisador
BRPI0500616A (pt) processos para aperfeiçoar uma ou mais caracterìsticas de desempenho de um ou mais catalisadores de óxido metálico, e para produzir ácidos carboxìlicos insaturados
BR0314812A (pt) Processo para a preparação de um componente de catalisador de polimerização de olefina, partìculas do componente de catalisador, catalisador de polimerização de olefina, e, uso do mesmo
BRPI0711018A8 (pt) Processo para a polimerização de etileno e uma ou mais alfa-olefinas ou diolefinas c-3-30, processo para a polimerização de etileno e uma ou mais alfa-olefinas c3-8 usando um complexo de zircônio e um cocatalizador de ativação e copolímero de etileno e uma ou mais alfa-olefinas c3-8
BRPI0918697A8 (pt) Processo para melhorar as propriedades de um procatalisador e composição de procatalisador
TWI315317B (en) Solid titanium catalyst component, catalyst for polymerization of olefin and process for producing olefin polymer
WO2009082451A3 (en) Method for controlling bimodal catalyst activity during polymerization
BR112012033011A2 (pt) sistema catalisador para a polimerização de olefinas
BRPI1004565A2 (pt) componente de catalisador sólido, catalisador de polimerização de olefina, e , processo para produzir um polímero de olefina.
BRPI0915034A2 (pt) catalisadores ziegler-natta de alta atividade, processo para produção de catalisadores e uso dos mesmos
BRPI0620230B8 (pt) processo para a regeneração de catalisador ácido usado por alquilação
BR112012021519A2 (pt) proccesso, composição de procatalisador, composição catalítica e processo para produzir um polímero a base de olefina
BRPI0823407A2 (pt) Novos compostos de metaloceno, catalisadores que os compreendem, processo para produção de um polímero de olefina por uso dos catalisadores e homo- e copolímeros de olefina
BR112012023536A2 (pt) composições catalisadoras de fcc de olefinas altamente leves
EP2206731A4 (en) SOLID TITANIUM AGENT COMPONENT, OLEFIN POLYMERIZATION CATALYST AND METHOD FOR OLEFIN POLYMERIZATION
WO2013148614A3 (en) Water resistant polymers for personal care
BRPI0500609A (pt) processos para preparar um ou mais catalisadores modificados, e, para a criotrituração de um ou mais catalisadores de óxido metálico
BR112012027074A2 (pt) formatação de catalisador ziegler-natta usando componentes não misturados
BR112013002101A2 (pt) processos para a preparação de um poliol polímero, e para a preparação de uma espuma de poliuretano, e, espuma de poliuretano
ATE425193T1 (de) Polymerisations- und herstellungsverfahren einer katalysatorzusammensetzung zur polymerisation von olefinen
FR2959751B1 (fr) Procede de production de base pour carburants a partir d'une charge ethylenique mettant en oeuvre au moins une etape d'oligomerisation en presence d'un systeme catalytique homogene.

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 8A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2308 DE 31/03/2015.