BRPI0809443A2 - composição sólida e processo de conversão catalítica de propano ou isobutano a nutrila insaturada ou ácido carboxílico insaturado por amoxidação - Google Patents

composição sólida e processo de conversão catalítica de propano ou isobutano a nutrila insaturada ou ácido carboxílico insaturado por amoxidação

Info

Publication number
BRPI0809443A2
BRPI0809443A2 BRPI0809443A BRPI0809443A BRPI0809443A2 BR PI0809443 A2 BRPI0809443 A2 BR PI0809443A2 BR PI0809443 A BRPI0809443 A BR PI0809443A BR PI0809443 A BRPI0809443 A BR PI0809443A BR PI0809443 A2 BRPI0809443 A2 BR PI0809443A2
Authority
BR
Brazil
Prior art keywords
unsaturated
amoxidation
isobutane
nutrient
propane
Prior art date
Application number
BRPI0809443A
Other languages
English (en)
Inventor
Alakananda Bhattacharyya
Christos Paparizos
James A Kaduk
James F Brazdil Jr
Original Assignee
Ineos Usa Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ineos Usa Llc filed Critical Ineos Usa Llc
Publication of BRPI0809443A2 publication Critical patent/BRPI0809443A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/38—Abrasion or attrition resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
BRPI0809443A 2007-04-03 2008-04-01 composição sólida e processo de conversão catalítica de propano ou isobutano a nutrila insaturada ou ácido carboxílico insaturado por amoxidação BRPI0809443A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/732,212 US8697596B2 (en) 2007-04-03 2007-04-03 Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
PCT/US2008/004228 WO2008123975A1 (en) 2007-04-03 2008-04-01 Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons

Publications (1)

Publication Number Publication Date
BRPI0809443A2 true BRPI0809443A2 (pt) 2016-10-04

Family

ID=39561934

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0809443A BRPI0809443A2 (pt) 2007-04-03 2008-04-01 composição sólida e processo de conversão catalítica de propano ou isobutano a nutrila insaturada ou ácido carboxílico insaturado por amoxidação

Country Status (11)

Country Link
US (1) US8697596B2 (pt)
EP (1) EP2134467A1 (pt)
JP (1) JP5547057B2 (pt)
KR (1) KR20100015614A (pt)
CN (1) CN101678326B (pt)
BR (1) BRPI0809443A2 (pt)
EG (1) EG26888A (pt)
MX (1) MX2009010708A (pt)
MY (1) MY154913A (pt)
RU (1) RU2476265C2 (pt)
WO (1) WO2008123975A1 (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8697596B2 (en) 2007-04-03 2014-04-15 Ineos Usa Llc Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
US20090005586A1 (en) * 2007-06-29 2009-01-01 Brazdil Jr James F Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
US20090198081A1 (en) * 2008-02-05 2009-08-06 Christos Paparizos Process for the ammoxidation of propane and isobutane
EP2310123A1 (en) * 2008-08-01 2011-04-20 Ineos USA, LLC Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
CN102179261B (zh) * 2011-03-31 2013-05-22 大庆石油管理局 一种丙烷选择氧化制备丙烯酸所用催化剂及其制备方法
WO2014050615A1 (ja) * 2012-09-27 2014-04-03 旭化成ケミカルズ株式会社 複合酸化物触媒及びその製造方法、並びに不飽和ニトリルの製造方法
KR101284214B1 (ko) * 2012-10-04 2013-07-08 한국과학기술연구원 질소산화물 분해 촉매 및 그 제조 방법
US9409156B2 (en) * 2012-10-19 2016-08-09 Instituto Mexicano Del Petroleo Oxidative dehydrogenation of ethane to ethylene and preparation of multimetallic mixed oxide catalyst for such process
US10059652B2 (en) 2013-08-30 2018-08-28 Sabic Global Technologies B.V. Heterogeneous catalysts for the transesterification of aromatic alcohols; and methods of making and use thereof
EP3498369B1 (en) 2016-08-12 2021-10-06 Asahi Kasei Kabushiki Kaisha Method for producing oxide catalyst useful for producing unsaturated nitriles and unsaturated acids
EP3513876B1 (en) * 2016-09-13 2021-12-01 Asahi Kasei Kabushiki Kaisha Method for producing oxide catalyst and method for producing unsaturated nitrile or unsaturated acid
CA2945435C (en) * 2016-10-18 2025-09-02 Nova Chemicals Corporation OXIDATING DEHYDROGENATING CATALYST TREATMENT WITH PEROXIDE AND LOW PRESSURE HYDROTHMIC GAS RELEASE
CA2953954A1 (en) 2017-01-06 2018-07-06 Nova Chemicals Corporation Double peroxide treatment of oxidative dehydrogenation catalyst
CN108970604B (zh) * 2017-06-02 2021-08-24 中国科学院青岛生物能源与过程研究所 一种钼钒铌基复合氧化物及其合成方法与应用
RU2732413C1 (ru) * 2017-06-09 2020-09-16 Асахи Касеи Кабусики Кайся Способ получения ненасыщенного нитрила
DE102017121709A1 (de) * 2017-09-19 2019-03-21 Clariant International Ltd Synthese eines MoVNbTe-Schalenkatalysators für die oxidative Dehydrierung von Ethan zu Ehtylen
WO2020246283A1 (ja) 2019-06-06 2020-12-10 旭化成株式会社 酸化物触媒及び不飽和ニトリルの製造方法
BR112022013676A2 (pt) 2020-01-31 2022-09-13 Asahi Chemical Ind Composição para produção de catalisador, método para produzir composição para produção de catalisador, e método de produção para produzir catalisador de óxido
CN114100652B (zh) * 2021-12-10 2023-10-13 北京道思克矿山装备技术有限公司 一种甲醇气相催化氨氧化生产氰化氢的催化剂及其制备方法和应用

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS501714A (pt) 1973-05-02 1975-01-09
GB1464198A (en) 1974-11-11 1977-02-09 Mobil Oil Corp Regeneration of vanadium-phosphorus catalyst complex with alkyl phosphates
EP0123467B1 (en) 1983-04-14 1990-11-22 Amoco Corporation Reactivation of phosphorus vanadium catalysts and process for the manufacture of maleic anhydride catalysts treated with alkyl esters of orthophosphoric acids in the presence of water
US4760159A (en) 1987-03-13 1988-07-26 The Standard Oil Company Method for ammoxidation of paraffins and catalyst therefor
US4797381A (en) 1987-07-30 1989-01-10 The Standard Oil Company Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts
US5011945A (en) 1987-08-31 1991-04-30 Amoco Corporation Continuous process for the production of maleic anhydride
JPH01126599A (ja) 1987-11-11 1989-05-18 Mitsubishi Electric Corp Ｘ線，γ線用コリメータ
US5049692A (en) 1987-11-25 1991-09-17 Mitsubishi Kasei Corporation Catalytic conversion of alkanes to nitriles, and a catalyst therefor
KR920021498A (ko) 1991-05-09 1992-12-18 에또 다께또시 니트릴의 제조 방법
KR930004254A (ko) 1991-08-08 1993-03-22 에또 다께또시 니트릴의 제조방법
DE69318684T2 (de) 1992-12-24 1999-01-14 Mitsubishi Chemical Corp., Tokio/Tokyo Herstellungsverfahren eines Katalysators zur Herstellung von Nitrilen
DE69402567T2 (de) 1993-01-28 1997-11-27 Mitsubishi Chem Corp Methode zur Herstellung einer ungesättigten Carbonsäure
JP3669077B2 (ja) * 1995-10-05 2005-07-06 三菱化学株式会社 ニトリルの製造法
US5750760A (en) * 1995-10-05 1998-05-12 Mitsubishi Chemical Corporation Method for producing a nitrile
US5850760A (en) * 1995-12-29 1998-12-22 Kia Heavy Industries Corporation Booster for transmission gear boxes
US5866502A (en) 1997-03-27 1999-02-02 The Standard Oil Co. Process for the preparation of antimonate catalysts for (AMM) oxidation of alkanes and alkenes
JPH10330343A (ja) * 1997-04-04 1998-12-15 Mitsubishi Chem Corp ニトリルの製造方法
DE19835247B4 (de) 1997-08-05 2022-04-28 Asahi Kasei Kabushiki Kaisha Ammonoxidationskatalysator und Verfahren zur Herstellung von Acrylnitril oder Methacrylnitril aus Propan oder Isobutan durch Ammonoxidation
EP0895809B1 (en) 1997-08-05 2014-03-19 Asahi Kasei Kabushiki Kaisha Process Using Niobium-containing Aqueous Solution in Producing Niobium-containing Oxide Catalyst
ID20720A (id) 1997-08-05 1999-02-18 Asahi Chemical Ind Larutan berair yang mengandung niobium untuk digunakan dalam pembuatan katalis oksida yang mengandung niobium
JP4030628B2 (ja) 1997-10-17 2008-01-09 旭化成ケミカルズ株式会社 触媒およびこれを用いた不飽和ニトリルの製造方法
US6156920A (en) 1998-03-26 2000-12-05 The Standard Oil Company Molybdenum promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
AU5445599A (en) * 1998-08-28 2000-03-21 Asahi Kasei Kabushiki Kaisha Method for producing oxide catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane
JP4187837B2 (ja) * 1998-08-28 2008-11-26 旭化成ケミカルズ株式会社 不飽和ニトリル製造用触媒の製造方法
JP4247565B2 (ja) * 1999-03-10 2009-04-02 東亞合成株式会社 アクリル酸製造用の触媒およびそれを用いたアクリル酸の製造方法
US6043185A (en) 1999-04-02 2000-03-28 The Standard Oil Company Gallium promoted molybdenum vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US6432870B1 (en) 1999-05-25 2002-08-13 Toagosei Co., Ltd. Process for preparing metal oxide catalyst for acrylic acid production
CN1174801C (zh) 2000-06-15 2004-11-10 旭化成株式会社 用于丙烷或异丁烷的气相催化氧化或气相催化氨氧化的催化剂
JP2004504288A (ja) 2000-07-18 2004-02-12 ビーエーエスエフ　アクチェンゲゼルシャフト 不均一系触媒作用によりプロパンを気相酸化することによるアクリル酸の製造方法
US6407031B1 (en) * 2000-09-28 2002-06-18 Rohm And Haas Company Promoted multi-metal oxide catalyst
JP4049363B2 (ja) * 2000-12-22 2008-02-20 日本化薬株式会社 アルカン酸化触媒、その製法及び不飽和酸素含有化合物の製造法
EP1346766B1 (en) 2000-12-22 2009-02-11 Nippon Kayaku Kabushiki Kaisha Process for producing oxygen-containing unsaturated compound
DE10117357A1 (de) 2001-04-06 2002-10-10 Basf Ag Verfahren zur Herstellung von Acrylsäure oder Methacrylsäure durch Gasphasenoxidation von Propan oder Isobutan
US6645906B2 (en) 2001-04-30 2003-11-11 Rohm And Haas Company High temperature mixing
TWI225426B (en) 2002-05-01 2004-12-21 Rohm & Haas Supported mixed metal oxide catalyst
EP1407819A3 (en) 2002-10-01 2004-06-23 Rohm And Haas Company Hydrothermally synthesized Mo-V-M-Nb-X oxide catalysts for the selective oxidation of hydrocarbons
US20040147393A1 (en) 2003-01-29 2004-07-29 Basf Akiengesellschaft Preparation of a multimetal oxide composition
US7229946B2 (en) 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
US20050054869A1 (en) 2003-06-06 2005-03-10 Lugmair Claus G. Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same
US7595277B2 (en) 2003-06-09 2009-09-29 Asahi Kasei Chemicals Corporation Catalyst for oxidation or ammoxidation
EP1806178B1 (en) 2004-08-17 2020-03-04 Asahi Kasei Kabushiki Kaisha Catalyst composed of complex oxide
US20060122055A1 (en) 2004-12-06 2006-06-08 Gaffney Anne M (Amm)oxidation catalyst and catalytic (amm)oxidation process for conversion of lower alkanes
EP1693107A1 (en) 2005-02-11 2006-08-23 Rohm And Haas Company Method for preparing mixed-metal oxide catalysts and the catalysts produced thereby
EP1704919A1 (en) 2005-03-25 2006-09-27 Arkema France Process for preparing improved catalysts for selective oxidation of propane into acrylic acid
JP4743620B2 (ja) * 2006-05-11 2011-08-10 旭化成ケミカルズ株式会社 改良触媒
US20080103326A1 (en) * 2006-10-31 2008-05-01 Bruce Irwin Rosen Lithium containing mixed metal oxide catalysts for ammoxidation of propane and isobutane
US20080103325A1 (en) * 2006-10-31 2008-05-01 Claus Lugmair Mixed metal oxide catalysts for the ammoxidation of propane and isobutane
US20080248947A1 (en) * 2007-04-03 2008-10-09 Zajac Gerry W Mixed metal oxide catalysts and catalytic processes for conversions of lower alkane hydrocarbons
MX2009008741A (es) 2007-02-16 2009-08-27 Ineos Usa Llc Catalizadores de oxido de metal mixto para la amoxidacion de propano e isobutano utilizando catalizadores de oxido de metal mixto.
US8697596B2 (en) 2007-04-03 2014-04-15 Ineos Usa Llc Mixed metal oxide catalysts and catalytic conversions of lower alkane hydrocarbons
JP5001714B2 (ja) 2007-05-17 2012-08-15 日星電気株式会社 面状ヒータ

Also Published As

Publication number Publication date
KR20100015614A (ko) 2010-02-12
CN101678326B (zh) 2015-09-16
WO2008123975A1 (en) 2008-10-16
US20080249328A1 (en) 2008-10-09
MY154913A (en) 2015-08-28
RU2009140374A (ru) 2011-05-10
JP5547057B2 (ja) 2014-07-09
RU2476265C2 (ru) 2013-02-27
MX2009010708A (es) 2009-10-26
US8697596B2 (en) 2014-04-15
CN101678326A (zh) 2010-03-24
EG26888A (en) 2014-11-19
EP2134467A1 (en) 2009-12-23
JP2010526649A (ja) 2010-08-05

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