BRPI0913336A2 - catalisador e método de produção de aldeído insaturado e ácido carboxílico insaturado - Google Patents

catalisador e método de produção de aldeído insaturado e ácido carboxílico insaturado

Info

Publication number
BRPI0913336A2
BRPI0913336A2 BRPI0913336A BRPI0913336A BRPI0913336A2 BR PI0913336 A2 BRPI0913336 A2 BR PI0913336A2 BR PI0913336 A BRPI0913336 A BR PI0913336A BR PI0913336 A BRPI0913336 A BR PI0913336A BR PI0913336 A2 BRPI0913336 A2 BR PI0913336A2
Authority
BR
Brazil
Prior art keywords
unsaturated
catalyst
production
carboxylic acid
unsaturated carboxylic
Prior art date
Application number
BRPI0913336A
Other languages
English (en)
Inventor
Hideki Sugi
Hiroyuki Onoue
Masaki Nakahara
Tatsuhiko Karakami
Yoshimasa Seo
Original Assignee
Nippon Kayaku Kk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Kk filed Critical Nippon Kayaku Kk
Publication of BRPI0913336A2 publication Critical patent/BRPI0913336A2/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BRPI0913336A 2008-06-02 2009-05-25 catalisador e método de produção de aldeído insaturado e ácido carboxílico insaturado BRPI0913336A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2008144213 2008-06-02
JP2009019750 2009-01-30
PCT/JP2009/059503 WO2009147965A1 (ja) 2008-06-02 2009-05-25 触媒並びに不飽和アルデヒド及び不飽和カルボン酸の製造方法

Publications (1)

Publication Number Publication Date
BRPI0913336A2 true BRPI0913336A2 (pt) 2015-11-24

Family

ID=41398041

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0913336A BRPI0913336A2 (pt) 2008-06-02 2009-05-25 catalisador e método de produção de aldeído insaturado e ácido carboxílico insaturado

Country Status (10)

Country Link
US (1) US20110137078A1 (pt)
EP (1) EP2298446A4 (pt)
JP (1) JPWO2009147965A1 (pt)
KR (1) KR20110025746A (pt)
CN (1) CN102046289A (pt)
BR (1) BRPI0913336A2 (pt)
MX (1) MX2010012988A (pt)
RU (1) RU2471554C2 (pt)
WO (1) WO2009147965A1 (pt)
ZA (1) ZA201008554B (pt)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012110806A (ja) * 2010-11-22 2012-06-14 Nippon Kayaku Co Ltd メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
WO2012091898A2 (en) * 2010-12-29 2012-07-05 Saint-Gobain Ceramics & Plastisc, Inc. A multi-lobed porous ceramic body and process for making the same
WO2013161703A1 (ja) 2012-04-23 2013-10-31 日本化薬株式会社 成型触媒の製造方法および該成型触媒を用いるジエンまたは不飽和アルデヒドおよび/または不飽和カルボン酸の製造方法
KR20150003214A (ko) * 2012-04-23 2015-01-08 닛뽄 가야쿠 가부시키가이샤 부타디엔의 제조용 촉매, 그 촉매의 제조 방법 및 그 촉매를 이용한 부타디엔의 제조 방법
KR101960919B1 (ko) * 2015-08-11 2019-03-22 주식회사 엘지화학 고성능 폴리옥소메탈레이트 촉매 및 이의 제조 방법
CN107848934B (zh) * 2015-08-24 2021-07-20 罗门哈斯公司 确定单体生产中使用的材料的惰性的方法
CN107848935B (zh) * 2015-08-24 2022-01-04 罗门哈斯公司 单体生产中使用的材料的惰性的确定方法
RU2715605C1 (ru) 2016-07-25 2020-03-03 Мицубиси Кемикал Корпорейшн Катализатор, способ получения акриловой кислоты и способ получения катализатора
WO2018181226A1 (ja) * 2017-03-27 2018-10-04 三菱ケミカル株式会社 触媒及び触媒群
JP6958390B2 (ja) * 2017-03-27 2021-11-02 三菱ケミカル株式会社 触媒
CA3058093A1 (en) * 2017-03-27 2018-10-04 Mitsubishi Chemical Corporation Catalyst and catalyst group
JP7070028B2 (ja) * 2017-05-16 2022-05-18 三菱ケミカル株式会社 触媒群
JP7070031B2 (ja) * 2017-05-16 2022-05-18 三菱ケミカル株式会社 触媒群
JP7375638B2 (ja) * 2020-03-18 2023-11-08 三菱ケミカル株式会社 不飽和カルボン酸合成用触媒の製造方法
JP7375639B2 (ja) * 2020-03-18 2023-11-08 三菱ケミカル株式会社 不飽和カルボン酸合成用触媒の製造方法
JP7459589B2 (ja) * 2020-03-18 2024-04-02 三菱ケミカル株式会社 アクリル酸合成用触媒の製造方法
JP7347282B2 (ja) * 2020-03-18 2023-09-20 三菱ケミカル株式会社 不飽和カルボン酸合成用触媒の製造方法
JP7347283B2 (ja) * 2020-03-18 2023-09-20 三菱ケミカル株式会社 不飽和カルボン酸合成用触媒の製造方法
CN114425326B (zh) * 2020-10-15 2024-02-02 中国石油化工股份有限公司 一种适于生产丙烯醛的催化剂及其制备方法和应用
JP7480672B2 (ja) * 2020-10-20 2024-05-10 三菱ケミカル株式会社 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の製造方法
JP7480671B2 (ja) * 2020-10-20 2024-05-10 三菱ケミカル株式会社 不飽和アルデヒド及び不飽和カルボン酸合成用触媒の製造方法

Family Cites Families (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2243583C3 (de) * 1972-09-05 1979-12-20 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung eines Kobaltmolybdat-Katalysators
JPS5821614B2 (ja) 1973-07-19 1983-05-02 日本化薬株式会社 メタクロレイン ノ セイゾウホウ
GB1513335A (en) * 1975-03-17 1978-06-07 Mitsubishi Rayon Co Process and a catalyst for the preparation of unsaturated carboxylic acid
JPS5246016A (en) * 1975-10-08 1977-04-12 Japan Synthetic Rubber Co Ltd Process for preparation of methacrylic acid
US4339355A (en) * 1975-10-09 1982-07-13 Union Carbide Corporation Catalytic oxide of molybdenum, vanadium, niobium and optional 4th metal
US4051180A (en) * 1976-01-02 1977-09-27 The Standard Oil Company Preparation of acrylic acid and methacrylic acid
US4358608A (en) * 1976-06-07 1982-11-09 The Standard Oil Company Process for producing unsaturated aliphatic acids
DE2626887B2 (de) * 1976-06-16 1978-06-29 Basf Ag, 6700 Ludwigshafen Katalysator für die Oxadation von (Methacrolein zu (Meth)Acrylsäure
JPS5945415B2 (ja) * 1976-12-13 1984-11-06 日本ゼオン株式会社 オレフイン酸化用触媒
JPS5319188A (en) * 1976-08-06 1978-02-22 Nippon Zeon Co Ltd Olefin oxidation catalyst
US4120876A (en) * 1976-10-19 1978-10-17 Standard Oil Company Preparation of maleic anhydride from four-carbon hydrocarbons
US4093635A (en) * 1976-10-19 1978-06-06 The Standard Oil Company Preparation of maleic anhydride from four-carbon hydrocarbons
JPS53146288A (en) * 1977-05-26 1978-12-20 Nippon Kayaku Co Ltd Production of supported catalyst
JPS6048495B2 (ja) * 1977-07-22 1985-10-28 東ソー株式会社 メタクリル酸の製造法
JPS6048496B2 (ja) * 1977-07-22 1985-10-28 東ソー株式会社 メタクリル酸の製造方法
JPS5492908A (en) * 1977-12-28 1979-07-23 Nippon Zeon Co Ltd Catalysts for oxidation use of isobutylene
JPS552619A (en) * 1978-06-21 1980-01-10 Nippon Kayaku Co Ltd Preparation of methacrylic acid and catalyst
US4379925A (en) * 1978-06-26 1983-04-12 The Standard Oil Co. Liquid phase ammoxidation of cyclohexanone and/or cyclohexanol
IT1160321B (it) * 1978-12-12 1987-03-11 Euteco Spa Catalizzatori per l'ossidazione di acroleina ad acido acrilico
JPS5811416B2 (ja) 1978-12-13 1983-03-02 日本化薬株式会社 メタクリル酸の製造法
US4271040A (en) * 1978-12-26 1981-06-02 Halcon Research And Development Corp. Catalyst and process for producing methacrylic acid
DE2909670A1 (de) * 1979-03-12 1980-10-02 Basf Ag Verfahren zur herstellung von schalenkatalysatoren
JPS55122734A (en) 1979-03-16 1980-09-20 Nippon Kayaku Co Ltd Preparation of methacrylic acid and its catalyst
US4251393A (en) * 1979-05-29 1981-02-17 Celanese Corporation Attrition resistant catalysts
US4317927A (en) * 1979-05-29 1982-03-02 Celanese Corporation Process for the catalytic conversion of olefinically unsaturated aldehydes to their corresponding acids
US4276196A (en) * 1979-08-09 1981-06-30 Celanese Corporation Attrition resistant catalysts
US4547588A (en) * 1979-10-03 1985-10-15 The Halcon Sd Group, Inc. Process for producing methacrylic acid
US4321160A (en) * 1979-12-27 1982-03-23 Standard Oil Company Method for the activation of phosphomolybdic acid based catalysts
US4390736A (en) * 1980-11-26 1983-06-28 Sumitomo Chemical Company, Limited Process for producing phenols
DE3167504D1 (en) * 1980-12-03 1985-01-10 Asahi Chemical Ind Process for producing malononitrile
JPS58112050A (ja) * 1981-12-24 1983-07-04 Ube Ind Ltd メタクリル酸製造用触媒の製法
DE3208571A1 (de) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator, insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
DE3208572A1 (de) * 1982-03-10 1983-09-22 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure
JPS59115750A (ja) * 1982-12-22 1984-07-04 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸合成用触媒
DE3308625A1 (de) * 1983-03-11 1984-09-13 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure
GB2138694B (en) * 1983-03-24 1986-12-10 Nippon Catalytic Chem Ind Heteropolyacid-type catalyst composition containing whiskers
DE3445289A1 (de) * 1984-12-12 1986-06-19 Basf Ag, 6700 Ludwigshafen Geformter katalysator fuer heterogen katalysierte reaktionen
JPH0753686B2 (ja) * 1986-10-27 1995-06-07 三菱レイヨン株式会社 メタクリル酸の製造法
JPH0813777B2 (ja) * 1986-12-11 1996-02-14 三菱化学株式会社 アクリル酸の製造法
ES2028180T3 (es) * 1987-06-05 1992-07-01 Nippon Shokubai Kagaku Kogyo Kabushiki Kaisha Catalizador para la oxidacion de acroleina y procedimiento para su preparacion.
DE3721865A1 (de) * 1987-07-02 1989-01-12 Basf Ag Verfahren zur herstellung von methacrylsaeure
JPH0813778B2 (ja) * 1988-07-11 1996-02-14 住友化学工業株式会社 メタクリル酸の製造方法
US5191116A (en) * 1989-05-22 1993-03-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for the preparation of methacrylic acid and methacrolein
DE69013623T3 (de) * 1989-08-29 2002-12-19 Nippon Shokubai Kagaku Kogyo Co., Ltd. Katalysator zur Herstellung von Methacrylsäure.
US5206431A (en) * 1990-02-08 1993-04-27 Nippon Shokubai Kagaku Kogyo Co., Ltd. Process for producing methacrylic acid
JPH03238051A (ja) * 1990-02-15 1991-10-23 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の調製法
JP3260185B2 (ja) 1992-12-11 2002-02-25 三菱レイヨン株式会社 不飽和アルデヒド及び不飽和カルボン酸合成用触媒及びその使用
JP2610090B2 (ja) * 1993-03-12 1997-05-14 株式会社日本触媒 固体有機物の除去方法
KR100247524B1 (ko) * 1994-05-31 2000-03-15 겐지 아이다 아크릴산 제조용 촉매 및 이 촉매를 이용한 아크릴산의 제조방법
KR100210642B1 (ko) * 1994-05-31 1999-07-15 겐지 아이다 메타크릴산 제조용촉매 및 이 촉매를 이용한 메타크릴산의 제조방법
EP0811597B1 (en) * 1994-11-14 2000-08-23 Nippon Shokubai Co., Ltd. Process for production of acrylic acid
JP3786297B2 (ja) * 1995-03-03 2006-06-14 日本化薬株式会社 触媒の製造方法
JP3537253B2 (ja) * 1996-03-06 2004-06-14 株式会社日本触媒 アクリル酸の製造方法
JP3793317B2 (ja) 1996-05-14 2006-07-05 日本化薬株式会社 触媒及び不飽和アルデヒドおよび不飽和酸の製造方法
JP3775872B2 (ja) * 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
CA2306234C (en) * 1997-10-14 2005-07-05 Japan Energy Corporation Catalyst support, catalyst, reactor for hydrogenation reaction, and catalytic reaction method
JP3948837B2 (ja) * 1998-08-10 2007-07-25 株式会社日本触媒 アクリル酸の製造方法
MY119958A (en) * 1999-03-10 2005-08-30 Basf Ag Catalytic gas-phase oxidation of propene to acrylic acid
US6762148B2 (en) * 1999-09-17 2004-07-13 Nippon Kayaku Kabushiki Kaisha Catalyst process of making
JP3883755B2 (ja) * 1999-09-17 2007-02-21 日本化薬株式会社 触媒の製造方法
DE10009017A1 (de) * 2000-02-25 2001-09-06 Basf Ag Geformte Katalysatoren
JP3892244B2 (ja) 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
EP1262235A3 (en) * 2001-05-23 2003-04-16 Rohm And Haas Company Mixed-metal oxide catalysts containing molybdenum and vanadium and processes for preparing the same
US7022643B2 (en) * 2002-08-20 2006-04-04 Nippon Shokubai Co., Ltd. Production process for catalyst
UA79540C2 (uk) * 2003-01-27 2007-06-25 Бп Кемікалз Лімітед Каталітична композиція окиснення, її одержання та спосіб селективного окиснення
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
US20050054869A1 (en) * 2003-06-06 2005-03-10 Lugmair Claus G. Mixed metal oxide catalysts for propane and isobutane oxidation and ammoxidation, and methods of preparing same
JP5097413B2 (ja) 2007-02-27 2012-12-12 住友化学株式会社 触媒の製造方法

Also Published As

Publication number Publication date
EP2298446A1 (en) 2011-03-23
MX2010012988A (es) 2010-12-20
WO2009147965A1 (ja) 2009-12-10
KR20110025746A (ko) 2011-03-11
CN102046289A (zh) 2011-05-04
RU2010152247A (ru) 2012-07-20
EP2298446A4 (en) 2012-07-04
US20110137078A1 (en) 2011-06-09
RU2471554C2 (ru) 2013-01-10
JPWO2009147965A1 (ja) 2011-10-27
ZA201008554B (en) 2012-01-25

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