BRPI0817893A2 - Composições de polietileno com propriedades aperfeiçoadas - Google Patents

Composições de polietileno com propriedades aperfeiçoadas

Info

Publication number
BRPI0817893A2
BRPI0817893A2 BRPI0817893A BRPI0817893A2 BR PI0817893 A2 BRPI0817893 A2 BR PI0817893A2 BR PI0817893 A BRPI0817893 A BR PI0817893A BR PI0817893 A2 BRPI0817893 A2 BR PI0817893A2
Authority
BR
Brazil
Prior art keywords
improved properties
polyethylene compositions
polyethylene
compositions
properties
Prior art date
Application number
Other languages
English (en)
Inventor
Mark G Goode
Rainer Kolb
Chi-I Kuo
Tae Hoon Kwalk
Dongming Li
Ching-Tai Lue
Francis C Rix
Daniel P Zilker
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BRPI0817893A2 publication Critical patent/BRPI0817893A2/pt
Publication of BRPI0817893B1 publication Critical patent/BRPI0817893B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B01J2231/122—Cationic (co)polymerisation, e.g. single-site or Ziegler-Natta type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
BRPI0817893-3A 2007-10-22 2008-10-09 Composição de polietileno, filme compreendendo a composição e processo de fase de gás para a polimerização de olefinas BRPI0817893B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US99990207P 2007-10-22 2007-10-22
US60/999,902 2007-10-22
PCT/US2008/011605 WO2009054888A1 (en) 2007-10-22 2008-10-09 Polyethylene compositions having improved properties

Publications (2)

Publication Number Publication Date
BRPI0817893A2 true BRPI0817893A2 (pt) 2015-03-31
BRPI0817893B1 BRPI0817893B1 (pt) 2019-08-06

Family

ID=40236339

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0817893-3A BRPI0817893B1 (pt) 2007-10-22 2008-10-09 Composição de polietileno, filme compreendendo a composição e processo de fase de gás para a polimerização de olefinas

Country Status (9)

Country Link
US (1) US8329835B2 (pt)
EP (3) EP2214820B1 (pt)
CN (1) CN101835536B (pt)
AR (1) AR068937A1 (pt)
BR (1) BRPI0817893B1 (pt)
ES (2) ES2784439T3 (pt)
RU (1) RU2448132C2 (pt)
TW (1) TW200932762A (pt)
WO (1) WO2009054888A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200932770A (en) * 2007-10-22 2009-08-01 Univation Tech Llc Metallocene catalysts and their use in polymerization processes
EP2356155B1 (en) * 2008-12-01 2013-01-23 Basell Polyolefine GmbH Process for the polymerization of ethylene, and ethylene polymers having broad molecular weight distribution and long- chain branching
EP2526133B1 (en) * 2010-01-22 2015-04-22 ExxonMobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
US9365661B2 (en) * 2012-08-03 2016-06-14 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified salan catalyst compounds
US9382349B2 (en) * 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
EP2880097B1 (en) * 2012-08-03 2023-10-18 ExxonMobil Chemical Patents Inc. Process to prepare a vinyl terminated polyethylene with long chain branching
EP2860031B1 (en) * 2013-10-11 2016-03-30 Borealis AG Machine direction oriented film for labels
BR112016019334B1 (pt) * 2014-02-11 2021-03-09 Univation Technologies, Llc método para formar uma composição de catalisador
KR101924198B1 (ko) * 2015-12-23 2018-11-30 주식회사 엘지화학 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체
KR102065719B1 (ko) * 2017-01-25 2020-01-13 주식회사 엘지화학 혼성 담지 촉매

Family Cites Families (188)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
DE2742585A1 (de) 1976-09-28 1978-03-30 Asahi Chemical Ind Neue polymerisationskatalysatoren und ihre verwendung (i)
US4271060A (en) 1979-09-17 1981-06-02 Phillips Petroleum Company Solution polymerization process
US4325837A (en) 1980-08-12 1982-04-20 Phillips Petroleum Company Catalyst, method of producing the catalyst, and polymerization process employing the catalyst
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4935474A (en) 1983-06-06 1990-06-19 Exxon Research & Engineering Company Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
US4613484A (en) 1984-11-30 1986-09-23 Phillips Petroleum Company Loop reactor settling leg system for separation of solid polymers and liquid diluent
JPS61189522U (pt) 1985-05-17 1986-11-26
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4665208A (en) 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
FR2586022B1 (fr) 1985-08-06 1987-11-13 Bp Chimie Sa Polymerisation d'olefines en phase gazeuse avec un catalyseur ziegler-natta et deux composes organometalliques
US5124418A (en) 1985-11-15 1992-06-23 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
DE3782243T2 (de) 1986-08-26 1993-03-04 Mitsui Petrochemical Ind Katalysator zur polymerisierung von alpha-olefin und verfahren.
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
EP0406912B1 (en) 1986-09-24 1994-11-30 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins
JPH0780933B2 (ja) 1986-11-20 1995-08-30 三井石油化学工業株式会社 オレフインの重合方法
KR910008277B1 (ko) 1986-12-03 1991-10-12 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀 중합용 고체촉매 및 그 제조법
JP2618384B2 (ja) 1986-12-27 1997-06-11 三井石油化学工業株式会社 オレフイン重合用固体触媒およびその製法
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5264405A (en) 1989-09-13 1993-11-23 Exxon Chemical Patents Inc. Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5096867A (en) 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
JPH0742301B2 (ja) 1987-02-14 1995-05-10 三井石油化学工業株式会社 微粒子状アルミノオキサン、その製法およびその用途
JP2538588B2 (ja) 1987-04-03 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒の製法
US5206199A (en) 1987-04-20 1993-04-27 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
US4925821A (en) 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US5008228A (en) 1988-03-29 1991-04-16 Exxon Chemical Patents Inc. Method for preparing a silica gel supported metallocene-alumoxane catalyst
US5149819A (en) 1988-04-28 1992-09-22 Ricoh Company, Ltd. Squarylium compounds and optical information recording medium using the same
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US5091352A (en) 1988-09-14 1992-02-25 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins
US4908463A (en) 1988-12-05 1990-03-13 Ethyl Corporation Aluminoxane process
US5103031A (en) 1989-02-21 1992-04-07 Ethyl Corporation Falling film aluminoxane process
US4968827A (en) 1989-06-06 1990-11-06 Ethyl Corporation Alkylaluminoxane process
US4924018A (en) 1989-06-26 1990-05-08 Ethyl Corporation Alkylaluminoxane process
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5227440A (en) 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5066741A (en) 1990-03-22 1991-11-19 The Dow Chemical Company Process for preparation of syndiotactic vinyl aromatic polymers
US5763549A (en) 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
EP0426637B2 (en) 1989-10-30 2001-09-26 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
FR2660926B1 (fr) 1990-04-11 1992-07-31 Bp Chemicals Snc Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere.
EP0551277B2 (en) 1990-06-22 2005-03-09 ExxonMobil Chemical Patents Inc. Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
DE69130320T2 (de) 1990-07-24 1999-04-08 Mitsui Chemicals Inc Katalysator für alpha-olefinpolymerisation und herstellung von poly(alpha)olefinen damit
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
DE59107926D1 (de) 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5243001A (en) 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
ES2071888T3 (es) * 1990-11-12 1995-07-01 Hoechst Ag Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas.
EP0513380B2 (en) 1990-11-30 2011-02-23 Idemitsu Kosan Company Limited Process for producing olefinic polymer
US5189192A (en) 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
US5206197A (en) 1991-03-04 1993-04-27 The Dow Chemical Company Catalyst composition for preparation of syndiotactic vinyl aromatic polymers
US5236998A (en) 1991-03-07 1993-08-17 Occidental Chemical Corporation Process for the manufacture of linear polyethylene containing α-alkene commonomers
TW218884B (pt) 1991-05-01 1994-01-11 Mitsubishi Kakoki Kk
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5235081A (en) 1992-03-18 1993-08-10 Ethyl Corporation Method of removing gel forming materials from methylaluminoxanes
US5308815A (en) 1991-07-26 1994-05-03 Ethyl Corporation Heterogeneous methylaluminoxane catalyst system
US5157137A (en) 1991-07-26 1992-10-20 Ethyl Corporation Method of making gel free alkylaluminoxane solutions
TW300901B (pt) 1991-08-26 1997-03-21 Hoechst Ag
CA2077744C (en) 1991-09-30 2003-04-15 Edwar Shoukri Shamshoum Homogeneous-heterogeneous catalyst system for polyolefins
US5589555A (en) 1991-10-03 1996-12-31 Novacor Chemicals (International) S.A. Control of a solution process for polymerization of ethylene
EP0537686B1 (de) 1991-10-15 2005-01-12 Basell Polyolefine GmbH Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
ES2108766T3 (es) 1991-10-15 1998-01-01 Dow Chemical Co Preparacion de complejos de coordinacion de metal.
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
US5359015A (en) 1991-11-07 1994-10-25 Exxon Chemical Patents Inc. Metallocene catalysts and their production and use
US5281679A (en) 1991-11-07 1994-01-25 Exxon Chemical Patents Inc. Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof
DE69224600T2 (de) 1991-11-12 1998-08-27 Nippon Oil Co Ltd Katalysatorbestandteile für Olefinpolymerisation
EP0544308B1 (en) 1991-11-28 1998-02-18 Showa Denko Kabushikikaisha Novel metallocene and process for producing polyolefin using the same
CA2105555C (en) 1992-01-06 2003-12-30 Brian W. S. Kolthammer Improved catalyst composition
US5391660A (en) 1992-01-14 1995-02-21 Nippon Oil Company, Limited Process for preparing polyolefines
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5374696A (en) 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
US5473202A (en) 1992-06-05 1995-12-05 Brian Platner Control unit for occupancy sensor switching of high efficiency lighting
US5238892A (en) 1992-06-15 1993-08-24 Exxon Chemical Patents Inc. Supported catalyst for 1-olefin(s) (co)polymerization
WO1994001471A1 (en) 1992-07-01 1994-01-20 Exxon Chemical Patents Inc. Transition metal olefin polymerization catalysts
EP1110974B1 (en) 1992-08-05 2007-11-28 ExxonMobil Chemical Patents Inc. Method for preparing a supported activator component
US5248801A (en) 1992-08-27 1993-09-28 Ethyl Corporation Preparation of methylaluminoxanes
DE69312306T2 (de) 1992-10-02 1997-11-13 Dow Chemical Co Aufträger homogener komplexkatalysator für olefinpolymerisation
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5939346A (en) 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group
US5391793A (en) 1992-11-02 1995-02-21 Akzo Nobel N.V. Aryloxyaluminoxanes
DE69307472T2 (de) 1992-11-10 1997-05-15 Mitsubishi Chem Corp Verfahren zur Herstellung von Alpha-Olefinpolymeren
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5391529A (en) 1993-02-01 1995-02-21 Albemarle Corporation Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene
TW298593B (pt) 1993-02-12 1997-02-21 Hoechst Ag
ATE204884T1 (de) 1993-04-07 2001-09-15 Atofina Res Verfahren zur herstellung von polyolefinkatalysatoren
JP3077940B2 (ja) 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
CN1087326C (zh) * 1993-05-13 2002-07-10 埃克森美孚化学专利公司 乙烯共聚物制备的薄膜及其制备方法
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
CA2127822A1 (en) 1993-07-13 1995-01-14 Yoshinori Morita Process for gas phase polymerization of olefin
CA2168883C (en) * 1993-08-06 2000-07-04 Moses Olukayode Jejelowo Polymerization catalysts, their production and use
CA2129794A1 (en) 1993-08-10 1995-02-11 Toshiyuki Tsutsui Olefin polymerization catalysts and methods of olefin polymerization
US5455214A (en) 1993-09-09 1995-10-03 Mobil Oil Corporation Metallocenes supported on ion exchange resins
US5422325A (en) 1993-09-17 1995-06-06 Exxon Chemical Patents Inc. Supported polymerization catalysts, their production and use
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE69421411T2 (de) 1993-11-19 2000-06-08 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
FI95276C (fi) 1993-12-03 1996-01-10 Borealis As Olefiinien polymerointikatalyytti ja menetelmä sen valmistamiseksi
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
DE69525042T3 (de) 1994-02-14 2005-10-20 Univation Technologies, LLC, Houston Polymerisationskatalysatorsysteme, ihre herstellung und ihre verwendung
IT1269931B (it) 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5629253A (en) 1994-04-26 1997-05-13 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
IT1269837B (it) 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
DE69522806T2 (de) 1994-06-24 2002-05-16 Exxonmobil Chemical Patents Inc., Baytown Monocyclopentadienyl-metalverbindungen als katalysatoren zur produktion von ethylen-alpha-olefincopolymeren
AU686836B2 (en) 1994-06-24 1998-02-12 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
CA2193882C (en) 1994-06-24 2005-07-26 Anthony Nicholas Speca Polymerization catalyst systems, their production and use
US5468702A (en) 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
IT1270070B (it) 1994-07-08 1997-04-28 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5643847A (en) 1994-08-03 1997-07-01 Exxon Chemical Patents Inc. Supported ionic catalyst composition
GB9417211D0 (en) 1994-08-25 1994-10-12 Solicitor For The Affairs Of H Nucleotide sequencing method
US5763543A (en) 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
EP0785955B1 (en) 1994-10-13 1999-07-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
KR100368194B1 (ko) 1994-10-13 2003-04-03 니혼폴리올레핀 가부시키가이샤 폴리올레핀제조용촉매성분,당해촉매성분을포함하는폴리올레핀제조용촉매및당해촉매존재하의폴리올레핀의제조방법
US5529965A (en) 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5770755A (en) 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
US6506866B2 (en) * 1994-11-17 2003-01-14 Dow Global Technologies Inc. Ethylene copolymer compositions
US5625015A (en) 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
US5714424A (en) 1995-01-09 1998-02-03 W. R. Grace & Co.-Conn. Multi-component polyolefin catalysts
NZ303800A (en) 1995-01-24 2000-05-26 Univ North Carolina Olefin polymers and block polymers, preparation, use, catalysts and catalyst intermediates
IT1274253B (it) 1995-02-21 1997-07-15 Himont Inc Processo per la preparazione di componenti catalitici solidi per la polimerizzazione di olefine
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US5705578A (en) 1995-05-04 1998-01-06 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
IT1275412B (it) 1995-06-01 1997-08-05 Enichem Spa Procedimento per la preparazione di ossidi misti silice-allumina porosi in forma sferica
US5767031A (en) 1995-06-07 1998-06-16 Fina Technology, Inc. Ziegler-Natta catalysts modified with metallocenes
US5898475A (en) * 1995-06-19 1999-04-27 Martin; David A. Precision fragrance dispenser apparatus
IT1275777B1 (it) 1995-07-06 1997-10-17 Enichem Spa Catalizzatore metallocenico per la (co)polimerizzazione delle olefine
JPH11508932A (ja) 1995-07-06 1999-08-03 エクソン・ケミカル・パテンツ・インク 予備重合され担持されたメタロセン触媒系の製造方法
US5677375A (en) 1995-07-21 1997-10-14 Union Carbide Chemicals & Plastics Technology Corporation Process for producing an in situ polyethylene blend
US5731253A (en) 1995-07-27 1998-03-24 Albemarle Corporation Hydrocarbylsilloxy - aluminoxane compositions
DE69602329T2 (de) 1995-09-14 1999-09-23 Showa Denko K.K., Tokio/Tokyo Katalysator für ethylenische Polymerisation
KR19990067026A (ko) 1995-10-27 1999-08-16 그레이스 스티븐 에스. 용이하게 지지될 수 있는 금속 착체
US5693838A (en) 1995-11-13 1997-12-02 Albemarle Corporation Aluminoxane process and product
US5688880A (en) 1995-12-11 1997-11-18 The Dow Chemical Company Readily supportable metal complexes
US5665818A (en) 1996-03-05 1997-09-09 Union Carbide Chemicals & Plastics Technology Corporation High activity staged reactor process
US5627242A (en) 1996-03-28 1997-05-06 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling gas phase fluidized bed polymerization reactor
ES2129323B1 (es) 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
CN1093141C (zh) 1996-05-17 2002-10-23 Bp化学有限公司 最大分子量出现在共聚单体含量最高的组合物部分中的聚烯烃共聚物组合物
US5723402A (en) 1996-05-30 1998-03-03 Pq Corporation Silicas with specific contents of cations as supports for olefin polymerization catalysts
US5693727A (en) 1996-06-06 1997-12-02 Union Carbide Chemicals & Plastics Technology Corporation Method for feeding a liquid catalyst to a fluidized bed polymerization reactor
DE19624581C2 (de) 1996-06-20 1999-02-04 Targor Gmbh Übergangsmetallverbindung und ein Verfahren zu ihrer Herstellung, sowie ihre Verwendung
US5731451A (en) 1996-07-12 1998-03-24 Akzo Nobel Nv Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
WO1998009996A1 (en) 1996-09-06 1998-03-12 Hyundai Petrochemical Co., Ltd. Catalyst system for (co)polymerization of olefins and process for the preparation of olefin (co)polymers using the catalyst system
WO1998011144A1 (en) 1996-09-12 1998-03-19 Bp Chemicals Limited Polymerisation catalyst
US5744656A (en) 1996-10-25 1998-04-28 Boulder Scientific Company Conversion of hexafluorobenzene to bromopentafluorobenzene
US6635778B1 (en) 1996-10-30 2003-10-21 Repsol Quimica S.A. Catalysts systems for the polymerization and copolymerization of alpha-olefins
US5753785A (en) * 1996-12-16 1998-05-19 Fina Technology, Inc. Production of E-B copolymers with a single metallocene catalyst and a single monomer
EP0954540B1 (en) 1997-01-14 2004-07-28 SABIC Polypropylenes B.V. A process for polymerizing olefins
NL1004992C2 (nl) 1997-01-14 1998-07-15 Dsm Nv Toepassing van verbindingen die Si, Ge, Sn of Pb bevatten als cokatalysator bij de polymerisatie van olefinen.
US5924597A (en) * 1997-09-19 1999-07-20 Lynn; David M. Building fragrance distribution system and method
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US6039212A (en) * 1998-02-20 2000-03-21 Ccl Industries Inc. Aerosol dispenser
US7354880B2 (en) 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
ATE420902T1 (de) * 1999-05-05 2009-01-15 Ineos Europe Ltd Ethylencopolymere und daraus hergestellte filme
US6339134B1 (en) * 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
CN1231506C (zh) * 1999-08-13 2005-12-14 巴塞尔聚烯烃股份有限公司 乙烯与C3－C12α－烯烃的共聚物
US6388155B1 (en) 2000-08-01 2002-05-14 Abb Lummus Global Inc. Styrene dehydrogenation reactor effluent treatment
ATE244075T1 (de) * 2000-08-30 2003-07-15 Pfeiffer Erich Gmbh & Co Kg Miniatur-spender zur abgabe von düften in verschiedenen anwendungsbereichen und umgebungen
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
CN1257198C (zh) * 2001-08-17 2006-05-24 出光兴产株式会社 乙烯基共聚物和包含它的膜
US6960634B2 (en) * 2001-10-31 2005-11-01 Univation Technologies, Llc Methods for adjusting melt properties of metallocene catalyzed olefin copolymers
US6841504B2 (en) * 2002-01-28 2005-01-11 Univation Technologies, Llc Polymerization catalyst activator and its use in a polymerization process
GB0217116D0 (en) * 2002-07-24 2002-09-04 Givaudan Sa Device
US6958306B2 (en) * 2003-08-28 2005-10-25 Univation Technologies, Llc Activated catalyst systems from substituted dialuminoxane complexes
US6870010B1 (en) 2003-12-01 2005-03-22 Univation Technologies, Llc Low haze high strength polyethylene compositions
US20050127206A1 (en) * 2003-12-10 2005-06-16 Xerox Corporation Device and system for dispensing fluids into the atmosphere
DE602005026837D1 (de) * 2004-10-21 2011-04-21 Basell Polyolefine Gmbh 1-buten-polymer und herstellungsverfahren dafür
TW200932770A (en) * 2007-10-22 2009-08-01 Univation Tech Llc Metallocene catalysts and their use in polymerization processes

Also Published As

Publication number Publication date
WO2009054888A1 (en) 2009-04-30
TW200932762A (en) 2009-08-01
EP3597294B1 (en) 2025-02-26
EP3597294A1 (en) 2020-01-22
ES2784439T3 (es) 2020-09-25
EP2214820B1 (en) 2018-09-12
US20110098422A1 (en) 2011-04-28
US8329835B2 (en) 2012-12-11
EP3372311A1 (en) 2018-09-12
EP3372311B1 (en) 2020-02-26
AR068937A1 (es) 2009-12-16
RU2010120473A (ru) 2011-11-27
CN101835536A (zh) 2010-09-15
EP2214820A1 (en) 2010-08-11
ES3022957T3 (en) 2025-05-29
RU2448132C2 (ru) 2012-04-20
CN101835536B (zh) 2015-05-20
BRPI0817893B1 (pt) 2019-08-06

Similar Documents

Publication Publication Date Title
EP2226357A4 (en) PROPYLENE POLYMER COMPOSITION
EP2167602A4 (en) COMPOSITIONS CONTAINING DIFLUOROMETHANE
BRPI0820483A2 (pt) Variantes de glicoamilase com propriedades alteradas
DK2164893T3 (da) Polyethylenskum
EP2280916A4 (en) HYDROCHLORFLUOROLEFINZUSAMMENSETZUNGEN
DK2106423T3 (da) Bituminøs sammensætning med termoreversible egenskaber
EP2381760A4 (en) CORN PROTEIN COMPOSITION
EP2246377A4 (en) Resin composition
BRPI0913806A2 (pt) "composição"
BRPI0814973A2 (pt) Composições poliolefínicas plastificadas
BRPI0810634A2 (pt) Composições fungicidas
HUE059171T2 (hu) Kompozíciók
DK3095856T3 (da) Sammensætninger med trombocytindhold
BRPI0813775A2 (pt) Composição
ATE528048T1 (de) Schweisshemmende/desodorierende zusammensetzung
DE602008001230D1 (de) Verbesserte Polymerzusammensetzung
BRPI1013222A2 (pt) composições de mirceno polimérico
EP2287246A4 (en) polyolefin resin
BRPI0810557A2 (pt) composição
BRPI0811274A2 (pt) Composição
BRPI0810004A2 (pt) composições asfálticas modificadas por polímero
BRPI0919718A2 (pt) Composição nutricional com propriedades antirregurgitação
PT2182988E (pt) Composição radiofarmacêutica
BRPI0811002A2 (pt) Composição biofertilizante
EP2151477A4 (en) POLYMER COMPOSITION

Legal Events

Date Code Title Description
B06G Technical and formal requirements: other requirements [chapter 6.7 patent gazette]
B06I Publication of requirement cancelled [chapter 6.9 patent gazette]

Free format text: ANULADA A PUBLICACAO CODIGO 6.7 NA RPI NO 2492 DE 09/10/2018 POR TER SIDO INDEVIDA.

B06T Formal requirements before examination [chapter 6.20 patent gazette]
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 06/08/2019, OBSERVADAS AS CONDICOES LEGAIS. (CO) 10 (DEZ) ANOS CONTADOS A PARTIR DE 06/08/2019, OBSERVADAS AS CONDICOES LEGAIS