CA1107926A - Fibres de siliciumcarbide a forte resistance, et methode de production connexe - Google Patents

Fibres de siliciumcarbide a forte resistance, et methode de production connexe

Info

Publication number: CA1107926A
Authority: CA; Canada
Prior art keywords: molecular weight; fibers; compound; temperature; high molecular
Prior art date: 1975-04-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA360,132A

Other languages

English (en)

Inventor

Seishi Yajima

Mamoru Omori

Josaburo Hayashi

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Research Institute for Iron Steel and Other Metals of Tohoku University

Original Assignee

Research Institute for Iron Steel and Other Metals of Tohoku University

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-04-25

Filing date

1980-09-11

Publication date

1981-09-01

1975-04-25 Priority claimed from JP5052975A external-priority patent/JPS51139929A/ja

1975-05-02 Priority claimed from JP50052472A external-priority patent/JPS51130325A/ja

1975-05-02 Priority claimed from JP50052471A external-priority patent/JPS5838534B2/ja

1975-05-16 Priority claimed from JP5803375A external-priority patent/JPS51149925A/ja

1975-05-16 Priority claimed from JP5803475A external-priority patent/JPS51149926A/ja

1975-06-11 Priority claimed from JP7030275A external-priority patent/JPS51147623A/ja

1975-06-11 Priority claimed from JP50070303A external-priority patent/JPS6028927B2/ja

1975-06-23 Priority claimed from JP7721975A external-priority patent/JPS521136A/ja

1975-06-30 Priority claimed from JP7997275A external-priority patent/JPS5838535B2/ja

1975-09-04 Priority claimed from JP10737175A external-priority patent/JPS5231126A/ja

1976-04-21 Priority claimed from CA250,637A external-priority patent/CA1095672A/fr

1980-09-11 Priority to CA360,132A priority Critical patent/CA1107926A/fr

1980-09-11 Application filed by Research Institute for Iron Steel and Other Metals of Tohoku University filed Critical Research Institute for Iron Steel and Other Metals of Tohoku University

1981-09-01 Publication of CA1107926A publication Critical patent/CA1107926A/fr

1981-09-01 Application granted granted Critical

Status Expired legal-status Critical Current

Links

239000000835 fiber Substances 0.000 title claims abstract description 575
229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 204
HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 193
238000004519 manufacturing process Methods 0.000 title claims abstract description 17
150000002605 large molecules Chemical class 0.000 claims abstract description 165
238000010438 heat treatment Methods 0.000 claims abstract description 146
238000009987 spinning Methods 0.000 claims abstract description 146
239000007789 gas Substances 0.000 claims abstract description 103
150000003384 small molecules Chemical class 0.000 claims abstract description 87
239000012298 atmosphere Substances 0.000 claims abstract description 52
229910052710 silicon Inorganic materials 0.000 claims abstract description 49
239000010703 silicon Substances 0.000 claims abstract description 49
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 32
229910052799 carbon Inorganic materials 0.000 claims abstract description 30
230000001590 oxidative effect Effects 0.000 claims abstract description 27
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 26
239000011261 inert gas Substances 0.000 claims abstract description 19
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 336
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 131
239000000243 solution Substances 0.000 claims description 123
150000001875 compounds Chemical class 0.000 claims description 122
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 120
238000006068 polycondensation reaction Methods 0.000 claims description 66
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 56
238000000034 method Methods 0.000 claims description 48
239000000203 mixture Substances 0.000 claims description 42
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 27
150000003961 organosilicon compounds Chemical class 0.000 claims description 24
230000032683 aging Effects 0.000 claims description 21
239000002904 solvent Substances 0.000 claims description 17
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 15
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 14
239000008096 xylene Substances 0.000 claims description 14
CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 13
WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 12
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 12
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
238000011282 treatment Methods 0.000 claims description 12
229910052760 oxygen Inorganic materials 0.000 claims description 10
239000001301 oxygen Substances 0.000 claims description 10
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 9
229910018540 Si C Inorganic materials 0.000 claims description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
230000007423 decrease Effects 0.000 claims description 9
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 8
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 8
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 8
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 8
HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims description 8
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 8
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 8
239000003054 catalyst Substances 0.000 claims description 7
239000004342 Benzoyl peroxide Substances 0.000 claims description 6
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 6
235000019400 benzoyl peroxide Nutrition 0.000 claims description 6
150000002978 peroxides Chemical class 0.000 claims description 6
229910008045 Si-Si Inorganic materials 0.000 claims description 5
229910006411 Si—Si Inorganic materials 0.000 claims description 5
150000002148 esters Chemical class 0.000 claims description 5
229910052736 halogen Inorganic materials 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
230000003647 oxidation Effects 0.000 claims description 5
238000007254 oxidation reaction Methods 0.000 claims description 5
SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 claims description 4
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 4
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 4
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 4
229910007991 Si-N Inorganic materials 0.000 claims description 4
229910008051 Si-OH Inorganic materials 0.000 claims description 4
229910002808 Si–O–Si Inorganic materials 0.000 claims description 4
229910006294 Si—N Inorganic materials 0.000 claims description 4
229910006358 Si—OH Inorganic materials 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 4
125000003118 aryl group Chemical group 0.000 claims description 4
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 4
230000007797 corrosion Effects 0.000 claims description 3
238000005260 corrosion Methods 0.000 claims description 3
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 claims description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 2
229910052794 bromium Inorganic materials 0.000 claims description 2
KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 claims description 2
239000012286 potassium permanganate Substances 0.000 claims description 2
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 9
UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 claims 6
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims 6
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 6
UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims 3
WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 claims 3
OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims 3
229950005499 carbon tetrachloride Drugs 0.000 claims 3
229940117389 dichlorobenzene Drugs 0.000 claims 3
229940058172 ethylbenzene Drugs 0.000 claims 3
VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims 3
238000002844 melting Methods 0.000 claims 3
230000008018 melting Effects 0.000 claims 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 3
229910002621 H2PtCl6 Inorganic materials 0.000 claims 2
235000011149 sulphuric acid Nutrition 0.000 claims 2
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
OPFTUNCRGUEPRZ-QLFBSQMISA-N Cyclohexane Natural products CC(=C)[C@@H]1CC[C@@](C)(C=C)[C@H](C(C)=C)C1 OPFTUNCRGUEPRZ-QLFBSQMISA-N 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 58
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 54
239000013078 crystal Substances 0.000 description 41
239000002244 precipitate Substances 0.000 description 41
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 36
238000001035 drying Methods 0.000 description 34
239000012300 argon atmosphere Substances 0.000 description 33
239000007795 chemical reaction product Substances 0.000 description 32
230000000694 effects Effects 0.000 description 28
229910052786 argon Inorganic materials 0.000 description 27
239000007788 liquid Substances 0.000 description 26
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 26
-1 poly(ethyleneoxysiloxane) Polymers 0.000 description 24
239000007858 starting material Substances 0.000 description 24
239000007787 solid Substances 0.000 description 23
239000000463 material Substances 0.000 description 22
239000000047 product Substances 0.000 description 22
238000004821 distillation Methods 0.000 description 18
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 16
LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 15
239000001257 hydrogen Substances 0.000 description 14
229910052739 hydrogen Inorganic materials 0.000 description 14
238000010517 secondary reaction Methods 0.000 description 14
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
239000000126 substance Substances 0.000 description 13
239000012265 solid product Substances 0.000 description 10
238000010586 diagram Methods 0.000 description 9
RTCLHEHPUHREBC-UHFFFAOYSA-N 1,1,2,2,3,3,4,4,5,5,6,6-dodecamethylhexasilinane Chemical compound C[Si]1(C)[Si](C)(C)[Si](C)(C)[Si](C)(C)[Si](C)(C)[Si]1(C)C RTCLHEHPUHREBC-UHFFFAOYSA-N 0.000 description 8
IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 8
235000019441 ethanol Nutrition 0.000 description 8
239000001294 propane Substances 0.000 description 8
238000003786 synthesis reaction Methods 0.000 description 8
239000004215 Carbon black (E152) Substances 0.000 description 7
239000000460 chlorine Substances 0.000 description 7
229910001873 dinitrogen Inorganic materials 0.000 description 7
229930195733 hydrocarbon Natural products 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
238000003756 stirring Methods 0.000 description 7
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
238000002003 electron diffraction Methods 0.000 description 6
NEXSMEBSBIABKL-UHFFFAOYSA-N hexamethyldisilane Chemical compound C[Si](C)(C)[Si](C)(C)C NEXSMEBSBIABKL-UHFFFAOYSA-N 0.000 description 6
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
125000000962 organic group Chemical group 0.000 description 6
229920000548 poly(silane) polymer Polymers 0.000 description 6
238000002441 X-ray diffraction Methods 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
230000008859 change Effects 0.000 description 5
125000004122 cyclic group Chemical group 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 5
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
229910002804 graphite Inorganic materials 0.000 description 5
239000010439 graphite Substances 0.000 description 5
229920006158 high molecular weight polymer Polymers 0.000 description 5
239000000155 melt Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 5
239000002184 metal Substances 0.000 description 5
239000005055 methyl trichlorosilane Substances 0.000 description 5
JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 5
229920000555 poly(dimethylsilanediyl) polymer Polymers 0.000 description 5
CZDYPVPMEAXLPK-UHFFFAOYSA-N tetramethylsilane Chemical compound C[Si](C)(C)C CZDYPVPMEAXLPK-UHFFFAOYSA-N 0.000 description 5
KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
239000008246 gaseous mixture Substances 0.000 description 4
239000001307 helium Substances 0.000 description 4
229910052734 helium Inorganic materials 0.000 description 4
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
239000002932 luster Substances 0.000 description 4
230000008569 process Effects 0.000 description 4
150000003254 radicals Chemical class 0.000 description 4
230000035882 stress Effects 0.000 description 4
239000005051 trimethylchlorosilane Substances 0.000 description 4
229920000049 Carbon (fiber) Polymers 0.000 description 3
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
229920000297 Rayon Polymers 0.000 description 3
239000002253 acid Substances 0.000 description 3
238000005452 bending Methods 0.000 description 3
239000004917 carbon fiber Substances 0.000 description 3
229910002091 carbon monoxide Inorganic materials 0.000 description 3
YGZSVWMBUCGDCV-UHFFFAOYSA-N chloro(methyl)silane Chemical compound C[SiH2]Cl YGZSVWMBUCGDCV-UHFFFAOYSA-N 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
239000003999 initiator Substances 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
238000000465 moulding Methods 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
229920001558 organosilicon polymer Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
238000004064 recycling Methods 0.000 description 3
MHBOFSJQAKACCM-UHFFFAOYSA-N 1,1,2,2,3,3,4,4-octakis-phenyltetrasiletane Chemical compound C1=CC=CC=C1[Si]1(C=2C=CC=CC=2)[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 MHBOFSJQAKACCM-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
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229910007161 Si(CH3)3 Inorganic materials 0.000 description 2
RQVFGTYFBUVGOP-UHFFFAOYSA-N [acetyloxy(dimethyl)silyl] acetate Chemical compound CC(=O)O[Si](C)(C)OC(C)=O RQVFGTYFBUVGOP-UHFFFAOYSA-N 0.000 description 2
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238000009835 boiling Methods 0.000 description 2
150000001723 carbon free-radicals Chemical class 0.000 description 2
HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 2
229910052681 coesite Inorganic materials 0.000 description 2
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238000004132 cross linking Methods 0.000 description 2
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OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 2
KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 2
IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 2
238000009826 distribution Methods 0.000 description 2
230000009977 dual effect Effects 0.000 description 2
229960003750 ethyl chloride Drugs 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000005048 methyldichlorosilane Substances 0.000 description 2
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239000002964 rayon Substances 0.000 description 2
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KNDAEDDIIQYRHY-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-(piperazin-1-ylmethyl)pyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CN1CCNCC1 KNDAEDDIIQYRHY-UHFFFAOYSA-N 0.000 description 1
VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
241000256844 Apis mellifera Species 0.000 description 1
125000006519 CCH3 Chemical group 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
101100353161 Drosophila melanogaster prel gene Proteins 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
241001274660 Modulus Species 0.000 description 1
VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
229910003849 O-Si Inorganic materials 0.000 description 1
229910003872 O—Si Inorganic materials 0.000 description 1
YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
241000212342 Sium Species 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
MRHIKEHTLHXDRQ-UHFFFAOYSA-N [diamino(methyl)silyl]methane Chemical compound C[Si](C)(N)N MRHIKEHTLHXDRQ-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
230000003064 anti-oxidating effect Effects 0.000 description 1
QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
238000007664 blowing Methods 0.000 description 1
239000004566 building material Substances 0.000 description 1
239000001273 butane Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
AGOYDEPGAOXOCK-KCBOHYOISA-N clarithromycin Chemical compound O([C@@H]1[C@@H](C)C(=O)O[C@@H]([C@@]([C@H](O)[C@@H](C)C(=O)[C@H](C)C[C@](C)([C@H](O[C@H]2[C@@H]([C@H](C[C@@H](C)O2)N(C)C)O)[C@H]1C)OC)(C)O)CC)[C@H]1C[C@@](C)(OC)[C@@H](O)[C@H](C)O1 AGOYDEPGAOXOCK-KCBOHYOISA-N 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
JZALIDSFNICAQX-UHFFFAOYSA-N dichloro-methyl-trimethylsilylsilane Chemical compound C[Si](C)(C)[Si](C)(Cl)Cl JZALIDSFNICAQX-UHFFFAOYSA-N 0.000 description 1
VDCSGNNYCFPWFK-UHFFFAOYSA-N diphenylsilane Chemical compound C=1C=CC=CC=1[SiH2]C1=CC=CC=C1 VDCSGNNYCFPWFK-UHFFFAOYSA-N 0.000 description 1
229920001971 elastomer Polymers 0.000 description 1
238000005485 electric heating Methods 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
239000002657 fibrous material Substances 0.000 description 1
239000012530 fluid Substances 0.000 description 1
230000002431 foraging effect Effects 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000003365 glass fiber Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
208000006278 hypochromic anemia Diseases 0.000 description 1
239000012784 inorganic fiber Substances 0.000 description 1
230000001788 irregular Effects 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002074 melt spinning Methods 0.000 description 1
239000012528 membrane Substances 0.000 description 1
MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
125000005699 methyleneoxy group Chemical group [H]C([H])([*:1])O[*:2] 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
235000014571 nuts Nutrition 0.000 description 1
150000001282 organosilanes Chemical class 0.000 description 1
125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
239000004033 plastic Substances 0.000 description 1
229920003023 plastic Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
230000005855 radiation Effects 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000005060 rubber Substances 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000000926 separation method Methods 0.000 description 1
FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
150000004756 silanes Chemical class 0.000 description 1
150000004819 silanols Chemical class 0.000 description 1
239000005049 silicon tetrachloride Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000010959 steel Substances 0.000 description 1
229920002994 synthetic fiber Polymers 0.000 description 1
239000012209 synthetic fiber Substances 0.000 description 1
UFHILTCGAOPTOV-UHFFFAOYSA-N tetrakis(ethenyl)silane Chemical compound C=C[Si](C=C)(C=C)C=C UFHILTCGAOPTOV-UHFFFAOYSA-N 0.000 description 1
WVMSIBFANXCZKT-UHFFFAOYSA-N triethyl(hydroxy)silane Chemical compound CC[Si](O)(CC)CC WVMSIBFANXCZKT-UHFFFAOYSA-N 0.000 description 1
125000003258 trimethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])[*:1] 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Landscapes

Inorganic Fibers (AREA)

CA360,132A 1975-04-25 1980-09-11 Fibres de siliciumcarbide a forte resistance, et methode de production connexe Expired CA1107926A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA360,132A CA1107926A (fr)	1975-04-25	1980-09-11	Fibres de siliciumcarbide a forte resistance, et methode de production connexe

Applications Claiming Priority (22)

Application Number	Priority Date	Filing Date	Title
JP50,529/75		1975-04-25
JP5052975A JPS51139929A (en)	1975-04-25	1975-04-25	Manufacturing silicon carbide fibers
JP50052471A JPS5838534B2 (ja)	1975-05-02	1975-05-02	コウキヨウドシリコンカ−バイドセンイノセイゾウホウホウ
JP52,472/75		1975-05-02
JP52,471/75		1975-05-02
JP50052472A JPS51130325A (en)	1975-05-02	1975-05-02	A process for manufacturing silicon carbide fibers
JP58,034/75		1975-05-16
JP5803475A JPS51149926A (en)	1975-05-16	1975-05-16	Method of producing silicon carbide fibers
JP58,033/75		1975-05-16
JP5803375A JPS51149925A (en)	1975-05-16	1975-05-16	Process for manufacturing high strength silicon carbide fibers
JP70,302/75		1975-06-11
JP70,303/75		1975-06-11
JP7030275A JPS51147623A (en)	1975-06-11	1975-06-11	A process for manufacturing silicon carbide fibers with high strength
JP50070303A JPS6028927B2 (ja)	1975-06-11	1975-06-11	シリコンカ−バイド繊維の製造方法
JP77,219/75		1975-06-23
JP7721975A JPS521136A (en)	1975-06-23	1975-06-23	Silicon carbide fibers with high tensile strength composed of ultrafin e silicon carbide
JP7997275A JPS5838535B2 (ja)	1975-06-30	1975-06-30	コウキヨウドシリコンカ−バイドセンイノセイゾウホウホウ
JP79,972/75		1975-06-30
JP107,371/75		1975-09-04
JP10737175A JPS5231126A (en)	1975-09-04	1975-09-04	Preparation of high strength silicon carbide fibers
CA250,637A CA1095672A (fr)	1975-04-25	1976-04-21	Procede d'obtention de fibres de carbure de silicium tres resistantes
CA360,132A CA1107926A (fr)	1975-04-25	1980-09-11	Fibres de siliciumcarbide a forte resistance, et methode de production connexe

Publications (1)

Publication Number	Publication Date
CA1107926A true CA1107926A (fr)	1981-09-01

Family

ID=27582864

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA360,132A Expired CA1107926A (fr)	1975-04-25	1980-09-11	Fibres de siliciumcarbide a forte resistance, et methode de production connexe

Country Status (1)

Country	Link
CA (1)	CA1107926A (fr)

1980
- 1980-09-11 CA CA360,132A patent/CA1107926A/fr not_active Expired

Legal Events

Date	Code	Title	Description
1998-09-01	MKEX	Expiry

Publication	Publication Date	Title
US4100233A (en)	1978-07-11	Silicon carbide fibers having a high strength and a method for producing said fibers
US4283376A (en)	1981-08-11	Method of producing silicon carbide fibers
EP0021844B1 (fr)	1982-06-23	Fibres inorganiques continues et procédé pour leur fabrication
CA1077512A (fr)	1980-05-13	Production de composes d'organosilicium a p.m. eleve, ayant un tronc principal de silicium et de carbone
CA1083789A (fr)	1980-08-19	Procede de fabrication de profiles de carbure de silicium fritte
US4663229A (en)	1987-05-05	Continuous inorganic fibers and process for production thereof
US4818611A (en)	1989-04-04	High-purity silicon nitride fibers
JPS6353293B2 (fr)	1988-10-21
EP0200326B2 (fr)	1993-05-12	Procédé de préparation de matériaux céramiques avec des teneurs en carbone réduites
KR850000153B1 (ko)	1985-02-28	실리콘 카바이드 전 · 중합체의 제조방법
US4916093A (en)	1990-04-10	Method of producing continuous inorganic fiber consisting of Si, N and O
US4948763A (en)	1990-08-14	Preparation of hollow ceramic fibers
CA1107926A (fr)	1981-09-01	Fibres de siliciumcarbide a forte resistance, et methode de production connexe
US4824918A (en)	1989-04-25	Method of producing silicon carbide preceramic vinyl-containing polymers
WO1987005612A1 (fr)	1987-09-24	Organopolyarylsilane, procede de production et fibres preparees a partir de ce compose
EP0048957B1 (fr)	1984-08-15	Fibres inorganiques continues et procédé pour leur fabrication
EP0361181B1 (fr)	1995-03-22	Procédé pour rendre infusibles des polysilazanes et procédé de préparation de fibres céramiques creuses
US5863848A (en)	1999-01-26	Preparation of substantially crystalline silicon carbide fibers from borosilazanes
JPS6050884B2 (ja)	1985-11-11	主としてＳｉＣよりなるシリコンカ−バイド繊維の製造方法
JPH064701B2 (ja)	1994-01-19	有機ケイ素重合体の製造方法
JPS5933682B2 (ja)	1984-08-17	コウミツドシリコンカ−バイドセンイノセイゾウホウホウ
JPH02277849A (ja)	1990-11-14	複合材料用繊維体並びにその製造方法
JPS6363646B2 (fr)	1988-12-08
CA2086266A1 (fr)	1997-03-12	Preparation de fibres de carbure de silicium pratiquement cristallise a partir de borosilazanes
JP2575280B2 (ja)	1997-01-22	酸窒化珪素繊維の製法