CA1108085A - Methode de demetallisation des hydrocarbures - Google Patents

Methode de demetallisation des hydrocarbures

Info

Publication number: CA1108085A
Authority: CA; Canada
Prior art keywords: hydrogen; catalyst; process according; sulphide; demetallization
Prior art date: 1976-07-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA279,210A

Other languages

English (en)

Inventor

Dirk Bode

Robert H. Van Dongen

Jakob Van Klinken

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shell Canada Ltd

Original Assignee

Shell Canada Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1976-07-08

Filing date

1977-05-26

Publication date

1981-09-01

1977-05-26 Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd

1981-09-01 Application granted granted Critical

1981-09-01 Publication of CA1108085A publication Critical patent/CA1108085A/fr

Status Expired legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 72
239000003921 oil Substances 0.000 title claims abstract description 42
229930195733 hydrocarbon Natural products 0.000 title claims abstract description 30
150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 30
239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 29
239000003054 catalyst Substances 0.000 claims abstract description 98
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 38
239000001257 hydrogen Substances 0.000 claims abstract description 23
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
229910052720 vanadium Inorganic materials 0.000 claims abstract description 21
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 21
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 19
229910052759 nickel Inorganic materials 0.000 claims abstract description 19
239000002245 particle Substances 0.000 claims abstract description 18
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 37
239000011148 porous material Substances 0.000 claims description 31
229910052751 metal Inorganic materials 0.000 claims description 25
239000002184 metal Substances 0.000 claims description 25
239000007789 gas Substances 0.000 claims description 23
230000000694 effects Effects 0.000 claims description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
239000007788 liquid Substances 0.000 claims description 11
239000010779 crude oil Substances 0.000 claims description 9
150000002739 metals Chemical class 0.000 claims description 9
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
239000000203 mixture Substances 0.000 claims description 7
238000004517 catalytic hydrocracking Methods 0.000 claims description 6
239000010941 cobalt Substances 0.000 claims description 5
229910017052 cobalt Inorganic materials 0.000 claims description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 5
230000003134 recirculating effect Effects 0.000 claims description 5
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
150000002431 hydrogen Chemical class 0.000 claims description 4
229910052750 molybdenum Inorganic materials 0.000 claims description 4
239000011733 molybdenum Substances 0.000 claims description 4
239000000377 silicon dioxide Substances 0.000 claims description 4
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
229910052721 tungsten Inorganic materials 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
239000005864 Sulphur Substances 0.000 claims description 3
230000003197 catalytic effect Effects 0.000 claims description 3
238000005336 cracking Methods 0.000 claims description 2
238000006467 substitution reaction Methods 0.000 claims description 2
238000006243 chemical reaction Methods 0.000 claims 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
238000002474 experimental method Methods 0.000 description 14
229910052757 nitrogen Inorganic materials 0.000 description 8
239000000969 carrier Substances 0.000 description 7
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
229910052753 mercury Inorganic materials 0.000 description 6
239000000463 material Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
230000035515 penetration Effects 0.000 description 3
238000007493 shaping process Methods 0.000 description 3
238000005029 sieve analysis Methods 0.000 description 3
238000002336 sorption--desorption measurement Methods 0.000 description 3
102000018361 Contactin Human genes 0.000 description 2
108060003955 Contactin Proteins 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000009849 deactivation Effects 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 2
238000011835 investigation Methods 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
238000001465 metallisation Methods 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000008188 pellet Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000004071 soot Substances 0.000 description 2
150000003568 thioethers Chemical class 0.000 description 2
101150002048 FUR1 gene Proteins 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
239000003570 air Substances 0.000 description 1
SMYKVLBUSSNXMV-UHFFFAOYSA-K aluminum;trihydroxide;hydrate Chemical compound O.[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-K 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
238000004523 catalytic cracking Methods 0.000 description 1
238000006555 catalytic reaction Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000003795 desorption Methods 0.000 description 1
UAMZXLIURMNTHD-UHFFFAOYSA-N dialuminum;magnesium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Mg+2].[Al+3].[Al+3] UAMZXLIURMNTHD-UHFFFAOYSA-N 0.000 description 1
239000008187 granular material Substances 0.000 description 1
230000003179 granulation Effects 0.000 description 1
238000005469 granulation Methods 0.000 description 1
239000000017 hydrogel Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
239000011859 microparticle Substances 0.000 description 1
DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
150000002816 nickel compounds Chemical class 0.000 description 1
HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
239000002002 slurry Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/651—50-500 nm

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Materials Engineering (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Catalysts (AREA)

CA279,210A 1976-07-08 1977-05-26 Methode de demetallisation des hydrocarbures Expired CA1108085A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
NL7607551		1976-07-08
NL7607551A NL7607551A (nl)	1976-07-08	1976-07-08	Werkwijze voor het ontmetalliseren van koolwater- stofolien.

Publications (1)

Publication Number	Publication Date
CA1108085A true CA1108085A (fr)	1981-09-01

Family

ID=19826555

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA279,210A Expired CA1108085A (fr)	1976-07-08	1977-05-26	Methode de demetallisation des hydrocarbures

Country Status (14)

Country	Link
JP (1)	JPS537705A (fr)
AU (1)	AU506785B2 (fr)
BE (1)	BE856236A (fr)
CA (1)	CA1108085A (fr)
DE (1)	DE2730564A1 (fr)
DK (1)	DK304277A (fr)
FI (1)	FI64634C (fr)
FR (1)	FR2357634A1 (fr)
GB (1)	GB1560590A (fr)
IT (1)	IT1081515B (fr)
NL (1)	NL7607551A (fr)
NO (1)	NO151505C (fr)
SE (1)	SE421803B (fr)
ZA (1)	ZA774070B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS601056B2 (ja) *	1980-02-19	1985-01-11	千代田化工建設株式会社	アスファルテンを含む重質炭化水素油の水素化処理
CA1174629A (fr) *	1980-05-29	1984-09-18	Huno Van Der Eijk	Methode de demetallisation du petrole
EP0683218B1 (fr)	1994-05-19	2001-04-11	Shell Internationale Researchmaatschappij B.V.	Procédé de conversion d'une huile résiduelle hydrocarbonée
WO2010084112A1 (fr)	2009-01-20	2010-07-29	Shell Internationale Research Maatschappij B.V.	Procédé d'hydrodémétallisation de charges d'hydrocarbure

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1407610A (en) *	1972-10-13	1975-09-24	Shell Int Research	Hydrocarbon conversion process
NL184479C (nl) *	1974-03-29	1989-08-01	Shell Int Research	Werkwijze voor het katalytisch hydrogenerend ontzwavelen van vooraf ontmetalliseerde koolwaterstoffen.

1976
- 1976-07-08 NL NL7607551A patent/NL7607551A/xx not_active Application Discontinuation
1977
- 1977-05-26 CA CA279,210A patent/CA1108085A/fr not_active Expired
- 1977-06-29 BE BE1008236A patent/BE856236A/xx not_active IP Right Cessation
- 1977-07-06 SE SE7707884A patent/SE421803B/xx not_active IP Right Cessation
- 1977-07-06 IT IT25451/77A patent/IT1081515B/it active
- 1977-07-06 AU AU26797/77A patent/AU506785B2/en not_active Expired
- 1977-07-06 NO NO772400A patent/NO151505C/no unknown
- 1977-07-06 DE DE19772730564 patent/DE2730564A1/de active Granted
- 1977-07-06 FI FI772120A patent/FI64634C/fi not_active IP Right Cessation
- 1977-07-06 GB GB28314/77A patent/GB1560590A/en not_active Expired
- 1977-07-06 DK DK304277A patent/DK304277A/da not_active Application Discontinuation
- 1977-07-06 FR FR7720825A patent/FR2357634A1/fr active Granted
- 1977-07-06 JP JP8002077A patent/JPS537705A/ja active Granted
- 1977-07-06 ZA ZA00774070A patent/ZA774070B/xx unknown

Also Published As

Publication number	Publication date
FI64634C (fi)	1983-12-12
DE2730564C2 (fr)	1987-11-05
FR2357634A1 (fr)	1978-02-03
BE856236A (nl)	1977-12-29
AU506785B2 (en)	1980-01-24
JPH0122320B2 (fr)	1989-04-26
FI772120A7 (fr)	1978-01-09
IT1081515B (it)	1985-05-21
NL7607551A (nl)	1978-01-10
ZA774070B (en)	1978-05-30
FI64634B (fi)	1983-08-31
SE421803B (sv)	1982-02-01
AU2679777A (en)	1979-01-11
GB1560590A (en)	1980-02-06
JPS537705A (en)	1978-01-24
NO772400L (no)	1978-01-10
NO151505C (no)	1985-04-24
NO151505B (no)	1985-01-07
DE2730564A1 (de)	1978-01-12
FR2357634B1 (fr)	1982-07-09
DK304277A (da)	1978-01-09
SE7707884L (sv)	1978-01-09

Legal Events

Date	Code	Title	Description
1998-09-01	MKEX	Expiry

Publication	Publication Date	Title
RU2376059C2 (ru)	2009-12-20	Способ и катализатор гидроконверсии тяжелого углеводородного исходного сырья
US3887455A (en)	1975-06-03	Ebullating bed process for hydrotreatment of heavy crudes and residua
JP2816491B2 (ja)	1998-10-27	水素化及び又は脱水素触媒
US4374020A (en)	1983-02-15	Catalytic hydroconversion process with catalyst retainer
US3997473A (en)	1976-12-14	Hydrodesulfurization catalysts supported on carbon
US3925197A (en)	1975-12-09	Hydrodesulfurization process
WO1997008274A1 (fr)	1997-03-06	Procede d'hydroconversion au moyen d'un catalyseur a repartition de dimensions de pores specifique, sans ajout de silice
WO2004053028A1 (fr)	2004-06-24	Hydrotraitement d'hydrocarbones au moyen d'un melange de catalyseurs
JPH07286184A (ja)	1995-10-31	炭化水素の水素化転換方法
CA1094490A (fr)	1981-01-27	Methode pour demetalliser les hydrocarbures
WO2002100541A1 (fr)	2002-12-19	Catalyseur d'hydrocraquage presentant un nombre eleve de macropores, et procede d'utilisation d'un tel catalyseur
JPH0431737B2 (fr)	1992-05-27
US4032435A (en)	1977-06-28	Hydrodesulfurization of petroleum residuum utilizing a carbon-supported catalyst
CA1108085A (fr)	1981-09-01	Methode de demetallisation des hydrocarbures
JPS6027714B2 (ja)	1985-07-01	炭化水素の転化方法
EP0159097B1 (fr)	1990-08-29	Procédé pour la conversion catalytique d'huiles hydrocarbonées lourdes
CA1102778A (fr)	1981-06-09	Traduction non-disponible
US4810363A (en)	1989-03-07	Process for the catalytic conversion of hydrocarbon oils
EP0224944B1 (fr)	1991-08-07	Procédé pour la conversion des huiles d'hydrocarbures
EP0041284B1 (fr)	1983-10-05	Procédé de démétallisation d'huiles d'hydrocarbures
JPS6027712B2 (ja)	1985-07-01	炭化水素の転化法
CA1081151A (fr)	1980-07-08	Procede de conversion d'hydrocarbures
JPS5947719B2 (ja)	1984-11-21	炭化水素転化方法
JPS6027713B2 (ja)	1985-07-01	炭化水素の変換方法
CA2088042A1 (fr)	1993-07-28	Procede utilise pour convertir une huile de petrole