CA1121644A - Precipitation de l'halogenure d'argent avec une sensibilisation spectrale par un colorant a base de methine; produits ainsi obtenus - Google Patents

Precipitation de l'halogenure d'argent avec une sensibilisation spectrale par un colorant a base de methine; produits ainsi obtenus

Info

Publication number: CA1121644A
Authority: CA; Canada
Prior art keywords: reaction vessel; dye; silver; salt; spectral sensitizing
Prior art date: 1978-02-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA000303408A

Other languages

English (en)

Inventor

Richard L. Daubendiek

David J. Locker

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Eastman Kodak Co

Original Assignee

Eastman Kodak Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-02-27

Filing date

1978-05-16

Publication date

1982-04-13

1978-05-16 Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co

1982-04-13 Application granted granted Critical

1982-04-13 Publication of CA1121644A publication Critical patent/CA1121644A/fr

Status Expired legal-status Critical Current

Links

230000003595 spectral effect Effects 0.000 title claims abstract description 101
-1 Silver halide Chemical class 0.000 title claims abstract description 90
229910052709 silver Inorganic materials 0.000 title claims abstract description 87
239000004332 silver Substances 0.000 title claims abstract description 87
238000000034 method Methods 0.000 title claims abstract description 72
238000001556 precipitation Methods 0.000 title claims abstract description 34
230000008569 process Effects 0.000 title claims abstract description 14
125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 title claims abstract description 13
206010070834 Sensitisation Diseases 0.000 title abstract description 10
230000008313 sensitization Effects 0.000 title abstract description 10
238000006243 chemical reaction Methods 0.000 claims abstract description 67
230000001235 sensitizing effect Effects 0.000 claims abstract description 66
231100000202 sensitizing Toxicity 0.000 claims description 65
239000000839 emulsion Substances 0.000 claims description 63
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 51
239000007864 aqueous solution Substances 0.000 claims description 26
230000006872 improvement Effects 0.000 claims description 22
239000012266 salt solution Substances 0.000 claims description 17
230000003111 delayed effect Effects 0.000 claims description 10
CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 9
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 8
108010010803 Gelatin Proteins 0.000 claims description 8
229920000159 gelatin Polymers 0.000 claims description 8
239000008273 gelatin Substances 0.000 claims description 8
235000019322 gelatine Nutrition 0.000 claims description 8
235000011852 gelatine desserts Nutrition 0.000 claims description 8
ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 claims description 8
IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 claims description 6
229910021607 Silver chloride Inorganic materials 0.000 claims description 5
DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 claims description 4
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 3
BCMCBBGGLRIHSE-UHFFFAOYSA-N 1,3-benzoxazole Chemical class C1=CC=C2OC=NC2=C1 BCMCBBGGLRIHSE-UHFFFAOYSA-N 0.000 claims description 2
229910021612 Silver iodide Inorganic materials 0.000 claims description 2
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 claims description 2
229940045105 silver iodide Drugs 0.000 claims description 2
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 claims 11
230000005855 radiation Effects 0.000 claims 8
150000003841 chloride salts Chemical group 0.000 claims 4
150000003842 bromide salts Chemical group 0.000 claims 3
HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 claims 1
150000004694 iodide salts Chemical group 0.000 claims 1
238000010899 nucleation Methods 0.000 abstract description 13
230000006911 nucleation Effects 0.000 abstract description 11
230000001376 precipitating effect Effects 0.000 abstract 1
239000000975 dye Substances 0.000 description 98
239000000243 solution Substances 0.000 description 49
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 18
238000007792 addition Methods 0.000 description 16
229910001868 water Inorganic materials 0.000 description 15
150000004820 halides Chemical class 0.000 description 14
150000003839 salts Chemical class 0.000 description 14
125000000217 alkyl group Chemical group 0.000 description 9
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
239000013078 crystal Substances 0.000 description 8
239000000047 product Substances 0.000 description 8
239000011248 coating agent Substances 0.000 description 7
238000000576 coating method Methods 0.000 description 7
ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
239000012153 distilled water Substances 0.000 description 6
239000000203 mixture Substances 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 5
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
159000000000 sodium salts Chemical class 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
238000007796 conventional method Methods 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 4
150000002460 imidazoles Chemical class 0.000 description 4
150000002916 oxazoles Chemical class 0.000 description 4
229910052700 potassium Inorganic materials 0.000 description 4
239000011591 potassium Substances 0.000 description 4
HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 4
SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 4
239000006228 supernatant Substances 0.000 description 4
WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 3
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
125000004181 carboxyalkyl group Chemical group 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
125000002768 hydroxyalkyl group Chemical group 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
230000004044 response Effects 0.000 description 3
239000011734 sodium Substances 0.000 description 3
239000011780 sodium chloride Substances 0.000 description 3
125000004964 sulfoalkyl group Chemical group 0.000 description 3
150000003557 thiazoles Chemical class 0.000 description 3
SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
238000013019 agitation Methods 0.000 description 2
125000004183 alkoxy alkyl group Chemical group 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229920002301 cellulose acetate Polymers 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
238000000635 electron micrograph Methods 0.000 description 2
150000002081 enamines Chemical class 0.000 description 2
238000005755 formation reaction Methods 0.000 description 2
KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
239000010931 gold Substances 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
125000000623 heterocyclic group Chemical group 0.000 description 2
235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 2
235000020004 porter Nutrition 0.000 description 2
238000011160 research Methods 0.000 description 2
230000035945 sensitivity Effects 0.000 description 2
239000002356 single layer Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
239000002904 solvent Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
XKWQNWOHLZAFPS-UHFFFAOYSA-N 1,1',3,3'-tetraethyl-5,5',6,6'-tetrachloroimidacarbocyanine Chemical compound CCN1C2=CC(Cl)=C(Cl)C=C2N(CC)C1=CC=CC1=[N+](CC)C2=CC(Cl)=C(Cl)C=C2N1CC XKWQNWOHLZAFPS-UHFFFAOYSA-N 0.000 description 1
KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical class CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 description 1
SAHAKBXWZLDNAA-UHFFFAOYSA-N 1,3-benzoxazol-6-ol Chemical compound OC1=CC=C2N=COC2=C1 SAHAKBXWZLDNAA-UHFFFAOYSA-N 0.000 description 1
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
DRLMMVPCYXFPEP-UHFFFAOYSA-N 2-bromo-1,3-benzothiazole Chemical class C1=CC=C2SC(Br)=NC2=C1 DRLMMVPCYXFPEP-UHFFFAOYSA-N 0.000 description 1
QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
UGWULZWUXSCWPX-UHFFFAOYSA-N 2-sulfanylideneimidazolidin-4-one Chemical compound O=C1CNC(=S)N1 UGWULZWUXSCWPX-UHFFFAOYSA-N 0.000 description 1
OYTKXVQRRLZCDC-UHFFFAOYSA-N 2-thiophen-2-yl-1,3-thiazole Chemical class C1=CSC(C=2SC=CN=2)=C1 OYTKXVQRRLZCDC-UHFFFAOYSA-N 0.000 description 1
GHAFJOZKMUPGRQ-UHFFFAOYSA-N 4-nitro-1,3-oxazole Chemical compound [O-][N+](=O)C1=COC=N1 GHAFJOZKMUPGRQ-UHFFFAOYSA-N 0.000 description 1
VWMQXAYLHOSRKA-UHFFFAOYSA-N 5-chloro-1,3-benzoxazole Chemical compound ClC1=CC=C2OC=NC2=C1 VWMQXAYLHOSRKA-UHFFFAOYSA-N 0.000 description 1
MNEOLRFGVQZMLA-UHFFFAOYSA-N 5-nitro-1,3-benzoxazole Chemical compound [O-][N+](=O)C1=CC=C2OC=NC2=C1 MNEOLRFGVQZMLA-UHFFFAOYSA-N 0.000 description 1
NNESGHWUVLNAML-UHFFFAOYSA-N 6-nitro-1,3-benzoxazole Chemical compound [O-][N+](=O)C1=CC=C2N=COC2=C1 NNESGHWUVLNAML-UHFFFAOYSA-N 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
125000005041 acyloxyalkyl group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000005078 alkoxycarbonylalkyl group Chemical group 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
125000004103 aminoalkyl group Chemical group 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
238000013459 approach Methods 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000003289 ascorbyl group Chemical class [H]O[C@@]([H])(C([H])([H])O*)[C@@]1([H])OC(=O)C(O*)=C1O* 0.000 description 1
150000007656 barbituric acids Chemical class 0.000 description 1
150000001556 benzimidazoles Chemical class 0.000 description 1
WMUIZUWOEIQJEH-UHFFFAOYSA-N benzo[e][1,3]benzoxazole Chemical compound C1=CC=C2C(N=CO3)=C3C=CC2=C1 WMUIZUWOEIQJEH-UHFFFAOYSA-N 0.000 description 1
235000019445 benzyl alcohol Nutrition 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
229960003237 betaine Drugs 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000001661 cadmium Chemical class 0.000 description 1
125000002837 carbocyclic group Chemical group 0.000 description 1
JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 description 1
125000000068 chlorophenyl group Chemical group 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000005345 coagulation Methods 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
230000000694 effects Effects 0.000 description 1
125000001240 enamine group Chemical group 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
230000006870 function Effects 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical group 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000003906 humectant Substances 0.000 description 1
ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000010410 layer Substances 0.000 description 1
239000006390 lc 2 Substances 0.000 description 1
239000000463 material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000003607 modifier Substances 0.000 description 1
RMHJJUOPOWPRBP-UHFFFAOYSA-N naphthalene-1-carboxamide Chemical compound C1=CC=C2C(C(=O)N)=CC=CC2=C1 RMHJJUOPOWPRBP-UHFFFAOYSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
239000010956 nickel silver Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
150000002918 oxazolines Chemical class 0.000 description 1
FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 1
MTWNQMHWLWHXGH-XEUPFTBBSA-N pag 8 Chemical compound C([C@H]1O[C@H]([C@@H]([C@@H](OC(C)=O)[C@@H]1OC(C)=O)OC(C)=O)OC[C@H](C(C1O[C@H](COC(C)=O)[C@@H](OC(C)=O)[C@@H]([C@H]1OC(C)=O)O[C@@H]1O[C@H](COC(C)=O)[C@@H](OC(O)=O)[C@@H]([C@H]1OC(C)=O)O[C@@H]1O[C@H](COC(C)=O)[C@@H](OC(C)=O)[C@@H]([C@H]1OC(C)=O)O[C@@H]1O[C@@H]([C@H]([C@H](O[C@H]2[C@@H]([C@@H](OC(O)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O2)OC(C)=O)[C@H]1OC(C)=O)OC(C)=O)COC(=O)C)C(O)=O)[C@@H](OC(C)=O)[C@@H](C(CC(C(C)=O)C(C)=O)OC(C)=O)C(C(C)=O)C(C)=O)OC(=C)O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O MTWNQMHWLWHXGH-XEUPFTBBSA-N 0.000 description 1
239000002245 particle Substances 0.000 description 1
229960005323 phenoxyethanol Drugs 0.000 description 1
QWYZFXLSWMXLDM-UHFFFAOYSA-M pinacyanol iodide Chemical class [I-].C1=CC2=CC=CC=C2N(CC)C1=CC=CC1=CC=C(C=CC=C2)C2=[N+]1CC QWYZFXLSWMXLDM-UHFFFAOYSA-M 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
238000000247 postprecipitation Methods 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
150000003222 pyridines Chemical class 0.000 description 1
150000003236 pyrrolines Chemical class 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000005070 ripening Effects 0.000 description 1
150000003378 silver Chemical class 0.000 description 1
229910001961 silver nitrate Inorganic materials 0.000 description 1
BQCADISMDOOEFD-RNFDNDRNSA-N silver-112 Chemical class [112Ag] BQCADISMDOOEFD-RNFDNDRNSA-N 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
230000007480 spreading Effects 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010186 staining Methods 0.000 description 1
125000005504 styryl group Chemical group 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
238000001429 visible spectrum Methods 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/015—Apparatus or processes for the preparation of emulsions
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/10—Organic substances
- G03C1/12—Methine and polymethine dyes
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/06—Additive

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)

CA000303408A 1978-02-27 1978-05-16 Precipitation de l'halogenure d'argent avec une sensibilisation spectrale par un colorant a base de methine; produits ainsi obtenus Expired CA1121644A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US88123078A	1978-02-27	1978-02-27
US881,230		1978-02-27

Publications (1)

Publication Number	Publication Date
CA1121644A true CA1121644A (fr)	1982-04-13

Family

ID=25378037

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000303408A Expired CA1121644A (fr)	1978-02-27	1978-05-16	Precipitation de l'halogenure d'argent avec une sensibilisation spectrale par un colorant a base de methine; produits ainsi obtenus

Country Status (5)

Country	Link
BE (1)	BE874497A (fr)
CA (1)	CA1121644A (fr)
DE (1)	DE2907596A1 (fr)
FR (1)	FR2418479A1 (fr)
GB (1)	GB2016724B (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2546645B2 (ja) *	1986-04-24	1996-10-23	コニカ株式会社	ハロゲン化銀カラー写真感光材料

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE519979A (fr) *	1952-05-15
GB1225241A (fr) *	1967-04-21	1971-03-17
IT996288B (it) *	1972-12-04	1975-12-10	Polaroid Corp	Procedimento per formare cristalli di alogenuro di argento per emu sioni fotografiche

1978
- 1978-05-16 CA CA000303408A patent/CA1121644A/fr not_active Expired
1979
- 1979-02-26 FR FR7904813A patent/FR2418479A1/fr active Granted
- 1979-02-27 BE BE0/193737A patent/BE874497A/fr not_active IP Right Cessation
- 1979-02-27 GB GB7906844A patent/GB2016724B/en not_active Expired
- 1979-02-27 DE DE19792907596 patent/DE2907596A1/de not_active Withdrawn

Also Published As

Publication number	Publication date
GB2016724A (en)	1979-09-26
FR2418479B1 (fr)	1982-06-04
FR2418479A1 (fr)	1979-09-21
DE2907596A1 (de)	1979-09-06
GB2016724B (en)	1982-05-26
BE874497A (fr)	1979-08-27

Legal Events

Date	Code	Title	Description
1999-04-13	MKEX	Expiry

Publication	Publication Date	Title
US4225666A (en)	1980-09-30	Silver halide precipitation and methine dye spectral sensitization process and products thereof
CA1106674A (fr)	1981-08-11	Procede d'addition d'un colorant de sensibilisation spectrale par pre-precipitation
US4683193A (en)	1987-07-28	Process for producing silver halide photographic emulsion
JPS6133178B2 (fr)	1986-07-31
JPH11102044A (ja)	1999-04-13	写真要素
CA1121644A (fr)	1982-04-13	Precipitation de l'halogenure d'argent avec une sensibilisation spectrale par un colorant a base de methine; produits ainsi obtenus
US4987064A (en)	1991-01-22	Silver halide photographic materials
US4039335A (en)	1977-08-02	Photographic silver halide emulsions
EP0312959A1 (fr)	1989-04-26	Emulsion photographique à l'halogénure d'argent
JPH07199390A (ja)	1995-08-04	写真要素及び写真方法
GB1570233A (en)	1980-06-25	Speciall sensitized silver halide photographic emulsions
JP3440152B2 (ja)	2003-08-25	アルキニルアミンドーピング剤含有写真要素
JPS5851255B2 (ja)	1983-11-15	ブンコウゾウカンサレタハロゲンカギンシヤシンニユウザイ
US5192653A (en)	1993-03-09	Method for spectrally sensitizing silver halide photographic emulsions
JPS6046418B2 (ja)	1985-10-16	色増感されたハロゲン化銀写真乳剤
JPH01100533A (ja)	1989-04-18	高感度のハロゲン化銀写真感光材料
US5494788A (en)	1996-02-27	Chemical and spectral sensitization of high-chloride tabular grains using high-temperature heat treatment
JP3248034B2 (ja)	2002-01-21	ハロゲン化銀写真感光材料及びその処理方法
JP2926451B2 (ja)	1999-07-28	ハロゲン化銀写真感光材料を用いた画像形成方法
JPH06308654A (ja)	1994-11-04	ハロゲン化銀写真感光材料
JPH02193139A (ja)	1990-07-30	ハロゲン化銀写真乳剤を分光増感する方法
JPH01216341A (ja)	1989-08-30	ハロゲン化銀写真感光材料
JPH0720593A (ja)	1995-01-24	ハロゲン化銀写真感光材料
JPH08146545A (ja)	1996-06-07	ハロゲン化銀写真感光材料及びその処理方法
JPH07325357A (ja)	1995-12-12	ハロゲン化銀写真乳剤、ハロゲン化銀写真感光材料及びその処理方法