CA1133196A - Methode de fabrication en continu de polymeres de chlorure de vinyle - Google Patents

Methode de fabrication en continu de polymeres de chlorure de vinyle

Info

Publication number: CA1133196A
Authority: CA; Canada
Prior art keywords: saturated; carbon atoms; water; weight; acid
Prior art date: 1977-04-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA300,152A

Other languages

English (en)

Inventor

Franz Botsch

Helmut Kraus

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hoechst AG

Original Assignee

Hoechst AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-04-02

Filing date

1978-03-31

Publication date

1982-10-05

1978-03-31 Application filed by Hoechst AG filed Critical Hoechst AG

1982-10-05 Application granted granted Critical

1982-10-05 Publication of CA1133196A publication Critical patent/CA1133196A/fr

Status Expired legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 32
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 27
238000000034 method Methods 0.000 title claims abstract description 25
238000004519 manufacturing process Methods 0.000 title description 8
150000003839 salts Chemical class 0.000 claims abstract description 39
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 35
239000003995 emulsifying agent Substances 0.000 claims abstract description 26
239000000178 monomer Substances 0.000 claims abstract description 21
239000000203 mixture Substances 0.000 claims abstract description 20
229920006395 saturated elastomer Polymers 0.000 claims abstract description 19
239000003054 catalyst Substances 0.000 claims abstract description 11
239000000839 emulsion Substances 0.000 claims abstract description 6
125000001931 aliphatic group Chemical group 0.000 claims abstract description 4
150000002762 monocarboxylic acid derivatives Chemical class 0.000 claims abstract description 3
238000002360 preparation method Methods 0.000 claims abstract description 3
-1 aliphatic monocarboxylic acid Chemical class 0.000 claims description 27
125000000217 alkyl group Chemical group 0.000 claims description 14
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 9
229910052700 potassium Inorganic materials 0.000 claims description 9
239000011591 potassium Substances 0.000 claims description 9
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
150000003863 ammonium salts Chemical class 0.000 claims description 8
229910052708 sodium Inorganic materials 0.000 claims description 8
239000011734 sodium Substances 0.000 claims description 8
125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 7
150000001735 carboxylic acids Chemical class 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 5
229920001577 copolymer Polymers 0.000 claims description 5
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
150000002148 esters Chemical class 0.000 claims description 3
229920000578 graft copolymer Polymers 0.000 claims description 3
239000003381 stabilizer Substances 0.000 abstract description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 7
229910052788 barium Inorganic materials 0.000 abstract description 5
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract description 5
150000002894 organic compounds Chemical class 0.000 abstract description 5
125000000542 sulfonic acid group Chemical group 0.000 abstract 1
238000006116 polymerization reaction Methods 0.000 description 33
150000002763 monocarboxylic acids Chemical class 0.000 description 13
238000006243 chemical reaction Methods 0.000 description 10
235000013350 formula milk Nutrition 0.000 description 8
230000006641 stabilisation Effects 0.000 description 8
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 7
238000011105 stabilization Methods 0.000 description 7
239000000843 powder Substances 0.000 description 6
150000007513 acids Chemical class 0.000 description 5
150000001768 cations Chemical class 0.000 description 5
239000004815 dispersion polymer Substances 0.000 description 5
229920000126 latex Polymers 0.000 description 5
235000007686 potassium Nutrition 0.000 description 5
229960003975 potassium Drugs 0.000 description 5
150000003254 radicals Chemical class 0.000 description 5
239000007787 solid Substances 0.000 description 5
UTOPWMOLSKOLTQ-UHFFFAOYSA-N Octacosancarbonsaeure Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
229910052793 cadmium Inorganic materials 0.000 description 4
RDVQTQJAUFDLFA-UHFFFAOYSA-N cadmium Chemical compound [Cd][Cd][Cd][Cd][Cd][Cd][Cd][Cd][Cd] RDVQTQJAUFDLFA-UHFFFAOYSA-N 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
159000000000 sodium salts Chemical class 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
239000000306 component Substances 0.000 description 3
238000007334 copolymerization reaction Methods 0.000 description 3
238000007720 emulsion polymerization reaction Methods 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
239000006260 foam Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
238000010030 laminating Methods 0.000 description 3
239000004816 latex Substances 0.000 description 3
OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
229920002554 vinyl polymer Polymers 0.000 description 3
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical class [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
150000001552 barium Chemical class 0.000 description 2
DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
238000002845 discoloration Methods 0.000 description 2
238000001035 drying Methods 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000012760 heat stabilizer Substances 0.000 description 2
239000000463 material Substances 0.000 description 2
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 2
229920000573 polyethylene Polymers 0.000 description 2
229920000915 polyvinyl chloride Polymers 0.000 description 2
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
238000005507 spraying Methods 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
239000000725 suspension Substances 0.000 description 2
150000003606 tin compounds Chemical class 0.000 description 2
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
239000004808 2-ethylhexylester Substances 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
206010001497 Agitation Diseases 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical class [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
241001295925 Gegenes Species 0.000 description 1
238000007869 Guerbet synthesis reaction Methods 0.000 description 1
PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical class [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000012491 analyte Substances 0.000 description 1
150000001449 anionic compounds Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
229950005228 bromoform Drugs 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
229910052804 chromium Chemical class 0.000 description 1
239000011651 chromium Chemical class 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Chemical class 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical class [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
230000002844 continuous effect Effects 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
230000008030 elimination Effects 0.000 description 1
238000003379 elimination reaction Methods 0.000 description 1
238000010556 emulsion polymerization method Methods 0.000 description 1
IGBZOHMCHDADGY-UHFFFAOYSA-N ethenyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OC=C IGBZOHMCHDADGY-UHFFFAOYSA-N 0.000 description 1
MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
239000007789 gas Substances 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
238000005286 illumination Methods 0.000 description 1
229910001412 inorganic anion Inorganic materials 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000003475 lamination Methods 0.000 description 1
229940070765 laurate Drugs 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
239000004611 light stabiliser Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
125000005395 methacrylic acid group Chemical group 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
150000004976 peroxydisulfates Chemical class 0.000 description 1
238000000053 physical method Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Chemical class 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
230000008719 thickening Effects 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
230000004584 weight gain Effects 0.000 description 1
235000019786 weight gain Nutrition 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)

CA300,152A 1977-04-02 1978-03-31 Methode de fabrication en continu de polymeres de chlorure de vinyle Expired CA1133196A (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE2714948A DE2714948C2 (de)	1977-04-02	1977-04-02	Verfahren zur kontinuierlichen Herstellung von Vinylchlorid-Polymerisaten
DEP2714948.0		1977-04-02

Publications (1)

Publication Number	Publication Date
CA1133196A true CA1133196A (fr)	1982-10-05

Family

ID=6005574

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA300,152A Expired CA1133196A (fr)	1977-04-02	1978-03-31	Methode de fabrication en continu de polymeres de chlorure de vinyle

Country Status (24)

Country	Link
JP (1)	JPS53123489A (fr)
AR (1)	AR222970A1 (fr)
AT (1)	AT365207B (fr)
AU (1)	AU515788B2 (fr)
BE (1)	BE865631A (fr)
BR (1)	BR7802036A (fr)
CA (1)	CA1133196A (fr)
CH (1)	CH635597A5 (fr)
DD (1)	DD136843A5 (fr)
DE (1)	DE2714948C2 (fr)
DK (1)	DK143478A (fr)
ES (1)	ES468234A1 (fr)
FR (1)	FR2385746A1 (fr)
GB (1)	GB1597285A (fr)
HU (1)	HU179485B (fr)
IT (1)	IT1094001B (fr)
NL (1)	NL7803495A (fr)
NO (1)	NO781129L (fr)
PL (1)	PL111001B1 (fr)
RO (1)	RO75157A (fr)
SE (1)	SE7803689L (fr)
SU (1)	SU755203A3 (fr)
YU (1)	YU75878A (fr)
ZA (1)	ZA781846B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3627287A1 (de) *	1986-08-12	1988-02-18	Huels Chemische Werke Ag	Verfahren zur verbesserten einhaltung des k-wertes und zur besseren erhaltung der leistung bei der kontinuierlichen polymerisation von vinylchlorid in emulsion
DE4142117A1 (de) *	1991-12-20	1993-06-24	Hoechst Ag	Verfahren zur bestimmung des umsatzes bei der polymerisation gasfoermiger monomerer
JP4921988B2 (ja) *	2007-01-16	2012-04-25	エスアイアイ・ネットワーク・システムズ株式会社	端子台用カバー機構
CN113748139B (zh) *	2019-09-11	2023-07-28	株式会社Lg化学	氯乙烯基聚合物的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
BE617775A (fr) *	1961-05-19	1962-11-19	Shell Int Research	Procédé de polymérisation de composés oléfiniquement non saturés
DE1645672B2 (de) *	1966-07-08	1972-12-21	Wacker-Chemie GmbH, 8000 München	Verfahren zur herstellung von homopolymerisaten des vinylchlorids bzw mindestens 80 gew.-% vinylchlorideinheiten enthaltenden mischpolymerisaten
US3546154A (en) *	1966-09-27	1970-12-08	Stauffer Chemical Co	Emulsion polymerization of vinyl compounds
DE2521862C3 (de) *	1975-05-16	1978-05-18	Hoechst Ag, 6000 Frankfurt	Verfahren zur kontinuierlichen Herstellung von Polymerisaten und Mischpolymerisaten des Vinylchlorids in wäßriger Emulsion

1977
- 1977-04-02 DE DE2714948A patent/DE2714948C2/de not_active Expired
1978
- 1978-03-27 ES ES468234A patent/ES468234A1/es not_active Expired
- 1978-03-30 YU YU00758/78A patent/YU75878A/xx unknown
- 1978-03-30 CH CH344278A patent/CH635597A5/de not_active IP Right Cessation
- 1978-03-30 HU HU78HO2059A patent/HU179485B/hu unknown
- 1978-03-31 AR AR271643A patent/AR222970A1/es active
- 1978-03-31 SU SU782596898A patent/SU755203A3/ru active
- 1978-03-31 AT AT0228978A patent/AT365207B/de not_active IP Right Cessation
- 1978-03-31 ZA ZA00781846A patent/ZA781846B/xx unknown
- 1978-03-31 DK DK143478A patent/DK143478A/da not_active Application Discontinuation
- 1978-03-31 SE SE7803689A patent/SE7803689L/xx unknown
- 1978-03-31 IT IT21898/78A patent/IT1094001B/it active
- 1978-03-31 JP JP3695378A patent/JPS53123489A/ja active Pending
- 1978-03-31 GB GB12658/78A patent/GB1597285A/en not_active Expired
- 1978-03-31 NO NO781129A patent/NO781129L/no unknown
- 1978-03-31 CA CA300,152A patent/CA1133196A/fr not_active Expired
- 1978-03-31 BR BR7802036A patent/BR7802036A/pt unknown
- 1978-03-31 NL NL7803495A patent/NL7803495A/xx not_active Application Discontinuation
- 1978-03-31 DD DD78204527A patent/DD136843A5/xx unknown
- 1978-03-31 RO RO7893689A patent/RO75157A/fr unknown
- 1978-04-01 PL PL1978205744A patent/PL111001B1/pl unknown
- 1978-04-03 BE BE186521A patent/BE865631A/fr not_active IP Right Cessation
- 1978-04-03 FR FR7809740A patent/FR2385746A1/fr active Pending
- 1978-04-03 AU AU34714/78A patent/AU515788B2/en not_active Expired

Also Published As

Publication number	Publication date
RO75157A (fr)	1980-11-30
HU179485B (en)	1982-10-28
PL205744A1 (pl)	1979-01-29
ZA781846B (en)	1979-04-25
DE2714948A1 (de)	1978-10-12
CH635597A5 (en)	1983-04-15
AR222970A1 (es)	1981-07-15
ATA228978A (de)	1981-05-15
NO781129L (no)	1978-10-03
DE2714948C2 (de)	1985-01-10
NL7803495A (nl)	1978-10-04
AU515788B2 (en)	1981-04-30
SU755203A3 (en)	1980-08-07
IT1094001B (it)	1985-07-26
AT365207B (de)	1981-12-28
SE7803689L (sv)	1978-10-02
IT7821898A0 (it)	1978-03-31
FR2385746A1 (fr)	1978-10-27
YU75878A (en)	1982-06-30
JPS53123489A (en)	1978-10-27
BE865631A (fr)	1978-10-03
PL111001B1 (en)	1980-08-30
ES468234A1 (es)	1978-12-01
DD136843A5 (de)	1979-08-01
DK143478A (da)	1978-10-03
BR7802036A (pt)	1978-11-28
GB1597285A (en)	1981-09-03
AU3471478A (en)	1979-10-11

Legal Events

Date	Code	Title	Description
1999-10-05	MKEX	Expiry

Publication	Publication Date	Title
US4025709A (en)	1977-05-24	Process for the polymerization of vinylidene fluoride
US4797458A (en)	1989-01-10	Colloidal stable vinyl halide polymerizations with mercaptan chain transfer agents
CA1133196A (fr)	1982-10-05	Methode de fabrication en continu de polymeres de chlorure de vinyle
US4098978A (en)	1978-07-04	Process for emulsion polymerization of vinylidene halides and product thereof
US3756991A (en)	1973-09-04	Copolymers of vinyl chloride with n substituted maleimides
US3219608A (en)	1965-11-23	Emulsion polymerization of vinyl acetate using allyl sulphosuccinates as polymerizable emulsifiers
US5006607A (en)	1991-04-09	Dispersant system for making polyvinyl chloride which produces low color chlorinated polyvinyl chloride
US6242541B1 (en)	2001-06-05	PVC polymerization with metered addition of emulsifiers
JP3437022B2 (ja)	2003-08-18	塩化ビニル系重合体の製造方法
US4286078A (en)	1981-08-25	Process for the continuous manufacture of vinyl chloride polymers
US3975338A (en)	1976-08-17	Process of producing vinyl chloride polymers
US2456231A (en)	1948-12-14	Chlorine-containing vinyl resins stabilized with a tri-(2-alkenyl)-phosphite
US3583956A (en)	1971-06-08	Vinyl chloride polymers
US3847853A (en)	1974-11-12	Process for the preparation of vinyl chloride resins having good thermal stability
US3202625A (en)	1965-08-24	Composition for water base paints
US3344100A (en)	1967-09-26	Emulsion polymerization using water insoluble metal salts of fatty acids
US4401798A (en)	1983-08-30	Process for the production of vinyl halide polymers that uses an alkyl-substituted trisphenol as the chain-terminating agent
US2971948A (en)	1961-02-14	Process for preparing copolymers of vinyl chloride
US3732178A (en)	1973-05-08	Vinyl chloride emulsion polymer and copolymer compositions
US3226370A (en)	1965-12-28	Granular polymerization in aqueous emulsion of normally crystalline vinylidene chloride
US4346203A (en)	1982-08-24	Emulsifier for the preparation of polymers
US5112522A (en)	1992-05-12	Mercaptan chain transfer agent compositions useful in aqueous polymerizations
US4918151A (en)	1990-04-17	Aqueous suspension process for producing low molecular weight vinyl copolymers
US5003038A (en)	1991-03-26	Process for the manufacture of vinyl chloride polymers modified with lactone polymers and product thereof
US3705883A (en)	1972-12-12	Thermally stable vinyl chloride copolymers