PL111001B1 - Method for manufacturing vinyl chloride polymers in continuous process - Google Patents

Method for manufacturing vinyl chloride polymers in continuous process Download PDF

Info

Publication number: PL111001B1
Authority: PL; Poland
Prior art keywords: acid; water; weight; carbon atoms; saturated
Prior art date: 1977-04-02

Application number

PL1978205744A

Other languages

English (en)

Polish (pl)

Other versions

PL205744A1 (pl

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1977-04-02

Filing date

1978-04-01

Publication date

1980-08-30

1978-04-01 Application filed by Hoechst Ag filed Critical Hoechst Ag

1979-01-29 Publication of PL205744A1 publication Critical patent/PL205744A1/xx

1980-08-30 Publication of PL111001B1 publication Critical patent/PL111001B1/pl

Links

229920000642 polymer Polymers 0.000 title claims description 44
238000000034 method Methods 0.000 title claims description 38
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 28
238000010924 continuous production Methods 0.000 title claims description 4
238000004519 manufacturing process Methods 0.000 title description 5
-1 alkyl radical Chemical class 0.000 claims description 47
125000004432 carbon atom Chemical group C* 0.000 claims description 42
238000006116 polymerization reaction Methods 0.000 claims description 42
239000003995 emulsifying agent Substances 0.000 claims description 41
150000003839 salts Chemical class 0.000 claims description 41
239000002253 acid Substances 0.000 claims description 33
150000002148 esters Chemical class 0.000 claims description 24
239000000178 monomer Substances 0.000 claims description 23
125000000217 alkyl group Chemical group 0.000 claims description 20
229920006395 saturated elastomer Polymers 0.000 claims description 19
239000000203 mixture Substances 0.000 claims description 18
150000002763 monocarboxylic acids Chemical class 0.000 claims description 14
150000003863 ammonium salts Chemical class 0.000 claims description 13
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 12
229910052700 potassium Inorganic materials 0.000 claims description 12
239000011591 potassium Substances 0.000 claims description 12
239000011734 sodium Substances 0.000 claims description 12
229910052708 sodium Inorganic materials 0.000 claims description 12
239000003054 catalyst Substances 0.000 claims description 10
230000008569 process Effects 0.000 claims description 7
150000001735 carboxylic acids Chemical class 0.000 claims description 6
229920001577 copolymer Polymers 0.000 claims description 6
150000002894 organic compounds Chemical class 0.000 claims description 6
125000001931 aliphatic group Chemical group 0.000 claims description 5
229920001519 homopolymer Polymers 0.000 claims description 5
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 4
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
125000005907 alkyl ester group Chemical group 0.000 claims description 3
125000001174 sulfone group Chemical group 0.000 claims description 3
KFTONPAKWUUXSN-UHFFFAOYSA-N 3-hexyldecanoic acid Chemical compound C(CCCCC)C(CC(=O)O)CCCCCCC KFTONPAKWUUXSN-UHFFFAOYSA-N 0.000 claims description 2
239000000725 suspension Substances 0.000 description 12
239000006260 foam Substances 0.000 description 11
230000006641 stabilisation Effects 0.000 description 9
238000011105 stabilization Methods 0.000 description 9
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 7
238000006243 chemical reaction Methods 0.000 description 7
239000000839 emulsion Substances 0.000 description 7
229910052718 tin Inorganic materials 0.000 description 7
UTOPWMOLSKOLTQ-UHFFFAOYSA-N Octacosancarbonsaeure Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 6
229920000126 latex Polymers 0.000 description 6
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 6
239000000843 powder Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
229910052793 cadmium Inorganic materials 0.000 description 5
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
150000003254 radicals Chemical class 0.000 description 5
238000005096 rolling process Methods 0.000 description 5
239000007787 solid Substances 0.000 description 5
239000003381 stabilizer Substances 0.000 description 5
229920002554 vinyl polymer Polymers 0.000 description 5
150000007513 acids Chemical class 0.000 description 4
229910052788 barium Inorganic materials 0.000 description 4
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 4
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
238000007720 emulsion polymerization reaction Methods 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
239000004816 latex Substances 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
229920000915 polyvinyl chloride Polymers 0.000 description 4
239000000126 substance Substances 0.000 description 4
150000003606 tin compounds Chemical class 0.000 description 4
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
239000004698 Polyethylene Substances 0.000 description 3
150000001298 alcohols Chemical class 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 3
238000005259 measurement Methods 0.000 description 3
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
229920000573 polyethylene Polymers 0.000 description 3
239000004800 polyvinyl chloride Substances 0.000 description 3
159000000000 sodium salts Chemical class 0.000 description 3
238000005507 spraying Methods 0.000 description 3
230000009466 transformation Effects 0.000 description 3
XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
OAOABCKPVCUNKO-UHFFFAOYSA-N 8-methyl Nonanoic acid Chemical compound CC(C)CCCCCCC(O)=O OAOABCKPVCUNKO-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
FCSHMCFRCYZTRQ-UHFFFAOYSA-N N,N'-diphenylthiourea Chemical compound C=1C=CC=CC=1NC(=S)NC1=CC=CC=C1 FCSHMCFRCYZTRQ-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
150000001450 anions Chemical class 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
DIKBFYAXUHHXCS-UHFFFAOYSA-N bromoform Chemical compound BrC(Br)Br DIKBFYAXUHHXCS-UHFFFAOYSA-N 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
230000015271 coagulation Effects 0.000 description 2
238000005345 coagulation Methods 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
238000007334 copolymerization reaction Methods 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
238000001035 drying Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
230000006872 improvement Effects 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
SIOLDWZBFABPJU-UHFFFAOYSA-N isotridecanoic acid Chemical compound CC(C)CCCCCCCCCC(O)=O SIOLDWZBFABPJU-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
239000000047 product Substances 0.000 description 2
239000011541 reaction mixture Substances 0.000 description 2
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
229920001567 vinyl ester resin Polymers 0.000 description 2
BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
239000004808 2-ethylhexylester Substances 0.000 description 1
ZJCPPSOBZDPPEI-UHFFFAOYSA-N 3-hexylundecanoic acid Chemical compound CCCCCCCCC(CC(O)=O)CCCCCC ZJCPPSOBZDPPEI-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Natural products CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
239000004908 Emulsion polymer Substances 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
241001295925 Gegenes Species 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
ATTZFSUZZUNHBP-UHFFFAOYSA-N Piperonyl sulfoxide Chemical compound CCCCCCCCS(=O)C(C)CC1=CC=C2OCOC2=C1 ATTZFSUZZUNHBP-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000012491 analyte Substances 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
150000001552 barium Chemical class 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
229950005228 bromoform Drugs 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
ISXSFOPKZQZDAO-UHFFFAOYSA-N formaldehyde;sodium Chemical compound [Na].O=C ISXSFOPKZQZDAO-UHFFFAOYSA-N 0.000 description 1
239000001530 fumaric acid Substances 0.000 description 1
AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
238000001879 gelation Methods 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
238000010559 graft polymerization reaction Methods 0.000 description 1
125000001188 haloalkyl group Chemical group 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
229950004531 hexyldecanoic acid Drugs 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
229940070765 laurate Drugs 0.000 description 1
150000002611 lead compounds Chemical class 0.000 description 1
239000004611 light stabiliser Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
239000011976 maleic acid Substances 0.000 description 1
235000013372 meat Nutrition 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
125000000962 organic group Chemical group 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
238000000053 physical method Methods 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
230000035945 sensitivity Effects 0.000 description 1
229910052709 silver Inorganic materials 0.000 description 1
239000004332 silver Substances 0.000 description 1
239000002002 slurry Substances 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
239000003017 thermal stabilizer Substances 0.000 description 1
230000008719 thickening Effects 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
238000000108 ultra-filtration Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Graft Or Block Polymers (AREA)

PL1978205744A 1977-04-02 1978-04-01 Method for manufacturing vinyl chloride polymers in continuous process PL111001B1 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2714948A DE2714948C2 (de)	1977-04-02	1977-04-02	Verfahren zur kontinuierlichen Herstellung von Vinylchlorid-Polymerisaten

Publications (2)

Publication Number	Publication Date
PL205744A1 PL205744A1 (pl)	1979-01-29
PL111001B1 true PL111001B1 (en)	1980-08-30

Family

ID=6005574

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PL1978205744A PL111001B1 (en)	1977-04-02	1978-04-01	Method for manufacturing vinyl chloride polymers in continuous process

Country Status (24)

Country	Link
JP (1)	JPS53123489A (fr)
AR (1)	AR222970A1 (fr)
AT (1)	AT365207B (fr)
AU (1)	AU515788B2 (fr)
BE (1)	BE865631A (fr)
BR (1)	BR7802036A (fr)
CA (1)	CA1133196A (fr)
CH (1)	CH635597A5 (fr)
DD (1)	DD136843A5 (fr)
DE (1)	DE2714948C2 (fr)
DK (1)	DK143478A (fr)
ES (1)	ES468234A1 (fr)
FR (1)	FR2385746A1 (fr)
GB (1)	GB1597285A (fr)
HU (1)	HU179485B (fr)
IT (1)	IT1094001B (fr)
NL (1)	NL7803495A (fr)
NO (1)	NO781129L (fr)
PL (1)	PL111001B1 (fr)
RO (1)	RO75157A (fr)
SE (1)	SE7803689L (fr)
SU (1)	SU755203A3 (fr)
YU (1)	YU75878A (fr)
ZA (1)	ZA781846B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3627287A1 (de) *	1986-08-12	1988-02-18	Huels Chemische Werke Ag	Verfahren zur verbesserten einhaltung des k-wertes und zur besseren erhaltung der leistung bei der kontinuierlichen polymerisation von vinylchlorid in emulsion
DE4142117A1 (de) *	1991-12-20	1993-06-24	Hoechst Ag	Verfahren zur bestimmung des umsatzes bei der polymerisation gasfoermiger monomerer
JP4921988B2 (ja) *	2007-01-16	2012-04-25	エスアイアイ・ネットワーク・システムズ株式会社	端子台用カバー機構
EP4029885B1 (fr) *	2019-09-11	2024-12-18	Lg Chem, Ltd.	Procédé de production d'un polymère à base de chlorure de vinyle

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
NL264978A (fr) *	1961-05-19	1964-06-10	Shell Int Research
DE1645672B2 (de) *	1966-07-08	1972-12-21	Wacker-Chemie GmbH, 8000 München	Verfahren zur herstellung von homopolymerisaten des vinylchlorids bzw mindestens 80 gew.-% vinylchlorideinheiten enthaltenden mischpolymerisaten
US3546154A (en) *	1966-09-27	1970-12-08	Stauffer Chemical Co	Emulsion polymerization of vinyl compounds
DE2521862C3 (de) *	1975-05-16	1978-05-18	Hoechst Ag, 6000 Frankfurt	Verfahren zur kontinuierlichen Herstellung von Polymerisaten und Mischpolymerisaten des Vinylchlorids in wäßriger Emulsion

1977
- 1977-04-02 DE DE2714948A patent/DE2714948C2/de not_active Expired
1978
- 1978-03-27 ES ES468234A patent/ES468234A1/es not_active Expired
- 1978-03-30 HU HU78HO2059A patent/HU179485B/hu unknown
- 1978-03-30 CH CH344278A patent/CH635597A5/de not_active IP Right Cessation
- 1978-03-30 YU YU00758/78A patent/YU75878A/xx unknown
- 1978-03-31 ZA ZA00781846A patent/ZA781846B/xx unknown
- 1978-03-31 AR AR271643A patent/AR222970A1/es active
- 1978-03-31 JP JP3695378A patent/JPS53123489A/ja active Pending
- 1978-03-31 DK DK143478A patent/DK143478A/da not_active Application Discontinuation
- 1978-03-31 NO NO781129A patent/NO781129L/no unknown
- 1978-03-31 AT AT0228978A patent/AT365207B/de not_active IP Right Cessation
- 1978-03-31 CA CA300,152A patent/CA1133196A/fr not_active Expired
- 1978-03-31 SU SU782596898A patent/SU755203A3/ru active
- 1978-03-31 RO RO7893689A patent/RO75157A/fr unknown
- 1978-03-31 NL NL7803495A patent/NL7803495A/xx not_active Application Discontinuation
- 1978-03-31 DD DD78204527A patent/DD136843A5/xx unknown
- 1978-03-31 GB GB12658/78A patent/GB1597285A/en not_active Expired
- 1978-03-31 BR BR7802036A patent/BR7802036A/pt unknown
- 1978-03-31 SE SE7803689A patent/SE7803689L/xx unknown
- 1978-03-31 IT IT21898/78A patent/IT1094001B/it active
- 1978-04-01 PL PL1978205744A patent/PL111001B1/pl unknown
- 1978-04-03 BE BE186521A patent/BE865631A/fr not_active IP Right Cessation
- 1978-04-03 FR FR7809740A patent/FR2385746A1/fr active Pending
- 1978-04-03 AU AU34714/78A patent/AU515788B2/en not_active Expired

Also Published As

Publication number	Publication date
IT1094001B (it)	1985-07-26
PL205744A1 (pl)	1979-01-29
ES468234A1 (es)	1978-12-01
AR222970A1 (es)	1981-07-15
BE865631A (fr)	1978-10-03
GB1597285A (en)	1981-09-03
FR2385746A1 (fr)	1978-10-27
NO781129L (no)	1978-10-03
ATA228978A (de)	1981-05-15
SE7803689L (sv)	1978-10-02
JPS53123489A (en)	1978-10-27
IT7821898A0 (it)	1978-03-31
BR7802036A (pt)	1978-11-28
SU755203A3 (en)	1980-08-07
DE2714948C2 (de)	1985-01-10
CH635597A5 (en)	1983-04-15
DE2714948A1 (de)	1978-10-12
AT365207B (de)	1981-12-28
ZA781846B (en)	1979-04-25
YU75878A (en)	1982-06-30
AU3471478A (en)	1979-10-11
NL7803495A (nl)	1978-10-04
HU179485B (en)	1982-10-28
RO75157A (fr)	1980-11-30
CA1133196A (fr)	1982-10-05
DK143478A (da)	1978-10-03
AU515788B2 (en)	1981-04-30
DD136843A5 (de)	1979-08-01

Publication	Publication Date	Title
US2557474A (en)	1951-06-19	Heat stabilization of vinyl polymers and copolymers
US4226748A (en)	1980-10-07	Fabric sizing emulsion
US3383346A (en)	1968-05-14	Particle size control in seed technique emulsion polymerization using hydroxyl group-containing modifier
US10696836B2 (en)	2020-06-30	Thermoplastic compositions containing acrylic copolymers as melt strength and clarity process aids
PL111001B1 (en)	1980-08-30	Method for manufacturing vinyl chloride polymers in continuous process
PL202098B1 (pl)	2009-06-30	Sposób wytwarzania nadtlenodiwęglanów i sposób rodnikowej polimeryzacji monomerów
US6277922B1 (en)	2001-08-21	Disperant system for making polyvinyl chloride which produces low color chlorinated polyvinyl chloride
US2666783A (en)	1954-01-19	Quaternary benzylchloride salts of 3-hydroxy 4-disubstituted aminobutene-1
EP1368422B1 (fr)	2005-08-24	Compositions polymeres comprenant des telomeres et des articles ou parties d'articles fabriques a l'aide de ces compositions
US4286078A (en)	1981-08-25	Process for the continuous manufacture of vinyl chloride polymers
NO783382L (no)	1979-04-09	Fremgangsmaate for polymerisering av vinylklorid
US4129710A (en)	1978-12-12	Fire retardant copolymer of triallyl phosphate and a bis (hydrocarbyl) vinylphosphonate
US3843734A (en)	1974-10-22	Process for preparing vinyl chloride based telomers and cotelomers of low molecular weight
US4401798A (en)	1983-08-30	Process for the production of vinyl halide polymers that uses an alkyl-substituted trisphenol as the chain-terminating agent
NO167211B (no)	1991-07-08	Fremgangsmaate for suspensjonspolymerisering av vinylklorid under anvendelse av hydroksypropylmetylcelluloseeter somsuspenderigsmiddel, og hydroksypropylmetylcelluloseeter for fremgangsmaatens utfoerelse.
NO761219L (fr)	1976-10-12
US3226370A (en)	1965-12-28	Granular polymerization in aqueous emulsion of normally crystalline vinylidene chloride
KR20070112871A (ko)	2007-11-27	페이스트화될 수 있는 중합체의 제조방법
JP2009057486A (ja)	2009-03-19	ペースト加工用塩化ビニル系樹脂及びその製造方法、並びにその用途
JPH0439310A (ja)	1992-02-10	塩化ビニル系多元共重合樹脂の製造方法
JPH07113041B2 (ja)	1995-12-06	ビニル系単量体のラジカル重合の反応抑制方法
US2831844A (en)	1958-04-22	Polymerization of vinyl chloride
KR20150138724A (ko)	2015-12-10	염화비닐계 수지의 제조방법
DE2322843A1 (de)	1974-01-17	Verfahren zur herstellung von polymeren auf der basis von vinylchlorid
EP3875497B1 (fr)	2025-06-04	Polymère à base de chlorure de vinyle et procédé de préparation s'y rapportant