CA1323280C - Detergents liquides - Google Patents

Detergents liquides

Info

Publication number: CA1323280C
Authority: CA; Canada
Prior art keywords: polymer; composition according; composition; electrolyte; viscosity
Prior art date: 1987-07-31
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000573102A

Other languages

English (en)

Inventor

Mario Bulfari

Johannes Cornelis Van De Pas

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-07-31

Filing date

1988-07-25

Publication date

1993-10-19

1987-07-31 Priority claimed from GB878718216A external-priority patent/GB8718216D0/en

1988-06-09 Priority claimed from GB888813689A external-priority patent/GB8813689D0/en

1988-07-25 Application filed by Unilever PLC filed Critical Unilever PLC

1993-10-19 Application granted granted Critical

1993-10-19 Publication of CA1323280C publication Critical patent/CA1323280C/fr

2010-10-19 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 83
239000007788 liquid Substances 0.000 title claims abstract description 25
239000003599 detergent Substances 0.000 title claims abstract description 22
229920000642 polymer Polymers 0.000 claims abstract description 118
239000003792 electrolyte Substances 0.000 claims abstract description 24
239000012071 phase Substances 0.000 claims abstract description 18
239000011149 active material Substances 0.000 claims abstract description 10
239000008346 aqueous phase Substances 0.000 claims abstract description 9
-1 alkali metal salt Chemical class 0.000 claims description 11
239000007787 solid Substances 0.000 claims description 11
229920001577 copolymer Polymers 0.000 claims description 9
239000007844 bleaching agent Substances 0.000 claims description 7
238000005191 phase separation Methods 0.000 claims description 7
239000003945 anionic surfactant Substances 0.000 claims description 6
239000007864 aqueous solution Substances 0.000 claims description 6
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical class O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 5
239000011976 maleic acid Substances 0.000 claims description 5
229910052783 alkali metal Inorganic materials 0.000 claims description 4
239000002736 nonionic surfactant Substances 0.000 claims description 4
229920001223 polyethylene glycol Polymers 0.000 claims description 4
239000002202 Polyethylene glycol Substances 0.000 claims description 2
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 2
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 claims description 2
239000011236 particulate material Substances 0.000 claims 4
LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 claims 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
239000000047 product Substances 0.000 description 17
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
239000011734 sodium Substances 0.000 description 14
229910052708 sodium Inorganic materials 0.000 description 14
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 12
230000000694 effects Effects 0.000 description 12
238000010348 incorporation Methods 0.000 description 8
239000002253 acid Substances 0.000 description 7
235000014113 dietary fatty acids Nutrition 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
150000004665 fatty acids Chemical class 0.000 description 6
239000000463 material Substances 0.000 description 6
239000002245 particle Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
239000011591 potassium Substances 0.000 description 6
239000000243 solution Substances 0.000 description 6
239000004094 surface-active agent Substances 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
239000007795 chemical reaction product Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
238000009472 formulation Methods 0.000 description 5
239000004615 ingredient Substances 0.000 description 5
229920000058 polyacrylate Polymers 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
102000004190 Enzymes Human genes 0.000 description 4
108090000790 Enzymes Proteins 0.000 description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
229910021536 Zeolite Inorganic materials 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
229910000323 aluminium silicate Inorganic materials 0.000 description 4
239000003240 coconut oil Substances 0.000 description 4
235000019864 coconut oil Nutrition 0.000 description 4
229940088598 enzyme Drugs 0.000 description 4
239000004744 fabric Substances 0.000 description 4
238000005259 measurement Methods 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 3
229910021538 borax Inorganic materials 0.000 description 3
229910001424 calcium ion Inorganic materials 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
238000000034 method Methods 0.000 description 3
239000002304 perfume Substances 0.000 description 3
239000000344 soap Substances 0.000 description 3
239000004328 sodium tetraborate Substances 0.000 description 3
235000010339 sodium tetraborate Nutrition 0.000 description 3
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
244000060011 Cocos nucifera Species 0.000 description 2
235000013162 Cocos nucifera Nutrition 0.000 description 2
229920002307 Dextran Polymers 0.000 description 2
229910019142 PO4 Inorganic materials 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
230000009286 beneficial effect Effects 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
239000004927 clay Substances 0.000 description 2
238000001493 electron microscopy Methods 0.000 description 2
150000002191 fatty alcohols Chemical class 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
239000002198 insoluble material Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
239000000693 micelle Substances 0.000 description 2
235000021317 phosphate Nutrition 0.000 description 2
125000003703 phosphorus containing inorganic group Chemical group 0.000 description 2
229920001296 polysiloxane Polymers 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
238000000518 rheometry Methods 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000003760 tallow Substances 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
229910021532 Calcite Inorganic materials 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 1
239000004367 Lipase Substances 0.000 description 1
102000004882 Lipase Human genes 0.000 description 1
108090001060 Lipase Proteins 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
108091034117 Oligonucleotide Proteins 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
229920000388 Polyphosphate Polymers 0.000 description 1
239000004365 Protease Substances 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
239000002280 amphoteric surfactant Substances 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
125000000129 anionic group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
235000012216 bentonite Nutrition 0.000 description 1
210000001217 buttock Anatomy 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
235000011148 calcium chloride Nutrition 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
239000003093 cationic surfactant Substances 0.000 description 1
239000003518 caustics Substances 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
MSJMDZAOKORVFC-UAIGNFCESA-L disodium maleate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C/C([O-])=O MSJMDZAOKORVFC-UAIGNFCESA-L 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
239000002001 electrolyte material Substances 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
238000001683 neutron diffraction Methods 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
239000001205 polyphosphate Substances 0.000 description 1
235000011176 polyphosphates Nutrition 0.000 description 1
235000015497 potassium bicarbonate Nutrition 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
235000011181 potassium carbonates Nutrition 0.000 description 1
TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical class [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
239000002243 precursor Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
230000002797 proteolythic effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000012088 reference solution Substances 0.000 description 1
238000009877 rendering Methods 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000004289 sodium hydrogen sulphite Substances 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
235000019832 sodium triphosphate Nutrition 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000007784 solid electrolyte Substances 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
230000008719 thickening Effects 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0026—Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Crystallography & Structural Chemistry (AREA)
Detergent Compositions (AREA)

CA000573102A 1987-07-31 1988-07-25 Detergents liquides Expired - Fee Related CA1323280C (fr)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB8718216		1987-07-31
GB878718216A GB8718216D0 (en)	1987-07-31	1987-07-31	Liquid detergent compositions
GB888813689A GB8813689D0 (en)	1988-06-09	1988-06-09	Liquid detergent compositions
GB8813689.0		1988-06-09

Publications (1)

Publication Number	Publication Date
CA1323280C true CA1323280C (fr)	1993-10-19

Family

ID=26292556

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000573102A Expired - Fee Related CA1323280C (fr)	1987-07-31	1988-07-25	Detergents liquides

Country Status (10)

Country	Link
EP (1)	EP0301882B1 (fr)
JP (1)	JPH0684520B2 (fr)
KR (1)	KR920000111B1 (fr)
AU (1)	AU600587B2 (fr)
BR (1)	BR8803786A (fr)
CA (1)	CA1323280C (fr)
DE (1)	DE3867749D1 (fr)
ES (1)	ES2029025T3 (fr)
NO (1)	NO171221C (fr)
TR (1)	TR23293A (fr)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8718217D0 (en) *	1987-07-31	1987-09-09	Unilever Plc	Liquid detergent compositions
GB8813978D0 (en) *	1988-06-13	1988-07-20	Unilever Plc	Liquid detergents
DE68905089T2 (de) *	1988-06-22	1993-07-22	Akzo Nv	Stabile, giessbare wasserhaltige bleichmittelzusammensetzungen, die feste organische peroxysaeure und mindestens zwei polymere enthalten.
GB8823655D0 (en) *	1988-10-07	1988-11-16	Unilever Plc	Liquid detergent compositions
ES2162785T3 (es) *	1989-02-27	2002-01-16	Unilever Nv	Composicion detergente liquida.
GB8924478D0 (en) *	1989-10-31	1989-12-20	Unilever Plc	Detergent compositions
BR9007879A (pt) *	1989-12-01	1992-09-29	Unilever Nv	Composicao detergente liquida e processo para o tratamento de tecidos e para a preparacao de uma composicao detergente e de um polimero desfloculante
ES2052279T3 (es) *	1989-12-07	1994-07-01	Unilever Nv	Detergentes liquidos.
GB8927729D0 (en) *	1989-12-07	1990-02-07	Unilever Plc	Liquid detergents
GB8928067D0 (en) *	1989-12-12	1990-02-14	Unilever Plc	Detergent compositions
WO1991013963A1 (fr) *	1990-03-06	1991-09-19	Unilever N.V.	Detergents liquides
US5066749A (en) *	1990-09-11	1991-11-19	National Starch And Chemical Investment Holding Corporation	Hydrophobically-modified polycarboxylates and process for their preparation
US5308530A (en) *	1990-11-21	1994-05-03	Lever Brothers Company, Division Of Conopco, Inc.	Detergent compositions containing polycarboxylates and calcium-sensitive enzymes
DE4216405A1 (de) *	1992-05-18	1993-11-25	Henkel Kgaa	Pumpfähige alkalische Reinigerkonzentrate
AU6080699A (en) *	1998-09-25	2000-04-17	Bijl, Dirk Johannes	Detergent composition
ES2409893T3 (es) *	2009-06-08	2013-06-28	The Procter & Gamble Company	Proceso para fabricar una composición limpiadora empleando la incorporación directa de tensioactivos concentrados
JP6675275B2 (ja) *	2016-06-15	2020-04-01	ライオン株式会社	繊維製品用液体洗浄剤組成物

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA666119A (en) *	1960-02-02	1963-07-02	A. Wright William	Liquid detergent composition
GB985503A (en) *	1963-02-15	1965-03-10	Ici Ltd	Detergent compositions
FR1439308A (fr) *	1964-04-24	1966-05-20	Unilever Nv	Compositions détergentes liquides
DE3151679A1 (de) *	1981-12-28	1983-07-07	Henkel KGaA, 4000 Düsseldorf	"verwendung von viskositaetsreglern fuer tensidkonzentrate"
ATE47424T1 (de) *	1982-02-05	1989-11-15	Albright & Wilson	Fluessige detergens-zusammensetzungen.
IT1164469B (it) *	1982-11-09	1987-04-08	Mira Lanza Spa	Composizione detergente concentrata sotto forma di liquido viscoso rapidamente solubile in acqua adatta alla preparazione mediante diluizione di detersivi liquidi pronti per l'uso
NZ207692A (en) *	1983-04-04	1986-04-11	Colgate Palmolive Co	Soil-release promoting liquid detergent containing terephthalate polymers
IN166360B (fr) *	1985-08-05	1990-04-14	Colgate Palmolive Co
US4891148A (en) *	1985-08-05	1990-01-02	Colgate-Palmolive Company	Low phosphate or phosphate free nonaqueous liquid nonionic laundry detergent comopsition and method of use
JPS63190502A (ja) *	1987-02-02	1988-08-08	Railway Technical Res Inst	パンタグラフの上昇検知装置
GB8718217D0 (en) *	1987-07-31	1987-09-09	Unilever Plc	Liquid detergent compositions

1988
- 1988-07-25 CA CA000573102A patent/CA1323280C/fr not_active Expired - Fee Related
- 1988-07-27 AU AU20076/88A patent/AU600587B2/en not_active Ceased
- 1988-07-29 JP JP63190503A patent/JPH0684520B2/ja not_active Expired - Lifetime
- 1988-07-29 EP EP19880307006 patent/EP0301882B1/fr not_active Expired - Lifetime
- 1988-07-29 BR BR8803786A patent/BR8803786A/pt not_active IP Right Cessation
- 1988-07-29 NO NO883388A patent/NO171221C/no not_active IP Right Cessation
- 1988-07-29 ES ES198888307006T patent/ES2029025T3/es not_active Expired - Lifetime
- 1988-07-29 DE DE8888307006T patent/DE3867749D1/de not_active Expired - Fee Related
- 1988-07-30 KR KR1019880009661A patent/KR920000111B1/ko not_active Expired
- 1988-08-01 TR TR523/88A patent/TR23293A/xx unknown

Also Published As

Publication number	Publication date
EP0301882B1 (fr)	1992-01-15
JPH0684520B2 (ja)	1994-10-26
TR23293A (tr)	1989-09-14
AU600587B2 (en)	1990-08-16
NO171221B (no)	1992-11-02
KR920000111B1 (ko)	1992-01-09
ES2029025T3 (es)	1992-07-16
KR890002383A (ko)	1989-04-10
NO883388L (no)	1989-02-01
AU2007688A (en)	1989-02-02
EP0301882A1 (fr)	1989-02-01
BR8803786A (pt)	1989-02-21
DE3867749D1 (de)	1992-02-27
JPH01103700A (ja)	1989-04-20
NO883388D0 (no)	1988-07-29
NO171221C (no)	1993-02-10

Legal Events

Date	Code	Title	Description
2002-10-21	MKLA	Lapsed

Publication	Publication Date	Title
US5108644A (en)	1992-04-28	Liquid detergent compositions containing a peg viscosity reducing polymer
US5776883A (en)	1998-07-07	Structured liquid detergent compositions containing nonionic structuring polymers providing enhanced shear thinning behavior
AU600587B2 (en)	1990-08-16	Liquid detergent compositions
EP0763595B1 (fr)	2002-01-16	Composition détergente
EP0526539B1 (fr)	1994-01-12	Compositions pour detergents liquides
US5205957A (en)	1993-04-27	Structured aqueous liquid detergents containing functional polymers
US5397493A (en)	1995-03-14	Process for making concentrated heavy duty detergents
CA1334919C (fr)	1995-03-28	Compositions de detergents liquides
JPS6169895A (ja)	1986-04-10	液体洗剤組成物
CA2070414C (fr)	2001-03-06	Compositions detergentes
EP0362916B1 (fr)	1995-04-19	Compositions détergentes liquides
GB2237813A (en)	1991-05-15	Liquid detergent
EP0359308B1 (fr)	1995-04-19	Compositions détergentes liquides
US5573701A (en)	1996-11-12	Liquid detergent composition
AU646018B2 (en)	1994-02-03	Liquid bleach composition
EP0346994B1 (fr)	1996-03-06	Compositions détergentes liquides
EP0301884B1 (fr)	1992-01-02	Compositions détergentes liquides
US5672580A (en)	1997-09-30	Liquid detergent compositions
AU643503B2 (en)	1993-11-18	Liquid bleach composition
CA2062781C (fr)	1997-11-25	Agent liquide de blanchiment
CA2073563C (fr)	1999-03-02	Composition de blanchisseur liquide
CA2064900C (fr)	1996-12-17	Detergents liquides