CA2015413A1 - Procede de preparation de membrane microporeuse et membrane ainsi produite - Google Patents
Procede de preparation de membrane microporeuse et membrane ainsi produiteInfo
- Publication number
- CA2015413A1 CA2015413A1 CA2015413A CA2015413A CA2015413A1 CA 2015413 A1 CA2015413 A1 CA 2015413A1 CA 2015413 A CA2015413 A CA 2015413A CA 2015413 A CA2015413 A CA 2015413A CA 2015413 A1 CA2015413 A1 CA 2015413A1
- Authority
- CA
- Canada
- Prior art keywords
- membrane
- hydrophilic polymer
- preparing
- leaching
- subsequently
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000012982 microporous membrane Substances 0.000 title abstract 2
- 229920001477 hydrophilic polymer Polymers 0.000 abstract 3
- 230000015271 coagulation Effects 0.000 abstract 2
- 238000005345 coagulation Methods 0.000 abstract 2
- 238000002386 leaching Methods 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 230000001112 coagulating effect Effects 0.000 abstract 1
- 239000012510 hollow fiber Substances 0.000 abstract 1
- 229920001600 hydrophobic polymer Polymers 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0016—Coagulation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0011—Casting solutions therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/003—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/04—Hydrophobization
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/30—Cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/36—Hydrophilic membranes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8901090A NL8901090A (nl) | 1989-04-28 | 1989-04-28 | Werkwijze voor het vervaardigen van een microporeus membraan en een dergelijk membraan. |
| NL8901090 | 1989-04-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2015413A1 true CA2015413A1 (fr) | 1990-10-28 |
| CA2015413C CA2015413C (fr) | 1997-02-25 |
Family
ID=19854581
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002015413A Expired - Lifetime CA2015413C (fr) | 1989-04-28 | 1990-04-25 | Procede de preparation de membrane microporeuse et membrane ainsi produite |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5076925A (fr) |
| EP (1) | EP0395133B1 (fr) |
| JP (1) | JP3196029B2 (fr) |
| AT (1) | ATE117912T1 (fr) |
| CA (1) | CA2015413C (fr) |
| DE (1) | DE69016491T2 (fr) |
| DK (1) | DK0395133T3 (fr) |
| ES (1) | ES2070263T3 (fr) |
| GR (1) | GR3015885T3 (fr) |
| HK (1) | HK1007697A1 (fr) |
| NL (1) | NL8901090A (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5954966A (en) * | 1997-01-31 | 1999-09-21 | University Of Ottawa | Membrane composition and method of preparation |
Families Citing this family (86)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5762798A (en) * | 1991-04-12 | 1998-06-09 | Minntech Corporation | Hollow fiber membranes and method of manufacture |
| US5444097A (en) * | 1992-07-07 | 1995-08-22 | Millipore Corporation | Porous polymeric structures and a method of making such structures by means of heat-induced phase separation |
| USRE36914E (en) * | 1992-10-07 | 2000-10-17 | Minntech Corp | Dialysate filter including an asymmetric microporous, hollow fiber membrane incorporating a polyimide |
| NL9301653A (nl) * | 1993-09-24 | 1995-04-18 | X Flow Bv | Werkwijze voor het verwijderen van troebelheid veroorzakende bestanddelen uit een vloeistof met behulp van microfiltratie. |
| WO1996035952A1 (fr) * | 1995-05-09 | 1996-11-14 | Smithkline Diagnostics, Inc. | Dispositifs et procedes de separation des composants cellulaires du sang d'avec la partie liquide |
| US6378907B1 (en) | 1996-07-12 | 2002-04-30 | Mykrolis Corporation | Connector apparatus and system including connector apparatus |
| US5885456A (en) * | 1996-08-09 | 1999-03-23 | Millipore Corporation | Polysulfone copolymer membranes and process |
| NL1004210C2 (nl) * | 1996-10-07 | 1998-04-10 | Prime Water Systems N V | Waterfiltratie-inrichting. |
| EP0952885B1 (fr) | 1996-12-20 | 2010-09-22 | Siemens Water Technologies Corp. | Procede de decapage |
| US5879951A (en) | 1997-01-29 | 1999-03-09 | Smithkline Diagnostics, Inc. | Opposable-element assay device employing unidirectional flow |
| US5939252A (en) | 1997-05-09 | 1999-08-17 | Lennon; Donald J. | Detachable-element assay device |
| US6218441B1 (en) | 1997-09-18 | 2001-04-17 | Timothy B. Meluch | Melt-spun polysulfone semipermeable membranes and methods for making the same |
| US7144505B2 (en) * | 1997-09-18 | 2006-12-05 | Baxter International Inc. | Melt-spun polysulfone semipermeable membranes and methods for making the same |
| US6641733B2 (en) | 1998-09-25 | 2003-11-04 | U. S. Filter Wastewater Group, Inc. | Apparatus and method for cleaning membrane filtration modules |
| AUPP985099A0 (en) | 1999-04-20 | 1999-05-13 | Usf Filtration And Separations Group Inc. | Membrane filtration manifold system |
| JP3940546B2 (ja) * | 1999-06-07 | 2007-07-04 | 株式会社東芝 | パターン形成方法およびパターン形成材料 |
| AUPQ680100A0 (en) | 2000-04-10 | 2000-05-11 | Usf Filtration And Separations Group Inc. | Hollow fibre restraining system |
| KR100826622B1 (ko) | 2000-05-12 | 2008-05-02 | 폴 코포레이션 | 필터 |
| JP4649092B2 (ja) | 2000-05-12 | 2011-03-09 | ポール・コーポレーション | ろ過装置およびろ過装置のための接続構造体 |
| US6528321B1 (en) | 2000-06-26 | 2003-03-04 | Beckman Coulter, Inc. | Opposable-element chromatographic assay device for detection of analytes in whole blood samples |
| EP1322395B1 (fr) | 2000-09-13 | 2011-02-23 | Entegris, Inc. | Appareil de filtration de liquides |
| AUPR064800A0 (en) | 2000-10-09 | 2000-11-02 | Usf Filtration And Separations Group Inc. | Improved membrane filtration system |
| AUPR143400A0 (en) | 2000-11-13 | 2000-12-07 | Usf Filtration And Separations Group Inc. | Modified membranes |
| AUPR421501A0 (en) | 2001-04-04 | 2001-05-03 | U.S. Filter Wastewater Group, Inc. | Potting method |
| AUPR584301A0 (en) | 2001-06-20 | 2001-07-12 | U.S. Filter Wastewater Group, Inc. | Membrane polymer compositions |
| AUPR692401A0 (en) | 2001-08-09 | 2001-08-30 | U.S. Filter Wastewater Group, Inc. | Method of cleaning membrane modules |
| US7469932B2 (en) | 2001-09-13 | 2008-12-30 | Entegris, Inc. | Receptor for a separation module |
| TW558448B (en) | 2001-09-13 | 2003-10-21 | Mykrolis Corp | Separation module |
| AUPR774201A0 (en) | 2001-09-18 | 2001-10-11 | U.S. Filter Wastewater Group, Inc. | High solids module |
| ATE333318T1 (de) | 2001-11-16 | 2006-08-15 | Us Filter Wastewater Group Inc | Methode zur reinigung von membranen |
| US7247238B2 (en) | 2002-02-12 | 2007-07-24 | Siemens Water Technologies Corp. | Poly(ethylene chlorotrifluoroethylene) membranes |
| AUPS300602A0 (en) | 2002-06-18 | 2002-07-11 | U.S. Filter Wastewater Group, Inc. | Methods of minimising the effect of integrity loss in hollow fibre membrane modules |
| AU2003258986A1 (en) * | 2002-07-05 | 2004-01-23 | Massachusetts Institute Of Technology | Graft copolymers |
| JP4803697B2 (ja) * | 2002-08-15 | 2011-10-26 | 三菱レイヨン株式会社 | 多孔質膜の製造方法 |
| CA2501628C (fr) | 2002-10-10 | 2012-12-04 | U.S. Filter Wastewater Group, Inc. | Agencement de filtration et de lavage a contre-courant pour modules de membranes |
| US7306105B2 (en) * | 2002-11-12 | 2007-12-11 | Mitsubishi Rayon Co., Ltd. | Composite porous membrane and method for producing the same |
| AU2002953111A0 (en) | 2002-12-05 | 2002-12-19 | U. S. Filter Wastewater Group, Inc. | Mixing chamber |
| AU2003903507A0 (en) | 2003-07-08 | 2003-07-24 | U. S. Filter Wastewater Group, Inc. | Membrane post-treatment |
| US8268176B2 (en) | 2003-08-29 | 2012-09-18 | Siemens Industry, Inc. | Backwash |
| AU2004289373B2 (en) | 2003-11-14 | 2010-07-29 | Evoqua Water Technologies Llc | Improved module cleaning method |
| US8758621B2 (en) | 2004-03-26 | 2014-06-24 | Evoqua Water Technologies Llc | Process and apparatus for purifying impure water using microfiltration or ultrafiltration in combination with reverse osmosis |
| WO2005107929A2 (fr) | 2004-04-22 | 2005-11-17 | Siemens Water Technologies Corp. | Appareil de filtration comprenant un bioreacteur a membrane et une cuve de traitement pour la digestion de matieres organiques |
| JP2008504122A (ja) | 2004-07-02 | 2008-02-14 | シーメンス・ウォーター・テクノロジーズ・コーポレーション | 気体輸送膜 |
| EP1773477B1 (fr) | 2004-07-05 | 2011-09-07 | Siemens Water Technologies Corp. | Membranes hydrophiliques |
| NZ588094A (en) | 2004-08-20 | 2012-04-27 | Siemens Water Tech Corp | Potting head for hollow fibre filter module |
| AU2005282211B2 (en) | 2004-09-07 | 2011-04-21 | Evoqua Water Technologies Llc | Reduction of backwash liquid waste |
| US8506806B2 (en) | 2004-09-14 | 2013-08-13 | Siemens Industry, Inc. | Methods and apparatus for removing solids from a membrane module |
| EP1807181A4 (fr) | 2004-09-15 | 2009-04-22 | Siemens Water Tech Corp | Aeration variable en continu |
| CN101068612B (zh) * | 2004-10-13 | 2010-12-15 | 3M创新有限公司 | 制备亲水性聚醚砜膜的方法 |
| US7591950B2 (en) | 2004-11-02 | 2009-09-22 | Siemens Water Technologies Corp. | Submerged cross-flow filtration |
| MY141919A (en) | 2004-12-03 | 2010-07-30 | Siemens Water Tech Corp | Membrane post treatment |
| CA2591580A1 (fr) | 2004-12-24 | 2006-06-29 | Siemens Water Technologies Corp. | Procede et appareil simples de lavage au gaz |
| ATE549076T1 (de) | 2004-12-24 | 2012-03-15 | Siemens Industry Inc | Reinigung in membranfiltrationssystemen |
| JP4839630B2 (ja) * | 2005-02-22 | 2011-12-21 | 東洋紡績株式会社 | ポリスルホン系選択透過性中空糸膜束および血液浄化器 |
| JP3772909B1 (ja) * | 2005-04-04 | 2006-05-10 | 東洋紡績株式会社 | 血液浄化器 |
| CN101184548B (zh) | 2005-04-29 | 2011-10-05 | 西门子水技术公司 | 用于膜滤器的化学清洗剂 |
| AU2006261581B2 (en) * | 2005-06-20 | 2012-03-15 | Evoqua Water Technologies Llc | Cross linking treatment of polymer membranes |
| NZ563980A (en) * | 2005-06-20 | 2011-07-29 | Siemens Water Tech Corp | Cross linking treatment of polymer membranes |
| WO2007006104A1 (fr) | 2005-07-14 | 2007-01-18 | Siemens Water Technologies Corp. | Traitement de membranes avec un monopersulfate |
| CN101287538B (zh) | 2005-08-22 | 2013-03-06 | 西门子工业公司 | 使用歧管以减少回洗的水过滤装置 |
| WO2007044415A2 (fr) | 2005-10-05 | 2007-04-19 | Siemens Water Technologies Corp. | Procédé et appareil destinés à traiter les eaux usées |
| US7563363B2 (en) | 2005-10-05 | 2009-07-21 | Siemens Water Technologies Corp. | System for treating wastewater |
| US7455765B2 (en) | 2006-01-25 | 2008-11-25 | Siemens Water Technologies Corp. | Wastewater treatment system and method |
| US8293098B2 (en) | 2006-10-24 | 2012-10-23 | Siemens Industry, Inc. | Infiltration/inflow control for membrane bioreactor |
| EP2129629A1 (fr) | 2007-04-02 | 2009-12-09 | Siemens Water Technologies Corp. | Commande d'infiltration/afflux améliorée pour bioréacteur à membranes |
| US9764288B2 (en) | 2007-04-04 | 2017-09-19 | Evoqua Water Technologies Llc | Membrane module protection |
| EP2152390B1 (fr) | 2007-05-29 | 2012-05-23 | Siemens Industry, Inc. | Nettoyage d'une membrane avec une pompe pneumatique pulsée |
| EP2331242B1 (fr) | 2008-07-24 | 2018-09-05 | Evoqua Water Technologies LLC | Système de cadre pour modules de filtration sur membrane |
| AU2009282912B2 (en) | 2008-08-20 | 2014-11-27 | Evoqua Water Technologies Llc | Improved membrane system backwash energy efficiency |
| MX342636B (es) * | 2008-09-26 | 2016-10-07 | Asahi Kasei Chemicals Corp | Membrana porosa, proceso para producir una membrana porosa, metodo para producir liquido aclarado y modulo de membrana porosa. |
| WO2010142673A1 (fr) | 2009-06-11 | 2010-12-16 | Siemens Water Technologies Corp. | Procédés de nettoyage d'une membrane polymère poreuse et kit pour le nettoyage d'une membrane polymère poreuse |
| WO2011010690A1 (fr) * | 2009-07-22 | 2011-01-27 | 三菱レイヨン株式会社 | Procédé de production dun film poreux |
| EP2563501B1 (fr) | 2010-04-30 | 2019-05-15 | Evoqua Water Technologies LLC | Dispositif de distribution d'un écoulement de fluide |
| US9022224B2 (en) | 2010-09-24 | 2015-05-05 | Evoqua Water Technologies Llc | Fluid control manifold for membrane filtration system |
| US9539547B2 (en) | 2011-08-03 | 2017-01-10 | Mitsubishi Rayon Co., Ltd. | Porous film manufacturing method and apparatus |
| JP5633576B2 (ja) * | 2011-09-15 | 2014-12-03 | 三菱レイヨン株式会社 | 多孔質中空糸膜の製造方法 |
| US9925499B2 (en) | 2011-09-30 | 2018-03-27 | Evoqua Water Technologies Llc | Isolation valve with seal for end cap of a filtration system |
| CN103958024B (zh) | 2011-09-30 | 2016-07-06 | 伊沃夸水处理技术有限责任公司 | 改进的歧管排列 |
| CN102443187B (zh) * | 2011-10-28 | 2013-03-27 | 湖北工业大学 | 一种利用亲水改性无机填料作为致孔剂制备多孔膜的方法 |
| AU2013280452B2 (en) | 2012-06-28 | 2017-07-20 | Evoqua Water Technologies Llc | A potting method |
| KR20150054918A (ko) | 2012-09-14 | 2015-05-20 | 에보쿠아 워터 테크놀로지스 엘엘씨 | 막을 위한 중합체 블렌드 |
| US9962865B2 (en) | 2012-09-26 | 2018-05-08 | Evoqua Water Technologies Llc | Membrane potting methods |
| WO2014052071A1 (fr) | 2012-09-26 | 2014-04-03 | Evoqua Water Technologies Llc | Dispositif de sécurisation de membrane |
| KR20150059788A (ko) | 2012-09-27 | 2015-06-02 | 에보쿠아 워터 테크놀로지스 엘엘씨 | 침지된 막을 위한 가스 스코어링 장치 |
| KR101785184B1 (ko) | 2013-03-15 | 2017-10-12 | 미쯔비시 케미컬 주식회사 | 다공질막용 수지 조성물, 제막 원액, 다공질막, 상기 다공질막을 사용한 중공사막, 수처리 장치, 전해질 지지체 및 세퍼레이터 |
| CN107847869B (zh) | 2015-07-14 | 2021-09-10 | 罗门哈斯电子材料新加坡私人有限公司 | 用于过滤系统的通气装置 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3957651A (en) * | 1971-12-16 | 1976-05-18 | Chemical Systems Incorporated | Microporous polyester membranes and polymer assisted phase inversion process for their manufacture |
| JPS59160506A (ja) * | 1983-02-28 | 1984-09-11 | Kuraray Co Ltd | 複合中空糸分離膜およびその製造法 |
| JPH0757825B2 (ja) * | 1985-04-17 | 1995-06-21 | 東レ株式会社 | ポリスルホン系樹脂多孔膜 |
| DE3681143D1 (de) * | 1985-12-23 | 1991-10-02 | Gelman Sciences Inc | Filtermembran und verfahren zu ihrer herstellung. |
| NL8602402A (nl) * | 1986-09-23 | 1988-04-18 | X Flow Bv | Werkwijze voor de vervaardiging van hydrofiele membranen en dergelijke membranen. |
| JPS6397202A (ja) * | 1986-10-15 | 1988-04-27 | Toray Ind Inc | ポリエ−テルスルホン系樹脂半透膜およびその製造方法 |
| JPS63141610A (ja) * | 1986-12-02 | 1988-06-14 | Fuji Photo Film Co Ltd | 微孔性膜の製造方法 |
-
1989
- 1989-04-28 NL NL8901090A patent/NL8901090A/nl not_active Application Discontinuation
-
1990
- 1990-04-10 ES ES90200879T patent/ES2070263T3/es not_active Expired - Lifetime
- 1990-04-10 DE DE69016491T patent/DE69016491T2/de not_active Expired - Lifetime
- 1990-04-10 AT AT90200879T patent/ATE117912T1/de not_active IP Right Cessation
- 1990-04-10 EP EP90200879A patent/EP0395133B1/fr not_active Expired - Lifetime
- 1990-04-10 DK DK90200879.6T patent/DK0395133T3/da active
- 1990-04-17 US US07/510,170 patent/US5076925A/en not_active Expired - Lifetime
- 1990-04-25 CA CA002015413A patent/CA2015413C/fr not_active Expired - Lifetime
- 1990-04-26 JP JP11158090A patent/JP3196029B2/ja not_active Expired - Lifetime
-
1995
- 1995-04-19 GR GR950401022T patent/GR3015885T3/el unknown
-
1998
- 1998-06-26 HK HK98106954A patent/HK1007697A1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5954966A (en) * | 1997-01-31 | 1999-09-21 | University Of Ottawa | Membrane composition and method of preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69016491D1 (de) | 1995-03-16 |
| JP3196029B2 (ja) | 2001-08-06 |
| DE69016491T2 (de) | 1995-08-24 |
| US5076925A (en) | 1991-12-31 |
| DK0395133T3 (da) | 1995-07-10 |
| NL8901090A (nl) | 1990-11-16 |
| ATE117912T1 (de) | 1995-02-15 |
| GR3015885T3 (en) | 1995-07-31 |
| CA2015413C (fr) | 1997-02-25 |
| HK1007697A1 (en) | 1999-04-23 |
| EP0395133A1 (fr) | 1990-10-31 |
| ES2070263T3 (es) | 1995-06-01 |
| JPH02302449A (ja) | 1990-12-14 |
| EP0395133B1 (fr) | 1995-02-01 |
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