CA2230017C - Hydrogen cyanide process and apparatus therefor - Google Patents

Hydrogen cyanide process and apparatus therefor Download PDF

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Publication number
CA2230017C
CA2230017C CA002230017A CA2230017A CA2230017C CA 2230017 C CA2230017 C CA 2230017C CA 002230017 A CA002230017 A CA 002230017A CA 2230017 A CA2230017 A CA 2230017A CA 2230017 C CA2230017 C CA 2230017C
Authority
CA
Canada
Prior art keywords
stream
oxidant
mixed
conduit
mixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002230017A
Other languages
English (en)
French (fr)
Other versions
CA2230017A1 (en
Inventor
Christopher Cowell
Ralph Doy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Lucite International UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite International UK Ltd filed Critical Lucite International UK Ltd
Publication of CA2230017A1 publication Critical patent/CA2230017A1/en
Application granted granted Critical
Publication of CA2230017C publication Critical patent/CA2230017C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/02—Preparation, separation or purification of hydrogen cyanide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/02—Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208—Preparation in gaseous phase
    • C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
    • C01C3/022—Apparatus therefor
    • C01C3/0225—Apparatus therefor characterised by the synthesis reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2415—Tubular reactors
    • B01J19/2425—Tubular reactors in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00—Cyanogen; Compounds thereof
    • C01C3/02—Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208—Preparation in gaseous phase
    • C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
CA002230017A 1995-09-01 1996-08-29 Hydrogen cyanide process and apparatus therefor Expired - Fee Related CA2230017C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP95113796.7 1995-09-01
EP95113796 1995-09-01
PCT/GB1996/002103 WO1997009273A1 (en) 1995-09-01 1996-08-29 Hydrogen cyanide process and apparatus therefor

Publications (2)

Publication Number Publication Date
CA2230017A1 CA2230017A1 (en) 1997-03-13
CA2230017C true CA2230017C (en) 2006-06-20

Family

ID=8219571

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002230017A Expired - Fee Related CA2230017C (en) 1995-09-01 1996-08-29 Hydrogen cyanide process and apparatus therefor

Country Status (13)

Country Link
US (2) US6491876B2 (2)
EP (1) EP0847372B1 (2)
JP (1) JP3889442B2 (2)
KR (1) KR100411692B1 (2)
CN (1) CN1095806C (2)
AT (1) ATE202541T1 (2)
AU (1) AU702825C (2)
BR (1) BR9610149A (2)
CA (1) CA2230017C (2)
DE (1) DE69613581T2 (2)
ES (1) ES2158339T3 (2)
TW (1) TW389741B (2)
WO (1) WO1997009273A1 (2)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69613581T2 (de) * 1995-09-01 2002-04-25 Ineos Acrylics Uk Ltd., Southampton Verfahren und vorrichtung zur herstellung von cyanwasserstoff
DE19754988A1 (de) * 1997-12-11 1999-06-17 Degussa Herstellung von Blausäure nach dem Andrussow-Verfahren
DE19810484A1 (de) * 1998-03-11 1999-09-16 Degussa Verfahren zur Herstellung von Blausäure
US6221327B1 (en) 1998-05-15 2001-04-24 Rohm And Haas Company Catalyst system using flow-through radiation shielding and a process for producing hydrogen cyanide using the same
AU4090600A (en) * 1999-06-30 2001-01-04 Rohm And Haas Company High performance heat exchangers
US6649137B2 (en) 2000-05-23 2003-11-18 Rohm And Haas Company Apparatus with improved safety features for high temperature industrial processes
DE10034194A1 (de) 2000-07-13 2003-09-11 Roehm Gmbh Verfahren zur Herstellung von Cyanwasserstoff
DE10034193A1 (de) 2000-07-13 2002-03-28 Roehm Gmbh Verfahren zur Herstellung von Cyanwasserstoff
EP1604947A1 (en) * 2004-06-07 2005-12-14 ETH Zürich Process and apparatus for producing hydrogen or ammonia
DE102007014586A1 (de) 2007-03-23 2008-09-25 Evonik Röhm Gmbh Verfahren zur Herstellung von Cyanwasserstoff (HCN)
DE102007034715A1 (de) * 2007-07-23 2009-01-29 Evonik Röhm Gmbh Reaktor zur Herstellung von Cyanwasserstoff nach dem Andrussow-Verfahren
TWI390145B (zh) * 2008-03-31 2013-03-21 Rohm & Haas 用於爆燃壓力衰減之方法及設備
WO2014099607A1 (en) 2012-12-18 2014-06-26 Invista Technologies S.A. R. L. Integrated process for hexamethylenediamine production
AU2013363333A1 (en) * 2012-12-18 2015-07-30 Invista Technologies S.A.R.L. Process for producing hydrogen cyanide and recovering hydrogen
CN103864113B (zh) 2012-12-18 2018-01-19 英威达纺织（英国）有限公司 使用转化器生产氰化氢的方法
WO2014099601A1 (en) * 2012-12-18 2014-06-26 Invista Technologies S.A.R.L. Process for stabilizing heat exchanger tubes in andrussow process
CN103864623B (zh) * 2012-12-18 2017-04-12 英威达科技公司 二胺生产的一体化工艺
WO2014099605A1 (en) * 2012-12-18 2014-06-26 Invista Technologies S.A R.L. Process for producing hydrogen cyanide using flow straightener
CN103864109A (zh) * 2012-12-18 2014-06-18 因温斯特技术公司 用于安德卢梭法中的再循环的系统和方法
EP2935094A1 (en) * 2012-12-18 2015-10-28 Invista Technologies S.à.r.l. Apparatus and method for hydrogen recovery in an andrussow process
EP2935115A1 (en) 2012-12-18 2015-10-28 Invista Technologies S.à.r.l. Operational controls for inert gas blanketing for andrussow process
CN113816398B (zh) * 2012-12-18 2023-11-10 英威达纺织（英国）有限公司 安德卢梭法中氨比例的变化
CN110127724A (zh) * 2013-07-12 2019-08-16 英威达纺织（英国）有限公司 使用第二废热锅炉的氰化氢制造方法
FR3008626B1 (fr) * 2013-07-19 2015-08-07 Arkema France Reacteur pour preparer du cyanure d'hydrogene par le procede d'andrussow, equipement comprenant ledit reacteur et procede utilisant un tel equipement
FR3008692B1 (fr) 2013-07-19 2016-12-23 Arkema France Installation et procede pour la preparation de cyanure d'hydrogene
US10323888B2 (en) * 2016-04-18 2019-06-18 Corrosion Monitoring Service Inc. System and method for installing external corrosion guards
CN120268332A (zh) * 2024-01-05 2025-07-08 中国天辰工程有限公司 一种制备氰化氢的反应器

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1934838A (en) 1930-04-14 1933-11-14 Ig Farbenindustrie Ag Production of hydrocyanic acid
DE1005049B (de) * 1951-12-06 1957-03-28 Goodrich Co B F Verfahren zur Erzeugung von Cyanwasserstoff
US2803522A (en) * 1953-04-15 1957-08-20 Du Pont Manufacture of hydrogen cyanide
US3112177A (en) * 1959-11-11 1963-11-26 Toyo Koatsu Ind Inc Method of separating ammonia from hydrogen cyanide
US3104945A (en) * 1961-07-19 1963-09-24 Du Pont Method of producing hydrogen cyanide
DE1161870B (de) 1961-09-19 1964-01-30 Hans J Zimmer Verfahrenstechni Verfahren zur Herstellung von Cyanwasserstoff
US3215495A (en) * 1962-01-23 1965-11-02 Du Pont Apparatus and process for preparing hydrogen cyanide
DE1190445B (de) * 1962-09-29 1965-04-08 Hans J Zimmer Verfahrenstechni Verfahren zur Herstellung von Cyanwasserstoff und Nitrilen
NL6604519A (2) 1965-04-14 1966-10-17
US3376500A (en) 1966-04-25 1968-04-02 Varian Associates Direct reading magnetic field intensity indicating apparatus
US4107278A (en) 1976-08-16 1978-08-15 E. I. Du Pont De Nemours And Company Process for making HCN
US4128622A (en) * 1976-08-27 1978-12-05 E. I. Du Pont De Nemours And Company Process for producing hydrogen cyanide
PL109343B1 (en) 1978-06-19 1981-11-30 Politechnika Wroclawska Method of producing hydrogen cyanide
US5266291A (en) * 1992-05-05 1993-11-30 Praxair Technology, Inc. Packed bed arrangement for oxidation reaction system
US5360603A (en) * 1993-08-23 1994-11-01 Praxair Technology, Inc. Packed bed arrangement useful for mixing and/or oxidation
DE69613581T2 (de) * 1995-09-01 2002-04-25 Ineos Acrylics Uk Ltd., Southampton Verfahren und vorrichtung zur herstellung von cyanwasserstoff

Also Published As

Publication number Publication date
US6491876B2 (en) 2002-12-10
DE69613581D1 (de) 2001-08-02
JP3889442B2 (ja) 2007-03-07
AU6879996A (en) 1997-03-27
DE69613581T2 (de) 2002-04-25
EP0847372B1 (en) 2001-06-27
CN1095806C (zh) 2002-12-11
CN1200102A (zh) 1998-11-25
KR19990044326A (ko) 1999-06-25
US6656442B2 (en) 2003-12-02
TW389741B (en) 2000-05-11
ES2158339T3 (es) 2001-09-01
CA2230017A1 (en) 1997-03-13
JPH11512070A (ja) 1999-10-19
KR100411692B1 (ko) 2004-02-18
MX9801546A (es) 1998-05-31
WO1997009273A1 (en) 1997-03-13
EP0847372A1 (en) 1998-06-17
BR9610149A (pt) 1999-02-02
US20020039553A1 (en) 2002-04-04
ATE202541T1 (de) 2001-07-15
AU702825B2 (en) 1999-03-04
US20020182137A1 (en) 2002-12-05
AU702825C (en) 2002-09-19

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Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20130829