JP3889442B2 - シアン化水素の製造方法及びそのための装置 - Google Patents

シアン化水素の製造方法及びそのための装置 Download PDF

Info

Publication number: JP3889442B2
Authority: JP; Japan
Prior art keywords: stream; oxidant; conduit; mixing; mixed
Prior art date: 1995-09-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

JP51093197A

Other languages

English (en)

Japanese (ja)

Other versions

JPH11512070A5 (2

JPH11512070A (ja

Inventor

カウエル，クリストファー

ドイ，ラルフ

Original Assignee

ルーサイトインターナショナルユーケーリミティド

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-09-01

Filing date

1996-08-29

Publication date

2007-03-07

1996-08-29 Application filed by ルーサイトインターナショナルユーケーリミティド filed Critical ルーサイトインターナショナルユーケーリミティド

1999-10-19 Publication of JPH11512070A publication Critical patent/JPH11512070A/ja

2004-08-26 Publication of JPH11512070A5 publication Critical patent/JPH11512070A5/ja

2007-03-07 Application granted granted Critical

2007-03-07 Publication of JP3889442B2 publication Critical patent/JP3889442B2/ja

2016-08-29 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 title claims abstract description 49
238000004519 manufacturing process Methods 0.000 title abstract description 6
239000007800 oxidant agent Substances 0.000 claims abstract description 44
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 42
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 42
230000001590 oxidative effect Effects 0.000 claims abstract description 42
239000003054 catalyst Substances 0.000 claims abstract description 23
229910021529 ammonia Inorganic materials 0.000 claims abstract description 21
238000000034 method Methods 0.000 claims abstract description 20
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 19
239000001301 oxygen Substances 0.000 claims abstract description 19
229910052760 oxygen Inorganic materials 0.000 claims abstract description 19
230000015572 biosynthetic process Effects 0.000 claims abstract description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 5
239000001257 hydrogen Substances 0.000 claims abstract description 5
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 5
230000003197 catalytic effect Effects 0.000 claims abstract 2
238000004200 deflagration Methods 0.000 claims description 14
238000006243 chemical reaction Methods 0.000 claims description 11
239000002360 explosive Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 8
238000004880 explosion Methods 0.000 claims description 7
230000001737 promoting effect Effects 0.000 claims description 2
238000006189 Andrussov oxidation reaction Methods 0.000 abstract description 3
238000005474 detonation Methods 0.000 abstract 1
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
239000007789 gas Substances 0.000 description 5
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
229910052757 nitrogen Inorganic materials 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
238000002485 combustion reaction Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000000926 separation method Methods 0.000 description 2
239000006227 byproduct Substances 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
239000000470 constituent Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Images

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
- C01C3/022—Apparatus therefor
- C01C3/0225—Apparatus therefor characterised by the synthesis reactor
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2425—Tubular reactors in parallel
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Toxicology (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Hydrogen, Water And Hydrids (AREA)
Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Exhaust Gas Treatment By Means Of Catalyst (AREA)

JP51093197A 1995-09-01 1996-08-29 シアン化水素の製造方法及びそのための装置 Expired - Fee Related JP3889442B2 (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP95113796.7		1995-09-01
EP95113796		1995-09-01
PCT/GB1996/002103 WO1997009273A1 (en)	1995-09-01	1996-08-29	Hydrogen cyanide process and apparatus therefor

Publications (3)

Publication Number	Publication Date
JPH11512070A JPH11512070A (ja)	1999-10-19
JPH11512070A5 JPH11512070A5 (2)	2004-08-26
JP3889442B2 true JP3889442B2 (ja)	2007-03-07

Family

ID=8219571

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP51093197A Expired - Fee Related JP3889442B2 (ja)	1995-09-01	1996-08-29	シアン化水素の製造方法及びそのための装置

Country Status (13)

Country	Link
US (2)	US6491876B2 (2)
EP (1)	EP0847372B1 (2)
JP (1)	JP3889442B2 (2)
KR (1)	KR100411692B1 (2)
CN (1)	CN1095806C (2)
AT (1)	ATE202541T1 (2)
AU (1)	AU702825C (2)
BR (1)	BR9610149A (2)
CA (1)	CA2230017C (2)
DE (1)	DE69613581T2 (2)
ES (1)	ES2158339T3 (2)
TW (1)	TW389741B (2)
WO (1)	WO1997009273A1 (2)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE69613581T2 (de) *	1995-09-01	2002-04-25	Ineos Acrylics Uk Ltd., Southampton	Verfahren und vorrichtung zur herstellung von cyanwasserstoff
DE19754988A1 (de) *	1997-12-11	1999-06-17	Degussa	Herstellung von Blausäure nach dem Andrussow-Verfahren
DE19810484A1 (de) *	1998-03-11	1999-09-16	Degussa	Verfahren zur Herstellung von Blausäure
US6221327B1 (en)	1998-05-15	2001-04-24	Rohm And Haas Company	Catalyst system using flow-through radiation shielding and a process for producing hydrogen cyanide using the same
AU4090600A (en) *	1999-06-30	2001-01-04	Rohm And Haas Company	High performance heat exchangers
US6649137B2 (en)	2000-05-23	2003-11-18	Rohm And Haas Company	Apparatus with improved safety features for high temperature industrial processes
DE10034194A1 (de)	2000-07-13	2003-09-11	Roehm Gmbh	Verfahren zur Herstellung von Cyanwasserstoff
DE10034193A1 (de)	2000-07-13	2002-03-28	Roehm Gmbh	Verfahren zur Herstellung von Cyanwasserstoff
EP1604947A1 (en) *	2004-06-07	2005-12-14	ETH Zürich	Process and apparatus for producing hydrogen or ammonia
DE102007014586A1 (de)	2007-03-23	2008-09-25	Evonik Röhm Gmbh	Verfahren zur Herstellung von Cyanwasserstoff (HCN)
DE102007034715A1 (de) *	2007-07-23	2009-01-29	Evonik Röhm Gmbh	Reaktor zur Herstellung von Cyanwasserstoff nach dem Andrussow-Verfahren
TWI390145B (zh) *	2008-03-31	2013-03-21	Rohm & Haas	用於爆燃壓力衰減之方法及設備
WO2014099607A1 (en)	2012-12-18	2014-06-26	Invista Technologies S.A. R. L.	Integrated process for hexamethylenediamine production
AU2013363333A1 (en) *	2012-12-18	2015-07-30	Invista Technologies S.A.R.L.	Process for producing hydrogen cyanide and recovering hydrogen
CN103864113B (zh)	2012-12-18	2018-01-19	英威达纺织（英国）有限公司	使用转化器生产氰化氢的方法
WO2014099601A1 (en) *	2012-12-18	2014-06-26	Invista Technologies S.A.R.L.	Process for stabilizing heat exchanger tubes in andrussow process
CN103864623B (zh) *	2012-12-18	2017-04-12	英威达科技公司	二胺生产的一体化工艺
WO2014099605A1 (en) *	2012-12-18	2014-06-26	Invista Technologies S.A R.L.	Process for producing hydrogen cyanide using flow straightener
CN103864109A (zh) *	2012-12-18	2014-06-18	因温斯特技术公司	用于安德卢梭法中的再循环的系统和方法
EP2935094A1 (en) *	2012-12-18	2015-10-28	Invista Technologies S.à.r.l.	Apparatus and method for hydrogen recovery in an andrussow process
EP2935115A1 (en)	2012-12-18	2015-10-28	Invista Technologies S.à.r.l.	Operational controls for inert gas blanketing for andrussow process
CN113816398B (zh) *	2012-12-18	2023-11-10	英威达纺织（英国）有限公司	安德卢梭法中氨比例的变化
CN110127724A (zh) *	2013-07-12	2019-08-16	英威达纺织（英国）有限公司	使用第二废热锅炉的氰化氢制造方法
FR3008626B1 (fr) *	2013-07-19	2015-08-07	Arkema France	Reacteur pour preparer du cyanure d'hydrogene par le procede d'andrussow, equipement comprenant ledit reacteur et procede utilisant un tel equipement
FR3008692B1 (fr)	2013-07-19	2016-12-23	Arkema France	Installation et procede pour la preparation de cyanure d'hydrogene
US10323888B2 (en) *	2016-04-18	2019-06-18	Corrosion Monitoring Service Inc.	System and method for installing external corrosion guards
CN120268332A (zh) *	2024-01-05	2025-07-08	中国天辰工程有限公司	一种制备氰化氢的反应器

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US1934838A (en)	1930-04-14	1933-11-14	Ig Farbenindustrie Ag	Production of hydrocyanic acid
DE1005049B (de) *	1951-12-06	1957-03-28	Goodrich Co B F	Verfahren zur Erzeugung von Cyanwasserstoff
US2803522A (en) *	1953-04-15	1957-08-20	Du Pont	Manufacture of hydrogen cyanide
US3112177A (en) *	1959-11-11	1963-11-26	Toyo Koatsu Ind Inc	Method of separating ammonia from hydrogen cyanide
US3104945A (en) *	1961-07-19	1963-09-24	Du Pont	Method of producing hydrogen cyanide
DE1161870B (de)	1961-09-19	1964-01-30	Hans J Zimmer Verfahrenstechni	Verfahren zur Herstellung von Cyanwasserstoff
US3215495A (en) *	1962-01-23	1965-11-02	Du Pont	Apparatus and process for preparing hydrogen cyanide
DE1190445B (de) *	1962-09-29	1965-04-08	Hans J Zimmer Verfahrenstechni	Verfahren zur Herstellung von Cyanwasserstoff und Nitrilen
NL6604519A (2)	1965-04-14	1966-10-17
US3376500A (en)	1966-04-25	1968-04-02	Varian Associates	Direct reading magnetic field intensity indicating apparatus
US4107278A (en)	1976-08-16	1978-08-15	E. I. Du Pont De Nemours And Company	Process for making HCN
US4128622A (en) *	1976-08-27	1978-12-05	E. I. Du Pont De Nemours And Company	Process for producing hydrogen cyanide
PL109343B1 (en)	1978-06-19	1981-11-30	Politechnika Wroclawska	Method of producing hydrogen cyanide
US5266291A (en) *	1992-05-05	1993-11-30	Praxair Technology, Inc.	Packed bed arrangement for oxidation reaction system
US5360603A (en) *	1993-08-23	1994-11-01	Praxair Technology, Inc.	Packed bed arrangement useful for mixing and/or oxidation
DE69613581T2 (de) *	1995-09-01	2002-04-25	Ineos Acrylics Uk Ltd., Southampton	Verfahren und vorrichtung zur herstellung von cyanwasserstoff

1996
- 1996-08-29 DE DE69613581T patent/DE69613581T2/de not_active Expired - Lifetime
- 1996-08-29 BR BR9610149A patent/BR9610149A/pt not_active IP Right Cessation
- 1996-08-29 AT AT96929384T patent/ATE202541T1/de not_active IP Right Cessation
- 1996-08-29 KR KR10-1998-0701566A patent/KR100411692B1/ko not_active Expired - Fee Related
- 1996-08-29 JP JP51093197A patent/JP3889442B2/ja not_active Expired - Fee Related
- 1996-08-29 CN CN96197711A patent/CN1095806C/zh not_active Expired - Fee Related
- 1996-08-29 EP EP96929384A patent/EP0847372B1/en not_active Expired - Lifetime
- 1996-08-29 ES ES96929384T patent/ES2158339T3/es not_active Expired - Lifetime
- 1996-08-29 WO PCT/GB1996/002103 patent/WO1997009273A1/en not_active Ceased
- 1996-08-29 US US09/029,536 patent/US6491876B2/en not_active Expired - Fee Related
- 1996-08-29 AU AU68799/96A patent/AU702825C/en not_active Ceased
- 1996-08-29 CA CA002230017A patent/CA2230017C/en not_active Expired - Fee Related
- 1996-09-05 TW TW085110881A patent/TW389741B/zh active
2002
- 2002-05-28 US US10/154,922 patent/US6656442B2/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
US6491876B2 (en)	2002-12-10
DE69613581D1 (de)	2001-08-02
AU6879996A (en)	1997-03-27
DE69613581T2 (de)	2002-04-25
EP0847372B1 (en)	2001-06-27
CN1095806C (zh)	2002-12-11
CN1200102A (zh)	1998-11-25
CA2230017C (en)	2006-06-20
KR19990044326A (ko)	1999-06-25
US6656442B2 (en)	2003-12-02
TW389741B (en)	2000-05-11
ES2158339T3 (es)	2001-09-01
CA2230017A1 (en)	1997-03-13
JPH11512070A (ja)	1999-10-19
KR100411692B1 (ko)	2004-02-18
MX9801546A (es)	1998-05-31
WO1997009273A1 (en)	1997-03-13
EP0847372A1 (en)	1998-06-17
BR9610149A (pt)	1999-02-02
US20020039553A1 (en)	2002-04-04
ATE202541T1 (de)	2001-07-15
AU702825B2 (en)	1999-03-04
US20020182137A1 (en)	2002-12-05
AU702825C (en)	2002-09-19

Legal Events

Date	Code	Title	Description
2006-10-24	TRDD	Decision of grant or rejection written
2006-10-31	A01	Written decision to grant a patent or to grant a registration (utility model)	Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20061031
2006-12-07	A61	First payment of annual fees (during grant procedure)	Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20061130
2006-12-08	R150	Certificate of patent or registration of utility model	Free format text: JAPANESE INTERMEDIATE CODE: R150
2009-12-08	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20101208 Year of fee payment: 4
2010-12-02	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20101208 Year of fee payment: 4
2010-12-07	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20111208 Year of fee payment: 5
2011-12-01	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20111208 Year of fee payment: 5
2011-12-06	FPAY	Renewal fee payment (event date is renewal date of database)	Free format text: PAYMENT UNTIL: 20121208 Year of fee payment: 6
2012-12-08	LAPS	Cancellation because of no payment of annual fees

Publication	Publication Date	Title
AU702825C (en)	2002-09-19	Hydrogen cyanide process and apparatus therefor
US5110563A (en)	1992-05-05	Catalytic combustion
RU2195425C2 (ru)	2002-12-27	Способ и устройство для ускоренного риформинга топлива с кислородом
US3958951A (en)	1976-05-25	Convective power reformer equipment and system
CA2286286A1 (en)	1998-11-05	Rapid injection process and apparatus for producing synthesis gas
AU598123B2 (en)	1990-06-14	Catalytic combustion
WO2009014980A2 (en)	2009-01-29	A flameless combustion heater
CN108862194A (zh)	2018-11-23	用于生产合成气的燃烧器和方法
JP2002147720A (ja)	2002-05-22	部分酸化法用予備混合バーナブロック
JP3775750B2 (ja)	2006-05-17	Ｎ▲下２▼ｏからのｎｏの製造
JPH0735887B2 (ja)	1995-04-19	ガス混合物の製造方法およびそのために用いるバーナノズル
RU2650153C2 (ru)	2018-04-09	Способ и система удаления аммиака из потока отходящего газа установки получения мочевины
US4230278A (en)	1980-10-28	Apparatus for reducing hydrocarbon fuel requirement for Haber ammonia synthesis
US6455012B1 (en)	2002-09-24	Acid gas burner and reactor apparatus and method
MXPA98001546A (en)	1998-10-23	Procedure for hydrogen cyanide and apparatus
TW201800146A (zh)	2018-01-01	生產反應產物的方法
EP1136443A1 (en)	2001-09-26	Gas and oxygen reactor and method for the production of reducing elements
SU284767A1 (ru)	1979-06-15	Реактор термоокислительного пиролиза углеводородов
SU740711A1 (ru)	1980-06-15	Способ получени восстановительного газа
US1508061A (en)	1924-09-09	Process of and apparatus for the manufacture of nitrogen oxide
CN119665235B (zh)	2026-01-23	工艺烧嘴、反应炉及工艺烧嘴处理气态燃料的方法
SU866338A2 (ru)	1981-09-23	Горелка
KR20250129025A (ko)	2025-08-28	수소를 포함하는 합성 가스 생성물을 생성하는 방법
JPH09156901A (ja)	1997-06-17	吸熱反応方法及び装置
TH28563A (th)	1998-04-24	สำหรับการกระทำกระบวนการที่มีคะตะไลส์ หรือไม่มีคะตะไลส์ ในที่ซึ่งออกซิเจนเป็นหนึ่งของสารที่เข้าทำปฏิกิริยา