CH86691A - Process for the preparation of an acidic dye containing chromium. - Google Patents
Process for the preparation of an acidic dye containing chromium.Info
- Publication number
- CH86691A CH86691A CH86691DA CH86691A CH 86691 A CH86691 A CH 86691A CH 86691D A CH86691D A CH 86691DA CH 86691 A CH86691 A CH 86691A
- Authority
- CH
- Switzerland
- Prior art keywords
- chromium
- acid
- dye
- preparation
- acidic dye
- Prior art date
Links
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims description 9
- 229910052804 chromium Inorganic materials 0.000 title claims description 9
- 239000011651 chromium Substances 0.000 title claims description 9
- 230000002378 acidificating effect Effects 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 4
- 239000000987 azo dye Substances 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000004251 Ammonium lactate Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 229940059265 ammonium lactate Drugs 0.000 description 1
- 235000019286 ammonium lactate Nutrition 0.000 description 1
- RZOBLYBZQXQGFY-HSHFZTNMSA-N azanium;(2r)-2-hydroxypropanoate Chemical compound [NH4+].C[C@@H](O)C([O-])=O RZOBLYBZQXQGFY-HSHFZTNMSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 229910021563 chromium fluoride Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- FTBATIJJKIIOTP-UHFFFAOYSA-K trifluorochromium Chemical compound F[Cr](F)F FTBATIJJKIIOTP-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
- C09B45/16—Monoazo compounds containing chromium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Description
Verfahren zur Herstellung eines chromhaltigen sauren Farbstoffs. Es wurde gefunden, dass man den metall empfindlichen Azofarbstoff aus dianotierter 5-Nitro-2-amido-l-ogybenzol-4-sulfosäure und der N-Methylensulfosäure des a-Naphtylamins durch Behandlung mit chromabgebenden Mit teln in einen chromhaltigen, sauren Farbstoff überfiibren kann, welcher das Chrom in mas kierter Bindung enthält, indem dasselbe aus der wässerigen Lösung durch Soda, Natron lauge oder Ammoniak nicht gefällt wird.
Der Farbstoff ist wasserlöslich, säurebeständig, nicht kupferempfindlich und färbt animalische Fasern aus saurem Bad in blaugrünen, walk und lichtechten Tönen.
<I>Beispiel</I> 5 Teile Azofarbstoff aus dianotierter 5 Nitro-2-amido-1-osy benzol-4 -sttlfosäure und der N-Methy lensulfosäure des R-Naplttylamins werden mit 200 Teilen Wasser, 7,5 Teilen Chromfluorid (mit einem 36,8% Crz0a ent- sprechenden Chromgehalt) und 10-20 Teilen Glaspulver oder der entsprechenden Menge eines andern säurebindenden Mittels, wie Natriumacetat,
Ammoniumlaktat und der gleichen, während 24 Stunden unter RÜCkfluss gekocht. Es scheidet sich die Chromverbin- dung der Farbsäure als schwerlöslicher Nie derschlag aus. Derselbe wird abfiltriert, in kalter, verdünnter Natronlauge (enthaltend 1 Teil Na0H) gelöst und mit Essigsäure schwach angesäuert. Aus der intensiv grünen Lösung wird der Farbstoff durch Aussahen ab geschieden, abfiltriert, gepreht und getrocknet.
Process for the preparation of an acidic dye containing chromium. It has been found that the metal-sensitive azo dye made from dianotized 5-nitro-2-amido-1-ogybenzene-4-sulfonic acid and the N-methylene sulfonic acid of α-naphthylamine can be converted into a chromium-containing, acidic dye by treatment with chromium-releasing agents which contains the chromium in a masked bond, as it is not precipitated from the aqueous solution by soda, caustic soda or ammonia.
The dye is water-soluble, acid-resistant, not sensitive to copper and dyes animal fibers from an acid bath in blue-green, milled and lightfast shades.
<I> Example </I> 5 parts of azo dye from dianotized 5-nitro-2-amido-1-osy benzene-4-sttlfosäure and the N-methylene sulfonic acid of R-naplttylamine are mixed with 200 parts of water, 7.5 parts of chromium fluoride ( with a chromium content corresponding to 36.8% Crz0a) and 10-20 parts glass powder or the corresponding amount of another acid-binding agent, such as sodium acetate,
Ammonium lactate and the like, refluxed for 24 hours. The chromium compound of the color acid precipitates out as a poorly soluble precipitate. The same is filtered off, dissolved in cold, dilute sodium hydroxide solution (containing 1 part NaOH) and made weakly acidic with acetic acid. The dye is separated from the intensely green solution by looking, filtered off, rolled and dried.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH86691T | 1917-10-12 | ||
| CH80096T | 1917-10-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH86691A true CH86691A (en) | 1920-09-16 |
Family
ID=25702632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH86691D CH86691A (en) | 1917-10-12 | 1917-10-12 | Process for the preparation of an acidic dye containing chromium. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH86691A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1006988B (en) * | 1954-03-05 | 1957-04-25 | Geigy Ag J R | Process for the production of chromium-containing azo dyes |
-
1917
- 1917-10-12 CH CH86691D patent/CH86691A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1006988B (en) * | 1954-03-05 | 1957-04-25 | Geigy Ag J R | Process for the production of chromium-containing azo dyes |
| DE1006988C2 (en) * | 1954-03-05 | 1957-10-03 | Geigy Ag J R | Process for the production of chromium-containing azo dyes |
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